The content of the invention
Based on this, it is necessary to can not be compatible with conventional soda acid process for etching for existing Buddha's warrior attendant wire cutting the problem of, carry
For a kind of silicon chip that can using Buddha's warrior attendant wire cutting and subsequently use conventional soda acid making herbs into wool.
A kind of silicon chip, there are some cut channel patterns arranged in the first direction on the cut surface of the silicon chip;The cut channel
Pattern bends connection by some strias or interconnection forms.
Above-mentioned silicon chip, because its cut channel pattern is by some strias bending connection or interconnection, by conventional soda acid
After process for etching, the light trapping structure of effect is could be formed with, so that Buddha's warrior attendant wire cutting technology and conventional soda acid process for etching are simultaneous
Hold.
In one of the embodiments, the gully being spaced apart in the first direction is additionally provided with the cut surface of the silicon chip;
The gully extends in a second direction, and the second direction is vertical with the first direction;Stria at the gully is parallel.
In one of the embodiments, the depth in the gully is 5~50 μm;The width in the gully be 0.1~
1.5mm。
Present invention also offers a kind of preparation method of silicon chip.
A kind of preparation method of silicon chip, comprises the following steps:
Silicon crystal is subjected to wire cutting with diamond wire;
During the wire cutting, the diamond dust on the diamond wire is set to vibrate in the first direction, to form cut channel figure
Case.
The preparation method of above-mentioned silicon chip, subsequently it can make diamond wire directly using the soda acid process for etching of routine come making herbs into wool
Cutting technique is mutually compatible with the soda acid process for etching of routine, and then reduces the cost of manufacture of photovoltaic cell.
In one of the embodiments, it is additionally included in during the wire cutting, makes the diamond dust on the diamond wire
Move in a second direction, to form gully.
Present invention also offers a kind of silicon slice wire cutting apparatus.
A kind of silicon slice wire cutting apparatus, including:
Two guide wheels, be arranged in parallel;At least one in described two guide wheels is non-circular guide wheel, the non-circular guide wheel
Surface each point to the maximum difference of the distance of the rotary shaft of the non-circular guide wheel be a, 0<a<1mm;
And diamond wire, it is tensioned between two guide wheels, and moved under the drive of guide wheel.
Above-mentioned silicon slice wire cutting apparatus, because special guide wheel is set, diamond dust on diamond wire can be made along the
While one direction is moved, also vibrate in a second direction, so as to form the cut channel pattern of the present invention in silicon chip surface, make Buddha's warrior attendant
Wire cutting technology can be compatible with the soda acid process for etching of routine, and then reduces the cost of manufacture of photovoltaic cell.
In one of the embodiments, described two guide wheels are in regular polygon.
In one of the embodiments, the guide wheel includes rounded base wheel and scalable is connected to the base wheel
Surface on some projections.
In one of the embodiments, the metal base undulate of the diamond wire.
In one of the embodiments, the diamond dust of the diamond wire includes the first diamond dust and the second diamond dust, institute
The ratio for stating the first diamond dust and second diamond dust is 9:1~1:1.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with embodiment
The present invention is further elaborated.It should be appreciated that embodiment described herein is only to explain the present invention,
It is not intended to limit the present invention.
It should be noted that when element is referred to as " being fixed on " another element, it can be directly on another element
Or there may also be element placed in the middle.When an element is considered as " connection " another element, it can be directly connected to
To another element or it may be simultaneously present centering elements.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention
The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein " and/or " include one or more phases
The arbitrary and all combination of the Listed Items of pass.
The silicon chip of existing Buddha's warrior attendant wire cutting, after conventional soda acid process for etching, its battery efficiency is not lifted
Decline on the contrary.The present inventor has found by research, referring to Fig. 1, the silicon chip 100 ' of existing Buddha's warrior attendant wire cutting, cuts shape
Into a plurality of parallel arrangement stria 101 ', the spacing between these strias 101 ' is about 1.6 μm, and stria 101 ' it
Between the silicon chip surface of similar mirror portion be present.After the soda acid process for etching of routine, because soda acid making herbs into wool utilizes soda acid
Corrosion anisotropy in crystal orientation, plus these parallel arrangements of stria 101 ', the cut surface of the silicon chip after making herbs into wool becomes on the contrary
It is smooth, light trapping structure is not formed.This reason for namely Buddha's warrior attendant wire cutting and conventional soda acid process for etching are incompatible.
Referring to Fig. 2, the silicon chip 100 of an embodiment of the present invention, formed by Buddha's warrior attendant wire cutting, it has cut surface.This is cut
There are some cut channel patterns 110 on face.(namely Y-direction in Fig. 2) periodic arrangement in the first direction of cut channel pattern 110.
Cut channel pattern 110 is made up of cutting stria of the diamond wire in cutting process.
The cut channel pattern 110 of the present invention is in " non-linear ", namely cut channel pattern 110 is by some strias bending connection or intersection
It is formed by connecting.Such as the mutually continued access such as " it ", " mutual ", " work ", " witch ", X-shaped, worm shape forms.The cut channel pattern of the present invention,
After conventional soda acid process for etching, the light trapping structure of surface rule change is formed.
Usually, the damage of cut channel pattern 110 is corresponding after Nano/micron level, the soda acid process for etching by routine
Ground light trapping structure is also Nano/micron level.
In order to further optimize the performance of silicon chip 100, the silicon chip 100 of present embodiment, it is additionally provided with along on its cut surface
The gully 104 that one direction is spaced apart;The gully of gully 104 extends in a second direction, and second direction is vertical with first direction
Direction (namely X-direction in second direction Fig. 2).Stria at gully 104 is parallel.
Specifically, the position in gully 104 and quantity, designed according to the position of the main gate line of photovoltaic cell and quantity.Example
Such as, the bar number in gully is 2,3,4,5 ... 18 etc..
Because gully 104 and main gate line are correspondingly arranged up and down, the stria at gully 104 it is parallel (i.e. with existing diamond wire
The stria of cutting is the same), after conventional soda acid process for etching, become more smooth, can so reduce reduction master
Recombination-rate surface and reduction main grid line resistance under grid line, so as to lift photovoltaic cell electricity conversion.
Preferably, the depth in gully 104 is 5~50 μm;The width in gully 104 is 0.1~1.5mm.
In the present embodiment, the number in gully is 4, and the depth in gully is 15 μm, and the width in gully is 0.8mm.
It is, of course, understood that in some cases, the present invention can also be not provided with gully 104.
Silicon chip provided by the present invention, because its cut channel pattern bends connection by some strias or intersects to form, passing through
After conventional soda acid process for etching, the light trapping structure of effect is could be formed with, so that Buddha's warrior attendant wire cutting technology and conventional soda acid
Process for etching is compatible, and then reduces the cost of manufacture of photovoltaic cell.
Present invention also offers a kind of preparation method of silicon chip.
A kind of preparation method of silicon chip, including silicon crystal is subjected to wire cutting with diamond wire.
Wherein, diamond wire includes metal base and the diamond dust being fixedly arranged on metal base;During cutting on line, make
Diamond dust in the first direction vibrate by (Y-direction in figure), to form cut channel pattern.
Because diamond dust while moving in X direction, also vibrated along Y-direction, so each diamond dust is in silicon chip surface
The stria generated is not a straight line in X direction, after the stria superposition of different diamond dust, that is, it is curved to form some strias
Folding connection or the cut channel pattern of interconnection.
In order to further optimize the performance of silicon chip, during cutting on line, in addition to diamond dust is set only to move in a second direction
Dynamic, stria now is the stria at gully.I.e. when needing to be formed gully, in certain period of time, diamond dust is only controlled
Moved along Y-direction.
Specifically, gully can by constant cutting position repeat cutting or it is constant cutting tension force repeat cutting method come
Realize.
The preparation method of above-mentioned silicon chip, subsequently it can make diamond wire directly using the soda acid process for etching of routine come making herbs into wool
Cutting technique is mutually compatible with the soda acid process for etching of routine.In addition, the present invention silicon chip preparation method, be applicable to monocrystalline and
Polycrystalline efficiency cutting manufacture.
Present invention also offers a kind of silicon wafer cutting device for being used to prepare above-mentioned silicon chip.
Referring to Fig. 3, silicon wafer cutting device 1000 includes two guide wheels 310,320, and diamond wire 400.
Wherein, the main function of two guide wheels 310,320 is to be tensioned diamond wire 400, and drives diamond wire 400 basic
Moved along the X-direction in figure.Specifically, two guide wheels 310,320 be arranged in parallel, and are spaced a distance in order to by silicon wafer
Body 200 is placed between two guide wheels 310,320.
Referring to Fig. 4, diamond wire 400 includes metal base 410 and diamond dust 420, and diamond dust 420 is fixedly arranged at metal base
On 410.The main function of metal base 410 is the carrier as diamond dust.Metal base 410 does not produce dissection substantially,
Play dissection is the diamond dust being fixedly arranged on metal base 410.
In cutting process, two guide wheels 310,320 run-in synchronisms, while the high-speed motion of diamond wire 400 is driven, so that
The high-speed motion of diamond dust 420, cutting is produced to silicon crystal 200.
It is, of course, understood that usually, silicon wafer cutting device 1000 also includes spray coolant device (not shown)
And silicon crystal hold-down devices (not shown) etc..These devices can use structure known in those skilled in the art,
This is repeated no more.
In the present invention, at least one in two guide wheels 310,320 is non-circular guide wheel, i.e. two guide wheels 310,320
In it is at least one in non-circular.The surface each point of non-circular guide wheel to the maximum difference of the distance of rotary shaft be a, 0<a<1mm.
It is, a is in the distance of point farthest apart from rotary shaft in non-circular guide pulley surface to rotary shaft and non-circular guide pulley surface
Difference of the point nearest apart from rotary shaft to the distance of rotary shaft.So because each point is apart from the distance not phase of the rotary shaft of guide wheel
Together, diamond wire is in motion process, while diamond dust 420 does not move only along an X, also has and is vibrated along Y-direction, and Y side
To vibration control within certain amplitude, so as to form the cut channel pattern of the present invention on the cut surface of silicon chip, and avoid
The parallel phenomenon of diamond wire cutting stria in the prior art.
It is highly preferred that 3~17 μm of a span.It so can further lift the performance of silicon chip.
In a preferred embodiment, two guide wheels are in regular polygon.It is of course also possible to it is that simply a guide wheel is in just
Polygon.
Illustrate the operation principle of the silicon wafer cutting device of the present invention with the guide wheel of positive 300 side shape below.
Two guide wheels in silicon wafer cutting device are identical, a length of 200mm in its footpath, and the spacing between two guide wheels is 400mm.
Because guide wheel is positive 300 side shape.In i.e. positive 300 side shape summit to the distance of rotary shaft be 100mm, positive 300 in shape while in
The distance of point to rotary shaft is 99.995mm.It is, positive 300 in shape summit with while midpoint arrive the distance of rotary shaft respectively
Difference a be 5 μm.
Two guide wheels are controlled by electric rotating machine, and synchronous rotary.Guide wheel drives diamond wire to be moved with 17m/s X-direction.
Due to positive 300 in shape summit from while midpoint arrive respectively rotary shaft distance it is different, cause the diamond dust on diamond wire in X side
Move and (vibrate in the Y direction) to while motion, there is periodic Y-direction again.
It is computed, because guide wheel is positive 300 side shape, i.e., guide wheel for each revolution, there is the Y-direction motion in 300 cycles.
Due to positive 300 in shape summit with while midpoint arrive respectively rotary shaft distance difference be 5 μm.That is, along with 17m/
S X-direction motion, the amplitude of diamond dust in the Y direction is 5 μm.
So that silicon chip width is 156mm as an example, then length of the diamond dust every about 500 μm in silicon chip X-direction makees one
Individual amplitude is 5 μm of stria.By the stria of different diamond dust, finally cut channel pattern is formed on the surface of silicon chip.
It is, of course, understood that guide wheel is not limited to regular polygon, other shapes, such as ellipse are can also be,
Also the partial arc section or on the circumference of guide wheel, it is (bent with substituted arc section by one or more straightway or arc section
Rate is different) or oval segmental arc or the substitution of other geometrical curves.Substitution can be uniform substitution spaced apart, also or
Irregular substitution.
It is, of course, also possible to be guide wheel include rounded base wheel and it is scalable be connected to it is some convex on base wheel surface
Rise.When the projection stretches out the periphery of base wheel, the diamond dust on diamond wire vibrates in the Y direction while X-direction moves,
The cut channel pattern of the present invention can now be formed.When the projection is retracted in the periphery of base wheel, now guide wheel recovers periphery,
Diamond dust on diamond wire only moves in X-direction, the stria that can be now formed at gully.
Preferably, metal base 410 is in wavy, namely " non-linear ".Metal base 410 can be plane in the present invention
Interior wave, can also be three-dimensional spatially spiral wave.
The metal base 410 designed using wave, the obstruction in X-Y directions can be buffered, be easy to " adaptive " bypass silicon
Hard spot on crystal 200, be advantageous to improve cutting speed, and avoid the hard spot disconnection problem of existing Buddha's warrior attendant wire cutting, from
And be advantageous to yield, cost and the production capacity of output silicon chip.Meanwhile wave design is combined with the design of guide wheel of the present invention, is made
Cutting movement spatial alternation, and then regular surface damage and making herbs into wool effect are formed, further lift power conversion efficiency (pce).
In the present embodiment, the wavelength of metal base 410 is 3mm, and the difference in height between trough and crest is 7 μm.
Preferably, diamond dust 420 is in non-uniform Distribution on metal base 410, crest, trough in metal base 410
Place is simultaneously or optionally one distribution is closeer.In the present embodiment, the density at crest, trough of diamond dust 420 is higher.
In the present embodiment, diamond dust 420 includes the first diamond dust 421 and the second diamond dust 422, the first diamond dust
421 and second diamond dust 422 be two kinds of different sizes diamond dust.Specifically, the particle diameter of the first diamond dust 421 is less than the second gold medal
The particle diameter of emery 422.
It is highly preferred that the ratio of the first diamond dust 421 and the second diamond dust 422 is 9:1~1:1.
Above-mentioned silicon slice wire cutting apparatus, because special guide wheel is set, diamond dust on diamond wire can be made along the
While one direction is moved, also vibrate in a second direction, so as to form the cut channel pattern of the present invention in silicon chip surface, make Buddha's warrior attendant
Wire cutting technology can be compatible with the soda acid process for etching of routine, and then reduces the cost of manufacture of photovoltaic cell.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned
The all possible combination of each technical characteristic in embodiment is all described, as long as however, the combination of these technical characteristics
In the absence of contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.