CN106280285A - A kind of flame retardant type glass flake plasticine - Google Patents
A kind of flame retardant type glass flake plasticine Download PDFInfo
- Publication number
- CN106280285A CN106280285A CN201610767555.8A CN201610767555A CN106280285A CN 106280285 A CN106280285 A CN 106280285A CN 201610767555 A CN201610767555 A CN 201610767555A CN 106280285 A CN106280285 A CN 106280285A
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- Prior art keywords
- glass flake
- flame retardant
- retardant type
- type glass
- flake plasticine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of flame retardant type glass flake plasticine, its raw material is as follows: flame retardant type epoxy vinyl ester resin 20 25 parts, glass flake 10 15 parts, 58 parts of firming agent, fire retardant 10 13 parts, carbon forming agent 58 parts, fire resistance fibre 23 parts, binding agent 12 parts.The present invention is compared with Conventional glass flake mortar, and mechanical property and the heat resistance of anti-flammability glass flake plasticine are constant, but oxygen index (OI) improves, and flame propagation velocity is slack-off, has self-extinguishment.
Description
Technical field
The present invention relates to glass flake plasticine technical field, be specially a kind of flame retardant type glass flake plasticine.
Background technology
Occur repeatedly in the phenomenon built or be burned off by glass flakes anticorrosion in built power plant's absorption tower antiseptic project.
Outwardly, cause due to administrative reasons such as crossed constructions.Essential problem is that glass flake plasticine does not has fire resistance,
Oxygen index (OI) is too low, and burning velocity is too fast, and once overdoing does not has self-extinguishment, easily causes large area to overdo, and causes and focuses on safe thing
Therefore.
The matrix resin of current glass flake plasticine is commonly used vinyl ester resin and is had superior corrosion resistance, and good
Manufacturability.In addition to resin, glass flake, firming agent, accelerator, pigment and function additive etc. are the required of glass flake plasticine
Component.Flat scale is overlapping arranged in parallel in resin, interlocks up and down, forms unique shielding construction.Be widely used in acid,
The various chemical attack medium such as alkali, salt.This product can be used for desulphurization plant, inner wall of stack, pasted with ceramic veneer sheet, ceramic foam vitreous
Brick.
Flame retardant type glass flake plasticine is the fire-retardant upgrade version on the basis of Conventional glass flake mortar, with Conventional glass
Flake mortar is compared, and mechanical property and the heat resistance of anti-flammability glass flake plasticine are constant, but oxygen index (OI) improves, and flame passes
Broadcast and slow, there is self-extinguishment.
Summary of the invention
It is an object of the invention to provide a kind of flame retardant type glass flake plasticine, to solve proposition in above-mentioned background technology
Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of flame retardant type glass flake plasticine, its raw material is as follows: flame retardant type epoxy vinyl ester resin 20-25
Part, glass flake 10-15 part, firming agent 5-8 part, fire retardant 10-13 part, carbon forming agent 5-8 part, fire resistance fibre 2-3 part, binding agent
1-2 part.
Preferably, described binding agent is celluloid.
Preferably, described firming agent is that methyl ethyl ketone peroxide forms than for 2:1 proportioning according to composition by weight with cobalt octoate liquid.
Preferably, described carbon forming agent is corn starch, and powder particle mesh number is between 800-1000.
Preferably, described fire retardant is that magnesium hydroxide forms than for 1:1 proportioning according to composition by weight with aluminium hydroxide, and all
For powder, powder mesh number is between 700-900.
Preferably, described fire resistance fibre is TDE fire-retardant high-strength polyvinyl.
Preferably, described binding agent is polyvinyl alcohol.
Preferably, described anti-flammability glass flake plasticine reaches B1 level, leading indicator: burn rate: 21W/S, oxygen index (OI):
31.7, tensile strength: 26MPa, comprcssive strength: 86MPa, bending strength 42MPa, impact strength 1.5MPa.
Preferably, the production equipment of described glass flake plasticine is evacuation five axle planet homogenizer.
Compared with prior art, the invention has the beneficial effects as follows: the present invention compared with Conventional glass flake mortar, anti-flammability
Mechanical property and the heat resistance of glass flake plasticine are constant, but oxygen index (OI) improves, and flame propagation velocity is slack-off, has self-extinguishment
Property.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, not
For limiting the present invention.
Embodiment 1
A kind of flame retardant type glass flake plasticine, its raw material is as follows: flame retardant type epoxy vinyl ester resin 20 parts,
Glass flake 10 parts, 5 parts of firming agent, fire retardant 10 parts, carbon forming agent 5 parts, fire resistance fibre 2 parts, binding agent 1 part.
Described binding agent is celluloid.
Described firming agent is that methyl ethyl ketone peroxide forms than for 2:1 proportioning according to composition by weight with cobalt octoate liquid.
Described carbon forming agent is corn starch, and powder particle mesh number is between 800-1000.
Described fire retardant is that magnesium hydroxide forms than for 1:1 proportioning according to composition by weight with aluminium hydroxide, and is powder
Shape, powder mesh number is between 700-900.
Described fire resistance fibre is TDE fire-retardant high-strength polyvinyl.
Described binding agent is polyvinyl alcohol.
Described anti-flammability glass flake plasticine reaches B1 level, leading indicator: burn rate: 21W/S, oxygen index (OI): 31.7, anti-
Tensile strength: 26MPa, comprcssive strength: 86MPa, bending strength 42MPa, impact strength 1.5MPa.
The production equipment of described glass flake plasticine is evacuation five axle planet homogenizer.
Embodiment 2
A kind of flame retardant type glass flake plasticine, its raw material is as follows: flame retardant type epoxy vinyl ester resin 23 parts,
Glass flake 13 parts, 6 parts of firming agent, fire retardant 12 parts, carbon forming agent 6 parts, fire resistance fibre 2.5 parts, binding agent 1.5 parts.
Described binding agent is celluloid.
Described firming agent is that methyl ethyl ketone peroxide forms than for 2:1 proportioning according to composition by weight with cobalt octoate liquid.
Described carbon forming agent is corn starch, and powder particle mesh number is between 800-1000.
Described fire retardant is that magnesium hydroxide forms than for 1:1 proportioning according to composition by weight with aluminium hydroxide, and is powder
Shape, powder mesh number is between 700-900.
Described fire resistance fibre is TDE fire-retardant high-strength polyvinyl.
Described binding agent is polyvinyl alcohol.
Described anti-flammability glass flake plasticine reaches B1 level, leading indicator: burn rate: 21W/S, oxygen index (OI): 31.7, anti-
Tensile strength: 26MPa, comprcssive strength: 86MPa, bending strength 42MPa, impact strength 1.5MPa.
The production equipment of described glass flake plasticine is evacuation five axle planet homogenizer.
Embodiment 3
A kind of flame retardant type glass flake plasticine, its raw material is as follows: flame retardant type epoxy vinyl ester resin 25 parts,
Glass flake 15 parts, 8 parts of firming agent, fire retardant 13 parts, carbon forming agent 8 parts, fire resistance fibre 3 parts, binding agent 2 parts.
Described binding agent is celluloid.
Described firming agent is that methyl ethyl ketone peroxide forms than for 2:1 proportioning according to composition by weight with cobalt octoate liquid.
Described carbon forming agent is corn starch, and powder particle mesh number is between 800-1000.
Described fire retardant is that magnesium hydroxide forms than for 1:1 proportioning according to composition by weight with aluminium hydroxide, and is powder
Shape, powder mesh number is between 700-900.
Described fire resistance fibre is TDE fire-retardant high-strength polyvinyl.
Described binding agent is polyvinyl alcohol.
Described anti-flammability glass flake plasticine reaches B1 level, leading indicator: burn rate: 21W/S, oxygen index (OI): 31.7, anti-
Tensile strength: 26MPa, comprcssive strength: 86MPa, bending strength 42MPa, impact strength 1.5MPa.
The production equipment of described glass flake plasticine is evacuation five axle planet homogenizer.
The present invention is compared with Conventional glass flake mortar, and the mechanical property of anti-flammability glass flake plasticine and heat resistance are not
Becoming, but oxygen index (OI) improves, flame propagation velocity is slack-off, has self-extinguishment.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (9)
1. a flame retardant type glass flake plasticine, it is characterised in that: its raw material is as follows: flame retardant type epoxy vinyl ester
Resin 20-25 part, glass flake 10-15 part, firming agent 5-8 part, fire retardant 10-13 part, carbon forming agent 5-8 part, fire resistance fibre 2-3
Part, binding agent 1-2 part.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described binding agent is that nitric acid is fine
Dimension element.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described firming agent is peroxidating
Butanone forms than for 2:1 proportioning according to composition by weight with cobalt octoate liquid.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described carbon forming agent is that Semen Maydis forms sediment
Powder, and powder particle mesh number is between 800-1000.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described fire retardant is hydroxide
Magnesium forms than for 1:1 proportioning according to composition by weight with aluminium hydroxide, and is powder, and powder mesh number is between 700-900.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described fire resistance fibre is ten bromines
Diphenylethane fire-retardant high-strength polyvinyl.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described binding agent is polyethylene
Alcohol.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described anti-flammability glass flake
Clay reaches B1 level, leading indicator: burn rate: 21W/S, oxygen index (OI): 31.7, tensile strength: 26MPa, comprcssive strength:
86MPa, bending strength 42MPa, impact strength 1.5MPa.
A kind of flame retardant type glass flake plasticine the most according to claim 1, it is characterised in that: described glass flake plasticine
Production equipment is evacuation five axle planet homogenizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767555.8A CN106280285B (en) | 2016-08-30 | 2016-08-30 | A kind of flame retardant type glass flake plasticine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767555.8A CN106280285B (en) | 2016-08-30 | 2016-08-30 | A kind of flame retardant type glass flake plasticine |
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| Publication Number | Publication Date |
|---|---|
| CN106280285A true CN106280285A (en) | 2017-01-04 |
| CN106280285B CN106280285B (en) | 2019-01-15 |
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|---|---|---|---|
| CN201610767555.8A Active CN106280285B (en) | 2016-08-30 | 2016-08-30 | A kind of flame retardant type glass flake plasticine |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057514A (en) * | 2017-05-03 | 2017-08-18 | 成都龙之泉科技股份有限公司 | One kind is used for heat-engine plant desulfurized corrosion-resistant flame retardant type glass flake plasticine and preparation method thereof |
| CN107488332A (en) * | 2017-09-08 | 2017-12-19 | 绵阳凤面科技有限公司 | A kind of flame retardant type glass flake plasticine |
| CN107880740A (en) * | 2017-12-01 | 2018-04-06 | 武汉博奇玉宇环保股份有限公司 | Anti-flammability glass flake plasticine and preparation method thereof |
| CN110028878A (en) * | 2019-05-21 | 2019-07-19 | 河南省华昌高新技术有限公司 | A kind of fireproof glass flake mortar and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1786093A (en) * | 2005-11-30 | 2006-06-14 | 北京北航天汇科技孵化器有限公司 | Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method |
| CN102060472A (en) * | 2010-11-16 | 2011-05-18 | 昆明永瑞防腐有限公司 | High-temperature resistant anti-corrosion clay special for acid pressure oxidative leaching high-pressure autoclave and preparation method thereof |
| CN102533043A (en) * | 2010-12-10 | 2012-07-04 | 深圳市嘉达高科产业发展有限公司 | Anticorrosive inflaming retarding epoxy glass scale paint |
| CN103013054A (en) * | 2011-09-27 | 2013-04-03 | 上海机电工程研究所 | Anti-burning type epoxy vinyl ester resin and preparation method thereof |
| CN104710938A (en) * | 2013-12-17 | 2015-06-17 | 中远关西涂料化工（天津）有限公司 | Vinyl glass flake coating applied to high temperature resistant strong acid occasions and preparation method thereof |
-
2016
- 2016-08-30 CN CN201610767555.8A patent/CN106280285B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1786093A (en) * | 2005-11-30 | 2006-06-14 | 北京北航天汇科技孵化器有限公司 | Expansion type fire retarding epoxide resin powder paint suitable for steel structure and its preparation method |
| CN102060472A (en) * | 2010-11-16 | 2011-05-18 | 昆明永瑞防腐有限公司 | High-temperature resistant anti-corrosion clay special for acid pressure oxidative leaching high-pressure autoclave and preparation method thereof |
| CN102533043A (en) * | 2010-12-10 | 2012-07-04 | 深圳市嘉达高科产业发展有限公司 | Anticorrosive inflaming retarding epoxy glass scale paint |
| CN103013054A (en) * | 2011-09-27 | 2013-04-03 | 上海机电工程研究所 | Anti-burning type epoxy vinyl ester resin and preparation method thereof |
| CN104710938A (en) * | 2013-12-17 | 2015-06-17 | 中远关西涂料化工（天津）有限公司 | Vinyl glass flake coating applied to high temperature resistant strong acid occasions and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057514A (en) * | 2017-05-03 | 2017-08-18 | 成都龙之泉科技股份有限公司 | One kind is used for heat-engine plant desulfurized corrosion-resistant flame retardant type glass flake plasticine and preparation method thereof |
| CN107488332A (en) * | 2017-09-08 | 2017-12-19 | 绵阳凤面科技有限公司 | A kind of flame retardant type glass flake plasticine |
| CN107880740A (en) * | 2017-12-01 | 2018-04-06 | 武汉博奇玉宇环保股份有限公司 | Anti-flammability glass flake plasticine and preparation method thereof |
| CN110028878A (en) * | 2019-05-21 | 2019-07-19 | 河南省华昌高新技术有限公司 | A kind of fireproof glass flake mortar and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106280285B (en) | 2019-01-15 |
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