CN106283208A - A kind of preparation method of easy cleaning height water suction Wiping material - Google Patents
A kind of preparation method of easy cleaning height water suction Wiping material Download PDFInfo
- Publication number
- CN106283208A CN106283208A CN201610672660.3A CN201610672660A CN106283208A CN 106283208 A CN106283208 A CN 106283208A CN 201610672660 A CN201610672660 A CN 201610672660A CN 106283208 A CN106283208 A CN 106283208A
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- China
- Prior art keywords
- solution
- wiping material
- pla
- degumming
- mass fraction
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- 239000000463 material Substances 0.000 title claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000004140 cleaning Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 77
- 239000002131 composite material Substances 0.000 claims abstract description 43
- 108010022355 Fibroins Proteins 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000009835 boiling Methods 0.000 claims abstract description 18
- 241000208202 Linaceae Species 0.000 claims abstract description 16
- 235000004431 Linum usitatissimum Nutrition 0.000 claims abstract description 16
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000011487 hemp Substances 0.000 claims abstract description 14
- 239000004744 fabric Substances 0.000 claims abstract description 12
- 229940059936 lithium bromide Drugs 0.000 claims abstract description 8
- 239000006166 lysate Substances 0.000 claims abstract description 8
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 54
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 43
- 239000004626 polylactic acid Substances 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 13
- 238000009987 spinning Methods 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- 238000009940 knitting Methods 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 7
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 claims description 6
- 241000255789 Bombyx mori Species 0.000 claims description 6
- 238000002242 deionisation method Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 6
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 150000008107 benzenesulfonic acids Chemical class 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 12
- 239000003344 environmental pollutant Substances 0.000 abstract description 7
- 231100000719 pollutant Toxicity 0.000 abstract description 7
- 230000003115 biocidal effect Effects 0.000 abstract description 6
- 230000003670 easy-to-clean Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 2
- 238000005520 cutting process Methods 0.000 abstract description 2
- 238000004513 sizing Methods 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract 1
- 238000005452 bending Methods 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000001467 acupuncture Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
- D01C1/00—Treatment of vegetable material
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/20—Protein-derived artificial fibres
- D10B2211/22—Fibroin
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses the preparation method of a kind of easy cleaning height water suction Wiping material, belong to Wiping material preparing technical field.China-hemp fibers soda boiling is first carried out degumming by the present invention, obtain degumming flax fiber, take natural silk degumming more dried, being dissolved in lithium-bromide solution, mix with PLA solution after being concentrated by lysate, after microwave treatment, electrostatic spinning obtains fibroin/PLA Composite Fiber, composite fibre is mixed with degumming flax fiber, spraying surfactant solution again to carry out being twisted blended yarns, be woven into grey cloth, sizing cutting prepares the method for easy cleaning height water suction Wiping material.Preparation process of the present invention is simple, and products obtained therefrom is easy to clean, and water absorption rate is high；Make full use of degumming china-hemp fibers composite silk albumen/PLA Composite Fiber and prepare Wiping material, strong not only for property, efficiently solve its dirt-removing power weak, wear no resistance problem, and it is good to have antibiotic property, mechanical property, and pollutant holding capability is high.
Description
Technical field
The present invention relates to the preparation method of a kind of easy cleaning height water suction Wiping material, belong to Wiping material technology of preparing neck
Territory.
Background technology
Along with improving constantly of people's living standard, people are more and more higher to the requirement of quality of life.Wiping material is made
For the consumable goods of daily life, can not only preferably save the time for people, rapid clean article.But Wiping material water suction at present
Property is poor, dirt-removing power is weak, wears no resistance, and cleans the problems such as the most thorough.Wiping material and people live closely bound up, and its kind is very
Many, according to the architectural feature of Wiping material, it is broadly divided into following a few class: dry goods can be subdivided into again woven species and knitted fabric
Class, woven species is interwoven by filling yarn, its structure compared with closely, the long property of intensity high, resistance to one good, but in wiping process oneself
Body is easily contaminated, and not easy cleaning, thus produces cross-contamination, and reusability is poor.It is woven that use Common synthetic fiber prepares
Thing dirt-removing power is poor, and feel is harder, and easy damaged is wiped the surface of article, the particularly skin covering of the surface of easy damaged optical instrument.Knitting
Species is to be formed by coil clasp joint, is characterized in all having the biggest extensional performance in any direction of plane, fabric
Space is relatively big, and knitting species Wiping material is the thickest, loose, soft, good water absorption, but knitted fabric easily falls hair, thus makes
Become the pollution again being wiped article.Non-woven dry goods Wiping material many employings chemical adhesion, heat bonding, acupuncture, spun lacing or wet method
Form etc. processes.Owing to non-woven material has special three dimensional structure, between fiber, leave bigger hole, therefore such
The structure of Wiping material is more loose, and the scope of thickness is big, adapts to different purposes.By chemical adhesion reinforce non-woven
Cloth, the binding agent of surface cure may make to be wiped article surface damage, also can bring problem of environmental pollution in the course of processing.Stationery
The general wood pulp using good hygroscopicity, is made by paper technology.Structure loosely, thin and strength the most relatively low, the wettest by force
Power is relatively low, and flexible towelette is usually present bits phenomenon.Complex class Wiping material is typically to certain special purposes or performance
Improvement, the Material cladding of two or more different structure form.Good water absorption, but poor durability.
Summary of the invention
The technical problem to be solved: poor for Wiping material water absorption, dirt-removing power is weak, wears no resistance, clearly
Clean halfway drawback, it is provided that china-hemp fibers soda boiling is first carried out degumming by one, obtains degumming flax fiber, then takes natural silk degumming
After drying, it is dissolved in lithium-bromide solution, mixes with PLA solution after lysate is concentrated, Static Spinning after microwave treatment
Silk obtains fibroin/PLA Composite Fiber, is mixed with degumming flax fiber by composite fibre, then sprays surfactant solution
Carrying out being twisted blended yarns, be woven into grey cloth, sizing cutting prepares the method for easy cleaning height water suction Wiping material.Prepared by the present invention
Step is simple, and products obtained therefrom is easy to clean, and water absorption rate is high；Make full use of degumming china-hemp fibers composite silk albumen/polylactic acid to be combined
Fiber prepares Wiping material, strong not only for property, efficiently solves its dirt-removing power weak, and wear no resistance problem, and has anti-
Bacterium property is good, excellent in mechanical performance, and pollutant holding capability is high.
For solving above-mentioned technical problem, the present invention uses the technical scheme as described below to be:
(1) weigh 50～70g china-hemp fibers, by solid-to-liquid ratio 1:10, be added in mass fraction 5% sodium hydroxide solution, stirring
After mixing, add sodium hydroxide solution volume 10～the mixing of 15% mass fraction 1% sodium sulfide solution, be heated to 90～100 DEG C, boil
After system 2～4h, filter to obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, 60～70 DEG C of temperature
Under be dried 6～8h, i.e. can get degumming flax fiber, standby；
(2) weigh 5～10g silkworm silks, by solid-to-liquid ratio 1:15, it is mixed with mass fraction 5% sodium hydroxide solution, be heated to boiling
Rise, after boiling 20～30min, filter to obtain boiled silk albumen, rinse after 3～5 times with deionization, put in baking oven, 50～
It is dried 5～7h at a temperature of 60 DEG C, obtains solids, by solid-to-liquid ratio 1:6, add it in mass fraction 15% lithium-bromide solution,
Stir at a temperature of 50～60 DEG C and be completely dissolved to solids, lysate is evaporated to original volume 10～20%, obtains fibroin
Concentrated solution；
(3) weigh 20～30g polylactic acid, by solid-to-liquid ratio 1:12, be added in hexafluoroisopropanol, stir at a temperature of 50～70 DEG C
Mix and dissolve to polylactic acid, obtain PLA solution, by fibroin concentrated solution obtained above and PLA solution by volume 1:
After 10 mix and blends 10～15min, microwave treatment 3～5min under 180～220W power, obtain spinning liquid, use electrostatic spinning,
Being 15～20kV at voltage, accepting distance is 10～20cm, and wire netting is as carrying out spinning under conditions of receiving screen, the most available
Fibroin/PLA Composite Fiber；
(4) by degumming flax fiber standby to the fibroin/PLA Composite Fiber of above-mentioned preparation and step (1), by quality
Mixing than 1:1, obtaining fibre fineness is 150～180 μm composite fibre, uniformly sprays mass fraction 1,0%0 on composite fibre surface
Dialkyl benzene sulfonic acids sodium solution, makes composite fibre humidity reach 40～50%, is twisted blended yarns subsequently, is used by blended yarns double
Face is knitting, and to cause density be 80～120g/m2Grey cloth, shaped, cut, i.e. can get easy cleaning height water suction Wiping material.
The easy cleaning height water suction Wiping material density that the present invention prepares is 80～120g/m2, water absorption rate reaches more than 89.2%,
Percentage reduction of area is 20～22%, and fracture strength is 5.12～5.68cN/dtex, and elongation at break is 28.32～31.26%, wipes
Wiping performance and reach Pyatyi, bending rigidity is 880～1220m N, and pollutant holding capability is the 150～220% of deadweight, and antibiotic property reaches 75%
Above.
The present invention is compared with additive method, and Advantageous Effects is:
(1) preparation process of the present invention is simple, and products obtained therefrom is easy to clean, and water absorption rate is high；
(2) make full use of degumming china-hemp fibers composite silk albumen/PLA Composite Fiber and prepare Wiping material, with strong points,
It is effectively increased its dirt-removing power and wearability；
(3) present invention prepares Wiping material, has good antibiotic property, the good and high pollutant holding capability of mechanical property.
Detailed description of the invention
First weigh 50～70g china-hemp fibers, by solid-to-liquid ratio 1:10, be added into mass fraction 5% sodium hydroxide solution
In, stirring mixing after, add sodium hydroxide solution volume 10～15% mass fraction 1% sodium sulfide solution mixing, be heated to 90～
100 DEG C, after boiling 2～4h, filter to obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, 60～
It is dried 6～8h at a temperature of 70 DEG C, i.e. can get degumming flax fiber, standby；Weigh 5～10g silkworm silks again, by solid-to-liquid ratio 1:15,
It is mixed with mass fraction 5% sodium hydroxide solution, is heated to boiling, after boiling 20～30min, filters to obtain boiled silk egg
In vain, after rinsing 3～5 times with deionization, put in baking oven, at a temperature of 50～60 DEG C, be dried 5～7h, obtain solids, by solid-liquid
Ratio 1:6, adds it in mass fraction 15% lithium-bromide solution, stirs to solids and be completely dissolved at a temperature of 50～60 DEG C,
Lysate is evaporated to original volume 10～20%, obtains fibroin concentrated solution；Then 20～30g polylactic acid are weighed, by solid-liquid
Ratio 1:12, is added in hexafluoroisopropanol, stirs and dissolves to polylactic acid, obtain PLA solution at a temperature of 50～70 DEG C, will
After fibroin concentrated solution obtained above and PLA solution 1:10 mix and blend 10～15min by volume, 180～
Microwave treatment 3～5min under 220W power, obtain spinning liquid, use electrostatic spinning, are 15～20kV at voltage, and accepting distance is 10
～20cm, wire netting, as carrying out spinning under conditions of receiving screen, i.e. can get fibroin/PLA Composite Fiber；Finally
By degumming flax fiber standby to the fibroin/PLA Composite Fiber of above-mentioned preparation and step, 1:1 in mass ratio mixes,
Obtaining fibre fineness is 150～180 μm composite fibre, uniformly sprays mass fraction 10% detergent alkylate sulphur on composite fibre surface
Acid sodium solution, makes composite fibre humidity reach 40～50%, is twisted blended yarns subsequently, and blended yarns uses two-sided knitting cause
Density is 80～120g/m2Grey cloth, shaped, cut, i.e. can get easy cleaning height water suction Wiping material.
Example 1
First weighing 50g china-hemp fibers, by solid-to-liquid ratio 1:10, be added in mass fraction 5% sodium hydroxide solution, stirring is mixed
After conjunction, add the mixing of sodium hydroxide solution volume 10% mass fraction 1% sodium sulfide solution, be heated to 90 DEG C, after boiling 2h, filter
Obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, at a temperature of 60 DEG C, be dried 6h, the most available
Degumming flax fiber, standby；Weigh 5g silkworm silk again, by solid-to-liquid ratio 1:15, it mixed with mass fraction 5% sodium hydroxide solution,
It is heated to boiling, after boiling 20min, filters to obtain boiled silk albumen, after rinsing 3 times with deionization, put in baking oven, at 50 DEG C
At a temperature of be dried 5h, obtain solids, by solid-to-liquid ratio 1:6, add it in mass fraction 15% lithium-bromide solution, 50 DEG C of temperature
The lower stirring of degree is completely dissolved to solids, lysate is evaporated to original volume 10%, obtains fibroin concentrated solution；Then claim
Take 20g polylactic acid, by solid-to-liquid ratio 1:12, be added in hexafluoroisopropanol, stir at a temperature of 50 DEG C and dissolve to polylactic acid, obtain
PLA solution, after fibroin concentrated solution obtained above and PLA solution 1:10 mix and blend 10min by volume,
Microwave treatment 3min under 180W power, obtains spinning liquid, uses electrostatic spinning, is 15kV at voltage, accepts distance for 10cm, gold
Genus net, as carrying out spinning under conditions of receiving screen, i.e. can get fibroin/PLA Composite Fiber；Finally by above-mentioned preparation
Fibroin/PLA Composite Fiber and the standby degumming flax fiber of step, 1:1 in mass ratio mixes, obtains fibre fineness
It is 150 μm composite fibre, uniformly sprays mass fraction 10% dodecylbenzene sodium sulfonate solution on composite fibre surface, make mixing
Fibre moisture reaches 40%, is twisted blended yarns subsequently, and blended yarns uses two-sided knitting to cause density be 80g/m2Grey cloth,
Shaped, cut, i.e. be can get easy cleaning height water suction Wiping material.Preparation process of the present invention is simple, and products obtained therefrom is easy to clean,
Water absorption rate is high；Make full use of degumming china-hemp fibers composite silk albumen/PLA Composite Fiber and prepare Wiping material, specific aim
By force, its dirt-removing power and wearability it are effectively increased；The easy cleaning height water suction Wiping material density prepared is 80g/m2, water absorption rate
Reaching 89.6%, percentage reduction of area is 20%, and fracture strength is 5.12cN/dtex, and elongation at break is 28.32%, and wiping properties reaches
Pyatyi, bending rigidity is 880m N, and pollutant holding capability is the 150% of deadweight, and antibiotic property reaches 78%.
Example 2
First weighing 60g china-hemp fibers, by solid-to-liquid ratio 1:10, be added in mass fraction 5% sodium hydroxide solution, stirring is mixed
After conjunction, add the mixing of sodium hydroxide solution volume 13% mass fraction 1% sodium sulfide solution, be heated to 95 DEG C, after boiling 3h, filter
Obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, at a temperature of 65 DEG C, be dried 7h, the most available
Degumming flax fiber, standby；Weigh 8g silkworm silk again, by solid-to-liquid ratio 1:15, it mixed with mass fraction 5% sodium hydroxide solution,
It is heated to boiling, after boiling 25min, filters to obtain boiled silk albumen, after rinsing 4 times with deionization, put in baking oven, at 55 DEG C
At a temperature of be dried 6h, obtain solids, by solid-to-liquid ratio 1:6, add it in mass fraction 15% lithium-bromide solution, 55 DEG C of temperature
The lower stirring of degree is completely dissolved to solids, lysate is evaporated to original volume 15%, obtains fibroin concentrated solution；Then claim
Take 25g polylactic acid, by solid-to-liquid ratio 1:12, be added in hexafluoroisopropanol, stir at a temperature of 60 DEG C and dissolve to polylactic acid, obtain
PLA solution, after fibroin concentrated solution obtained above and PLA solution 1:10 mix and blend 13min by volume,
Microwave treatment 4min under 200W power, obtains spinning liquid, uses electrostatic spinning, is 18kV at voltage, accepts distance for 15cm, gold
Genus net, as carrying out spinning under conditions of receiving screen, i.e. can get fibroin/PLA Composite Fiber；Finally by above-mentioned preparation
Fibroin/PLA Composite Fiber and the standby degumming flax fiber of step, 1:1 in mass ratio mixes, obtains fibre fineness
It is 165 μm composite fibre, uniformly sprays mass fraction 10% dodecylbenzene sodium sulfonate solution on composite fibre surface, make mixing
Fibre moisture reaches 45%, is twisted blended yarns subsequently, and blended yarns uses two-sided knitting to cause density be 100g/m2Grey cloth,
Shaped, cut, i.e. be can get easy cleaning height water suction Wiping material.Preparation process of the present invention is simple, and products obtained therefrom is easy to clean,
Water absorption rate is high；Make full use of degumming china-hemp fibers composite silk albumen/PLA Composite Fiber and prepare Wiping material, specific aim
By force, its dirt-removing power and wearability it are effectively increased；The easy cleaning height water suction Wiping material density prepared is 100g/m2, water suction
Rate reaches 90.4%, and percentage reduction of area is 21%, and fracture strength is 5.40cN/dtex, and elongation at break is 29.79%, and wiping properties reaches
To Pyatyi, bending rigidity is 1050m N, and pollutant holding capability is the 185% of deadweight, and antibiotic property reaches 80%.
Example 3
First weighing 70g china-hemp fibers, by solid-to-liquid ratio 1:10, be added in mass fraction 5% sodium hydroxide solution, stirring is mixed
After conjunction, add the mixing of sodium hydroxide solution volume 15% mass fraction 1% sodium sulfide solution, be heated to 100 DEG C, after boiling 4h, mistake
Filter to obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, at a temperature of 70 DEG C, be dried 8h,
To degumming flax fiber, standby；Weigh 10g silkworm silk again, by solid-to-liquid ratio 1:15, it is mixed with mass fraction 5% sodium hydroxide solution
Close, be heated to boiling, after boiling 30min, filter to obtain boiled silk albumen, after rinsing 5 times with deionization, put in baking oven,
It is dried 7h at a temperature of 60 DEG C, obtains solids, by solid-to-liquid ratio 1:6, add it in mass fraction 15% lithium-bromide solution, 60
Stir at a temperature of DEG C and be completely dissolved to solids, lysate is evaporated to original volume 20%, obtain fibroin concentrated solution；So
After weigh 30g polylactic acid, by solid-to-liquid ratio 1:12, be added in hexafluoroisopropanol, stir to polylactic acid molten at a temperature of 70 DEG C
Solve, obtain PLA solution, by fibroin concentrated solution obtained above and PLA solution 1:10 mix and blend by volume
After 15min, microwave treatment 5min under 220W power, obtain spinning liquid, use electrostatic spinning, be 20kV at voltage, accept distance
For 20cm, wire netting, as carrying out spinning under conditions of receiving screen, i.e. can get fibroin/PLA Composite Fiber；Finally
By degumming flax fiber standby to the fibroin/PLA Composite Fiber of above-mentioned preparation and step, 1:1 in mass ratio mixes,
Obtaining fibre fineness is 180 μm composite fibre, uniformly sprays mass fraction 10% dodecylbenzene sodium sulfonate on composite fibre surface molten
Liquid, makes composite fibre humidity reach 50%, is twisted blended yarns subsequently, and blended yarns uses two-sided knitting to cause density be 120g/
m2Grey cloth, shaped, cut, i.e. can get easy cleaning height water suction Wiping material.Preparation process of the present invention is simple, and gained produces
Product are easy to clean, and water absorption rate is high；Make full use of degumming china-hemp fibers composite silk albumen/PLA Composite Fiber and prepare wiping material
Material, with strong points, it is effectively increased its dirt-removing power and wearability；The easy cleaning height water suction Wiping material density prepared is
120g/m2, water absorption rate reaches 91.3%, and percentage reduction of area is 22%, and fracture strength is 5.68cN/dtex, and elongation at break is
31.26%, wiping properties reaches Pyatyi, and bending rigidity is 1220m N, and pollutant holding capability is the 220% of deadweight, and antibiotic property reaches 82%.
Claims (1)
1. the preparation method of kind of easy cleaning height water suction Wiping material, it is characterised in that concrete preparation process is:
(1) weigh 50～70g china-hemp fibers, by solid-to-liquid ratio 1:10, be added in mass fraction 5% sodium hydroxide solution, stirring
After mixing, add sodium hydroxide solution volume 10～the mixing of 15% mass fraction 1% sodium sulfide solution, be heated to 90～100 DEG C, boil
After system 2～4h, filter to obtain filtering residue, be washed with deionized after being neutrality to cleaning mixture, put in baking oven, 60～70 DEG C of temperature
Under be dried 6～8h, i.e. can get degumming flax fiber, standby；
(2) weigh 5～10g silkworm silks, by solid-to-liquid ratio 1:15, it is mixed with mass fraction 5% sodium hydroxide solution, be heated to boiling
Rise, after boiling 20～30min, filter to obtain boiled silk albumen, rinse after 3～5 times with deionization, put in baking oven, 50～
It is dried 5～7h at a temperature of 60 DEG C, obtains solids, by solid-to-liquid ratio 1:6, add it in mass fraction 15% lithium-bromide solution,
Stir at a temperature of 50～60 DEG C and be completely dissolved to solids, lysate is evaporated to original volume 10～20%, obtains fibroin
Concentrated solution；
(3) weigh 20～30g polylactic acid, by solid-to-liquid ratio 1:12, be added in hexafluoroisopropanol, stir at a temperature of 50～70 DEG C
Mix and dissolve to polylactic acid, obtain PLA solution, by fibroin concentrated solution obtained above and PLA solution by volume 1:
After 10 mix and blends 10～15min, microwave treatment 3～5min under 180～220W power, obtain spinning liquid, use electrostatic spinning,
Being 15～20kV at voltage, accepting distance is 10～20cm, and wire netting is as carrying out spinning under conditions of receiving screen, the most available
Fibroin/PLA Composite Fiber；
(4) by degumming flax fiber standby to the fibroin/PLA Composite Fiber of above-mentioned preparation and step (1), by quality
Mixing than 1:1, obtaining fibre fineness is 150～180 μm composite fibre, uniformly sprays mass fraction 1,0%0 on composite fibre surface
Dialkyl benzene sulfonic acids sodium solution, makes composite fibre humidity reach 40～50%, is twisted blended yarns subsequently, is used by blended yarns double
Face is knitting, and to cause density be 80～120g/m2Grey cloth, shaped, cut, i.e. can get easy cleaning height water suction Wiping material.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108588852A (en) * | 2018-03-20 | 2018-09-28 | 青岛大学 | A kind of method of high lignin raw material cleaning degumming |
| CN110241508A (en) * | 2019-05-30 | 2019-09-17 | 秦月 | A kind of preparation method of the antistatic Wiping material of high water absorption |
| CN114059208A (en) * | 2020-07-30 | 2022-02-18 | 湖南科力嘉纺织股份有限公司 | Easy abluent yarn for weaving |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010077423A (en) * | 2000-02-01 | 2001-08-20 | 방윤혁 | Method of manufacturing a regenerated cellulose fiber from the rice straw |
| US20060257616A1 (en) * | 2005-05-12 | 2006-11-16 | Stowe-Pharr Mills, Inc. (D/B/A Pharr Yarns, Inc.) | Renewable nonwoven carpet |
| CN101418472A (en) * | 2008-11-17 | 2009-04-29 | 苏州大学 | Spider silk protein/polylactic acid composite nano fibre yarn and preparation method thereof |
| CN101550653A (en) * | 2009-05-16 | 2009-10-07 | 太原理工大学 | Hemp fiber degumming boiling-off additive and preparing method thereof |
| CN104998163A (en) * | 2015-08-01 | 2015-10-28 | 张进 | Antibacterial wet tissue paper and manufacturing method thereof |
| CN105821584A (en) * | 2016-05-24 | 2016-08-03 | 无锡市长安曙光手套厂 | Wiping material and preparation method thereof |
-
2016
- 2016-08-16 CN CN201610672660.3A patent/CN106283208B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010077423A (en) * | 2000-02-01 | 2001-08-20 | 방윤혁 | Method of manufacturing a regenerated cellulose fiber from the rice straw |
| US20060257616A1 (en) * | 2005-05-12 | 2006-11-16 | Stowe-Pharr Mills, Inc. (D/B/A Pharr Yarns, Inc.) | Renewable nonwoven carpet |
| CN101418472A (en) * | 2008-11-17 | 2009-04-29 | 苏州大学 | Spider silk protein/polylactic acid composite nano fibre yarn and preparation method thereof |
| CN101550653A (en) * | 2009-05-16 | 2009-10-07 | 太原理工大学 | Hemp fiber degumming boiling-off additive and preparing method thereof |
| CN104998163A (en) * | 2015-08-01 | 2015-10-28 | 张进 | Antibacterial wet tissue paper and manufacturing method thereof |
| CN105821584A (en) * | 2016-05-24 | 2016-08-03 | 无锡市长安曙光手套厂 | Wiping material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108588852A (en) * | 2018-03-20 | 2018-09-28 | 青岛大学 | A kind of method of high lignin raw material cleaning degumming |
| CN108588852B (en) * | 2018-03-20 | 2020-08-18 | 青岛大学 | Method for cleaning and degumming high-lignin raw material |
| CN110241508A (en) * | 2019-05-30 | 2019-09-17 | 秦月 | A kind of preparation method of the antistatic Wiping material of high water absorption |
| CN114059208A (en) * | 2020-07-30 | 2022-02-18 | 湖南科力嘉纺织股份有限公司 | Easy abluent yarn for weaving |
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