CN106287669A - Hydrogen Energy is produced and applies boiler - Google Patents
Hydrogen Energy is produced and applies boiler Download PDFInfo
- Publication number
- CN106287669A CN106287669A CN201510263021.7A CN201510263021A CN106287669A CN 106287669 A CN106287669 A CN 106287669A CN 201510263021 A CN201510263021 A CN 201510263021A CN 106287669 A CN106287669 A CN 106287669A
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- CN
- China
- Prior art keywords
- steam
- burner
- pot
- vapour
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 23
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000002309 gasification Methods 0.000 claims abstract description 32
- 239000003245 coal Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002485 combustion reaction Methods 0.000 claims abstract description 13
- 239000007789 gas Substances 0.000 claims description 45
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000779 smoke Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 6
- 230000005540 biological transmission Effects 0.000 claims description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- 230000006698 induction Effects 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000002737 fuel gas Substances 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 238000010025 steaming Methods 0.000 claims 1
- 238000011109 contamination Methods 0.000 abstract 1
- 101100298222 Caenorhabditis elegans pot-1 gene Proteins 0.000 description 7
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 210000005239 tubule Anatomy 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002308 calcification Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Solid-Fuel Combustion (AREA)
Abstract
A kind of Hydrogen Energy is produced and applies boiler, this boiler utilizes the steam of self by the steam decomposing system being located in burner hearth, water vapour is decomposed the coal gasification systems generating hydrogen and being located at outside pot, " coal " gasification is transformed into " hydrogen " and is directly entered the combustion system burning being located in stove, " coal-fired " boiler originally having pollution is transformed into the boiler of free of contamination " combustion hydrogen ".
Description
Art
The present invention for work, agricultural and life heating boiler, particularly one can make coal modification gasify,
What water vapour resolved into hydrogen produces the boiler with application function voluntarily.
Background technology
In the prior art, the coal-burning boiler of heating of living, produce is exactly directly to heat with coal combustion, efficiency
Low, pollute big, be unfavorable for the development of the economic society of today.
It is an object of the invention to provide " coal " needed for a kind of personal consumption and pollute the hydrogen of fuel modifying one-tenth cleaning
Gas supply combustion heating produces steam, then it is raw to extract spontaneous part steam utilization burner hearth high-temperature self decomposition
Become hydrogen make to use, therefrom reduce the low-cost high-efficiency of coal consumption amount, without the multifunctional pot furnace apparatus discharged.
Summary of the invention
To achieve the above object, the present invention uses following technical proposals: the present invention comprises as having technology
Have for holding the pot that water combustion heating steams, it is characterised in that in the burner hearth of pot central authorities arrange one infrared
Line burner, above the burner hearth air vent of pot top, centre arranges an infrared burner, burner top
Arranging a steam filtration divides vapour fort, pot top, steam filtration to divide vapour fort week body to dispose an independence to rise
That unloads intercepts the depurator polluting steam reaction, respectively sets a tail gas transmission, raw coal about pot lower outside
Gasify dual-purpose gasification pot.
So boiler preheating is first directly burnt with " coal " and is started the steam produced, and steam is processed by distribution and extracts
Partly, heated to decompose through burner hearth inside turn by snakelike tubule respectively and be directly entered burner and substitute a part of combustion
Material supply is burnt, and entrance gasification pot carries out coal gasification, and the modified gasification of coal generates with H2, CO be main
The mixed gas wanting composition accesses the gas that infrared burner and the steam of burner hearth decomposes and is mixed burning,
Therefrom reduce coal consumption amount, promote the scientific and technological level that Hydrogen Energy is produced and applied.So be located at simultaneously boiler top,
Point top, vapour fort pollute the heating fuel source intercepting depurator, waved the dust fire risen by intercepting burner hearth
The waste heat of exit gas, and the hydrogen of steam decomposition, two combination burnings, burning digestion to dust flue gas
Meanwhile, the steam humidification absorption polluter of generation, carry and stay carbon dioxide, calcification calculus, then the tail circulation
Gas introduces raw coal gasification pot, participates in modification conversion gasification, improves the utilization rate of fuel, reduces primary energy and disappear
Take, protect environment.
Above-mentioned Hydrogen Energy produces and applies the structure of boiler to design: in the burner hearth that pot contains, central authorities arrange burning
The composition of device is: is provided with in the bottom of burner gather qi together well and connects the gas entrance that steam decomposes, gather qi together well
Bottom, the left and right sides be provided with connect coal gasification gas entrance, in gather qi together well in the middle of dispose one gear gas put down
Weighing apparatus net, for balancing the fusion burning of different source of the gas, balance net one block of infrared ray disposed above combustion of gather qi together well
Burn plate, strengthen gas modification resolution with infrared radiation, improve fuel value.
The structure of the infrared burner that pot top, burner hearth air vent are provided above；Also in gather qi together well
Middle arrangement one gear gas balance net, infrared combustion plate disposed above, going to the bottom to be provided with connects what steam decomposed
Source of the gas inlet port, gather qi together well side is provided with the gaseous fuel inlet port introducing primary energy, for boiler startup
The dense smoke period that heating burning raw coal produces introduces the digestion to dense smoke and burns.
The steam filtration that burner is provided above divides the structure in vapour fort to be: the air intake that is arranged above with in point vapour fort connects
Breather pipe is connected with the steam outlet of bottom pot, and is provided with steam and separates mouth and connect a point vapour outlet tube, point
Vapour is protected side of going to the bottom and is provided with heavy water outlet, and the Rong Shuizhong of heavy water connecting line through furnace intracoelomic cavity, on chamber, fort
Side, portion sets steam outlet, and outlet connects snakelike tubule and spirals and lower suction through burner hearth air vent entrance burner hearth
Receive flame heating, snakelike tubule lower end arranges a steam reaction, steam distributes, dual-purpose reaction allotter,
Allotter inner chamber is provided with a gear catalytic reaction net, and the side of allotter is provided with gas outlet and connects snakelike little steam pipe,
Spiral up from down in burner hearth and be connected with the infrared burner source of the gas inlet port above burner hearth air vent, point
The centre of going to the bottom of orchestration is provided with the gas outlet snakelike tubule of connection fiery some central authorities in burner hearth and rotates at the bottom of burner
Portion is connected with gas entrance.
Boiler placed on top, point vapour fort week body, the structure intercepting pollution steam reaction depurator of setting: be
Individual possess identical with inferior boiler hold water heating and steam the appearance water tower body of function, within holding water tower body and containing
Chamber circumference arranges the ceramic honeycombed screen plate of absorbing carbon dioxide, arranges a scattered vapour fort in the middle of inner chamber, and steam leads to
Cross and dissipate vapour fort and distribute distribution intracavity space and the adsorption plate of circumference, the stop calcification of absorbing carbon dioxide and remaining
Substance reaction modification purify.
The air vent holding water tower body top is provided above a dense smoke induction apparatus；Hold water tower body leftover bits and pieces outer wall side
Arrange one connect primary energy gaseous fuel gas former automatically supply gas, feeder, main body boiler heating open
The dense smoke sensing of dynamic burning raw coal period on fire, is started to burning voluntarily by induction apparatus, line sensing feeder
Device is supplied gas burning, releases the dense smoke risen by main body boiler furnace and expands.
Lower portion thereof outer wall both sides respectively set one, the gasification of " tail gas attract deposit transmission, raw coal gasification " double-purpose functional
Pot: boiler is when long-term heating runs, and this gasification pot is used for Coal Gasification, by the gasification of left and right " two pots "
Gas intersection persistently supplies use to hearth combustor；When short time heating split run runs, this boiler is still adopted
With directly burning coal, heating uses；Its gasification pot be used as absorption tail gas reaction transmit burner in the stove circulating combustion,
Also environmental protection purpose can be reached；The composition of this gasification pot is monomer, the gasification vessel additionally heated, gasification pot with
Upper furnace, depurator exhaust emission tube connect, gasification pot be arranged over charging aperture, lower section is provided with out
Cinder notch, outside are provided with for heat the oxidation steam of coal, the access port of oxygen, that inner side is provided with gas outlet is straight
Connect the burner supply in burner hearth.
The present invention compared with prior art, has a prominent feature: be do not put into single Hydrogen Energy produce,
A series of equipment that hydrogen supply uses, take just on the spot, by the raw materials that can make two extraction Hydrogen Energies of boiler itself
Realizing producing Hydrogen Energy, slitless connection application on the spot, low cost, efficiency are high, pollution-free simultaneously.
It is described further below in conjunction with the accompanying drawings.
Accompanying drawing is the structural representation of one embodiment of the present of invention.
Preferred embodiment of the invention is to see accompanying drawing.
Detailed description of the invention
The composition of this hydrogen energy boiler is: the burner hearth 3 contained by pot 1, and the lower central at burner hearth 3 arranges one
Individual burner 21, the gather qi together bottom of burner 21 is provided with and connects the gas entrance that steam decomposes, gather qi together well
The left and right sides, bottom be provided with connect raw coal gasification gas entrance, in gather qi together well in the middle of dispose one gear gas
Balance net, balance net one piece of infrared combustion plate disposed above of gather qi together well.Pot 1 top, burner hearth 3
Air vent is provided above an infrared burner 5, equally disposes a gear gas in the middle of the gather qi together well of burner 5
Balance net, infrared combustion plate disposed above, go to the bottom and be provided with connection steam decomposition source of the gas inlet port, gather qi together well
Side is provided with the gaseous fuel inlet port introducing primary energy.Burner 5 be provided above a steam filtration
Dividing vapour fort 13, the air intake that is arranged above with in point vapour fort 13 connects the steam row of breather pipe 14 and bottom pot 1
Outlet is connected, and steam separates mouth and connects a point vapour outlet tube 4, and a side bottom in point vapour fort 13 is provided with heavy water row
Outlet connects water service pipe 15, and the inner chamber of the lower end straight cutting pot 1 of water service pipe 15 holds in water, point vapour fort 13
One upper lateral part is provided with point steam ports and connects snakelike little steam pipe 17, under snakelike little steam pipe 17 is in burner hearth 3 inside turn,
Lower end arranges a steam reaction, steam distributes dual-purpose reaction allotter 22, and the inner chamber of allotter 22 is provided with
One gear catalytic reaction net, the side of allotter 22 is provided with point steam ports connection one snakelike little steam pipe 18 at burner hearth
Interior spiraling up from down is connected, in the bottom of allotter 22 with the infrared burner 5 above burner hearth air vent
Between be provided with point steam ports and connect snakelike little steam pipe 2 in burner hearth；Fire point central disc above infrared burner 21
The bottom rotating to burner 21 is connected with gas entrance.
Pot 1 placed on top, the circumference in point vapour fort 13 arranges one and intercepts pollution steam reaction depurator 7,
The inner chamber of depurator 7 is arranged around the ceramic honeycombed screen plate 6 of a set of absorbing carbon dioxide, the top of depurator 7
Being provided with steam steam drain and connect breather pipe 9, the lower end of breather pipe 9 arranges a scattered vapour fort 12, dissipates vapour fort 12
Circumference be provided with vapour dissipating tube, spatial balance in thorax is dissipated vapour, dissipate vapour fort 12 bottom be provided with heavy water outlet；
The upper air vent of depurator 7 is provided above a dense smoke induction apparatus 10, and induction apparatus 10 has line 11 with clean
Change the leftover bits and pieces outer wall side of device 7 to arrange one and connect automatically the supplying gas of primary energy gaseous fuel, feeder 16.
Outer wall both sides, pot 1 bottom respectively set the identical tail gas of structure and attract deposit transmission, raw coal gasification, double-purpose functional
Gasification pot 19, gasification pot 19 top connect pot 1 depurator 7 exhaust emission tube 8, gasify pot 19
Top be provided with charging aperture, lower section is provided with slag notch, and outside is provided with steam, oxygen access port, and inner side is provided with
Connecting tube of giving vent to anger 20 is connected conveying Coal Gasification gas with the burner 21 in burner hearth 3.
Claims (6)
1. the Hydrogen Energy of work, agricultural and life heating is produced and applies a boiler, and it holds kettle body (1) at one
Burner hearth (3) the interior lower central contained arranges an infrared burner (21), the top of pot (1),
Arranging an infrared burner (5) in the middle of above the air vent of burner hearth (3), burner (5) top sets
Putting a steam filtration divides vapour fort (13), pot (1) placed on top, the circumference in point vapour fort (13) to arrange
One intercepts pollution steam reaction depurator (7), and the outer wall both sides, bottom of pot (1) respectively set a structure phase
With, tail gas is attracted deposit transmission, raw coal gasification, the gasification pot (19) of double-purpose functional.
Hydrogen Energy the most according to claim 1 is produced and applies boiler, it is characterised in that infrared in burner hearth (3)
The composition of line burner (21): the gather qi together bottom at burner (21) is offered and connected the gas that steam decomposes
Body inlet port, the gas entrance connecting raw coal gasification is offered in the left and right sides, bottom of gather qi together well, in gather qi together well
Middle arrangement one gear gas balance net, balance net one piece of infrared combustion plate disposed above of gather qi together well.
Hydrogen Energy the most according to claim 1 is produced and applies boiler, it is characterised in that the top of pot (1),
The composition of the infrared burner (5) in the middle of above the air vent of burner hearth (3): the gather qi together of burner (5)
Disposing a gear gas balance net in the middle of well, gather qi together well infrared combustion plate disposed above, gather qi together is offered at the bottom of down-hole
Having and connect the source of the gas inlet port that steam decomposes, gather qi together well side is provided with the gaseous fuel entrance introducing primary energy
Mouthful.
Hydrogen Energy the most according to claim 1 is produced and applies boiler, it is characterised in that burner (5) top sets
The steam filtration put divides the composition of vapour fort (13): the air intake that is arranged above with in point vapour fort (13) connects steaming
The steam outlet linking of pipe (14) and bottom pot (1) and be provided with steam and separate mouth and be connected point vapour and export
Pipe (4), a side bottom in point vapour fort (13) is provided with heavy water outlet and connects water service pipe (15), water service pipe (15)
The inner chamber of lower end straight cutting pot (1) hold in water, a upper lateral part in point vapour fort (13) is provided with a point steam ports connection
Snakelike little steam pipe (17), snakelike little steam pipe (17) in burner hearth inside turn under to arrange a steam anti-in lower end
Answer, steam distributes dual-purpose reaction allotter (22), and the inner chamber of allotter (22) is provided with a gear steam reaction
Net, the side of allotter (22) is provided with point steam ports and connects a snakelike little steam pipe (18), snakelike little steam pipe (18)
Spiral up from down in burner hearth (3) with burner hearth (3) upper air vent above infrared burner (5)
Linking is supplied gas, and is provided with point steam ports and connects snakelike little steam pipe (2) in burner hearth (3) in the middle of the bottom of allotter (22)
In, the central volution of fire point of infrared burner (21) top, forward bottom and the gas of burner (21) to
The linking of body inlet port is supplied gas.
Hydrogen Energy the most according to claim 1 is produced and applies boiler, it is characterised in that pot (1) placed on top,
The pollution that point vapour fort (13) circumference is arranged intercepts the composition of reaction vapor depurator (7): depurator (7)
Inner chamber week circle the ceramic honeycombed screen plate (6) of a set of absorbing carbon dioxide is set, the top of depurator (7) sets
Having Vapor outlet to connect steam breather pipe (9), the lower end of breather pipe (9) arranges a scattered vapour fort (12),
The circumference dissipating vapour fort (12) is provided with vapour dissipating tube vapour scattered to cavity space balance, and the bottom dissipating vapour fort (12) sets
There is heavy water outlet；The upper air vent of depurator (7) is provided above a dense smoke induction apparatus (10), sense
Answer device (10) to have line (11) to arrange one with the leftover bits and pieces outer wall side of depurator (7) and be connected primary energy
What gaseous fuel gas was former supply gas automatically, feeder (16).
Hydrogen Energy the most according to claim 1 is produced and applies boiler, it is characterised in that outside the bottom of pot (1)
Wall both sides respectively set the identical tail gas of structure and attract deposit the gasification pot (19) of transmission, raw coal gasification double-purpose functional,
The top of gasification pot (19) connects pot (1), the exhaust emission tube (8) of depurator (7), gasification pot (19)
Top be provided with charging aperture, bottom is provided with slag notch, and outside is provided with steam, oxygen access port, and inner side is provided with
Connecting tube of giving vent to anger (20), connecting tube of giving vent to anger (20) enter burner hearth (3) through the bottom of pot (1) in
The gas entrance linking conveying Coal Gasification gas of burner (21).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510263021.7A CN106287669B (en) | 2015-05-15 | 2015-05-15 | Hydrogen Energy is produced and applies boiler |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510263021.7A CN106287669B (en) | 2015-05-15 | 2015-05-15 | Hydrogen Energy is produced and applies boiler |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106287669A true CN106287669A (en) | 2017-01-04 |
| CN106287669B CN106287669B (en) | 2019-08-06 |
Family
ID=57633962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510263021.7A Active CN106287669B (en) | 2015-05-15 | 2015-05-15 | Hydrogen Energy is produced and applies boiler |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106287669B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107542546A (en) * | 2017-08-14 | 2018-01-05 | 张达积 | Automobile and diesel engine vent gas infrared ray steam modifier |
| WO2019033690A1 (en) * | 2017-08-14 | 2019-02-21 | 张达积 | Water decomposition combustion air heat-conduction and -supply furnace |
| CN110436412A (en) * | 2019-07-25 | 2019-11-12 | 张达积 | Boiler smoke modifier |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2065724U (en) * | 1989-12-16 | 1990-11-14 | 杜一 | High-effcient coal-saving infrared ray coal stove |
| US20030017428A1 (en) * | 2001-07-02 | 2003-01-23 | Rafael Armament Development Authority Ltd. | Method and apparatus for generating superheated steam |
| US20080241614A1 (en) * | 2007-03-26 | 2008-10-02 | Advanced Hydrogen Power Systems, Inc. | Hydrogen mobile power plant that extracts hydrogen fuel from water |
| CN202733898U (en) * | 2012-07-17 | 2013-02-13 | 张达积 | Infrared hydrogen energy combustor |
| CN204648215U (en) * | 2015-05-15 | 2015-09-16 | 张达积 | Hydrogen Energy is produced and is applied boiler |
-
2015
- 2015-05-15 CN CN201510263021.7A patent/CN106287669B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2065724U (en) * | 1989-12-16 | 1990-11-14 | 杜一 | High-effcient coal-saving infrared ray coal stove |
| US20030017428A1 (en) * | 2001-07-02 | 2003-01-23 | Rafael Armament Development Authority Ltd. | Method and apparatus for generating superheated steam |
| US20080241614A1 (en) * | 2007-03-26 | 2008-10-02 | Advanced Hydrogen Power Systems, Inc. | Hydrogen mobile power plant that extracts hydrogen fuel from water |
| CN202733898U (en) * | 2012-07-17 | 2013-02-13 | 张达积 | Infrared hydrogen energy combustor |
| CN204648215U (en) * | 2015-05-15 | 2015-09-16 | 张达积 | Hydrogen Energy is produced and is applied boiler |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107542546A (en) * | 2017-08-14 | 2018-01-05 | 张达积 | Automobile and diesel engine vent gas infrared ray steam modifier |
| WO2019033690A1 (en) * | 2017-08-14 | 2019-02-21 | 张达积 | Water decomposition combustion air heat-conduction and -supply furnace |
| CN110436412A (en) * | 2019-07-25 | 2019-11-12 | 张达积 | Boiler smoke modifier |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106287669B (en) | 2019-08-06 |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20181229 Address after: 352100 No. 49 East Building, Xiafan Village, Zhangwan Town, Dongqiao District, Ningde City, Fujian Province Applicant after: Ningde Vick Trading Co., Ltd. Address before: Room 402, Building D, Hefeng Commercial City, Jiaocheng District, Ningde City, Fujian Province Applicant before: Zhang Daji |
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