CN106280035A - The formula of high transparency rubber sole and preparation method - Google Patents
The formula of high transparency rubber sole and preparation method Download PDFInfo
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- CN106280035A CN106280035A CN201610757721.6A CN201610757721A CN106280035A CN 106280035 A CN106280035 A CN 106280035A CN 201610757721 A CN201610757721 A CN 201610757721A CN 106280035 A CN106280035 A CN 106280035A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 39
- 239000005060 rubber Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000006229 carbon black Substances 0.000 claims abstract description 14
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 13
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 13
- 239000002250 absorbent Substances 0.000 claims abstract description 12
- 230000002745 absorbent Effects 0.000 claims abstract description 12
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007822 coupling agent Substances 0.000 claims abstract description 11
- 229940125725 tranquilizer Drugs 0.000 claims abstract description 11
- 239000003204 tranquilizing agent Substances 0.000 claims abstract description 11
- 230000002936 tranquilizing effect Effects 0.000 claims abstract description 11
- 230000003213 activating effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 238000006396 nitration reaction Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 2
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical group CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 claims 1
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 claims 1
- 239000012965 benzophenone Substances 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 238000004383 yellowing Methods 0.000 abstract description 3
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 6
- 239000004568 cement Substances 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229950002083 octabenzone Drugs 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Disclosed by the invention is formula and the preparation method of a kind of high transparency rubber sole, its feature is made up of following raw material in parts by weight: solution polymerized butadiene styrene rubber 10～30 parts, butadiene rubber 20～60 parts, ethylene propylene diene rubber 30～70 parts, coupling agent 1.0～2.0 parts, antioxidant 0.5～2.0 parts, UV absorbent 0.5～2.0 parts, anhydrous White Carbon black 30.0～40.0 parts, activating agent 0.3～2.0 parts, tranquilizer 0.2～0.4 part, white oil 20.0～30.0 parts, vulcanizing agent 0.5～1.5 parts.Present invention discover that use ethylene propylene diene rubber can significantly improve, the anti-yellowing property of high transparency rubber sole, but owing to the half finished rubber cohesive of ethylene propylene diene rubber is poor, need and improve half finished rubber cohesive with butadiene rubber and butadiene-styrene rubber.Find to use ethylene propylene diene rubber simultaneously, the loading of white oil can be increased, enhance the transparency.
Description
Technical field
The present invention relates to formula and the preparation method at high transparency rubber (being commonly called as glass cement) the big end, it is adaptable to cold glutinous motion
Footwear and the production at the vulcanized rubber shoes big end.
Background technology
Cold glutinous sport shoes and the method producing employing molded vulcanization mostly at the vulcanized rubber shoes big end, and high transparency rubber sole
(being commonly called as glass cement) uses transparent general purpose rubber to add anhydrous White Carbon black, vulcanizes with organic peroxide.And due to organic mistake
Oxide to the instability of hot oxygen and general purpose rubber UV resistant is poor, simultaneously ultraviolet penetrate readily through high transparent rubber
The reasons such as glue, cause high transparency rubber anti-yellowing property poor.Simultaneously high transparency rubber as to be fabricated to cold glutinous sport shoes or
The vulcanized rubber shoes big end, it is necessary to meet the color inhibition requirement at the big end.General shoe sole requires that color inhibition reaches more than 4 grades (HG/
T3689-2014 standard testing), and high transparency rubber can only achieve 2～3 grades.
Summary of the invention
It is an object of the present invention to provide a kind of color inhibition to reach more than 4 grades (UV fluorescent tube method × 6 hour) high transparency rubber and (be commonly called as
Glass cement) rubber compounding and preparation method thereof at the big end.
In order to achieve the above object, the technical scheme is that formula and the preparation of a kind of high transparency rubber sole is provided
Method, its feature is made up of following raw material in parts by weight: solution polymerized butadiene styrene rubber 10～30 parts, butadiene rubber 20～60 parts,
Ethylene propylene diene rubber 30～70 parts, coupling agent 1.0～2.0 parts, antioxidant 0.5～2.0 parts, UV absorbent 0.5～2.0
Part, anhydrous White Carbon black 30.0～40.0 parts, activating agent 0.3～2.0 parts, tranquilizer 0.2～0.4 part, white oil 20.0～30.0 parts,
Vulcanizing agent 0.5～1.5 parts.
Further, described solution polymerized butadiene styrene rubber is Japan Asahi Chemical Industry Asaprene 303.
Described butadiene rubber is Qilu Petrochemical BR9000.
Described ethylene propylene diene rubber is Mitsui 4045M.
Described coupling agent is vinyl three (b-methoxy ethoxy) silane, Chinese name silane coupling A 172.
Described antioxidant is 2,6-di-tert-butyl-4-methy phenol, Chinese name antioxidant BHT.
Described UV absorbent is Octabenzone, Chinese name UV-531.
Described anhydrous White Carbon black is day Bender mountain QS-20LS.
Described activating agent is stearic acid and Polyethylene Glycol and combinations thereof.
Described tranquilizer is Degussa sipemat 820A.
Described white oil is Maoming Petrochemical 10# white oil.
Described vulcanizing agent is 1,1-di-t-butyl peroxy-3, and 5,5-trimethyl-cyclohexanes are commonly called as vulcanizing agent 3M and 2,5-
Dimethyl-2,5 pairs (t-butyl peroxy) hexane, is commonly called as vulcanizing agent double 25.
Present invention discover that use ethylene propylene diene rubber can significantly improve, the resistance to Huang at high transparency rubber (being commonly called as glass cement) the big end
Degeneration energy.But owing to the half finished rubber cohesive of ethylene propylene diene rubber is poor, need and with butadiene rubber and butadiene-styrene rubber
Improve half finished rubber cohesive.Find to use ethylene propylene diene rubber simultaneously, the loading of white oil can be increased, improve high transparency
The transparency of rubber sole.Simultaneously antioxidant, UV absorbent, the Fruit variety of tranquilizer and ratio, saturating to height
The anti-yellowing property impact at bright rubber (being commonly called as glass cement) the big end is greatly.
Detailed description of the invention
The formula of a kind of high transparency rubber sole and preparation method, raw material composition the most in parts by weight: solution polymerized butylbenzene
Rubber 10～30 parts, butadiene rubber 20～60 parts, ethylene propylene diene rubber 30～70 parts, coupling agent 1.0～2.0 parts, antioxidant 0.5
～2.0 parts, UV absorbent 0.5～2.0 parts, anhydrous White Carbon black 30.0～40.0 parts, activating agent 0.3～2.0 parts, tranquilizer
0.2～0.4 part, white oil 20.0～30.0 parts, vulcanizing agent 0.5～1.5 parts.
Described solution polymerized butadiene styrene rubber is Japan Asahi Chemical Industry Asaprene 303.
Described butadiene rubber is Qilu Petrochemical BR9000.
Described ethylene propylene diene rubber is Mitsui 4045M.
Described coupling agent is vinyl three (b-methoxy ethoxy) silane, and Chinese name silane coupling A 172, for upper
Hai Ruihuan industry and trade is supplied.
Described antioxidant is 2,6-di-tert-butyl-4-methy phenol, Chinese name antioxidant BHT, for Shanghai Hua Yi group
Hua Yuan Chemical Co., Ltd. supplies.
Described UV absorbent is Octabenzone, Chinese name UV-531.
Described anhydrous White Carbon black is day Bender mountain QS-20LS.
Described activating agent is stearic acid and Polyethylene Glycol and combinations thereof, and stearic acid is that production and supply are contained in sky, Fujian, poly-
The petrochemical iy produced supply of ethylene glycol Hai'an.
Described tranquilizer is Degussa sipemat 820A.
Described white oil is Maoming Petrochemical 10# color inhibition white oil.
Described vulcanizing agent is 1,1-di-t-butyl peroxy-3, and 5,5-trimethyl-cyclohexanes are commonly called as vulcanizing agent 3M and 2,
5-dimethyl-2,5 pairs of (t-butyl peroxy) hexanes, it is commonly called as vulcanizing agent double 25, for the supply of Dongguan Yue Bang scientific & technical corporation.
1. embodiment 1
It is made up of following raw material in parts by weight: solution polymerized butadiene styrene rubber 303 10 parts；Butadiene rubber BR9000 20 parts；Ternary
EP rubbers 4045M 70.0 parts；Coupling agent A172 2.0 parts；Stearic acid 0.3 part；Polyethylene Glycol PEG4000 1.0 parts；Antioxygen
Agent BHT 1.5 parts；UV absorbent 2.0 parts；White Carbon black QS-20LS 35 parts；10# white oil 25 parts；Tranquilizer 820A 1.5
Part；Vulcanizing agent 3M 0.3 part；Double 25 0.8 parts of vulcanizing agent.
The preparation of above-mentioned composition uses banbury one section mixing, and mill two-stage nitration adds the method for sulfur. and its concrete steps are such as
Under:
Banbury one section is mixing: add solution polymerized butadiene styrene rubber and butadiene rubber, 30s after the most load weighted ethylene-propylene-diene monomer glue laminated is soft
The while of rear 3/4 anhydrous White Carbon black and coupling agent, add antioxidant, activating agent, UV absorbent, tranquilizer, white after 120s
Oil and remaining 1/4 anhydrous White Carbon black, binder removal after 240s.Putting into mill to refine, after about 5 minutes, bottom sheet is parked again.Wherein banbury
Dump temperature controls≤120 DEG C, mill temperature control≤60 DEG C.
In order to make filler have more preferable dispersibility and the more preferable contractility of rubber molecule, one section of elastomeric compound needs to park
Within at least 12 hours, (typically requiring between 12 hours to three months) just can add vulcanizing agent.
Mill two-stage nitration adds sulfur: will add after soft for one section of mixing glue laminated under after vulcanizing agent 3M and double 25,180 seconds of vulcanizing agent
Sheet is parked.Crossing range request to be uniformly dispersed, mill mixer roller temperature controls at 40～60 DEG C.
2. embodiment 2
It is made up of following raw material in parts by weight: solution polymerized butadiene styrene rubber 303 10 parts；Butadiene rubber BR9000 50 parts；Ternary
EP rubbers 4045M 40.0 parts；Coupling agent A172 1.05 parts；Stearic acid 0.2 part；Polyethylene Glycol PEG4000 1.0 parts；Antioxygen
Agent BHT 2.5 parts；UV absorbent 2.0 parts；White Carbon black QS-20LS 30 parts；10# white oil 12 parts；Tranquilizer 820A 1.0
Part；Vulcanizing agent 3M 0.1 part；Double 25 0.6 parts of vulcanizing agent.
Remarks: preparation method is same as in Example 1.
Claims (13)
1. the formula of high transparency rubber sole, it is characterised in that: it is made up of following raw material in parts by weight: solution polymerized butadiene styrene rubber
10～30 parts, butadiene rubber 20～60 parts, ethylene propylene diene rubber 30～70 parts, coupling agent 1.0～2.0 parts, antioxidant 0.5～
2.0 parts, UV absorbent 0.5～2.0 parts, anhydrous White Carbon black 30.0～40.0 parts, activating agent 0.3～2.0 parts, tranquilizer
0.2～0.4 part, white oil 20.0～30.0 parts, vulcanizing agent 0.5～1.5 parts.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described solution polymerized butadiene styrene rubber is day
This Asahi Chemical Industry Asaprene 303.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described butadiene rubber is Shandong stone
Change BR9000.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described ethylene propylene diene rubber is day
These three well 4045M.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described coupling agent is vinyl three
(b-methoxy ethoxy) silane.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described antioxidant is 2,6-bis-uncle
Butyl-4-methylphenol.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described UV absorbent is 2-
Hydroxyl-4-oxy-octyl benzophenone.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described anhydrous White Carbon black is Japan
Moral mountain QS-20LS.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described activating agent be stearic acid and
Polyethylene Glycol and combinations thereof.
The formula of high transparency rubber sole the most according to claim 1, it is characterised in that: described tranquilizer is Degussa
sipemat 820A。
The formula of 11. high transparency rubber soles according to claim 1, it is characterised in that: described white oil is Maoming Petrochemical
10# white oil.
The formula of 12. high transparency rubber soles according to claim 1, it is characterised in that: described vulcanizing agent is 1,1-bis-
T-butylperoxy-3,5,5-trimethyl-cyclohexane and 2,5-dimethyl-2,5 pairs (t-butyl peroxy) hexane.
The preparation method of 13. high transparency rubber soles according to claim 1, it is characterised in that it specifically comprises the following steps that
Banbury one section is mixing: add solution polymerized butadiene styrene rubber and butadiene rubber, 30s after the most load weighted ethylene-propylene-diene monomer glue laminated is soft
After be simultaneously introduced 3/4 anhydrous White Carbon black and coupling agent, add antioxidant, activating agent, UV absorbent, stable after 120s
Agent, white oil and remaining 1/4 White Carbon black, binder removal after 240s, put into mill and refine, and after about 5 minutes, bottom sheet is parked, wherein banbury
Dump temperature controls≤120 DEG C, and mill temperature controls≤60 DEG C；
Mill two-stage nitration adds sulfur: adding vulcanizing agent after soft for one section of mixing glue laminated, after 180 seconds, bottom sheet is parked, and crosses range request dispersion
Uniformly, mill mixer roller temperature controls at 40～60 DEG C.
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| CN201610757721.6A CN106280035A (en) | 2016-08-30 | 2016-08-30 | The formula of high transparency rubber sole and preparation method |
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Cited By (6)
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|---|---|---|---|---|
| CN107793602A (en) * | 2017-12-07 | 2018-03-13 | 福建省安源橡胶科技有限公司 | High-strength transparence glass rubber and its manufacture craft |
| CN109971078A (en) * | 2019-04-28 | 2019-07-05 | 南通江中光电有限公司 | A kind of formula of escalator handrail |
| CN110041626A (en) * | 2019-04-28 | 2019-07-23 | 南通江中光电有限公司 | A kind of preparation method of the formula of escalator handrail |
| CN110305366A (en) * | 2019-07-29 | 2019-10-08 | 山东省临沂市三丰化工有限公司 | A kind of antioxidative stabilizer composition and modified butadiene rubber |
| CN110343340A (en) * | 2019-06-30 | 2019-10-18 | 瑞声科技(新加坡)有限公司 | A kind of light transmission rubber composition, preparation method and the application in electro-acoustic element |
| CN115850820A (en) * | 2022-09-30 | 2023-03-28 | 福建省莆田市联盛鞋业有限公司 | A kind of anti-cracking transparent rubber material and its processing method and application |
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| CN109971078A (en) * | 2019-04-28 | 2019-07-05 | 南通江中光电有限公司 | A kind of formula of escalator handrail |
| CN110041626A (en) * | 2019-04-28 | 2019-07-23 | 南通江中光电有限公司 | A kind of preparation method of the formula of escalator handrail |
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| CN110343340B (en) * | 2019-06-30 | 2022-04-22 | 瑞声科技(新加坡)有限公司 | Light-transmitting rubber composition, preparation method and application in electroacoustic device |
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| CN110305366B (en) * | 2019-07-29 | 2021-03-12 | 山东省临沂市三丰化工有限公司 | Antioxidant stabilizer composition and modified butadiene rubber |
| CN115850820A (en) * | 2022-09-30 | 2023-03-28 | 福建省莆田市联盛鞋业有限公司 | A kind of anti-cracking transparent rubber material and its processing method and application |
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