CN106317859A - 一种耐刺穿性尼龙复合薄膜 - Google Patents

一种耐刺穿性尼龙复合薄膜 Download PDF

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CN106317859A
CN106317859A CN201610685653.7A CN201610685653A CN106317859A CN 106317859 A CN106317859 A CN 106317859A CN 201610685653 A CN201610685653 A CN 201610685653A CN 106317859 A CN106317859 A CN 106317859A
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composite film
butyl
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张复光
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Tongcheng City Hong Ye Plastic Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/08—Cellulose derivatives
    • C08J2401/16—Esters of inorganic acids
    • C08J2401/18—Cellulose nitrate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/14—Gas barrier composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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Abstract

本发明公开一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙60‑70份、硝化棉树酯15‑20份、刚玉细粉14‑20份、氰尿酸三聚氰胺盐9‑13份、碳化硅6‑12份、碳化硼12‑25份、玻璃纤维23‑29份、三氧化二铝3‑7份、钛白粉1‑3份、三氧化二锑0.5‑2份、安息香乙醚1‑2份、纳米蒙脱土7‑9份、钛酸四丁酯1.2‑1.4份、苎麻麻骨12‑14份、明胶2‑3份、硬脂酸镁1‑2份、乙酰柠檬酸三丁酯13‑15份、2，6‑二叔丁基‑4‑,甲基苯酚1‑1.5份、3‑羟基苯甲酸4‑6份、月桂醇硫酸盐1‑2份、植物皂角苷4‑6份。本发明方法所制备的尼龙复合薄膜具有很高的耐刺穿性能，在抽真空拉伸后棱角处无破损，从而仍可保有较高的阻氧、阻水、阻水蒸气功能，为有棱角商品的提供了一种很好的包装材料。

Description

一种耐刺穿性尼龙复合薄膜
技术领域
本发明涉及材料技术领域，具体是一种耐刺穿性尼龙复合薄膜。
背景技术
随着社会的进步，商品对包装也提出了越来越高的要求，许多有棱角的商品如猪蹄、牛排、鸡鹅，以及电子印刷线路板，通过抽真空包装，在包装的过程中普通的尼龙复合膜棱角处往往因尼龙层被拉伸造成破损，而影响了包装的阻隔性能。因此商品的包装除了要求包装薄膜的阻氧，阻水蒸气功能外，也要求许多有棱角的商品抽真空包装后，包装的棱角边缘处包装薄膜不破损。这就要求共挤出复合薄膜在具有阻氧，阻水蒸气的功能外，还要具有很好的耐剌穿性。
发明内容
本发明的目的在于提供一种耐刺穿性尼龙复合薄膜。
本发明的目的可以通过以下技术方案实现：
一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙60-70份、硝化棉树酯15-20份、刚玉细粉14-20份、氰尿酸三聚氰胺盐9-13份、碳化硅6-12份、碳化硼12-25份、玻璃纤维23-29份、三氧化二铝3-7份、钛白粉1-3份、三氧化二锑0.5-2份、安息香乙醚1-2份、纳米蒙脱土7-9份、钛酸四丁酯1.2-1.4份、苎麻麻骨12-14份、明胶2-3份、硬脂酸镁1-2份、乙酰柠檬酸三丁酯13-15份、2，6-二叔丁基-4-,甲基苯酚1-1.5份、3-羟基苯甲酸4-6份、月桂醇硫酸盐1-2份、植物皂角苷4-6份。
优选的，所述的一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙60份、硝化棉树酯15份、刚玉细粉14份、氰尿酸三聚氰胺盐9份、碳化硅6份、碳化硼12份、玻璃纤维23份、三氧化二铝3份、钛白粉1份、三氧化二锑0.5份、安息香乙醚1份、纳米蒙脱土7份、钛酸四丁酯1.2份、苎麻麻骨12份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯13份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸4份、月桂醇硫酸盐1份、植物皂角苷4份。
优选的，所述的一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙70份、硝化棉树酯20份、刚玉细粉20份、氰尿酸三聚氰胺盐13份、碳化硅12份、碳化硼25份、玻璃纤维29份、三氧化二铝7份、钛白粉3份、三氧化二锑2份、安息香乙醚2份、纳米蒙脱土9份、钛酸四丁酯1.4份、苎麻麻骨14份、明胶3份、硬脂酸镁2份、乙酰柠檬酸三丁酯15份、2，6-二叔丁基-4-,甲基苯酚1.5份、3-羟基苯甲酸6份、月桂醇硫酸盐2份、植物皂角苷6份。
优选的，所述的一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙65份、硝化棉树酯18份、刚玉细粉16份、氰尿酸三聚氰胺盐10份、碳化硅10份、碳化硼18份、玻璃纤维25份、三氧化二铝5份、钛白粉2份、三氧化二锑1份、安息香乙醚1份、纳米蒙脱土8份、钛酸四丁酯1.3份、苎麻麻骨13份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯14份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸5份、月桂醇硫酸盐1份、植物皂角苷5份。
本发明的有益效果：本发明方法所制备的尼龙复合薄膜具有很高的耐刺穿性能，在抽真空拉伸后棱角处无破损，从而仍可保有较高的阻氧、阻水、阻水蒸气功能，为有棱角商品的提供了一种很好的包装材料。
具体实施方式
下面结合具体实施例对本发明作进一步详细描述。
实施例1
一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙60份、硝化棉树酯15份、刚玉细粉14份、氰尿酸三聚氰胺盐9份、碳化硅6份、碳化硼12份、玻璃纤维23份、三氧化二铝3份、钛白粉1份、三氧化二锑0.5份、安息香乙醚1份、纳米蒙脱土7份、钛酸四丁酯1.2份、苎麻麻骨12份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯13份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸4份、月桂醇硫酸盐1份、植物皂角苷4份。
本发明的制备方法与现有技术相同。
实施例2
一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙70份、硝化棉树酯20份、刚玉细粉20份、氰尿酸三聚氰胺盐13份、碳化硅12份、碳化硼25份、玻璃纤维29份、三氧化二铝7份、钛白粉3份、三氧化二锑2份、安息香乙醚2份、纳米蒙脱土9份、钛酸四丁酯1.4份、苎麻麻骨14份、明胶3份、硬脂酸镁2份、乙酰柠檬酸三丁酯15份、2，6-二叔丁基-4-,甲基苯酚1.5份、3-羟基苯甲酸6份、月桂醇硫酸盐2份、植物皂角苷6份。
本发明的制备方法与现有技术相同。
实施例3
一种耐刺穿性尼龙复合薄膜，按重量份计，包括以下原料组分：尼龙65份、硝化棉树酯18份、刚玉细粉16份、氰尿酸三聚氰胺盐10份、碳化硅10份、碳化硼18份、玻璃纤维25份、三氧化二铝5份、钛白粉2份、三氧化二锑1份、安息香乙醚1份、纳米蒙脱土8份、钛酸四丁酯1.3份、苎麻麻骨13份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯14份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸5份、月桂醇硫酸盐1份、植物皂角苷5份。
本发明的制备方法与现有技术相同。

Claims (4)

1.一种耐刺穿性尼龙复合薄膜，其特征在于，按重量份计，包括以下原料组分：尼龙60-70份、硝化棉树酯15-20份、刚玉细粉14-20份、氰尿酸三聚氰胺盐9-13份、碳化硅6-12份、碳化硼12-25份、玻璃纤维23-29份、三氧化二铝3-7份、钛白粉1-3份、三氧化二锑0.5-2份、安息香乙醚1-2份、纳米蒙脱土7-9份、钛酸四丁酯1.2-1.4份、苎麻麻骨12-14份、明胶2-3份、硬脂酸镁1-2份、乙酰柠檬酸三丁酯13-15份、2，6-二叔丁基-4-,甲基苯酚1-1.5份、3-羟基苯甲酸4-6份、月桂醇硫酸盐1-2份、植物皂角苷4-6份。
2.根据权利要求1所述的一种耐刺穿性尼龙复合薄膜，其特征在于，按重量份计，包括以下原料组分：尼龙60份、硝化棉树酯15份、刚玉细粉14份、氰尿酸三聚氰胺盐9份、碳化硅6份、碳化硼12份、玻璃纤维23份、三氧化二铝3份、钛白粉1份、三氧化二锑0.5份、安息香乙醚1份、纳米蒙脱土7份、钛酸四丁酯1.2份、苎麻麻骨12份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯13份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸4份、月桂醇硫酸盐1份、植物皂角苷4份。
3.根据权利要求1所述的一种耐刺穿性尼龙复合薄膜，其特征在于，按重量份计，包括以下原料组分：尼龙70份、硝化棉树酯20份、刚玉细粉20份、氰尿酸三聚氰胺盐13份、碳化硅12份、碳化硼25份、玻璃纤维29份、三氧化二铝7份、钛白粉3份、三氧化二锑2份、安息香乙醚2份、纳米蒙脱土9份、钛酸四丁酯1.4份、苎麻麻骨14份、明胶3份、硬脂酸镁2份、乙酰柠檬酸三丁酯15份、2，6-二叔丁基-4-,甲基苯酚1.5份、3-羟基苯甲酸6份、月桂醇硫酸盐2份、植物皂角苷6份。
4.根据权利要求1所述的一种耐刺穿性尼龙复合薄膜，其特征在于，按重量份计，包括以下原料组分：尼龙65份、硝化棉树酯18份、刚玉细粉16份、氰尿酸三聚氰胺盐10份、碳化硅10份、碳化硼18份、玻璃纤维25份、三氧化二铝5份、钛白粉2份、三氧化二锑1份、安息香乙醚1份、纳米蒙脱土8份、钛酸四丁酯1.3份、苎麻麻骨13份、明胶2份、硬脂酸镁1份、乙酰柠檬酸三丁酯14份、2，6-二叔丁基-4-,甲基苯酚1份、3-羟基苯甲酸5份、月桂醇硫酸盐1份、植物皂角苷5份。
CN201610685653.7A 2016-08-18 2016-08-18 一种耐刺穿性尼龙复合薄膜 Pending CN106317859A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107586453A (zh) * 2017-09-26 2018-01-16 桐城市正阳包装有限公司 一种羟丙基淀粉‑尼龙共混耐刺穿性复合薄膜

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013108A (zh) * 2012-11-25 2013-04-03 安徽六方重联机械股份有限公司 一种含有尼龙pa66的包装用塑料薄膜
CN104804289A (zh) * 2015-04-20 2015-07-29 青岛康泰鑫环保科技有限公司 一种抗菌性农用塑料地膜

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013108A (zh) * 2012-11-25 2013-04-03 安徽六方重联机械股份有限公司 一种含有尼龙pa66的包装用塑料薄膜
CN104804289A (zh) * 2015-04-20 2015-07-29 青岛康泰鑫环保科技有限公司 一种抗菌性农用塑料地膜

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107586453A (zh) * 2017-09-26 2018-01-16 桐城市正阳包装有限公司 一种羟丙基淀粉‑尼龙共混耐刺穿性复合薄膜

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Application publication date: 20170111