CN106336912A - 一种高性能醇基燃料 - Google Patents

一种高性能醇基燃料 Download PDF

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CN106336912A
CN106336912A CN201610869791.0A CN201610869791A CN106336912A CN 106336912 A CN106336912 A CN 106336912A CN 201610869791 A CN201610869791 A CN 201610869791A CN 106336912 A CN106336912 A CN 106336912A
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蒙呈星
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Guangxi Tonki Energy Technology Co Ltd
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Abstract

本发明公开了一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇60～70份、异丙醇2～4份、丙烯醇3～6份、异辛烷1～3份、异丁酮2～4份、二叔丁基对甲酚1～3份、聚甲醛二甲醚1～3份、叔戊基甲基醚0.4～0.8份、过氧化氢2～5份、氯酸钾0.4～0.6份、硫酸铈铵0.01～0.03份、异丁基锂0.02～0.04份、甘油0.3～0.7份、木质素磺酸钠0.01～0.03份、复合剂2～4份、乙酸乙酯0.2～0.5份、纳米镁粉0.4～0.7份、纳米氧化铁0.2～0.4份。该高性能醇基燃料不仅具有良好的燃烧性能，还具有低的腐蚀性、高的稳定性能等特点，是一种很有发展前景的燃料。

Description

一种高性能醇基燃料
技术领域
本发明涉及一种高性能醇基燃料，属于燃料技术领域。
背景技术
随着社会经济的快速发展，自然资源消耗不断地增加，尤其是石油资源，逐渐面临日益枯竭的状态。因此，寻找替代能源已成为了本领域技术人员研究的热点。醇基燃料不仅是以醇类(如甲醇、乙醇、丁醇等)物质为主体配置的燃料，同时还是一种廉价、仅次于氢气的最清洁的燃料，可来源于生物质发酵和煤、石油、天然气等石化燃料。醇基燃料作为新能源和碳循环的载体，其不但解决了能源的高效贮存和分配问题，而且其多种合成途径降低了人类对煤和石油等传统能源的依赖度，甚至可以回收大气以及工业废弃物中的二氧化碳作为原料合成反复循环利用，对缓解全球变暖有重大贡献。
近年来，醇基燃料在国内民用餐饮行业发展迅速，并得到了市场的广泛认可。但是，随着本领域技术人员对研究的深入，发现醇基燃料存在着腐蚀性强、热值低、储存稳定性能差等缺点。为克服此不足，本领域技术人员已展开研究，并取得一定的研究成果。例如，中国专利公开号为CN105670715A公开了名为“一种高性能环保醇基燃料及其制备方法”的专利，该醇基燃料是由以下重量份的原料制成：甲醇40-100份、乙醇2-8份、丁辛醇5-40份、丙醇1-8份、松节油1-5份。虽然其能获得6000～8500千卡/千克热值，但是该热值并不十分理想。因此，继续探索与研究醇基燃料的热值是必要的。
发明内容
针对上述现有技术的不足，本发明所要解决的技术问题是提出了一种高性能醇基燃料。
一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇60～70份、异丙醇2～4份、丙烯醇3～6份、异辛烷1～3份、异丁酮2～4份、二叔丁基对甲酚1～3份、聚甲醛二甲醚1～3份、叔戊基甲基醚0.4～0.8份、过氧化氢2～5份、氯酸钾0.4～0.6份、硫酸铈铵0.01～0.03份、异丁基锂0.02～0.04份、甘油0.3～0.7份、木质素磺酸钠0.01～0.03份、复合剂2～4份、乙酸乙酯0.2～0.5份、纳米镁粉0.4～0.7份、纳米氧化铁0.2～0.4份。
优选地，
一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇65份、异丙醇3份、丙烯醇4份、异辛烷2份、丁酮3份、二叔丁基对甲酚2份、聚甲醛二甲醚2份、叔戊基甲基醚0.6份、过氧化氢4份、氯酸钾0.5份、硫酸铈铵0.02份、异丁基锂0.03份、甘油0.5份、木质素磺酸钠0.02份、复合剂3份、乙酸乙酯0.3份、纳米镁粉0.6份、纳米氧化铁0.3份。
所述的复合剂是由0.3～0.5份硝酸钠、1～3份氯化镁、0.4～0.7份氯化钙、1～3份硫酸铜、2～4份氯化铁和0.1～0.3份磷酸钾复合而成。
优选地，
所述的复合剂是由0.4份硝酸钠、2份氯化镁、0.5份氯化钙、2份硫酸铜、3份氯化铁和0.2份磷酸钾复合而成。
所述的纳米镁粉、纳米氧化铁的粒径为50～100nm。
与现有技术相比，本发明的有益效果是：
1、本发明中，甲醇作为主体燃料，能够降低成本，同时还添加具有良好燃烧性能的异丙醇、丙烯醇、异辛烷、丁酮、二叔丁基对甲酚、聚甲醛二甲醚、叔戊基甲基醚，不仅具有调整高性能醇基燃料的碳、氢、氧之间比例、促进充分燃烧和增加燃烧热值等效果，而且还能改善高性能醇基燃料体系中的互溶性，防止分层，使得高性能醇基燃料燃烧更加充分。
2、过氧化氢、氯酸钾、硫酸铈铵、异丁基锂、复合剂起到助燃增热剂的作用，增加高性能醇基燃料的热值、燃烧更充分、燃烧效率更高；甘油，一方面可以促进高性能醇基燃料各成分之间充分互溶，提高燃烧性能，增加高性能醇基燃料的热值，另一方面可以调整高性能醇基燃料的沸点，促进气化；木质素磺酸钠具有降低界面张力、分散剂和稳定剂的作用，可以提高增溶性能，从而使高性能醇基燃料燃烧更加充分，同时还具有催化助燃的作用，提高醇基燃料的热值和燃烧效率；乙酸乙酯既可作为热值提升剂，增加热值，又可以作为腐蚀抑制剂，减少对金属的腐蚀，延长设备的使用寿命。
3、纳米镁粉、纳米氧化铁具有高的表面活化能，减少了高性能醇基燃料燃烧过程中副反应的进行，提高了燃烧的效率；同时还能与游离的碳发生反应，生成一氧化碳，从而降低了游离碳发生氧化反应的活化能。再者，它们还可以中和甲醇的酸，防止甲醇腐蚀。
具体实施方式
实施例1
一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇65份、异丙醇3份、丙烯醇4份、异辛烷2份、丁酮3份、二叔丁基对甲酚2份、聚甲醛二甲醚2份、叔戊基甲基醚0.6份、过氧化氢4份、氯酸钾0.5份、硫酸铈铵0.02份、异丁基锂0.03份、甘油0.5份、木质素磺酸钠0.02份、复合剂3份、乙酸乙酯0.3份、纳米镁粉0.6份、纳米氧化铁0.3份。
所述的复合剂是由0.4份硝酸钠、2份氯化镁、0.5份氯化钙、2份硫酸铜、3份氯化铁和0.2份磷酸钾复合而成。
所述的纳米镁粉、纳米氧化铁的粒径为90nm。
实施例2
一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇60份、异丙醇2份、丙烯醇3份、异辛烷1份、异丁酮2份、二叔丁基对甲酚1份、聚甲醛二甲醚1份、叔戊基甲基醚0.4份、过氧化氢2份、氯酸钾0.4份、硫酸铈铵0.01份、异丁基锂0.02份、甘油0.3份、木质素磺酸钠0.01份、复合剂2份、乙酸乙酯0.2份、纳米镁粉0.4份、纳米氧化铁0.2份。
所述的复合剂是由0.3份硝酸钠、1份氯化镁、0.4份氯化钙、1份硫酸铜、2份氯化铁和0.1份磷酸钾复合而成。
所述的纳米镁粉、纳米氧化铁的粒径为50nm。
实施例3
一种高性能醇基燃料，由以下重量份配比的各组分制成：甲醇70份、异丙醇4份、丙烯醇6份、异辛烷3份、异丁酮4份、二叔丁基对甲酚3份、聚甲醛二甲醚3份、叔戊基甲基醚0.8份、过氧化氢5份、氯酸钾0.6份、硫酸铈铵0.03份、异丁基锂0.04份、甘油0.7份、木质素磺酸钠0.03份、复合剂4份、乙酸乙酯0.5份、纳米镁粉0.7份、纳米氧化铁0.4份。
所述的复合剂是由0.5份硝酸钠、3份氯化镁、0.7份氯化钙、3份硫酸铜、4份氯化铁和0.3份磷酸钾复合而成。
所述的纳米镁粉、纳米氧化铁的粒径为100nm。
对比例1(对比例1与实施例1的差别仅在于，对比例1中的纳米镁粉、纳米氧化铁的粒径为80nm，其余的同实施例1)。
对比例2(对比例2与实施例1的差别仅在于，对比例2中的复合剂是由0.3份硝酸钠、1份氯化镁、0.6份氯化钙、3份硫酸铜、4份氯化铁和0.1份磷酸钾复合而成，其余的同实施例1)。
将上述实施例1-3、对比例1-2和背景技术(CN105670715A)制得的醇基燃料采用现有技术进行测试，测试结果如下表1所示：
表1醇基燃料测试结果
当然，上面只是本发明优选的具体实施方式作了详细描述，并非以此限制本发明的实施范围，凡依本发明的原理、构造以及结构所作的等效变化，均应涵盖于本发明的保护范围内。

Claims (5)

1.一种高性能醇基燃料，其特征在于：由以下重量份配比的各组分制成：甲醇60～70份、异丙醇2～4份、丙烯醇3～6份、异辛烷1～3份、异丁酮2～4份、二叔丁基对甲酚1～3份、聚甲醛二甲醚1～3份、叔戊基甲基醚0.4～0.8份、过氧化氢2～5份、氯酸钾0.4～0.6份、硫酸铈铵0.01～0.03份、异丁基锂0.02～0.04份、甘油0.3～0.7份、木质素磺酸钠0.01～0.03份、复合剂2～4份、乙酸乙酯0.2～0.5份、纳米镁粉0.4～0.7份、纳米氧化铁0.2～0.4份。
2.根据权利要求1所述的高性能醇基燃料，其特征在于：由以下重量份配比的各组分制成：甲醇65份、异丙醇3份、丙烯醇4份、异辛烷2份、丁酮3份、二叔丁基对甲酚2份、聚甲醛二甲醚2份、叔戊基甲基醚0.6份、过氧化氢4份、氯酸钾0.5份、硫酸铈铵0.02份、异丁基锂0.03份、甘油0.5份、木质素磺酸钠0.02份、复合剂3份、乙酸乙酯0.3份、纳米镁粉0.6份、纳米氧化铁0.3份。
3.根据权利要求1或2所述的高性能醇基燃料，其特征在于：所述的复合剂是由0.3～0.5份硝酸钠、1～3份氯化镁、0.4～0.7份氯化钙、1～3份硫酸铜、2～4份氯化铁和0.1～0.3份磷酸钾复合而成。
4.根据权利要求3所述的高性能醇基燃料，其特征在于：所述的复合剂是由0.4份硝酸钠、2份氯化镁、0.5份氯化钙、2份硫酸铜、3份氯化铁和0.2份磷酸钾复合而成。
5.根据权利要求1所述的高性能醇基燃料，其特征在于：所述的纳米镁粉、纳米氧化铁的粒径为50～100nm。
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CN108395913A (zh) * 2018-04-15 2018-08-14 郑州圣洲新能源科技有限公司 一种新能油
CN108485726A (zh) * 2018-02-05 2018-09-04 河南云牛网络技术有限公司 一种高热值甲醇燃料
CN110283635A (zh) * 2019-07-09 2019-09-27 广州聚变科学研究所 一种海洋醇基燃料添加剂及其醇基燃料
CN110342619A (zh) * 2019-07-09 2019-10-18 广州聚变科学研究所 一种海洋醇基燃料添加剂提取系统及其提取方法
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10851320B2 (en) 2017-10-25 2020-12-01 Lyondell Chemical Technology, L.P. Product compositions for dimethoxymethane oligomers mixed with distillate fuels
CN108485726A (zh) * 2018-02-05 2018-09-04 河南云牛网络技术有限公司 一种高热值甲醇燃料
CN108395913A (zh) * 2018-04-15 2018-08-14 郑州圣洲新能源科技有限公司 一种新能油
CN110283635A (zh) * 2019-07-09 2019-09-27 广州聚变科学研究所 一种海洋醇基燃料添加剂及其醇基燃料
CN110342619A (zh) * 2019-07-09 2019-10-18 广州聚变科学研究所 一种海洋醇基燃料添加剂提取系统及其提取方法

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