CN106316463B - A kind of fireproof heat insulating building blocks - Google Patents

A kind of fireproof heat insulating building blocks Download PDF

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Publication number
CN106316463B
CN106316463B CN201610709127.XA CN201610709127A CN106316463B CN 106316463 B CN106316463 B CN 106316463B CN 201610709127 A CN201610709127 A CN 201610709127A CN 106316463 B CN106316463 B CN 106316463B
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China
Prior art keywords
parts
hydrophobic film
methyltriethoxysilane
added dropwise
concrete segment
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CN201610709127.XA
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CN106316463A (en
Inventor
姚恒
任伟滨
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Jiangsu Urban Planning And Design Institute Co ltd
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JIANGSU INSTITUTE OF URBAN PLANNING AND DESIGN
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/64Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/495Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
    • C04B41/4961Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C1/00Building elements of block or other shape for the construction of parts of buildings
    • E04C1/40Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
    • E04C1/41Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts composed of insulating material and load-bearing concrete, stone or stone-like material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Building Environments (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Abstract

The present invention provides a kind of fireproof heat insulating building blocks, which includes concrete segment and polystyrene filler, and the concrete segment opens up inner cavity, and the polystyrene filler is filled in inner cavity.Polystyrene filler is built in concrete segment by fireproof heat insulating building blocks of the invention, again in the silicone-coated hydrophobic film layer in concrete segment surface, waterproof, enhancing thermal insulation property can be reached, the effect of ventilative hydrofuge can be carried out again, foam styrofoam grinding bodies water swelling is avoided, wall rupture event is caused to occur.

Description

A kind of fireproof heat insulating building blocks
Technical field
The invention belongs to building element technical fields, and in particular to a kind of fireproof heat insulating building blocks.
Background technique
Insulation blocks have good self-insurance temperature function.External wall is fitted in, building heat preservation performance can be improved.But It is that most of existing insulation blocks are inflammable thing.If fire occurs, it is on fire to will lead to the building Zheng Dong, and fire spreading is fast, go out Fire tool acquires a certain degree of difficulty.Those skilled in the art prevent in order to solve the above technical problems, being typically employed in the coating of insulation blocks surface Fiery coating reduces the combustibility on insulation blocks surface, blocks the rapid sprawling of fire.However, in above-mentioned technical proposal, although The combustibility on insulation blocks surface can be reduced to a certain extent.But if fireproof coating destroys, insulation blocks are from interior Portion is lighted rapidly, and fireproof coating is caused to fail.
Summary of the invention
The technical issues of solution: a kind of fireproof heat insulating block is provided the purpose of the present invention is overcome the deficiencies in the prior art Block, the fireproof heat insulating building blocks have the advantages that heat insulation effect is good, fire protecting performance is excellent.
Technical solution: a kind of fireproof heat insulating building blocks, including concrete segment and polystyrene filler, the concrete are built Block opens up inner cavity, and the polystyrene filler is filled in inner cavity.
Further, polystyrene filler filling exit is provided at the top of concrete segment, bottom position is equipped with protrusion, fills Dress mouth is matched with the size of protrusion.
Further, polysiloxane hydrophobic film layer is coated in concrete segment outer surface.
Further, the coating method of the polysiloxane hydrophobic film layer are as follows:
Polysiloxane hydrophobic film solution A is coated on concrete segment surface by step 1, and coating thickness 3-5mm is stood 6 hours, form base;
Polysiloxane hydrophobic film B solution is coated on substrate surface by step 2, and it is small to stand 10 by coating thickness 1-2mm When, obtain polysiloxane hydrophobic film layer.
Further, the polysiloxane hydrophobic film solution A the preparation method is as follows:
A. methyltriethoxysilane and ethyl alcohol are mixed, stirring is added dropwise acid solution, continues to stir after being added dropwise, quiet It sets, obtains mixed liquor;
B. aqueous slkali is added dropwise into mixed liquor, after being added dropwise, ageing obtains polysiloxane hydrophobic film solution A;
Wherein, methyltriethoxysilane and the volume ratio of ethyl alcohol are 1:6, and the volume and acid of methyltriethoxysilane are molten The ratio of the amount of the substance of liquid is 20mL:0.2mmol, and the ratio of the amount of the substance of the volume and alkali of methyltriethoxysilane is 20mL:3mmol;The acid is sulfuric acid or weak acid, and alkali is weak base.
Further, the polysiloxane hydrophobic film B solution the preparation method is as follows:
A. methyltriethoxysilane and ethyl alcohol are mixed, stirring is added dropwise acid solution, continues to stir after being added dropwise, quiet It sets, obtains mixed liquor;
B. aqueous slkali is added dropwise into mixed liquor, after being added dropwise, ageing obtains polysiloxane hydrophobic film solution A;
Wherein, methyltriethoxysilane and the volume ratio of ethyl alcohol are 1:9, and the volume and acid of methyltriethoxysilane are molten The ratio of the amount of the substance of liquid is 20mL:0.3mmol, and the ratio of the amount of the substance of the volume and alkali of methyltriethoxysilane is 20mL:4mmol;The acid is sulfuric acid or weak acid, and alkali is weak base.
Further, the concrete segment includes the raw material of following parts by weight: 200 parts of flyash, alkyl triethoxy 10 parts of silane, 0.1 part of silane coupling agent, 0.5-3 parts of polyvinyl alcohol, 90 parts of carbide slag, 22 parts of polypropylene fibre, epoxy resin 6- 9 parts, 3-6 parts of silicon ash, 1 part of foaming agent, 20 parts of gypsum, 11 parts of cement, 80 parts of water.
Further, described interior intracavitary also vertically equipped with support column.
The utility model has the advantages that fireproof heat insulating building blocks of the invention have the advantages that heat insulation effect is good, fire protecting performance is excellent.By polyphenyl second Alkene filler is built in concrete segment, then in the silicone-coated hydrophobic film layer in concrete segment surface, can be reached anti- Water enhances thermal insulation property, and can carry out ventilative hydrofuge, avoids foam styrofoam grinding bodies water swelling, wall is caused to rupture feelings Condition occurs.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of 1 insulation blocks of embodiment,
Wherein, 1 is solidifying cob brick block, and 2 be filling aperture, and 3 be protrusion, and 4 be foam styrofoam grinding bodies, and 5 dredge for polysiloxanes Moisture film coating, 6 be support column.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution of the present invention is clearly and completely described, it is clear that Described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to The scope of protection of the invention.
The embodiments described below with reference to the accompanying drawings are exemplary, it is intended to be used to explain the present invention, and cannot understand For limitation of the present invention.In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length Degree ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", The orientation or positional relationship of the instructions such as "outside", " clockwise ", " counterclockwise " is to be based on the orientation or positional relationship shown in the drawings, only It is that for the convenience of describing the present invention and simplifying the description, rather than the device or element of indication or suggestion meaning must have specifically Orientation is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.
According to Fig. 1, a kind of fireproof heat insulating building blocks, including concrete segment 1 and polystyrene filler 4, it is described mixed Solidifying earth building blocks 1 open up inner cavity, and the polystyrene filler 4 is filled in inner cavity;Polyphenyl second is provided at the top of concrete segment 1 Alkene filler filling exit 2, bottom position are equipped with protrusion 3, and filling exit 2 is matched with the size of protrusion 3;Outside concrete segment 1 Surface is coated with polysiloxane hydrophobic film layer 5.
Concrete segment 1 is made of the raw material components of following parts by weight: 200 parts of flyash, alkyl triethoxysilane 10 Part, 0.1 part of silane coupling agent, 0.5-3 parts of polyvinyl alcohol, 90 parts of carbide slag, 22 parts of polypropylene fibre, 6-9 parts of epoxy resin, silicon 3-6 parts grey, 1 part of foaming agent, 20 parts of gypsum, 11 parts of cement, 80 parts of water.
The preparation method of concrete segment 1 includes the following steps:
Pretreatment of raw material: 200 parts of flyash, 90 parts of carbide slags and 3-6 parts of silicon ashes feeding ball mills are levigate, make production Concrete segment is even closer, reduces hole, increases the anti-extrusion ability of Concrete brick.
Stirring: flyash, carbide slag and silicon ash after will be levigate be put into agitator tank, at the same be added 20 parts of gypsum, 22 parts it is poly- Tacryl, 6-9 part epoxy resin, 11 parts of cement, 10 parts of alkyl triethoxysilanes, 0.1 part of silane coupling agent, 0.5-3 parts Polyvinyl alcohol, 70 parts of water stir 5min, 1000~1500r/min of revolving speed.
Foaming: being added 1 part of foaming agent and 10 parts of water in material after agitation, stirs 1 minute, revolving speed 500-800r/ Min is then allowed to stand 1~2min.
Casting: 60~120min is heated to the material after foaming.Temperature is controlled at 45~70 DEG C, makes brick molding more It is firm.It is cut after standing 60min.
It is steam-cured: the material after cutting to be transferred to steam-cured kettle, steam-cured 80~90min, temperature is 205 DEG C, and pressure is 11MPa, material thus obtained is non-friable in use, and surface of material dust and sundries are few.It is cooled to room Temperature is to get product.
Concrete segment 1 opens up inner cavity.The filling exit 2 of the inner cavity is set to the top of concrete segment, in bottom position Equipped with protrusion 3, protrusion 3 is corresponding to filling exit 2.Protrusion is sequentially connected with concrete segment first place, improves for being inserted into filling exit The connective stability of two fireproof heat insulating building blocks is connected, and guarantees polystyrene filling after one piece of fireproof heat insulating building blocks damages Object is ignited, and being ignited without will lead to other fireproof heat insulating building blocks, being hindered the sprawling of the intensity of a fire.By filling exit by polystyrene Filler is filling in the inner cavity of concrete segment.Polystyrene filler is by the expandability containing volatile fluid foaming agent Polystyrene bead, after heated pre- hair in the inner cavity of concrete segment the fine hole-closing structure of formation of hot briquetting white Solid structure.
The coating method of polysiloxane hydrophobic film layer are as follows:
Step 1: by polysiloxane hydrophobic film solution A be coated on the concrete segment surface, coating thickness 3-5mm, 6 hours are stood, base is formed;
Step 2: being coated on the substrate surface for polysiloxane hydrophobic film B solution, and brushing twice is in right-angled intersection, Guarantee to occur without latasuture leak.Coating thickness is 1-2mm, stands 10 hours, obtains polysiloxane hydrophobic film layer 5.Double-layer structure Waterproof performance is improved, and guarantees polysiloxane hydrophobic film thickness, avoids disposable thickness too big, causes polysiloxane hydrophobic film portion Subregion is not easy the case where doing, making film surface easy to damage generation.
Prepare polysiloxane hydrophobic film solution A:
A, methyltriethoxysilane, ethyl alcohol, acid solution and aqueous slkali are weighed;Control methyltriethoxysilane and ethyl alcohol Volume ratio be 1:6, the ratio of the amount of the substance of the volume of methyltriethoxysilane and acid is 20mL:0.2mmol, methyl three The ratio of the amount of the substance of the volume and alkali of Ethoxysilane is 20mL:3mmol;The acid is sulfuric acid or weak acid;The alkali For weak base;
B, methyltriethoxysilane and ethyl alcohol are mixed, is stirred evenly;Then acid solution is added dropwise, continues after being added dropwise Stirring stands, obtains mixed liquor;
C, aqueous slkali is added dropwise into the mixed liquor of step b, after being added dropwise, ageing obtains polysiloxane hydrophobic film solution A.
Prepare polysiloxane hydrophobic film B solution:
A, methyltriethoxysilane, ethyl alcohol, acid solution and aqueous slkali are weighed;Control methyltriethoxysilane and ethyl alcohol Volume ratio be 1:9, the ratio of the amount of the substance of the volume of methyltriethoxysilane and acid is 20mL:0.3mmol, methyl three The ratio of the amount of the substance of the volume and alkali of Ethoxysilane is 20mL:4mmol;The acid is sulfuric acid or weak acid;The alkali For weak base;
B, methyltriethoxysilane and ethyl alcohol are mixed, is stirred evenly;Then acid solution is added dropwise, is added dropwise subsequent Continuous stirring, stands, obtains mixed liquor;
C, aqueous slkali is added dropwise into the mixed liquor of step b, after being added dropwise, ageing obtains polysiloxane hydrophobic film B solution.
It in one embodiment, further include support column 6,6 vertical line of support column is set in the inner cavity, to inner cavity Inner wall play a supporting role, improve the stability of concrete segment.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (5)

1. a kind of fireproof heat insulating building blocks, it is characterised in that: including concrete segment and polystyrene filler, the concrete is built Block opens up inner cavity, and the polystyrene filler is filled in inner cavity;Polystyrene filler is provided at the top of concrete segment Filling exit, bottom position are equipped with protrusion, and filling exit is matched with the size of protrusion;Poly- silicon is coated in concrete segment outer surface Oxygen alkane hydrophobic film layer;
The coating method of the polysiloxane hydrophobic film layer are as follows:
Polysiloxane hydrophobic film solution A is coated on concrete segment surface by step 1, and it is small to stand 6 by coating thickness 3-5mm When, form base;
Polysiloxane hydrophobic film B solution is coated on substrate surface by step 2, and coating thickness 1-2mm stands 10 hours, obtains Obtain polysiloxane hydrophobic film layer.
2. fireproof heat insulating building blocks according to claim 1, it is characterised in that: the system of the polysiloxane hydrophobic film solution A Preparation Method is as follows:
A. methyltriethoxysilane and ethyl alcohol are mixed, stirring is added dropwise acid solution, continues to stir after being added dropwise, and stands, obtains Mixed liquor;
B. aqueous slkali is added dropwise into mixed liquor, after being added dropwise, ageing obtains polysiloxane hydrophobic film solution A;
Wherein, methyltriethoxysilane and the volume ratio of ethyl alcohol are 1:6, the volume of methyltriethoxysilane and acid solution The ratio of the amount of substance is 20mL:0.2mmol, and the ratio of the amount of the substance of the volume and alkali of methyltriethoxysilane is 20mL:3mmol;The acid is sulfuric acid or weak acid, and alkali is weak base.
3. fireproof heat insulating building blocks according to claim 1, it is characterised in that: the system of the polysiloxane hydrophobic film B solution Preparation Method is as follows:
A. methyltriethoxysilane and ethyl alcohol are mixed, stirring is added dropwise acid solution, continues to stir after being added dropwise, and stands, obtains Mixed liquor;
B. aqueous slkali is added dropwise into mixed liquor, after being added dropwise, ageing obtains polysiloxane hydrophobic film solution A;
Wherein, methyltriethoxysilane and the volume ratio of ethyl alcohol are 1:9, the volume of methyltriethoxysilane and acid solution The ratio of the amount of substance is 20mL:0.3mmol, and the ratio of the amount of the substance of the volume and alkali of methyltriethoxysilane is 20mL:4mmol;The acid is sulfuric acid or weak acid, and alkali is weak base.
4. described in any item fireproof heat insulating building blocks according to claim 1, it is characterised in that: the concrete segment includes following The raw material of parts by weight: 200 parts of flyash, 10 parts of alkyl triethoxysilane, 0.1 part of silane coupling agent, polyvinyl alcohol 0.5-3 Part, 90 parts of carbide slag, 22 parts of polypropylene fibre, 6-9 parts of epoxy resin, 3-6 parts of silicon ash, 1 part of foaming agent, 20 parts of gypsum, cement 11 parts, 80 parts of water.
5. fireproof heat insulating building blocks according to claim 1, it is characterised in that: supported in interior intracavitary also vertical be equipped with Column.
CN201610709127.XA 2016-08-23 2016-08-23 A kind of fireproof heat insulating building blocks Active CN106316463B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108643379B (en) * 2018-04-27 2019-11-12 刘孟凡 A kind of construction heat insulation wall structure
CN112324044A (en) * 2020-09-21 2021-02-05 安徽鋐硕绿色建材科技有限公司 Coal gangue hollow insulating brick

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1148578A (en) * 1995-10-23 1997-04-30 卢崇德 High fly-ash-contained foam concrete building block and production method thereof
CN202787637U (en) * 2012-08-15 2013-03-13 宁波秦汉陶粒墙材有限公司 Self-insulation ceramsite concrete composite block
CN103774781A (en) * 2012-10-25 2014-05-07 庄海东 Building block
CN104525275A (en) * 2015-01-07 2015-04-22 北京方信立华科技有限公司 SCR denitration catalyst with hydrophobic membrane and preparation method thereof
CN104612311A (en) * 2014-12-12 2015-05-13 广西科技大学 Polystyrene building block convenient for installation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1148578A (en) * 1995-10-23 1997-04-30 卢崇德 High fly-ash-contained foam concrete building block and production method thereof
CN202787637U (en) * 2012-08-15 2013-03-13 宁波秦汉陶粒墙材有限公司 Self-insulation ceramsite concrete composite block
CN103774781A (en) * 2012-10-25 2014-05-07 庄海东 Building block
CN104612311A (en) * 2014-12-12 2015-05-13 广西科技大学 Polystyrene building block convenient for installation
CN104525275A (en) * 2015-01-07 2015-04-22 北京方信立华科技有限公司 SCR denitration catalyst with hydrophobic membrane and preparation method thereof

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Address after: 210019 Building B3, No. 1, Yunlongshan Road, Jianye District, Nanjing, Jiangsu

Patentee after: Jiangsu urban planning and Design Institute Co.,Ltd.

Address before: 210036 Jiangsu Jianshe Building, No. 88, Caochangmen Street, Gulou District, Nanjing, Jiangsu

Patentee before: JIANGSU INSTITUTE OF URBAN PLANNING AND DESIGN