CN106283070A - A kind of spring steel surface corrosion inhibition treating agent - Google Patents

A kind of spring steel surface corrosion inhibition treating agent Download PDF

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Publication number
CN106283070A
CN106283070A CN201610683330.4A CN201610683330A CN106283070A CN 106283070 A CN106283070 A CN 106283070A CN 201610683330 A CN201610683330 A CN 201610683330A CN 106283070 A CN106283070 A CN 106283070A
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CN
China
Prior art keywords
parts
spring steel
oil
steel surface
phenolic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610683330.4A
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Chinese (zh)
Inventor
余昌国
李红杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Hongqiao Metal Manufacturing Co Ltd
Original Assignee
Anhui Hongqiao Metal Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Hongqiao Metal Manufacturing Co Ltd filed Critical Anhui Hongqiao Metal Manufacturing Co Ltd
Priority to CN201610683330.4A priority Critical patent/CN106283070A/en
Publication of CN106283070A publication Critical patent/CN106283070A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/173—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/12—Oxygen-containing compounds
    • C23F11/124—Carboxylic acids
    • C23F11/126—Aliphatic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/167—Phosphorus-containing compounds
    • C23F11/1673—Esters of phosphoric or thiophosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of spring steel surface corrosion inhibition treating agent, it is made by following raw material: 20 30 parts of salicyl benzoic acid, polyimides 15 20 parts, oil-soluble phenolic resin 15 20 parts, 15 20 parts of acetone, tributyl phosphate 15 20 parts, polyacrylamide 5 10 parts, polyaluminium chloride 5 10 parts, 10 20 parts of surfactant, stearic acid 0.02 0.4 parts；Instant invention overcomes the deficiencies in the prior art, it is possible to be effectively improved the antiseptic property on spring steel surface, environmental pollution is minimum, without compromising on health during use, and low cost, it is easy to promote.

Description

A kind of spring steel surface corrosion inhibition treating agent
Technical field
The present invention relates to spring steel material technical field of anticorrosion, specifically a kind of spring steel surface slow corrosion treatment Agent.
Background technology
The corrosion of spring steel is often there is during spring steel is processed and is used, so that spring steel material Or the service life of spring steel equipment reduce, and existing spring steel preservative exists that cost is high, raw material is because having toxicity Harm workman is healthy, pollute the problems such as environment, therefore, is badly in need of a kind of environmentally safe, does not damage person health Spring steel preservative.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of spring steel surface corrosion inhibition treating agent, overcome existing The deficiency of technology, it is possible to be effectively improved the antiseptic property of spring steel, environmental pollution is minimum, without compromising on human body during use Health, and low cost, it is easy to promote.
For realizing object above, the present invention is achieved by the following technical programs:
The invention provides a kind of spring steel surface corrosion inhibition treating agent, the raw material of following parts by weight be made: Salicyl benzoic acid 20-30 part, polyimides 15-20 part, oil-soluble phenolic resin 15-20 part, acetone 15-20 part, tricresyl phosphate Butyl ester 15-20 part, polyacrylamide 5-10 part, polyaluminium chloride 5-10 part, surfactant 10-20 part, stearic acid 0.02-0.4 Part.
Preferably, the raw material of following parts by weight it is made: salicyl benzoic acid 22-28 part, polyimides 16-19 Part, oil-soluble phenolic resin 16-18 part, acetone 15-20 part, tributyl phosphate 16-18 part, polyacrylamide 6-9 part is polychloride Aluminum 6-8 part, surfactant 12-16 part, stearic acid 0.1-0.3 part.
Preferably, the raw material of following parts by weight it is made: 22 parts of salicyl benzoic acid, polyimides 16 parts, oil 16 parts of dissolubility phenolic resin, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, polyaluminium chloride 6 parts, surfactant 12 parts, stearic acid 0.1 part.
Preferably, the raw material of following parts by weight it is made: 22 parts of salicyl benzoic acid, polyimides 16 parts, oil 16 parts of dissolubility phenolic resin, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, polyaluminium chloride 6 parts, surfactant 12 parts, stearic acid 0.1 part.
Preferably, described oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Preferably, described surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 Mixed material beneficial effects of the present invention.
The method have the benefit that
The present invention can effectively prevent the antiseptic property improving metal of metal, and environmental pollution is minimum, during use Without compromising on health, and low cost, it is easy to promote.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the enforcement of the present invention Example, is clearly and completely described the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection Scope.
Embodiment 1:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 20 parts, polyimides 15 parts, oil-soluble phenolic resin 15 parts, 15 parts of acetone, tributyl phosphate 15 parts, polyacrylamide 5 parts, poly- 5 parts of aluminum chloride, 10 parts of surfactant, stearic acid 0.02 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Embodiment 2:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 30 parts, polyimides 20 parts, oil-soluble phenolic resin 20 parts, 20 parts of acetone, tributyl phosphate 20 parts, polyacrylamide 10 parts, Polyaluminium chloride 10 parts, 20 parts of surfactant, stearic acid 0.4 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Embodiment 3:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 22 parts, polyimides 16 parts, oil-soluble phenolic resin 16 parts, 15 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, poly- 6 parts of aluminum chloride, 12 parts of surfactant, stearic acid 0.1 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Embodiment 4:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 28 parts, polyimides 19 parts, oil-soluble phenolic resin 18 parts, 20 parts of acetone, tributyl phosphate 18 parts, polyacrylamide 9 parts, poly- 8 parts of aluminum chloride, 16 parts of surfactant, stearic acid 0.3 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Embodiment 5:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 22 parts, polyimides 16 parts, oil-soluble phenolic resin 16 parts, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, poly- 6 parts of aluminum chloride, 12 parts of surfactant, stearic acid 0.1 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Embodiment 6:
A kind of spring steel surface corrosion inhibition treating agent, is made by the raw material of following parts by weight: salicyl benzoic acid 22 parts, polyimides 16 parts, oil-soluble phenolic resin 16 parts, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, poly- 6 parts of aluminum chloride, 12 parts of surfactant, stearic acid 0.1 part.
Wherein: oil-soluble phenolic resin is the oil-soluble phenolic resin of the short oil with dimethylbenzene as solvent.
Surfactant be sodium laurylsulfate with sodium lauryl sulphate weight ratio be 3:1 mixed material.
Above example only in order to technical scheme to be described, is not intended to limit；Although with reference to previous embodiment The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent；And these amendment or Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a spring steel surface corrosion inhibition treating agent, it is characterised in that be made by the raw material of following parts by weight: bigcatkin willow Yl benzoic acid 20-30 part, polyimides 15-20 part, oil-soluble phenolic resin 15-20 part, acetone 15-20 part, tributyl phosphate 15-20 part, polyacrylamide 5-10 part, polyaluminium chloride 5-10 part, surfactant 10-20 part, stearic acid 0.02-0.4 part.
2. spring steel surface as claimed in claim 1 corrosion inhibition treating agent, it is characterised in that by the raw material of following parts by weight It is made: salicyl benzoic acid 22-28 part, polyimides 16-19 part, oil-soluble phenolic resin 16-18 part, acetone 15-20 Part, tributyl phosphate 16-18 part, polyacrylamide 6-9 part, polyaluminium chloride 6-8 part, surfactant 12-16 part, stearic acid 0.1-0.3 part.
3. spring steel surface as claimed in claim 2 corrosion inhibition treating agent, it is characterised in that by the raw material of following parts by weight It is made: 22 parts of salicyl benzoic acid, polyimides 16 parts, oil-soluble phenolic resin 16 parts, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, polyaluminium chloride 6 parts, 12 parts of surfactant, stearic acid 0.1 part.
4. spring steel surface as claimed in claim 2 corrosion inhibition treating agent, it is characterised in that by the raw material of following parts by weight It is made: 22 parts of salicyl benzoic acid, polyimides 16 parts, oil-soluble phenolic resin 16 parts, 16 parts of acetone, tributyl phosphate 16 parts, polyacrylamide 6 parts, polyaluminium chloride 6 parts, 12 parts of surfactant, stearic acid 0.1 part.
5. spring steel surface as claimed in claim 1 corrosion inhibition treating agent, it is characterised in that described oil-soluble phenolic resin It it is the oil-soluble phenolic resin of short oil with dimethylbenzene as solvent.
6. spring steel surface as claimed in claim 1 corrosion inhibition treating agent, it is characterised in that described surfactant is the moon Lauryl sulfate and sodium lauryl sulphate weight ratio be 3:1 mixed material.
CN201610683330.4A 2016-08-17 2016-08-17 A kind of spring steel surface corrosion inhibition treating agent Pending CN106283070A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610683330.4A CN106283070A (en) 2016-08-17 2016-08-17 A kind of spring steel surface corrosion inhibition treating agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610683330.4A CN106283070A (en) 2016-08-17 2016-08-17 A kind of spring steel surface corrosion inhibition treating agent

Publications (1)

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CN106283070A true CN106283070A (en) 2017-01-04

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5891174A (en) * 1981-11-21 1983-05-31 Seiwa Kogyo Kk Rust preventive material for brine of inorganic salt
CN103740159A (en) * 2013-12-10 2014-04-23 王刚 Metallic paint preservative
CN104559611A (en) * 2014-12-05 2015-04-29 东来涂料技术（上海）有限公司 Easy-to-clean fluorocarbon paint and preparation method thereof
CN105350002A (en) * 2015-11-25 2016-02-24 安徽红桥金属制造有限公司 Corrosion-inhibiting treatment agent for metal part and application thereof
CN105506654A (en) * 2015-12-31 2016-04-20 安徽红桥金属制造有限公司 Derusting processing process of spring steel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5891174A (en) * 1981-11-21 1983-05-31 Seiwa Kogyo Kk Rust preventive material for brine of inorganic salt
CN103740159A (en) * 2013-12-10 2014-04-23 王刚 Metallic paint preservative
CN104559611A (en) * 2014-12-05 2015-04-29 东来涂料技术（上海）有限公司 Easy-to-clean fluorocarbon paint and preparation method thereof
CN105350002A (en) * 2015-11-25 2016-02-24 安徽红桥金属制造有限公司 Corrosion-inhibiting treatment agent for metal part and application thereof
CN105506654A (en) * 2015-12-31 2016-04-20 安徽红桥金属制造有限公司 Derusting processing process of spring steel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
魏星跃 等: "《应用化学专业实验》", 30 April 2016, 西安交通大学出版社 *

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Application publication date: 20170104

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