CN106283640B - A kind of softener and preparation method thereof - Google Patents
A kind of softener and preparation method thereof Download PDFInfo
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- CN106283640B CN106283640B CN201610790153.XA CN201610790153A CN106283640B CN 106283640 B CN106283640 B CN 106283640B CN 201610790153 A CN201610790153 A CN 201610790153A CN 106283640 B CN106283640 B CN 106283640B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to softener field, and in particular to a kind of softener and preparation method thereof.Softener of the present invention, including following components and its percetage by weight：Double (butter acylamino- ethyl) the 2 hydroxyethyl ammonium methosulfates 3 6% of methyl, hydroxyethyl cellulose 0.1 0.4%, the PAMC aqueous solution 0.1 0.5%, dodecyl benzyl dimethyl ammonium chloride 0.1 0.5%, essence 0.2 0.6% and water 94 95%.Softener of the present invention not only has good submissive effect, and with good biological degradability, it is environmentally friendly, also, simple production process, energy- and time-economizing, save production cost.
Description
Technical field
The present invention relates to softener field, and in particular to a kind of softener and preparation method thereof.
Background technology
Fabric softener is put into by E.E.Staley and P＆G companies in 1950s later development, and successfully first
American market, also there is fabric softener in Japan and European market to the beginning of the sixties.Chinese fabric softener is born in 20
The beginning of the eighties in century, at that time Guangzhou Oil Chemical Plant be proposed the dust-proof softening agent of the beautiful board in day, as first item in Chinese market
Fabric softening agent.
Fabric softener is from initially single compliance function to a variety of function developments.Chinese fabric softener market is in recent years
To emphasize the functional character of product by mainly selling as softener in addition to the submissive and antistatic basic function of prominent product
Point.
VARISOFT TA100 (D1821) is due to the performance such as its excellent softness, antibacterial, antistatic, last
Middle and later periods in century is used widely, but because its toxicity is big, biological degradability is poor, is disabled by European Union.Dihydrogenated tallow two
Ammonio methacrylate (DTDMAC), due to biodegradable sex chromosome mosaicism, the composition is biological in developed countries such as Europe, Japan
The excellent esterquat surfactant of degradability is replaced.
The country, traditional fabric softener remains unchanged substantial amounts of use VARISOFT TA100.With the depth of research
Enter, it has been found that have its advantage and disadvantage as the various cationic surfactants of softener primary raw material, how in formula
The relation of the various performances of softener is balanced, is always the problem that formulator faces.
Chinese patent CN101935949B discloses a kind of fabric softener, from double ox ester group ethoxycarbonyl hydroxyethyl methyls
Sulfate methyl ammonium and dimethyl silicone polymer two quaternary amines, two kinds of cationic surfactants, although primary raw material biological can drop
Solution, environmental protection, but formula components are complicated, and heating is still needed in preparation process, and add cost.
The content of the invention
To solve to add the poor surfactant of poisonous, biological degradability in existing softener, or formula is complicated, cost
High the problem of, the present invention provides a kind of softener and preparation method thereof, and the softener can be reached excellent on the basis of environmental protection
Submissive effect and be formulated simple, cost is relatively low.
Above-mentioned purpose of the present invention is achieved by the following technical programs：
A kind of softener, including following components and its percetage by weight：Double (butter acylamino- the ethyl) -2- hydroxyl second of methyl
Base ammonium methosulfate 3-6%, hydroxyethyl cellulose 0.1-0.4%, PAMC aqueous solution 0.1-0.5%, ten
Dialkyl dimethyl benzyl ammonium chloride 0.1-0.5%, essence 0.2-0.6% and water 94-95%.
Preferably, above-mentioned fabric softener, is made up of following components and mass percent：Double (the butter acylamino- second of methyl
Base) -2- hydroxyethyl ammoniums methosulfate 4.5%, hydroxyethyl cellulose 0.2%, the PAMC aqueous solution
0.25%, dodecyl benzyl dimethyl ammonium chloride 0.3%, essence 0.4% and water 94.35%.
Double (butter acylamino- ethyl) -2- hydroxyethyl ammonium methosulfates of methyl in softener of the present invention are purchased from
Stepan companies, article No. is ACCOSOFT 501.Double (butter acylamino- the ethyl) -2- hydroxyethyl ammoniums methosulfate tools of methyl
There is excellent flexibility, it is environmentally friendly with good biological degradability, it is easy to disperse and stability is good, with good
The features such as compatibility, rewettability.Simultaneously diamide Quaternary Ammonium salt have wider dispersion concentration, excellent storage stability,
The very fast dispersing and dissolving of energy, cold at room temperature to match somebody with somebody in cold water, so that submissive agent producing process is enormously simplify, energy- and time-economizing,
Save production cost.
The PAMC aqueous solution in softener of the present invention is purchased from Jiangsu Na Ke Science and Technology Ltd.s, and article No. is
CAC1200, wherein PAMC percetage by weight are 50-60%, preferably 55%.PAMC water
Solution is chain macromolecule compound, and good water solubility can be also completely dissolved in cold water.Because it has a variety of active bases
Group, can it is affine with many materials, absorption form hydrogen bond.Mainly flocculate negatively charged colloid, with turbidity removal, decolouring, absorption,
The functions such as bonding.
Hydroxyethyl cellulose in softener of the present invention, it is nontoxic, tasteless, soluble in water, with thickening, suspension, bonding, breast
Change, disperse, keep the performance such as moisture and protecting colloid, be a kind of important thickener.
Dodecyl benzyl dimethyl ammonium chloride in softener of the present invention, is a kind of cationic surfactant, can be dropped
Low surface tension, makes fat emulsification, there is cleaning decontamination effect.It is soluble in water, do not influenceed by the water hardness, be a kind of important soft
Soft dose, antistatic additive, emulsifying agent.
Essence, is purchased from fragrant kindness (Firmenich), article No.：ARIZONAPOP 227262-POPSCENT, wherein microcapsules
Coated essence is 12.5%.
In addition, present invention also offers a kind of preparation method of softener, comprising the following steps：
(1) hydroxyethyl cellulose is added to the water, stirred to being completely dissolved, be subsequently added into double (the butter acylamino- second of methyl
Base) -2- hydroxyethyl ammonium methosulfates, 15-20min is to being completely dissolved for stirring, obtains solution A；
(2) PAMC water soluble (CO) polymers are taken, are extremely dissolved with the water stirring and dissolving 10-15min of its volume 1%
Uniformly, it is added into above-mentioned solution A, quickly stirs 10-20min, obtains solution B；
(3) into above-mentioned solution B, dodecyl benzyl dimethyl ammonium chloride is added, is well mixed, essence, stirring is added
Uniformly, softener is obtained.
Compared with prior art, the present invention has the advantages that：
(1) softener of the present invention has good biological degradability, environmentally friendly；
(2) softener invention simple production process of the present invention, production cost is saved in energy- and time-economizing；
(3) the essence part used in softener of the present invention is encapsulation type essence so that clothing lasting is lasting；
(4) softener of the present invention is soluble, and with good antistatic property and submissive effect.
Embodiment
It is explained further the present invention with reference to embodiments, but embodiment is not that any type of limit is done to the present invention
It is fixed.
Embodiment 1
Softener of the present invention is made up of following components and percetage by weight：
Double (butter acylamino- the ethyl) -2- hydroxyethyl ammoniums methosulfates 4.5% of methyl, hydroxyethyl cellulose 0.2%,
The PAMC aqueous solution 0.25%, dodecyl benzyl dimethyl ammonium chloride 0.3%, essence 0.4%, water
94.35%.
Preparation method：
(1) hydroxyethyl cellulose is added to the water, stirred to being completely dissolved, be subsequently added into double (the butter acylamino- second of methyl
Base) -2- hydroxyethyl ammonium methosulfates, 20min is to being completely dissolved for stirring, obtains solution A；
(2) PAMC water soluble (CO) polymers are taken, it is equal to dissolving with the water stirring and dissolving 15min of its volume 1%
It is even, it is added into above-mentioned solution A, quickly stirs 20min, obtains solution B；
(3) into above-mentioned solution B, dodecyl benzyl dimethyl ammonium chloride is added, is well mixed, essence, stirring is added
Uniformly, softener is obtained.
Embodiment 2
Softener of the present invention is made up of following components and percetage by weight：
Double (butter acylamino- the ethyl) -2- hydroxyethyl ammoniums methosulfates 3% of methyl, hydroxyethyl cellulose 0.1%, sun
The cationic polyacrylamide aqueous solution 1%, dodecyl benzyl dimethyl ammonium chloride 0.1%, essence 0.2%, water 95.6%.
Preparation method：
(1) hydroxyethyl cellulose is added to the water, stirred to being completely dissolved, be subsequently added into double (the butter acylamino- second of methyl
Base) -2- hydroxyethyl ammonium methosulfates, 15min is to being completely dissolved for stirring, obtains solution A；
(2) PAMC water soluble (CO) polymers are taken, it is equal to dissolving with the water stirring and dissolving 10min of its volume 1%
It is even, it is added into above-mentioned solution A, quickly stirs 10min, obtains solution B；
(3) into above-mentioned solution B, dodecyl benzyl dimethyl ammonium chloride is added, is well mixed, essence, stirring is added
Uniformly, softener is obtained.
Embodiment 3
Softener of the present invention is made up of following components and percetage by weight：
Double (butter acylamino- the ethyl) -2- hydroxyethyl ammoniums methosulfates 6% of methyl, hydroxyethyl cellulose 0.4%, sun
The cationic polyacrylamide aqueous solution 0.5%, dodecyl benzyl dimethyl ammonium chloride 0.5%, essence 0.6%, water 92%.
Preparation method：
(1) hydroxyethyl cellulose is added to the water, stirred to being completely dissolved, be subsequently added into double (the butter acylamino- second of methyl
Base) -2- hydroxyethyl ammonium methosulfates, 20min is to being completely dissolved for stirring, obtains solution A；
(2) PAMC water soluble (CO) polymers are taken, it is equal to dissolving with the water stirring and dissolving 15min of its volume 1%
It is even, it is added into above-mentioned solution A, quickly stirs 20min, obtains solution B；
(3) into above-mentioned solution B, dodecyl benzyl dimethyl ammonium chloride is added, is well mixed, essence, stirring is added
Uniformly, softener is obtained.
Comparative example 1
This softener is made up of following components and percetage by weight：
Hydroxyethyl cellulose 4.7%, the PAMC aqueous solution 0.25%, dodecyl dimethyl Benzylmagnesium chloride
Ammonium 0.3%, essence 0.4%, water 94.35%.
Preparation method is similar to Example 1.
Difference with embodiment 1 is, does not add double (butter acylamino- the ethyl) -2- hydroxyethyl ammonium methyl esters sulphur of methyl
Hydrochlorate, increases the content of hydroxyethyl cellulose.
Comparative example 2
This softener is made up of following components and percetage by weight：
VARISOFT TA100 4.5%, hydroxyethyl cellulose 0.2%, the PAMC aqueous solution
0.25%, dodecyl benzyl dimethyl ammonium chloride 0.3%, essence 0.4%, water 94.35%.
Preparation method is similar to Example 1.
Difference with embodiment 1 is, double (butter acylamino- the ethyl) -2- hydroxyethyl ammonium methosulfates of methyl are replaced
It is changed to VARISOFT TA100.
Comparative example 3
Double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums 4.5%, hydroxyethyl cellulose 0.2%, cation poly- third
The acrylamide aqueous solution 0.25%, dodecyl benzyl dimethyl ammonium chloride 0.3%, essence 0.4%, water 94.35%.
Preparation method is similar to Example 1.
Difference with embodiment 1 is, double (butter acylamino- the ethyl) -2- hydroxyethyl ammonium methosulfates of methyl are replaced
It is changed to double ox ester group ethoxycarbonyl hydroxyethyl methyl sulfate methyl ammoniums.
The detection of the antistatic property of test example 1
Test object：Softener prepared by embodiment 1-3, softener and a kind of commercially available softener prepared by comparative example 1-3.
Test content：According to《GB/T 12703.1-2008 textile antistatic properties》Test request, to above-mentioned test pair
As the fabric after processing carries out electrostatic potential and the measure of half-life period, 1 the results are shown in Table.
The antistatic property of softener is mainly reflected by static of the fabric voltage and electrostatic pressure half-life period.Electrostatic potential master
Judge the size of static of the fabric；Electrostatic pressure half-life period is that fabric face electrostatic potential decays to the time required during half,
The speed degree of main reflection static of the fabric decay.Both comprehensive analysis, the antistatic property of softener could be judged more comprehensively,
After being handled through softener, if static of the fabric voltage journey is low, it can decay rapidly again, the antistatic property of this softener is ratio
Outstanding；If electrostatic potential is higher, but decay is rapid, or electrostatic potential is relatively low, but the rate of decay is slow, this submissive
The antistatic property of agent is more general；If electrostatic potential is high, the rate of decay is again slow, and the antistatic property of this softener is just
It is undesirable.
The present invention gained softener antistatic property of table 1
| Sample | Electrostatic pressure (V) | Electrostatic half-life (s) |
| Embodiment 1 | 875 | 0.5 |
| Embodiment 2 | 910 | 0.7 |
| Embodiment 3 | 890 | 0.6 |
| Comparative example 1 | 935 | 0.9 |
| Comparative example 2 | 964 | 1.0 |
| Comparative example 3 | 942 | 0.9 |
| Commercially available softener | 930 | 0.8 |
As shown in Table 1, compared with commercially available softener, the electrostatic potential journey of the fabric after softener of the present invention processing
The low and rate of decay is fast, illustrates that softener antistatic property of the present invention is strong, the wherein softener antistatic property of embodiment 1 is most strong.
The bending softness detection of test example 2
Test object：Softener prepared by embodiment 1-3, softener and a kind of commercially available softener prepared by comparative example 1-3.
Test content：Bending softness detection is carried out to the fabric after the processing of above-mentioned test object, 2 are the results are shown in Table.
The present invention gained softener bending softness of table 2
Wherein bending length is smaller, illustrates that fabric is more soft.As shown in Table 2, compared with commercially available softener, by this hair
The bending length of fabric after bright softener processing is small, illustrates that softener flexibility of the present invention is good, wherein the softener of embodiment 1 is imitated
Fruit is optimal.
The study on the stability of test example 3
Test object：Softener prepared by embodiment 1-3, softener and a kind of commercially available softener prepared by comparative example 1-3.
Test content：Above-mentioned test object is placed 30 days in 48 DEG C of constant temperature oven, taking-up is cooled to room temperature, carried out
Performance, as a result such as table 3.
The softener of the present invention of table 3 is stable
As shown in Table 3, after softener of the present invention is placed 30 days in 48 DEG C of constant temperature oven, stability is more soft than commercially available
It is high along agent, and the stability highest of embodiment 1.
Claims (4)
1. a kind of softener, it is characterised in that by following components and its percetage by weight：Methyl double (butter acylamino- ethyls)-
2- hydroxyethyl ammoniums methosulfate 3-6%, hydroxyethyl cellulose 0.1-0.4%, PAMC aqueous solution 0.1-
0.5%, dodecyl benzyl dimethyl ammonium chloride 0.1-0.5%, essence 0.2-0.6% and water 94-95%；
The percetage by weight of the PAMC aqueous polymer cationic polyacrylamide is 50-60%；
Encapsulation type essence is 12.5% in the essence.
2. softener according to claim 1, it is characterised in that the softener is by following components and its percetage by weight
Composition：Double (butter acylamino- the ethyl) -2- hydroxyethyl ammoniums methosulfates 4.5% of methyl, hydroxyethyl cellulose 0.2%, sun
The cationic polyacrylamide aqueous solution 0.25%, dodecyl benzyl dimethyl ammonium chloride 0.3%, essence 0.4% and water
94.35%.
3. the preparation method of softener according to claim 2, it is characterised in that the PAMC is water-soluble
The percetage by weight of polymer cationic polyacrylamide is 55%.
4. according to the preparation method of any described softeners of claim 1-3, it is characterised in that the preparation side of the softener
Method is divided into following steps：
(1) hydroxyethyl cellulose is added to the water, stirred to being completely dissolved, be subsequently added into methyl double (butter acylamino- ethyl)-
2- hydroxyethyl ammonium methosulfates, 15-20min is to being completely dissolved for stirring, obtains solution A；
(2) PAMC water soluble (CO) polymers are taken, it is equal to dissolving with the water stirring and dissolving 10-15min of its volume 1%
It is even, it is added into above-mentioned solution A, quickly stirs 10-20min, obtains solution B；
(3) into above-mentioned solution B, dodecyl benzyl dimethyl ammonium chloride is added, is well mixed, essence is added, stirs,
Obtain softener.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110734815B (en) * | 2019-10-18 | 2021-06-04 | 广州大白生物科技有限公司 | Microcapsule essence laundry detergent and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107675498A (en) * | 2017-10-13 | 2018-02-09 | 洛娃科技实业集团有限公司 | A kind of softener and preparation method |
| CN110699194B (en) * | 2019-10-18 | 2021-06-04 | 广州大白生物科技有限公司 | Laundry detergent capable of stably dispersing microcapsule essence |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110734815B (en) * | 2019-10-18 | 2021-06-04 | 广州大白生物科技有限公司 | Microcapsule essence laundry detergent and preparation method thereof |
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