CN106291783B - Sterilize plated film film layer structure and preparation method thereof - Google Patents

Sterilize plated film film layer structure and preparation method thereof Download PDF

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Publication number
CN106291783B
CN106291783B CN201610687620.6A CN201610687620A CN106291783B CN 106291783 B CN106291783 B CN 106291783B CN 201610687620 A CN201610687620 A CN 201610687620A CN 106291783 B CN106291783 B CN 106291783B
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layer
film
film layer
layer unit
unit component
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CN106291783A (en
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许远飞
周旭华
李顶雄
周全
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Xuzhou Kaicheng Technology Co ltd
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Tiantong (jiaxing) New Material Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

The present invention relates to translucent element surface coating technical field, specifically, is related to a kind of sterilization plated film film layer structure and preparation method thereof.The sterilization plated film film layer structure includes being used for the film layer body located at matrix surface, film layer body includes at least one layer of film layer unit, film layer unit is included in the film layer unit component layer A and film layer unit component layer B stacked gradually on the direction away from matrix surface, film layer unit component layer A material is silica, and film layer unit component layer B material is silver chlorate.The film layer body of the present invention has preferable bactericidal property and anti-reflection performance concurrently.

Description

Sterilize plated film film layer structure and preparation method thereof
Technical field
The present invention relates to translucent element surface coating technical field, specifically, is related to a kind of sterilization plated film film layer structure And preparation method thereof.
Background technology
For the translucent element in the panel of such as various displays, optical instrument, because it is direct exposure mostly In external environment, therefore have to anti-microbial property required.On the other hand, due to the reflection on translucent element surface, not only Its thang-kng energy can be influenceed, but also veiling glare can be formed, and then translucent effect can be impacted.In the prior art, lack It is a kind of to have sterilization and antireflective effect concurrently such as film layer structure used in translucent element surface.
The content of the invention
The invention provides one kind to sterilize plated film film layer structure, and it can overcome certain or some defects of prior art.
According to the sterilization plated film film layer structure of the present invention, it includes being used for the film layer body located at matrix surface, film layer sheet Body includes at least one layer of film layer unit, and film layer unit is included in the film layer unit group stacked gradually on the direction away from matrix surface Part layer A and film layer unit component layer B, film layer unit component layer A material are silica, film layer unit component layer B material For silver chlorate.
In the sterilization plated film film layer structure of the present invention, film layer unit component layer B material is silver chlorate so that film layer unit Component layer B can have micro silver ion, and the micro silver ion can destroy the protein of bacterium, thus have very strong sterilization to make With, and it is smaller relative to other harm of heavy metal silver to human body.
Preferably, the quantity of at least one layer of film layer unit is 3, respectively on the direction away from matrix surface Stack gradually the first film layer unit, the second film layer unit and third membrane layer unit.
Preferably, the first film layer unit includes the first film layer unit component layer A and the first film layer unit component layer B, the One film layer unit component layer A thickness is 95.42nm, and the first film layer unit component layer B thickness is 5.46nm;
Second film layer unit includes the second film layer unit component layer A and the second film layer unit component layer B, the second film layer unit Component layer A thickness is 61.46nm, and the second film layer unit component layer B thickness is 34.88nm;
Third membrane layer unit includes third membrane layer unit block layer A and third membrane layer unit block layer B, third membrane layer unit Component layer A thickness is 16.40nm, and third membrane layer unit block layer B thickness is 69.91nm.
In the sterilization plated film film layer structure of the present invention, by setting 3 tunic layer units, and cause the 3 tunic layer unit It is configured to aforesaid way so that the film layer body can possess preferable antireflective effect, and its reflectivity to visible ray exists substantially 0.5% or so.
Present invention also offers it is a kind of sterilize plated film film layer its preparation method, its can overcome prior art certain or Some defects.
According to its preparation method of the sterilization plated film film layer of the present invention, it comprises the following steps:
(1) material that one layer of first film layer unit component layer A, the first film layer unit component layer A are plated in matrix surface is two Silica, thickness 95.42nm;
(2) one layer of first film layer unit component layer B, the first film layer unit group are plated on the first film layer unit component layer A surfaces Part layer B material is silver chlorate, thickness 5.46nm;
(3) one layer of second film layer unit component layer A, the second film layer unit group are plated in the first film layer unit component layer B surface Part layer A material is silica, thickness 61.46nm;
(4) one layer of second film layer unit component layer B, the second film layer unit group are plated on the second film layer unit component layer A surfaces Part layer B material is silver chlorate, thickness 34.88nm;
(5) one layer of third membrane layer unit block layer A, third membrane layer unit group are plated in the second film layer unit component layer B surface Part layer A material is silica, thickness 16.40nm;
(6) one layer of third membrane layer unit block layer B, third membrane layer unit group are plated on third membrane layer unit block layer A surfaces Part layer B material is silver chlorate, thickness 69.91nm.
Preferably, the film plating process in step (1)~(6) uses evaporation coating method or magnetron sputtering coating method.
Pass through its preparation method of the sterilization plated film film layer of the present invention, enabling preferable matrix surface forms a tunic Layer body, and the film layer body can have preferable sterilizing ability and preferable antireflective effect concurrently simultaneously.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram of sterilization plated film film layer structure in embodiment 1;
Fig. 2 is reflectance relationship figure of the film layer body in embodiment 1 to different wave length light.
In Fig. 2, transverse axis is wavelength (nm), and the longitudinal axis is reflectivity (%).
Embodiment
To further appreciate that present disclosure, the present invention is described in detail in conjunction with the accompanying drawings and embodiments.It should be understood that , embodiment be only the present invention is explained and and it is non-limiting.
Embodiment 1
As shown in figure 1, present embodiments provide a kind of sterilization plated film film layer structure, it is characterised in that:Including for located at The film layer body 120 on the surface of matrix 110, film layer body 120 include at least one layer of film layer unit, and film layer unit is included in away from base The film layer unit component layer A and film layer unit component layer B stacked gradually on the direction on the surface of body 110, film layer unit component layer A's Material is silica, and film layer unit component layer B material is silver chlorate.
In the present embodiment, the quantity of film layer unit is 3, the layer successively respectively on the direction away from the surface of matrix 110 Folded first film layer unit, the second film layer unit and third membrane layer unit.
First film layer unit includes the first film layer unit component layer A121 and the first film layer unit component layer B122, the first film Layer unit component layer A121 thickness is 95.42nm, and the first film layer unit component layer B122 thickness is 5.46nm.
Second film layer unit includes the second film layer unit component layer A123 and the second film layer unit component layer B124, the second film Layer unit component layer A123 thickness is 61.46nm, and the second film layer unit component layer B124 thickness is 34.88nm.
Third membrane layer unit includes third membrane layer unit block layer A125 and third membrane layer unit block layer B126, tertiary membrane Layer unit component layer A125 thickness is 16.40nm, and third membrane layer unit block layer B126 thickness is 69.91nm.
As shown in Fig. 2 the film layer body 120 in the present embodiment is provided with relatively low reflectivity in the range of visible ray, Especially in the scope of common light, reflectivity can be maintained at 0.5% or so.
Embodiment 2
A kind of its preparation method for sterilizing plated film film layer is present embodiments provided, it comprises the following steps:
1st, one layer of first film layer unit component layer A121, the first film layer unit component layer A121 material are plated in matrix surface For silica, thickness 95.42nm;
2nd, one layer of first film layer unit component layer B122, the first film layer list are plated on the first film layer unit component layer A121 surfaces First component layer B122 material is silver chlorate, thickness 5.46nm;
3rd, one layer of second film layer unit component layer A123, the second film layer list are plated on the first film layer unit component layer B122 surfaces First component layer A123 material is silica, thickness 61.46nm;
4th, one layer of second film layer unit component layer B124, the second film layer list are plated on the second film layer unit component layer A123 surfaces First component layer B124 material is silver chlorate, thickness 34.88nm;
5th, one layer of third membrane layer unit block layer A125, third membrane layer list are plated on the second film layer unit component layer B124 surfaces First component layer A125 material is silica, thickness 16.40nm;
6th, one layer of third membrane layer unit block layer B126, third membrane layer list are plated on third membrane layer unit block layer A125 surfaces First component layer B126 material is silver chlorate, thickness 69.91nm.
In the present embodiment, the film plating process in step 1~6 can use evaporation coating method or magnetron sputtering plating side Method.
Schematically the present invention and embodiments thereof are described above, this describes no restricted, institute in accompanying drawing What is shown is also one of embodiments of the present invention, and actual structure is not limited thereto.So if common skill of this area Art personnel are enlightened by it, without departing from the spirit of the invention, without designing and the technical scheme for creativeness Similar frame mode and embodiment, protection scope of the present invention all should be belonged to.

Claims (5)

1. sterilize plated film film layer structure, it is characterised in that:Including for the film layer body (120) located at matrix (110) surface, film Layer body (120) includes at least one layer of film layer unit, and film layer unit is included on the direction away from matrix (110) surface layer successively Folded film layer unit component layer A and film layer unit component layer B, film layer unit component layer A material are silica, film layer unit Component layer B material is silver chlorate.
2. sterilization plated film film layer structure according to claim 1, it is characterised in that:The number of at least one layer of film layer unit Measure as 3, respectively away from matrix (110) surface direction on stack gradually the first film layer unit, the second film layer unit and Third membrane layer unit.
3. sterilization plated film film layer structure according to claim 2, it is characterised in that:First film layer unit includes the first film layer Unit block layer A (121) and the first film layer unit component layer B (122), the first film layer unit component layer A (121) thickness are 95.42nm, and the first film layer unit component layer B (122) thickness is 5.46nm;
Second film layer unit includes the second film layer unit component layer A (123) and the second film layer unit component layer B (124), the second film Layer unit component layer A (123) thickness is 61.46nm, and the second film layer unit component layer B (124) thickness is 34.88nm;
Third membrane layer unit includes third membrane layer unit block layer A (125) and third membrane layer unit block layer B (126), tertiary membrane Layer unit component layer A (125) thickness is 16.40nm, and third membrane layer unit block layer B (126) thickness is 69.91nm.
4. a kind of preparation method for sterilizing plated film mold layer, it comprises the following steps:
(1) one layer of first film layer unit component layer A (121), the first film layer unit component layer A (121) material are plated in matrix surface Matter is silica, thickness 95.42nm;
(2) one layer of first film layer unit component layer B (122), the first film layer are plated on first film layer unit component layer A (121) surface Unit block layer B (122) material is silver chlorate, thickness 5.46nm;
(3) one layer of second film layer unit component layer A (123), the second film layer are plated on first film layer unit component layer B (122) surface Unit block layer A (123) material is silica, thickness 61.46nm;
(4) one layer of second film layer unit component layer B (124), the second film layer are plated on second film layer unit component layer A (123) surface Unit block layer B (124) material is silver chlorate, thickness 34.88nm;
(5) one layer of third membrane layer unit block layer A (125), third membrane layer are plated on second film layer unit component layer B (124) surface Unit block layer A (125) material is silica, thickness 16.40nm;
(6) one layer of third membrane layer unit block layer B (126), third membrane layer are plated on third membrane layer unit block layer A (125) surface Unit block layer B (126) material is silver chlorate, thickness 69.91nm.
5. the preparation method of sterilization plated film mold layer according to claim 4, it is characterised in that:Plating in step (1)~(6) Film method uses evaporation coating method or magnetron sputtering coating method.
CN201610687620.6A 2016-08-19 2016-08-19 Sterilize plated film film layer structure and preparation method thereof Active CN106291783B (en)

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CN112456812B (en) * 2020-11-30 2022-04-01 江苏中新瑞光学材料有限公司 Preparation method of AF (AF) coated glass with antibacterial effect
CN112429974B (en) * 2020-12-07 2022-03-22 苏州安洁科技股份有限公司 Composite antibacterial base material with anti-fingerprint function

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Publication number Priority date Publication date Assignee Title
CN101606537A (en) * 2009-06-23 2009-12-23 哈尔滨工业大学 A kind of SiO 2The preparation method of-AgCl composite antibacterial thin films
CN204694870U (en) * 2014-08-11 2015-10-07 深圳市康视佳网络科技发展有限公司 A kind of Multifunctional lens
CN105425413A (en) * 2015-12-31 2016-03-23 奥特路(漳州)光学科技有限公司 Sterilizing waterproof wear-resistant lens resisting oil dirt and preparing method thereof
CN205485119U (en) * 2016-01-13 2016-08-17 江苏康美达光学有限公司 Antibiotic grease proofing dirt and safety goggles against radiation piece

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US8912202B2 (en) * 2011-08-08 2014-12-16 Merck Patent Gmbh N-(benzimimdazol-2-yl)-cyclopropane carboxamides as lysophosphatidic acid antagonists
KR101739176B1 (en) * 2012-06-21 2017-05-23 코니카 미놀타 가부시키가이샤 Polarizing plate, method for manufacturing polarizing plate, and image display device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101606537A (en) * 2009-06-23 2009-12-23 哈尔滨工业大学 A kind of SiO 2The preparation method of-AgCl composite antibacterial thin films
CN204694870U (en) * 2014-08-11 2015-10-07 深圳市康视佳网络科技发展有限公司 A kind of Multifunctional lens
CN105425413A (en) * 2015-12-31 2016-03-23 奥特路(漳州)光学科技有限公司 Sterilizing waterproof wear-resistant lens resisting oil dirt and preparing method thereof
CN205485119U (en) * 2016-01-13 2016-08-17 江苏康美达光学有限公司 Antibiotic grease proofing dirt and safety goggles against radiation piece

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Effective date of registration: 20200722

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Address before: 314005 Jiaxing, South Lake District, Zhejiang, Asia Pacific Road, No. 1

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Patentee before: Tiantong fine Technology Co.,Ltd.