CN106316142A - Atomization liquid for anti-dazzling processing of dragon tail glass and preparation method and application of atomization liquid - Google Patents
Atomization liquid for anti-dazzling processing of dragon tail glass and preparation method and application of atomization liquid Download PDFInfo
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- CN106316142A CN106316142A CN201610725040.1A CN201610725040A CN106316142A CN 106316142 A CN106316142 A CN 106316142A CN 201610725040 A CN201610725040 A CN 201610725040A CN 106316142 A CN106316142 A CN 106316142A
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- Prior art keywords
- glass
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- ammonium
- atomized liquid
- atomization liquid
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
Abstract
The invention discloses an atomization liquid for anti-dazzling processing of dragon tail glass. The atomization liquid is prepared from, by weight, 7-12 parts of ammonium fluoride, 18-26 parts of ammonium bifluoride, 25-33 parts of pure water, 29-50 parts of polyhydric alcohols and 0.01-0.1 part of interfacial agent. The invention further discloses a method and application of the atomization liquid. Compared with the prior art, the atomization liquid has the advantages that HF is not contained in polishing processing, transport and use are safe, environment pollution is avoided, the atomization liquid makes full contact with the surface of glass, the granularity of the prepared anti-dazzling glass can be controlled according to requirements, granularity distribution is uniform, reflected light is soft, display definition is high, and the prepared dragon tail glass is stable in property, high in hardness and durable in use.
Description
Technical field
The present invention relates to the preparation method of a kind of atomized liquid resisting dizzy processing for glass, specifically, be a kind of special
The preparation method of the atomized liquid of dizzy processing is resisted in dragon tail glass.
Background technology
Dragon tail glass is a kind of aluminosilicate glass that Japan AGC produces, South China's great majority referred to as " dragon tail glass ",
North China's great majority referred to as " rise dragon glass ".This glass has high durability and anti-scratch property, it is possible to bear squeezing of strength
Pressure and touch repeatedly, it is possible to meet the demand of high-volume user.The processing mode on anti-dazzle glas surface be divided into physics spraying and
Two kinds of methods of chemical etching, the glass feature after processing is to make bare glass reflecting surface become diffuse-reflectance surface (glass surface product
Raw fine irregularities is uneven).There is compared with bare glass relatively low reflectivity, can be decreased obviously and then allow display at luminous reflectance
Screen shows and becomes apparent from transparent visual effect.
The imperial tail glass surface that physics spraying is made is the simple accumulation of micron particles, irregularly bringing of granule profile
The uncertainty of light scattering, affects display effect, furthermore the glass surface less stable that physics spraying is formed, long-term outdoor
Top layer is used easily to come off.And the method for chemially etching of routine uses strong inorganic acid, HF, fluoride salt and the formula body of alkali metal salt
System makes glass atomization liquid, first HF chemical polishing after atomization, and the glass-faced construction of formation is stable, and mist degree is controlled, but its glass
The dazzle prevention means structure on glass surface is excessive, and cannot change, and can reduce display resolution for high-resolution display device, simultaneously
Penetrance display bright spot can be produced, affect display quality, and HF stores, transports, uses process hazard and seriously polluted.
Summary of the invention
Goal of the invention: it is an object of the invention to provide a kind of atomized liquid being exclusively used in and manufacturing dragon tail anti-dazzle glas.
Technical scheme: the present invention uses following technological means to be realized: a kind of mist resisting dizzy processing for dragon tail glass
Change liquid, be made up of each component of following parts by weight: ammonium fluoride 7-12 part, ammonium acid fluoride 18-26 part, pure water 25-33 part, polynary
Alcohol 29-50 part, interfacial agent 0.01-0.1 part.
As preferably, described polyhydric alcohol is dihydroxylic alcohols or trihydroxylic alcohol.
As preferably, described interfacial agent is cetyl ichthyodin.
The invention also discloses the preparation method of a kind of atomized liquid resisting dizzy processing for dragon tail glass: include following step
Rapid:
1) ammonium fluoride, ammonium acid fluoride are dissolved in pure water,
2) add polyhydric alcohol and interfacial agent, stir and be heated to 15-25 DEG C,.
Third object of the present invention is to disclose the application of a kind of above-mentioned atomized liquid, comprises the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 1-20min in the KOH that mass concentration is 1-5% or NaOH solution of protecting film will be posted, remove
Remove surface oily matter；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity requires 0.1-20 μ s/cm；
4) use baking oven to toast 10-90min at 40-120 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 1-30min；
6) clean glass after being atomized, place into ammonium acid fluoride that mass concentration is 95% and mass concentration is 98%
Polishing 10-300min in the mixed liquor of sulphuric acid, in polishing fluid, ammonium acid fluoride mass fraction is 3-10 part, and sulphuric acid is 10-30
Part, surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
Beneficial effect: compared to the prior art the present invention, without HF in atomized liquid and polishing, transports and use peace
Entirely, it is to avoid environmental pollution, atomized liquid is fully contacted with glass surface, manufactured anti-dazzle glas granular size can be according to need
Controlling, even particle size distribution, reflection light is soft, and display resolution is high, and dragon tail glass property is stable, and hardness is high, the most resistance to
With.
Detailed description of the invention
In the present invention, in the present invention, substrate glass, for using made by floating process, divides air surface and stannum face.Level is clear
Washing machine is produced by Xin Yuda plant equipment company limited of Shenzhen.Acidproof protecting film is institute of Shuo Cheng Science and Technology Ltd. of Shenzhen
Producing, model is SC-838-J, a size of 820mm*100m.
Polyhydric alcohol can be dihydroxylic alcohols or trihydroxylic alcohol.Such as ethylene glycol, propylene glycol, glycerol, butantriol etc..
Interfacial agent is cetyl ichthyodin.
Embodiment 1:
A kind of atomized liquid, is made up of each component of following parts by weight: ammonium fluoride 7 parts, ammonium acid fluoride 18 parts, pure water 25
Part, polyhydric alcohol 29 parts, interfacial agent 0.1 part, specifically, polyhydric alcohol is glycerol, and interfacial agent is cetyl sulphur
Acid ammonium.
The preparation of above-mentioned atomized liquid comprises the following steps:
1) 7 parts of ammonium fluorides, 18 parts of ammonium acid fluorides are dissolved in 25 parts of pure water,
2) add 29 parts of glycerol and 0.1 part of interfacial agent, stir and be heated to 25 DEG C.
Atomized liquid application in terms of preparing anti-dazzle glas, comprises the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 20min in the NaOH solution that mass concentration is 5% of protecting film will be posted, remove surface oiliness
Material；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity is 10 μ s/cm；
4) use baking oven to toast 90min at 80 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 5min；
6) clean glass after being atomized, place into polishing 100min in the mixed liquor of ammonium acid fluoride and sulphuric acid, throw
In light liquid, 95% ammonium acid fluoride mass fraction is 3 parts, and 98% sulphuric acid is 10 parts, and surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
The anti-dazzle glas of the present invention: mist degree: 10%, glossiness: 75%, surface particles average diameter: 7 μm, meet various
Equipment uses demand, and definition, up to 98-99%, was generally not more than 95% in the past.
Embodiment 2:
A kind of atomized liquid, is made up of each component of following parts by weight: ammonium fluoride 11 parts, ammonium acid fluoride 26 parts, pure water 33
Part, polyhydric alcohol 50 parts, interfacial agent 0.01 part, specifically, polyhydric alcohol is glycerol, and interfacial agent is cetyl sulphur
Acid ammonium.
The preparation of above-mentioned atomized liquid comprises the following steps:
1) 11 parts of ammonium fluorides, 26 parts of ammonium acid fluorides are dissolved in 33 parts of pure water,
2) add 50 parts of glycerol and 0.01 part of interfacial agent, stir and be heated to 25 DEG C.
Atomized liquid application in terms of preparing anti-dazzle glas, comprises the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 20min in the NaOH solution that mass concentration is 5% of protecting film will be posted, remove surface oiliness
Material；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity is 10 μ s/cm；
4) use baking oven to toast 90min at 80 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 10min；
6) clean glass after being atomized, place into polishing 150min in the mixed liquor of ammonium acid fluoride and sulphuric acid, throw
In light liquid, 95% ammonium acid fluoride mass fraction is 5 parts, and 98% sulphuric acid is 15 parts, and surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
The anti-dazzle glas of the present invention: mist degree: 30%, glossiness: 63%, surface particles average diameter: 9 μm, meet various
Equipment uses demand, and definition, up to 98-99%, was generally not more than 95% in the past.
Embodiment 3:
A kind of atomized liquid, is made up of each component of following parts by weight: ammonium fluoride 10 parts, ammonium acid fluoride 23 parts, pure water 30
Part, polyhydric alcohol 40 parts, interfacial agent 0.01 part, specifically, polyhydric alcohol is propylene glycol, and interfacial agent is cetyl sulphur
Acid ammonium.
The preparation of above-mentioned atomized liquid comprises the following steps:
1) 10 parts of ammonium fluorides, 23 parts of ammonium acid fluorides are dissolved in 30 parts of pure water,
2) add 40 parts of propylene glycol and 0.01 part of interfacial agent, stir and be heated to 25 DEG C.
Atomized liquid application in terms of preparing anti-dazzle glas, comprises the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 20min in the NaOH solution that mass concentration is 5% of protecting film will be posted, remove surface oiliness
Material；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity is 20 μ s/cm；
4) use baking oven to toast 70min at 60 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 10min；
6) clean glass after being atomized, place into polishing 300min in the mixed liquor of ammonium acid fluoride and sulphuric acid, throw
In light liquid, 95% ammonium acid fluoride mass fraction is 5 parts, and 98% sulphuric acid is 15 parts, and surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
The anti-dazzle glas of the present invention: mist degree: 3%, glossiness: 95%, surface particles average diameter: 14 μm, meet various
Equipment uses demand, and definition, up to 98-99%, was generally not more than 95% in the past.
Embodiment 4:
A kind of atomized liquid, is made up of each component of following parts by weight: ammonium fluoride 9 parts, ammonium acid fluoride 23 parts, pure water 33
Part, polyhydric alcohol 29 parts, interfacial agent 0.01 part, specifically, polyhydric alcohol is propylene glycol, and interfacial agent is cetyl sulphur
Acid ammonium.
The preparation of above-mentioned atomized liquid comprises the following steps:
1) 9 parts of ammonium fluorides, 23 parts of ammonium acid fluorides are dissolved in 33 parts of pure water,
2) add 29 parts of propylene glycol and 0.01 part of interfacial agent, stir and be heated to 25 DEG C.
Atomized liquid application in terms of preparing anti-dazzle glas, comprises the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 20min in the NaOH solution that mass concentration is 5% of protecting film will be posted, remove surface oiliness
Material；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity is 20 μ s/cm；
4) use baking oven to toast 70min at 60 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 10min；
6) clean glass after being atomized, place into polishing 300min in the mixed liquor of ammonium acid fluoride and sulphuric acid, throw
In light liquid, 95% ammonium acid fluoride mass fraction is 5 parts, and 98% sulphuric acid is 15 parts, and surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
The anti-dazzle glas of the present invention: mist degree: 3%, glossiness: 95%, surface particles average diameter: 14 μm, meet various
Equipment uses demand, and definition, up to 98-99%, was generally not more than 95% in the past.
Claims (5)
1. the atomized liquid resisting dizzy processing for dragon tail glass, it is characterised in that: it is made up of each component of following parts by weight:
Ammonium fluoride 7-12 part, ammonium acid fluoride 18-26 part, pure water 25-33 part, polyhydric alcohol 29-50 part, interfacial agent 0.01-0.1 part.
2. atomized liquid as claimed in claim 1, it is characterised in that: described polyhydric alcohol is dihydroxylic alcohols or trihydroxylic alcohol.
3. atomized liquid as claimed in claim 1 or 2, it is characterised in that: described interfacial agent is cetyl ichthyodin.
4. the preparation method of the atomized liquid resisting dizzy processing for dragon tail glass: it is characterized in that: comprise the following steps:
1) ammonium fluoride, ammonium acid fluoride are dissolved in pure water,
2) add polyhydric alcohol and interfacial agent, stir and be heated to 15-25 DEG C,.
5. the application of the atomized liquid according to any one of claim 1-3, it is characterised in that: comprise the steps:
1) first acidproof protecting film is pasted in substrate glass stannum face；
2) glass immersion 1-20min in the KOH that mass concentration is 1-5% or NaOH solution of protecting film will be posted, remove table
Face oily matter；
3) glass immersion completes the cleaning of laggard horizontal cleaning machine, and rinse water electrical conductivity requires 0.1-20 μ s/cm；
4) use baking oven to toast 10-90min at 40-120 DEG C after having cleaned, remove glass surface moisture；
5) after glass baking completes, naturally cool to room temperature, be then placed in atomized liquid being atomized 1-30min；
6) clean glass after being atomized, place into ammonium acid fluoride that mass concentration is 95% and mass concentration is the sulphuric acid of 98%
Mixed liquor in polishing 10-300min, in polishing fluid, ammonium acid fluoride mass fraction is 3-10 part, and sulphuric acid is 10-30 part,
Surplus adds water to 100 parts；
7) clean after polishing and dyestripping checks specifications index.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610725040.1A CN106316142A (en) | 2016-08-24 | 2016-08-24 | Atomization liquid for anti-dazzling processing of dragon tail glass and preparation method and application of atomization liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610725040.1A CN106316142A (en) | 2016-08-24 | 2016-08-24 | Atomization liquid for anti-dazzling processing of dragon tail glass and preparation method and application of atomization liquid |
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| Publication Number | Publication Date |
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| CN106316142A true CN106316142A (en) | 2017-01-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610725040.1A Pending CN106316142A (en) | 2016-08-24 | 2016-08-24 | Atomization liquid for anti-dazzling processing of dragon tail glass and preparation method and application of atomization liquid |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108516693A (en) * | 2018-06-22 | 2018-09-11 | 佛山市庆通玻璃科技有限公司 | It is a kind of to match Preparation Method and production technology without interference flash-point glare proof glass and etching solution |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101314522A (en) * | 2008-06-12 | 2008-12-03 | 东华大学 | Method for preparing anti-dazzle glass |
| CN101560058A (en) * | 2008-04-15 | 2009-10-21 | 株式会社东进世美肯 | Cleaning and etching composition for glass substrate for liquid crystal display device and method for etching glass substrate using the same |
| CN101694855B (en) * | 2009-10-10 | 2012-05-30 | 苏州泰岳太阳能玻璃有限公司 | Solar battery encapsulating glass and preparation process thereof |
-
2016
- 2016-08-24 CN CN201610725040.1A patent/CN106316142A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560058A (en) * | 2008-04-15 | 2009-10-21 | 株式会社东进世美肯 | Cleaning and etching composition for glass substrate for liquid crystal display device and method for etching glass substrate using the same |
| CN101314522A (en) * | 2008-06-12 | 2008-12-03 | 东华大学 | Method for preparing anti-dazzle glass |
| CN101694855B (en) * | 2009-10-10 | 2012-05-30 | 苏州泰岳太阳能玻璃有限公司 | Solar battery encapsulating glass and preparation process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108516693A (en) * | 2018-06-22 | 2018-09-11 | 佛山市庆通玻璃科技有限公司 | It is a kind of to match Preparation Method and production technology without interference flash-point glare proof glass and etching solution |
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Application publication date: 20170111 |
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