CN106310867A - Device for treating vacuum calcining waste gas and treatment method - Google Patents

Device for treating vacuum calcining waste gas and treatment method Download PDF

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Publication number
CN106310867A
CN106310867A CN201610687557.6A CN201610687557A CN106310867A CN 106310867 A CN106310867 A CN 106310867A CN 201610687557 A CN201610687557 A CN 201610687557A CN 106310867 A CN106310867 A CN 106310867A
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CN
China
Prior art keywords
gas
waste gas
pipeline
air inlet
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610687557.6A
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Chinese (zh)
Inventor
张孟江
陈炎猛
黄绍荣
郭学伟
顾君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Dafa Chemical Fiber Co Ltd
Original Assignee
Ningbo Dafa Chemical Fiber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201610687557.6A priority Critical patent/CN106310867A/en
Publication of CN106310867A publication Critical patent/CN106310867A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2247/00Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/10Means for removing the washing fluid dispersed in the gas or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

The invention discloses a device for treating vacuum calcining waste gas and a treatment method. The device comprises gas-water separators, a washing tower and an activated carbon adsorption device, wherein a first gas inlet and a first gas outlet are formed in each gas-water separator; a water draining port communicated with a water collecting tank is formed in the lower end of each gas-water separator; a second gas inlet is formed in the side wall of the washing tower; a second gas outlet is formed in the upper end of the washing tower; a third gas inlet is formed in one side of the activated carbon adsorption device; a third gas outlet is formed in the upper part of the activated carbon adsorption device; each first gas inlet is connected with a calcining waste gas exhausting pipe, and a water ring vacuum pump is arranged on each connecting pipe; each first gas outlet and the corresponding second gas inlet are connected through a pipe; the second gas outlet and the third gas inlet are connected through a pipe, and a fan is arranged on the connecting pipe. The invention has the advantages as follows: dust and volatile organic compounds can be effectively separated, activated carbon does not adsorb a large amount of dust, the adsorption efficiency of the activated carbon is improved, the service life of the activated carbon is prolonged, and the running cost is reduced.

Description

Process device and the processing method of vacuum calcining waste gas
Technical field:
The invention mainly relates to vacuum calcining waste gas technical field, particularly relate to a kind of device processing vacuum calcining waste gas And processing method.
Background technology:
At the spinning process of chemical fibre industry, its filter assemblies used, such as web plate, filtration core etc., have at filter process A lot of plastics lumps gather on filter assemblies so that crossed assembly blocking, needed to be replaced, and the filter assemblies after changing Need to remove plastics lumps through high-temperature calcination, and calcination process can produce substantial amounts of dust and harmful gas such as VOC, non-first The gases such as alkane total hydrocarbon, volatility low molecule organic matter;Can not directly be thrown in air, if directly environment can be caused by discharge Pollute greatly.
At present, main processing mode is to use water ring vacuum pump the aqueous vapor after calcining to be evacuated to together in collecting pond, converges Added with lid above Ji Chi, then directly it is evacuated to absorbent charcoal adsorber with blower fan;Use above-mentioned this processing mode, can make to give up In gas, substantial amounts of dust is directly adsorbed on the activated carbon of absorbent charcoal adsorber, causes activated carbon to use the time short, absorption effect Rate is poor, and operating cost is higher.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of prior art, it is provided that one can efficiently separate dust and volatile organic matter, no Can cause a large amount of dust of activated carbon adsorption, improve adsorption efficiency and the service life of activated carbon, the process reducing operating cost is true The device of empty calcining waste gas.
In order to solve above-mentioned technical problem, the technical solution used in the present invention is: a kind of dress processing vacuum calcining waste gas Putting, this device includes moisture trap, scrubbing tower and absorbent charcoal adsorber;It is provided with first on described moisture trap to enter QI KOU is provided with, with the first gas outlet, lower end, the discharge outlet connected with collecting-tank;The sidewall of described scrubbing tower is provided with second Air inlet, upper end is provided with the second gas outlet;The side of described absorbent charcoal adsorber is provided with the 3rd air inlet, and top sets It is equipped with the 3rd gas outlet;The first described air inlet is connected with calciner emission discharge duct and is connected on pipeline and is provided with Water ring vacuum pump, the first described gas outlet is connected by pipeline with the second air inlet, described the second gas outlet and the 3rd Air inlet is connected by pipeline and is provided with blower fan on interconnective pipeline.
Using said structure, the waste gas after calcining is not directly to enter in absorbent charcoal adsorber, but is introduced into Moisture trap, the dust in this process waste gas is separated by water, is flowed in collecting-tank then decontaminated water treating stations with water, This process can remove a large amount of dust;Then gas enters into the second air inlet of scrubbing tower after the first gas outlet is out, should Process so that gas is also deposited big fraction dust and volatility low molecule organic matter, by washing after dust and molten water Property organic matter removal falls;Then gas enters into activated carbon suction through the second gas outlet of scrubbing tower through the effect of centrifugal blower In adsorption device, after the effect of activated carbon, the organic gas containing VOC, NMHC is removed by activated carbon adsorption, Clearance more than 75%, and too much dust will not be adhered to.By the exhaust device of the present invention, activated carbon can be used the longevity Life can increase by 500 above, greatly reduces production cost.
As preferably, described moisture trap is provided with multiple, and multiple moisture traps are arranged side by side, and each air water divides The first air inlet and a water ring vacuum pump on device are connected;It is provided with multiple on described calciner emission discharge duct Exhaust branch pipe in parallel, each exhaust branch pipe correspondence connects a water ring vacuum pump;On each moisture trap first is given vent to anger Mouth is connected with the second air inlet of scrubbing tower by total pipeline, and the discharge outlet on each moisture trap passes through main sewer road It is connected with collecting-tank;Use said structure, can use multiple moisture trap that waste gas is separated, improve dust with The separation efficiency of gas and dust removal amount.
As preferably, described scrubbing tower is positioned at top and is provided with except mist packing layer, except the lower section of mist packing layer is provided with Spraying layer and hollow ball packing layer, described spraying layer and hollow ball packing layer are two-layer and alternately arranged;Use this structure Can ensure that raising dust and water soluble organic substance removal efficiency and removal amount, remove compared to single spraying layer and packing layer Effect is more preferable, removal the most thorough.
As further preferably, the described thickness except mist packing layer is 120-160mm, and the thickness of hollow ball packing layer is 180-240mm;Preferably, the described thickness except mist packing layer is 150mm, and the thickness of hollow ball packing layer is 200mm.
As preferably, being provided with Honeycomb-type activated layer of charcoal in described absorbent charcoal adsorber, described is Honeycomb-type activated The thickness of carbon-coating is 450-550mm, a diameter of 1300-1600mm.This structure is used can effectively to go removing exhaust gas contains VOC, the organic gas of NMHC, clearance more than 75%, and too much dust will not be adhered to.Further, described The thickness of Honeycomb-type activated carbon-coating be 500mm, a diameter of 1500mm
The present invention also provides for the processing method of the device of a kind of above-mentioned process vacuum calcining waste gas, and concrete steps include:
(1) first, under the effect of water ring vacuum pump, it is incorporated into aerofluxus from calciner emission discharge duct waste gas out Arm, through vacuum cycle pump enter into the first air inlet then into moisture trap in separate, the water after separation Entering into collecting-tank after discharge outlet is pooled to main sewer road, gas then enters total pipeline after the first gas outlet is gone out, so Gas in rear total pipeline enters into scrubbing tower through the second air inlet;
(2) gas entering into scrubbing tower runs from the bottom up, and shower water runs from top to bottom, thus water, gas are abundant Contact, it is achieved the washing to gas, the second exhaust port from scrubbing tower top of the gas after washing is discharged through piping, at blower fan Effect under be incorporated into absorbent charcoal adsorber, be then passed through active carbon layer absorption after from the 3rd gas outlet connection pipeline row Go out.
Total pipeline and the caliber of calciner emission discharge duct described in step of the present invention (1) are 180-220mm, are preferably 200mm。
The caliber of the pipeline described in step of the present invention (2) is 180-220mm, preferably 200mm.
Waste gas flow velocity in inventive pipeline is 2500-3500m3/ h, preferably 3000m3/h。
It is high that the above-mentioned method of the present invention has clearance, can realize dust and be sufficiently separated with gas, making of prolongation activated carbon With the life-span, reduce the harmful substance contents of discharge gas, improve the purpose of environment.
Accompanying drawing explanation
Accompanying drawing 1 apparatus of the present invention structural representation.
The top view structural representation that accompanying drawing 2 moisture trap of the present invention is connected with the exhausting waste gas pipeline of calcining.
Accompanying drawing 3 scrubbing tower of the present invention sectional view structural representation.
Accompanying drawing 4 absorbent charcoal adsorber of the present invention sectional view structural representation.
The moisture trap structural representation that accompanying drawing 5 present invention is single.
Detailed description of the invention
Describe the present invention in detail below by specific embodiment, but the present invention is not limited solely to following example.
As shown in Figure 1: a kind of device processing vacuum calcining waste gas of the present invention, this device include moisture trap 1, Scrubbing tower 2 and absorbent charcoal adsorber 3;The first air inlet 1.1 and the first gas outlet it is provided with on described moisture trap 1 1.2 (as shown in Figure 5: the first air inlet is arranged at the sidewall of moisture trap, the first gas outlet is arranged at moisture trap Upper end), lower end be provided with the discharge outlet 1.3 connected with collecting-tank 4;The sidewall of described scrubbing tower is provided with the second air inlet 2.1, upper end is provided with the second gas outlet 2.2;The side of described absorbent charcoal adsorber is provided with the 3rd air inlet 3.1, on Portion is provided with the 3rd gas outlet 3.2;The first described air inlet is connected with the exhausting waste gas pipeline 5 of calcining and is connected pipeline On be provided with water ring vacuum pump 6, the first described gas outlet is connected by pipeline with the second air inlet, and described second is given vent to anger Mouthful it is connected by pipeline with the 3rd air inlet and on interconnective pipeline, is provided with blower fan 7.
Using said structure, the waste gas after calcining is not directly to enter in absorbent charcoal adsorber, but is introduced into Moisture trap, the dust in this process waste gas is separated by water, is flowed in collecting-tank then decontaminated water treating stations with water, This process can remove a large amount of dust;Then gas enters into the second air inlet of scrubbing tower after the first gas outlet is out, should Process so that the fraction dust that there is also in gas and volatility low molecule organic matter, by after washing dust and molten Aqueous organic is got rid of;Then gas through the second gas outlet of scrubbing tower blower fan (such as centrifugal blower) effect enter In absorbent charcoal adsorber, after the effect of activated carbon, the organic gas containing VOC, NMHC is inhaled by activated carbon Attached removed, clearance more than 75%, and too much dust on activated carbon, will not be adhered to.Filled by the waste gas of the present invention Put, can activated carbon can be increased by 500 above service life, greatly reduce production cost.
As shown in accompanying drawing 1,2 and 5: moisture trap of the present invention is provided with multiple, the present embodiment specifically can set Putting four, four moisture traps are arranged side by side, the first air inlet on each moisture trap and a water ring vacuum pump phase Connect;Being provided with the exhaust branch pipe 5.1 of multiple parallel connection on the exhausting waste gas pipeline of described calcining, each exhaust branch pipe correspondence is even (the first air inlet on the most each exhaust branch pipe and each moisture trap directly passes through Water-ring vacuum to connect a water ring vacuum pump Pump connects);The first gas outlet on each moisture trap is connected, often with the second air inlet of scrubbing tower by total pipeline 8 Discharge outlet on individual moisture trap is connected with collecting-tank by main sewer road 9;Use said structure, it is possible to achieve simultaneously Use multiple moisture trap that waste gas is separated, improve dust and the separation efficiency of gas and dust removal amount.
As described in accompanying drawing 3: as described in scrubbing tower be positioned at top and be provided with except mist packing layer 2.3, except the lower section of mist packing layer It is provided with spraying layer 2.4 and hollow ball packing layer 2.5, described spraying layer and hollow ball packing layer be two-layer and alternately arrange Row;This structure is used to can ensure that raising dust and water soluble organic substance removal efficiency and removal amount, compared to single spray Layer and packing layer removal effect are more preferable, removal the most thorough.The described thickness except mist packing layer is 120-160mm, empty The thickness of bulbus cordis packing layer is 180-240mm;The thickness except mist packing layer described in the present embodiment is 150mm, hollow ball filler The thickness of layer is 200mm.
As shown in Figure 4: in described absorbent charcoal adsorber, be provided with Honeycomb-type activated charcoal (Alveolate activated carbon) layer 3.3, the thickness of described Honeycomb-type activated carbon-coating is 450-550mm, a diameter of 1300-1600mm.This structure is used to have The VOC going to contain in removing exhaust gas of effect, the organic gas of NMHC, clearance more than 75%, and will not adhere to too much Dust.The thickness of the Honeycomb-type activated carbon-coating described in the present embodiment is 500mm, a diameter of 1500mm.
The present invention utilizes the method for the device of above-mentioned process vacuum calcining waste gas, and concrete steps include:
(1) first, under the effect of water ring vacuum pump, it is incorporated into from vacuum calcining furnace exhaust discharge duct waste gas out Exhaust branch pipe, through vacuum cycle pump enter into the first air inlet then into moisture trap in separate, after separation Water after discharge outlet is pooled to main sewer road, enter into collecting-tank, gas then after the first gas outlet is gone out enter house steward Road, then the gas in total pipeline enters into scrubbing tower through the second air inlet;
(2) gas entering into scrubbing tower runs from the bottom up, and shower water runs from top to bottom, thus water, gas are abundant Contact, it is achieved the washing to gas, the second exhaust port from scrubbing tower top of the gas after washing is discharged through piping, at blower fan Effect under be incorporated into absorbent charcoal adsorber, be then passed through active carbon layer absorption after from the 3rd gas outlet connection pipeline row Go out.
The caliber of the total pipeline described in step of the present invention (1) is 200mm.The caliber of the pipeline described in step of the present invention (2) For 200mm.Waste gas flow velocity in inventive pipeline is 3000m3/h。
By the structures and methods that the present invention is above-mentioned, after treatment, from absorbent charcoal adsorber gas out Clearance containing VOC, the organic gas of NMHC reaches 90%;And the dust content clearance in gas also reaches 90% Left and right, the replacing construction of activated carbon extends to original 5 times, substantially increases service efficiency, extends service life, reduction Production cost, what is more important effectively eliminates pollutant simultaneously, reduces the discharge capacity of harmful substance, optimizes the environment.
Alveolate activated carbon of the present invention, all uses commercially available prod except mist filler etc..

Claims (10)

1. the device processing vacuum calcining waste gas, it is characterised in that: this device includes moisture trap, scrubbing tower and activity Charcoal adsorbent equipment;It is provided with the first air inlet on described moisture trap and the first gas outlet, lower end are provided with and collecting-tank The discharge outlet of connection;The sidewall of described scrubbing tower is provided with the second air inlet, and upper end is provided with the second gas outlet;Described work The side of property charcoal adsorbent equipment is provided with the 3rd air inlet, and top is provided with the 3rd gas outlet;The first described air inlet with forge Burning furnace exhaust discharge duct is connected and connects and is provided with water ring vacuum pump on pipeline, and the first described gas outlet is entered with second QI KOU is connected by pipeline, and the second described gas outlet is connected and interconnective pipe by pipeline with the 3rd air inlet Blower fan it is provided with on road.
The device of process vacuum calcining waste gas the most according to claim 1, it is characterised in that: described moisture trap sets Being equipped with multiple, multiple moisture traps are arranged side by side, the first air inlet on each moisture trap and a water ring vacuum pump It is connected;Being provided with the exhaust branch pipe of multiple parallel connection on described calciner emission discharge duct, each exhaust branch pipe correspondence is even Connect a water ring vacuum pump;The first gas outlet on each moisture trap is by the second air inlet phase of total pipeline with scrubbing tower Connection, the discharge outlet on each moisture trap is connected with collecting-tank by main sewer road.
The device of process vacuum calcining waste gas the most according to claim 1, it is characterised in that: in upper in described scrubbing tower Portion is provided with except mist packing layer, except the lower section of mist packing layer is provided with spraying layer and hollow ball packing layer, described spraying layer and Hollow ball packing layer is two-layer and alternately arranged.
The device of process vacuum calcining waste gas the most according to claim 3, it is characterised in that: described except mist packing layer Thickness is 120-160mm, and the thickness of hollow ball packing layer is 180-240mm.
The device of process vacuum calcining waste gas the most according to claim 1, it is characterised in that: described activated carbon adsorption dress Being provided with Honeycomb-type activated layer of charcoal in putting, the thickness of described Honeycomb-type activated carbon-coating is 450-550mm, a diameter of 1300- 1600mm。
6. one kind utilizes the method that the device processing vacuum calcining waste gas processes waste gas, it is characterised in that: concrete steps include:
(1) first, under the effect of water ring vacuum pump, it is incorporated into aerofluxus from calciner emission discharge duct waste gas out and props up Pipe, through vacuum cycle pump enter into the first air inlet then into moisture trap in separate, the water after separation from Discharge outlet enters into collecting-tank after being pooled to main sewer road, gas then enters total pipeline after the first gas outlet is gone out, then Gas in total pipeline enters into scrubbing tower through the second air inlet;
(2) gas entering into scrubbing tower runs from the bottom up, and shower water runs from top to bottom, thus water, gas are fully contacted, Realizing washing to gas, the second exhaust port from scrubbing tower top of the gas after washing is discharged through piping, at the work of blower fan Being incorporated into absorbent charcoal adsorber under with, after being then passed through active carbon layer absorption, the pipeline from the 3rd gas outlet connection is discharged.
Utilization the most according to claim 6 processes the method that the device of vacuum calcining waste gas processes waste gas, it is characterised in that: Total pipeline and the caliber of calciner emission discharge duct described in step (1) are 180-220mm.
Utilization the most according to claim 6 processes the method that the device of vacuum calcining waste gas processes waste gas, it is characterised in that: The caliber of the pipeline described in step (2) is 180-220mm.
Utilization the most according to claim 6 processes the method that the device of vacuum calcining waste gas processes waste gas, it is characterised in that: Waste gas flow velocity in pipeline is 2500-3500m3/h。
Utilization the most according to claim 9 processes the method that the device of vacuum calcining waste gas processes waste gas, and its feature exists In: the waste gas flow velocity in pipeline is 3000m3/h。
CN201610687557.6A 2016-08-17 2016-08-17 Device for treating vacuum calcining waste gas and treatment method Pending CN106310867A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107511017A (en) * 2017-09-26 2017-12-26 中盐昆山有限公司 Soda manufacture calcination process suction dust collecting device and dust collecting process

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Publication number Priority date Publication date Assignee Title
CN101125651A (en) * 2007-06-05 2008-02-20 浙江大学 Method for reclaiming carbon dioxide from tail gas of calcium formate producing process
CN201978626U (en) * 2011-02-19 2011-09-21 本松工程塑料(杭州)有限公司 Exhaust gas and dust processing system in plastic-rubber modifying industry
KR101188375B1 (en) * 2012-05-22 2012-10-08 한국에너지기술연구원 Composite particle separation apparatus
CN103272460A (en) * 2013-05-29 2013-09-04 山东道先为能源科技有限公司 Waste heat regeneration absorption dryer
CN203586232U (en) * 2013-11-08 2014-05-07 蚌埠玻璃工业设计研究院 Wet purifying device for exhaust gases caused by APCVD (Atmospheric Pressure Chemical Vapor Deposition) on-line plating of functional membranes
US20150196874A1 (en) * 2013-01-22 2015-07-16 Steen Research, Llc Methods and Equipment for Treatment of Odorous Gas Steams
CN204865533U (en) * 2015-07-21 2015-12-16 深圳市明鑫高分子技术有限公司 Gas treating system
CN205903758U (en) * 2016-08-17 2017-01-25 宁波大发化纤有限公司 Handle device of calcining waste gas in vacuum

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125651A (en) * 2007-06-05 2008-02-20 浙江大学 Method for reclaiming carbon dioxide from tail gas of calcium formate producing process
CN201978626U (en) * 2011-02-19 2011-09-21 本松工程塑料(杭州)有限公司 Exhaust gas and dust processing system in plastic-rubber modifying industry
KR101188375B1 (en) * 2012-05-22 2012-10-08 한국에너지기술연구원 Composite particle separation apparatus
US20150196874A1 (en) * 2013-01-22 2015-07-16 Steen Research, Llc Methods and Equipment for Treatment of Odorous Gas Steams
CN103272460A (en) * 2013-05-29 2013-09-04 山东道先为能源科技有限公司 Waste heat regeneration absorption dryer
CN203586232U (en) * 2013-11-08 2014-05-07 蚌埠玻璃工业设计研究院 Wet purifying device for exhaust gases caused by APCVD (Atmospheric Pressure Chemical Vapor Deposition) on-line plating of functional membranes
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CN205903758U (en) * 2016-08-17 2017-01-25 宁波大发化纤有限公司 Handle device of calcining waste gas in vacuum

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107511017A (en) * 2017-09-26 2017-12-26 中盐昆山有限公司 Soda manufacture calcination process suction dust collecting device and dust collecting process

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Application publication date: 20170111