CN106398233A - Rubber material for wire harness shell - Google Patents

Rubber material for wire harness shell Download PDF

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Publication number
CN106398233A
CN106398233A CN201610799059.0A CN201610799059A CN106398233A CN 106398233 A CN106398233 A CN 106398233A CN 201610799059 A CN201610799059 A CN 201610799059A CN 106398233 A CN106398233 A CN 106398233A
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CN
China
Prior art keywords
parts
wire harness
elastomeric material
harness shell
carbon black
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Withdrawn
Application number
CN201610799059.0A
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Chinese (zh)
Inventor
程秀云
赵剑
王春
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HEFEI BANGLI ELECTRONIC CO Ltd
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HEFEI BANGLI ELECTRONIC CO Ltd
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Priority to CN201610799059.0A priority Critical patent/CN106398233A/en
Publication of CN106398233A publication Critical patent/CN106398233A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/10Block- or graft-copolymers containing polysiloxane sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/458Block-or graft-polymers containing polysiloxane sequences containing polyurethane sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/05Polymer mixtures characterised by other features containing polymer components which can react with one another
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a rubber material for a wire harness shell. The rubber material is prepared from the following raw materials in parts by weight: 60 to 80 parts of modified silicon rubber, 40 to 60 parts of ethylene propylene terpolymer rubber, 60 to 80 parts of composite fillers, 20 to 30 parts of nanometer sodium hydroxide, 10 to 12 parts of melamine cyanurate, 6 to 8 parts of red phosphorus, 2 to 4 parts of epoxy silkworm chrysalis butyl oleate, 1 to 2 parts of 2-ethyl hexyl ester of epoxidized soybean oil, 1 to 2 parts of sulphur, 0.4 to 0.6 part of dicumyl peroxide, 0.2 to 0.4 part of accelerants TMTD, 0.2 to 0.3 part of accelerants D, 4 to 6 parts of Ca/Zn compound stabilizers, 0.6 to 0.8 part of anti-aging agents and 1 to 3 parts of paraffin. The rubber material has the advantages that the anti-impact performance is high; low temperature resistance can be realized; the corrosion resistance performance is good.

Description

A kind of elastomeric material for wire harness shell
Technical field
The present invention relates to field of rubber technology, more particularly, to a kind of elastomeric material for wire harness shell.
Background technology
Wire harness shell is used for protection wire, is externally exposed for a long time in environment, can be corroded by various materials, also can be subject to To the impact of various strength, therefore wire harness shell needs there is certain corrosion-resistant, shock resistance, but in low temperature environment In, its shock resistance can reduce, easily damaged, accordingly, it is desirable to provide a kind of low temperature resistant and shock resistance the wire harness deposited Shell.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of elastomeric material for wire harness shell, this Invention shock resistance is high, low temperature resistant, corrosion resistance and good.
A kind of elastomeric material for wire harness shell proposed by the present invention, its raw material includes by weight:Modified silicon rubber 60-80 part, ethylene propylene diene rubber 40-60 part, compounded mix 60-80 part, nanometer sodium hydroxide 20-30 part, melamine cyanurea Hydrochlorate 10-12 part, red phosphorus 6-8 part, epoxy Pupa bombycises butyl oleate 2-4 part, ethyl hexyl ester of epoxidized soybean oil 1-2 part, sulfur 1-2 part, Cumyl peroxide 0.4-0.6 part, Vulcanization accelerator TMTD 0.2-0.4 part, diphenylguanidine 0.2-0.3 part, Ca/Zn stable composition Agent 4-6 part, age resistor 0.6-0.8 part, paraffin 1-3 part.
Preferably, in the preparation process of modified silicon rubber, in nitrogen atmosphere, with 2,4 toluene diisocyanate, gather Ethylene glycol 1000, dibutyl tin laurate, BDO prepare material A;Season four amylalcohol 3 third is added in material A Olefin(e) acid ester, adjusts temperature and is 50-60 DEG C, insulated and stirred 6-7h, plus triethylamine neutralization obtains material B;Material B and silicone rubber are mixed Even, it is warming up to 50-70 DEG C, modified silicon rubber is obtained with the speed banburying 3-4h of 1000-1500r/min.
Preferably, in the preparation process of modified silicon rubber, silicone rubber is methyl vinyl silicone rubber.
Preferably, in the preparation process of modified silicon rubber, the weight of material B and silicone rubber is than for 2-3:13-17.
Preferably, in the preparation process of modified silicon rubber, 2,4 toluene diisocyanate, Macrogol 1000, February Dilaurylate, BDO, the weight of season four amylalcohol triacrylate are than for 8.6-11.6:9-11:0.2-0.4: 2.5-3.5:3-4.
Preferably, the raw material of compounded mix includes:Nano titanium oxide, modified potter's clay, white carbon black.
Preferably, in compounded mix, nano titanium oxide, modified potter's clay, the weight ratio of white carbon black are for 1-2:4-6:4-6.
Preferably, in compounded mix, modified potter's clay is potter's clay through γ-methacryloxypropyl trimethoxy silane Modification obtains.
Preferably, in compounded mix, modified potter's clay is 400-500 mesh.
Preferably, in compounded mix, white carbon black is made up of white carbon black N220, white carbon black N219, white carbon black N330.
The preparation process of above-mentioned material A is the preparation process of base polyurethane prepolymer for use as, is this area routine techniquess means.
The preparation method of the present invention is:By each raw material blending banburying, then adjust the temperature to 150 DEG C, adjust pressure to 200Kgf/cm2, vulcanize 5min and obtain the elastomeric material for wire harness shell through twin screw extruder extrusion.
The present invention has excellent low temperature resistant, high temperature resistant, corrosion-resistant, the performance such as insulation from silicone rubber;But mechanicalness Can not be high;Polyurethane has good shock resistance, elasticity, high and low temperature resistance, wearability;Ethylene propylene diene rubber has good Tensile strength well, decay resistance;The polyurethane that material B blocks for double bond is obtained by each raw material reaction, close with silicone rubber Refining, makes the upper polyurethane of silicone rubber grafting by carbon-carbon double bond condensation, and silicone rubber is well low temperature resistant, corrosion-resistant, insulation keeping While performance, considerably increase the mechanical performances such as shock resistance, the elasticity of silicone rubber, and increased silicone rubber and EPDM The compatibility of rubber, makes the two dispersed, stops and is separated, thus greatly increasing the impact resistance of the present invention, elasticity, toughness Etc. mechanical performance, and keep good low temperature resistant, decay resistance;Remaining carbon-carbon double bond and EPDM on modified silicon rubber Carbon-carbon double bond on rubber can crosslink, and forms complex network, increases the shock resistance of the present invention further;Titanium dioxide May be uniformly dispersed in modified silicon rubber, increase impact resistance and the anti-ultraviolet property of the present invention;γ-methacryloxypropyl Base propyl trimethoxy silicane modification potter's clay, may be homogenously dispersed in modified silicon rubber and ethylene propylene diene rubber, and with wherein Carbon-carbon double bond be cross-linked to form network, further increase the present invention shock resistance;Potter's clay has good resistance to low temperature, The resistance to low temperature of the present invention can be increased further;Nano titanium oxide, modified potter's clay, white carbon black cooperate, and can enter one Step increases shock resistance and the resistance to low temperature of the present invention;Nanometer sodium hydroxide, melamine cyanurate, red phosphorus phase interworking Close, increase the anti-flammability of the present invention;Epoxy Pupa bombycises butyl oleate, ethyl hexyl ester of epoxidized soybean oil cooperate, and can keep this While bright shock resistance, adjust the toughness of the present invention;Ca/Zn complex stabilizer, age resistor cooperate the increase present invention Heat stability and ageing resistace;Sulfur, cumyl peroxide, Vulcanization accelerator TMTD, diphenylguanidine cooperate, crosslinked sulfur Change and form complex network, paraffin promotes each material to be dispersed in cross-linked network, increases the mechanical performance of the present invention;Each material Cooperate so that the present invention has good lower temperature resistance, corrosion resistance, impact resistance and toughness.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of elastomeric material for wire harness shell, its raw material includes by weight:70 parts of modified silicon rubber, EPDM 50 parts of rubber, 70 parts of compounded mix, 25 parts of nanometer sodium hydroxide, 11 parts of melamine cyanurate, 7 parts of red phosphorus, epoxy Pupa bombycises 3 parts of butyl oleate, 1.5 parts of ethyl hexyl ester of epoxidized soybean oil, 1.5 parts of sulfur, 0.5 part of cumyl peroxide, Vulcanization accelerator TMTD 0.3 part, 0.25 part of diphenylguanidine, 5 parts of Ca/Zn complex stabilizer, 0.7 part of age resistor, 2 parts of paraffin.
Embodiment 2
A kind of elastomeric material for wire harness shell, its raw material includes by weight:60 parts of modified silicon rubber, EPDM 60 parts of rubber, 60 parts of compounded mix, 30 parts of nanometer sodium hydroxide, 10 parts of melamine cyanurate, 8 parts of red phosphorus, epoxy Pupa bombycises 2 parts of butyl oleate, 2 parts of ethyl hexyl ester of epoxidized soybean oil, 1 part of sulfur, 0.6 part of cumyl peroxide, 0.2 part of Vulcanization accelerator TMTD, 0.3 part of diphenylguanidine, 4 parts of Ca/Zn complex stabilizer, 0.8 part of age resistor, 1 part of paraffin;
Wherein, in the preparation process of modified silicon rubber, in nitrogen atmosphere, with 2,4 toluene diisocyanate, poly- second Glycol 1000, dibutyl tin laurate, BDO prepare material A;Season four amylalcohol three propylene is added in material A Acid esters, adjusts temperature and is 50 DEG C, insulated and stirred 7h, plus triethylamine neutralization obtains material B;By material B and methyl ethylene silicon rubber Glue mixes, and is warming up to 50 DEG C, obtains modified silicon rubber with the speed banburying 3h of 1500r/min, wherein, material B and ethylene methacrylic The weight of base silicone rubber is than for 3:13,2,4 toluene diisocyanate, Macrogol 1000, dibutyl tin laurate, Isosorbide-5-Nitrae- Butanediol, the weight of season four amylalcohol triacrylate are than for 11.6:9:0.4:2.5:4;
The raw material of compounded mix includes:Nano titanium oxide, 400 mesh γ-methacryloxypropyl trimethoxy silicon Alkane modification potter's clay, white carbon black, wherein, nano titanium oxide, γ-methacryloxypropyl trimethoxy silane modification potter's clay, The weight of white carbon black is than for 1:2:3;
White carbon black is made up of white carbon black N220, white carbon black N219, white carbon black N330.
Embodiment 3
A kind of elastomeric material for wire harness shell, its raw material includes by weight:80 parts of modified silicon rubber, EPDM 40 parts of rubber, 80 parts of compounded mix, 20 parts of nanometer sodium hydroxide, 12 parts of melamine cyanurate, 6 parts of red phosphorus, epoxy Pupa bombycises 4 parts of butyl oleate, 1 part of ethyl hexyl ester of epoxidized soybean oil, 2 parts of sulfur, 0.4 part of cumyl peroxide, 0.4 part of Vulcanization accelerator TMTD, 0.2 part of diphenylguanidine, 6 parts of Ca/Zn complex stabilizer, 0.6 part of age resistor, 3 parts of paraffin;
Wherein, in the preparation process of modified silicon rubber, in nitrogen atmosphere, with 2,4 toluene diisocyanate, poly- second Glycol 1000, dibutyl tin laurate, BDO prepare material A;Season four amylalcohol three propylene is added in material A Acid esters, adjusts temperature and is 60 DEG C, insulated and stirred 6h, plus triethylamine neutralization obtains material B;By material B and methyl ethylene silicon rubber Glue mixes, and is warming up to 70 DEG C, obtains modified silicon rubber with the speed banburying 4h of 1000r/min, wherein, material B and ethylene methacrylic The weight of base silicone rubber is than for 2:17,2,4 toluene diisocyanate, Macrogol 1000, dibutyl tin laurate, Isosorbide-5-Nitrae- Butanediol, the weight of season four amylalcohol triacrylate are than for 8.6:11:0.2:3.5:3;
The raw material of compounded mix includes:Nano titanium oxide, 500 mesh γ-methacryloxypropyl trimethoxy silicon Alkane modification potter's clay, white carbon black, wherein, nano titanium oxide, γ-methacryloxypropyl trimethoxy silane modification potter's clay, The weight of white carbon black is than for 1:6:4;
White carbon black is made up of white carbon black N220, white carbon black N219, white carbon black N330.
Embodiment 4
A kind of elastomeric material for wire harness shell, its raw material includes by weight:65 parts of modified silicon rubber, EPDM 55 parts of rubber, 65 parts of compounded mix, 28 parts of nanometer sodium hydroxide, 10.5 parts of melamine cyanurate, 7.5 parts of red phosphorus, epoxy 2.5 parts of Pupa bombycises butyl oleate, 1.7 parts of ethyl hexyl ester of epoxidized soybean oil, 1.3 parts of sulfur, 0.55 part of cumyl peroxide, accelerator 0.25 part of TMTD, 0.27 part of diphenylguanidine, 4.5 parts of Ca/Zn complex stabilizer, 0.75 part of age resistor, 1.5 parts of paraffin;
Wherein, in the preparation process of modified silicon rubber, in nitrogen atmosphere, with 2,4 toluene diisocyanate, poly- second Glycol 1000, dibutyl tin laurate, BDO prepare material A;Season four amylalcohol three propylene is added in material A Acid esters, adjusts temperature and is 58 DEG C, insulated and stirred 6.2h, plus triethylamine neutralization obtains material B;By material B and methyl ethylene silicon Rubber mixes, and is warming up to 65 DEG C, obtains modified silicon rubber with the speed banburying 3.7h of 1200r/min, wherein, material B and methyl The weight of vinylsiloxane rubber is than for 2.2:16,2,4 toluene diisocyanate, Macrogol 1000, di lauric dibutyl Stannum, BDO, the weight of season four amylalcohol triacrylate are than for 9:10.5:0.25:3.3:3.2;
The raw material of compounded mix includes:Nano titanium oxide, 500 mesh γ-methacryloxypropyl trimethoxy silicon Alkane modification potter's clay, white carbon black, wherein, nano titanium oxide, γ-methacryloxypropyl trimethoxy silane modification potter's clay, The weight of white carbon black is than for 1.2:5.5:4.5;
White carbon black is made up of white carbon black N220, white carbon black N219, white carbon black N330.
Embodiment 5
A kind of elastomeric material for wire harness shell, its raw material includes by weight:75 parts of modified silicon rubber, EPDM 45 parts of rubber, 75 parts of compounded mix, 22 parts of nanometer sodium hydroxide, 11.5 parts of melamine cyanurate, 6.5 parts of red phosphorus, epoxy 3.5 parts of Pupa bombycises butyl oleate, 1.3 parts of ethyl hexyl ester of epoxidized soybean oil, 1.7 parts of sulfur, 0.45 part of cumyl peroxide, accelerator 0.35 part of TMTD, 0.23 part of diphenylguanidine, 5.5 parts of Ca/Zn complex stabilizer, 0.65 part of age resistor, 2.5 parts of paraffin;
Wherein, in the preparation process of modified silicon rubber, in nitrogen atmosphere, with 2,4 toluene diisocyanate, poly- second Glycol 1000, dibutyl tin laurate, BDO prepare material A;Season four amylalcohol three propylene is added in material A Acid esters, adjusts temperature and is 52 DEG C, insulated and stirred 6.8h, plus triethylamine neutralization obtains material B;By material B and methyl ethylene silicon Rubber mixes, and is warming up to 55 DEG C, obtains modified silicon rubber with the speed banburying 3.3h of 1400r/min, wherein, material B and methyl The weight of vinylsiloxane rubber is than for 2.8:14,2,4 toluene diisocyanate, Macrogol 1000, di lauric dibutyl Stannum, BDO, the weight of season four amylalcohol triacrylate are than for 11:9.5:0.35:2.7:3.8;
The raw material of compounded mix includes:Nano titanium oxide, 400 mesh γ-methacryloxypropyl trimethoxy silicon Alkane modification potter's clay, white carbon black, wherein, nano titanium oxide, γ-methacryloxypropyl trimethoxy silane modification potter's clay, The weight of white carbon black is than for 1.8:4.5:5.5;
White carbon black is made up of white carbon black N220, white carbon black N219, white carbon black N330.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (10)

1. a kind of elastomeric material for wire harness shell is it is characterised in that its raw material includes by weight:Modified silicon rubber 60- 80 parts, ethylene propylene diene rubber 40-60 part, compounded mix 60-80 part, nanometer sodium hydroxide 20-30 part, melamine cyanurate 10-12 part, red phosphorus 6-8 part, epoxy Pupa bombycises butyl oleate 2-4 part, ethyl hexyl ester of epoxidized soybean oil 1-2 part, sulfur 1-2 part, peroxide Change diisopropylbenzene (DIPB) 0.4-0.6 part, Vulcanization accelerator TMTD 0.2-0.4 part, diphenylguanidine 0.2-0.3 part, Ca/Zn complex stabilizer 4-6 Part, age resistor 0.6-0.8 part, paraffin 1-3 part.
2. it is used for the elastomeric material of wire harness shell according to claim 1 it is characterised in that preparation in modified silicon rubber Cheng Zhong, in nitrogen atmosphere, with 2,4 toluene diisocyanate, Macrogol 1000, dibutyl tin laurate, Isosorbide-5-Nitrae-fourth two Alcohol prepares material A;Add season four amylalcohol triacrylate in material A, adjust temperature and be 50-60 DEG C, insulated and stirred 6- 7h, plus triethylamine neutralization obtain material B;Material B and silicone rubber are mixed, is warming up to 50-70 DEG C, with 1000-1500r/min's Speed banburying 3-4h obtains modified silicon rubber.
3. it is used for the elastomeric material of wire harness shell according to claim 2 it is characterised in that preparation in modified silicon rubber Cheng Zhong, silicone rubber is methyl vinyl silicone rubber.
4. it is used for the elastomeric material of wire harness shell according to claim 2 it is characterised in that preparation in modified silicon rubber Cheng Zhong, the weight of material B and silicone rubber is than for 2-3:13-17.
5. it is used for the elastomeric material of wire harness shell according to claim 2 it is characterised in that preparation in modified silicon rubber Cheng Zhong, 2,4 toluene diisocyanate, Macrogol 1000, dibutyl tin laurate, BDO, season four amylalcohol 3 third The weight of olefin(e) acid ester is than for 8.6-11.6:9-11:0.2-0.4:2.5-3.5:3-4.
6. the elastomeric material for wire harness shell according to claim 1 or claim 2 is it is characterised in that the raw material bag of compounded mix Include:Nano titanium oxide, modified potter's clay, white carbon black.
7. it is used for the elastomeric material of wire harness shell according to claim 6 it is characterised in that in compounded mix, nanometer two Titanium oxide, modified potter's clay, the weight ratio of white carbon black are for 1-2:4-6:4-6.
8. it is used for the elastomeric material of wire harness shell according to claim 6 or 7 it is characterised in that in compounded mix, modified Potter's clay obtains through γ-methacryloxypropyl trimethoxy silane modification for potter's clay.
9. it is used for the elastomeric material of wire harness shell according to claim 6 or 7 it is characterised in that in compounded mix, modified Potter's clay is 400-500 mesh.
10. it is used for the elastomeric material of wire harness shell according to claim 6 or 7 it is characterised in that in compounded mix, charcoal Black it is made up of white carbon black N220, white carbon black N219, white carbon black N330.
CN201610799059.0A 2016-08-31 2016-08-31 Rubber material for wire harness shell Withdrawn CN106398233A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107805351A (en) * 2017-10-30 2018-03-16 安徽蓝德仪表有限公司 A kind of oil gas engineering light thin-wall instrument cable

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440686A (en) * 2015-12-08 2016-03-30 宁国市开源橡塑汽车零部件有限公司 Damping high-temperature resistant rubber material
CN105623275A (en) * 2016-03-16 2016-06-01 王社兵 Tear-resistant and heat-resistant silicone rubber cable
CN105802243A (en) * 2016-04-21 2016-07-27 安徽万泰电缆有限公司 High-temperature-resisting and low-temperature-resisting tearing-resisting cable material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440686A (en) * 2015-12-08 2016-03-30 宁国市开源橡塑汽车零部件有限公司 Damping high-temperature resistant rubber material
CN105623275A (en) * 2016-03-16 2016-06-01 王社兵 Tear-resistant and heat-resistant silicone rubber cable
CN105802243A (en) * 2016-04-21 2016-07-27 安徽万泰电缆有限公司 High-temperature-resisting and low-temperature-resisting tearing-resisting cable material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107805351A (en) * 2017-10-30 2018-03-16 安徽蓝德仪表有限公司 A kind of oil gas engineering light thin-wall instrument cable

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Application publication date: 20170215