CN107793602A - High-strength transparence glass rubber and its manufacture craft - Google Patents
High-strength transparence glass rubber and its manufacture craft Download PDFInfo
- Publication number
- CN107793602A CN107793602A CN201711282591.6A CN201711282591A CN107793602A CN 107793602 A CN107793602 A CN 107793602A CN 201711282591 A CN201711282591 A CN 201711282591A CN 107793602 A CN107793602 A CN 107793602A
- Authority
- CN
- China
- Prior art keywords
- rubber
- glass rubber
- strength transparence
- banburying
- bolt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses high-strength transparence glass rubber, including following raw material to form：Solution polymerized butadiene styrene rubber, butadiene rubber, ethylene propylene diene rubber, softening oil, reinforcing agent, plasticizer, antioxidant, light stabilizer, ultraviolet absorber, bridging agent, matched by above-mentioned raw materials, solution polymerized butadiene styrene rubber, butadiene rubber and ethylene propylene diene rubber are disposably first put into banbury, start main frame, under the bolt that bears down on one start banburying, be then put into other surplus stocks, last discharge in three times again, mill, slice, cooling, packaging, the invention has the advantages that：Pass through above-mentioned technical proposal, the present invention passes through adjusting component formula, test piece tensile strength is brought up into >=12MPa, tearing strength >=50.0KN/m, elongation rate of tensile failure >=600%, transparency is high, and optimization protection system, the yellowing resistance of rubber, weatherability are greatly enhanced, second heat air tank vulcanization can be carried out, yellowing >=4 grade, improve product service life.
Description
Technical field
The present invention relates to High-molecular rubber material technical field, and in particular to high-strength transparence glass rubber and its making work
Skill.
Background technology
Transparent rubber is divided into two kinds, and one kind is translucent rubber, and popular city shoe with beef tendon sole, another kind is pure transparent rubber, is commonly called as
Glass cement.And there is following defect in glass cement product during the manufacturing：
1. conventional clear glass rubber tensile low intensity（＜ 9.0MPa）Or tearing strength is low（＜ 40KN/m）, it is impossible to meet high
Client is held to need；
2. conventional clear glass rubber yellowing resistance is poor（4 grades of ＜）, finished product is old to put easy flavescence, influences product quality and outward appearance.
The content of the invention
In place of overcoming above shortcomings in the prior art, it is an object of the invention to provide a kind of high intensity is saturating
Bright glass rubber.
It is another object of the present invention to provide a kind of manufacture craft of high-strength transparence glass rubber.
To achieve the above object, the technical solution adopted by the present invention is as follows：High-strength transparence glass rubber, including it is following heavy
Measure the raw material composition of percentage：
Solution polymerized butadiene styrene rubber 20%
Butadiene rubber 30%
Ethylene propylene diene rubber 10%
Softening oil 7%
Reinforcing agent 30%
Plasticizer 1.5%
Antioxidant 0.6%
Light stabilizer 0.5%
Ultraviolet absorber 0.4%
Bridging agent 0.27%.
Preferably, softening oil of the present invention of stating uses paraffin oil.
Preferably, reinforcing agent of the present invention uses white carbon.
Preferably, plasticizer of the present invention uses stearic acid.
Preferably, antioxidant of the present invention is mixed using antioxidant 1010 with phosphite ester, and it is 5 that it, which is matched,:1.
Preferably, light stabilizer of the present invention uses hindered amine as light stabilizer 791.
Preferably, UV resistant agent of the present invention uses ultra-violet absorber UV-B1211.
Preferably, bridging agent of the present invention is 1,1- di-t-butyl peroxies -3,3,5- trimethyl cyclohexanes.
A kind of manufacture craft of above-mentioned high-strength transparence glass rubber, comprises the following steps：
A, banburying：Match, first disposably put into solution polymerized butadiene styrene rubber, butadiene rubber and ethylene propylene diene rubber close by above-mentioned raw materials
Mill, start main frame, under the bolt that bears down on one start banburying, after banburying 200 seconds, lift top bolt and continue to put into paraffin oil, stearic acid, antioxygen
Agent 1010, phosphite ester, hindered amine as light stabilizer, the ratio of each raw material proportions of ultra-violet absorber UV-B1211 and 1/2 white carbon
After continuing banburying 150 seconds again, lift top bolt sweep powder continue to put into 1/4 white carbon proportion continue banburying 100 seconds after, lift top bolt
Sweep powder to continue after putting into remaining white carbon continuation banburying 100 seconds, carry bolt and sweep powder and overturn raw material, carry bolt again and sweep powder and overturn
Raw material, bolt is carried again and sweeps powder and overturns raw material；Last discharge, dump temperature are 117 DEG C -123 DEG C；
B, mill：The roll spacing of mill, roll spacing 7mm-9mm are first adjusted, 1/3 input that step A banburies are discharged to material is opened
In mill, the material left and right sides of discharge is each to beat triangle bag twice；
C, slice：Thickness is adjusted according to customer requirement, cut into slices by the cut-off knife in mill, you can go out clear glass
Rubber；
D, cool down：The clear glass rubber that step C is cut out is placed on cooling frame, opened transparent on blower fan blow-through cooling frame
Glass rubber cools down, clear glass rubber undercarriage temperature≤50 DEG C；
E, pack：Clear glass rubber after step D is cooled down is put into the packing case of adhesive label, and is put into the frame prepared
Bridge agent inner wrapping, carry out finished product packing.
Compared with prior art, the invention has the advantages that：Pass through above-mentioned technical proposal, the present invention pass through adjustment
Component prescription, test piece tensile strength is brought up into >=12MPa, tearing strength >=50.0KN/m, elongation rate of tensile failure >=600% is transparent
Degree is high, and optimizes protection system, greatly enhances the yellowing resistance of rubber, weatherability, can carry out second heat air tank vulcanization, yellow
>=4 grades of degree, improve product service life.
Embodiment
With reference to embodiment, the invention will be further described, and mode of the invention includes but are not limited to following implementation
Example.
Embodiment 1
A kind of high-strength transparence glass rubber, include the raw material composition of following mass ratio：
Solution polymerized butadiene styrene rubber 16kg
The kg of butadiene rubber 24
The kg of ethylene propylene diene rubber 8
The kg of paraffin oil 5.6
The kg of white carbon 24
The kg of stearic acid 1.2
The kg of antioxidant 1010 0.4
The kg of phosphite ester 0.08
The kg of hindered amine as light stabilizer 0.4
The kg of ultra-violet absorber UV-B1211 0.32
1,1- di-t-butyl peroxy -3,3, the kg of 5- trimethyl cyclohexanes 0.216.
A kind of manufacture craft of above-mentioned high-strength transparence glass rubber, comprises the following steps：
A, banburying：Matched by above-mentioned raw materials, first by 16kg solution polymerized butadiene styrene rubbers, 24 kg butadiene rubbers and 8 kg ethylene-propylene-diene monomers
Glue disposably puts into banbury, starts main frame, under the bolt that bears down on one start banburying, after banburying 200 seconds, lift top bolt and continue input 5.6
Kg paraffin oils, 1.2 kg stearic acid, 0.4 kg antioxidant 1010s, 0.08 kg phosphite esters, 0.4 kg hindered amine as light stabilizer,
After the proportion of 0.32 kg ultra-violet absorbers UV-B1211 and 12 kg white carbons continues banburying 150 seconds, lift top bolt sweep powder after
After the proportion of 6 kg white carbons of continuous input continues banburying 100 seconds, lift top bolt sweep powder continue to put into remaining 6kg white carbons continue it is close
After refining 100 seconds, carry bolt and sweep powder and overturn raw material, carry bolt again and sweep powder and overturn raw material, carry bolt again and sweep powder and overturn raw material；Finally
Discharge, dump temperature are 117 DEG C -123 DEG C；
B, mill：The roll spacing of mill, roll spacing 8mm are first adjusted, step A banburies are discharged into material 1/3 puts into mill
In, the material left and right sides of discharge is each to beat triangle bag twice；
C, slice：Thickness is adjusted according to customer requirement, cut into slices by the cut-off knife in mill, you can go out clear glass
Rubber；
D, cool down：The clear glass rubber that step C is cut out is placed on cooling frame, opened transparent on blower fan blow-through cooling frame
Glass rubber cools down, clear glass rubber undercarriage temperature≤50 DEG C；
E, pack：Clear glass rubber after step D is cooled down is put into the packing case of adhesive label, and is put into the frame prepared
Bridge agent inner wrapping, finished product packing is carried out, and the proportion of bridging agent can be put into according to customer demand, meet that client is producing
Before the rubbers such as sole, according to the demand of oneself add the dosage of bridging agent.
Above-described embodiment is only the preferred embodiment of the present invention, should not be taken to limit protection scope of the present invention, but
All body design thought in the present invention and that mentally makes have no the change of essential meaning or polishing, its technology solved
Problem is still consistent with the present invention, should be included within protection scope of the present invention.
Claims (9)
1. high-strength transparence glass rubber, it is characterised in that：Raw material composition including following percentage by weight：
Solution polymerized butadiene styrene rubber 20%
Butadiene rubber 30%
Ethylene propylene diene rubber 10%
Softening oil 7%
Reinforcing agent 30%
Plasticizer 1.5%
Antioxidant 0.6%
Light stabilizer 0.5%
Ultraviolet absorber 0.4%
Bridging agent 0.27%.
2. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The softening oil of stating uses paraffin
Oil.
3. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The reinforcing agent uses hard charcoal
It is black.
4. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The plasticizer is using stearic
Acid.
5. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The antioxidant uses antioxidant
1010 mix with phosphite ester, and it is 5 that it, which is matched,:1.
6. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The light stabilizer is used and is obstructed
Amine light stabilizer 791.
7. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The UV resistant agent is using purple
Ultraviolet absorbers UV-B1211.
8. the high-strength transparence glass rubber according to claim 1, it is characterised in that：The bridging agent is the uncles of 1,1- bis-
Butyl peroxy -3,3,5- trimethyl cyclohexanes.
9. the manufacture craft of the high-strength transparence glass rubber according to claim 1, it is characterised in that：Including following step
Suddenly：
A, banburying：Match, first disposably put into solution polymerized butadiene styrene rubber, butadiene rubber and ethylene propylene diene rubber close by above-mentioned raw materials
Mill, start main frame, under the bolt that bears down on one start banburying, after banburying 200 seconds, lift top bolt and continue to put into paraffin oil, stearic acid, antioxygen
Agent 1010, phosphite ester, hindered amine as light stabilizer, the ratio of each raw material proportions of ultra-violet absorber UV-B1211 and 1/2 white carbon
After continuing banburying 150 seconds again, lift top bolt sweep powder continue to put into 1/4 white carbon proportion continue banburying 100 seconds after, lift top bolt
After sweeping the remaining white carbon continuation banburying of powder input continuation 100 seconds, carry bolt and sweep powder and overturn raw material, carry bolt again and sweep powder and overturn
Raw material, bolt is carried again and sweeps powder and overturns raw material；Last discharge, dump temperature are 117 DEG C -123 DEG C；
B, mill：The roll spacing of mill, roll spacing 7mm-9mm are first adjusted, 1/3 weight that step A banburies are discharged to material is thrown
Enter in mill, material of discharge or so beats triangle bag twice；
C, slice：Thickness is adjusted according to customer requirement, cut into slices by the cut-off knife in mill, you can go out clear glass
Rubber；
D, cool down：The clear glass rubber that step C is cut out is placed on cooling frame, opened transparent on blower fan blow-through cooling frame
Glass rubber cools down, clear glass rubber undercarriage temperature≤50 DEG C；
E, pack：Clear glass rubber after step D is cooled down is put into the packing case of adhesive label, and is put into the frame prepared
Bridge agent inner wrapping, carry out finished product packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282591.6A CN107793602A (en) | 2017-12-07 | 2017-12-07 | High-strength transparence glass rubber and its manufacture craft |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282591.6A CN107793602A (en) | 2017-12-07 | 2017-12-07 | High-strength transparence glass rubber and its manufacture craft |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107793602A true CN107793602A (en) | 2018-03-13 |
Family
ID=61537791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711282591.6A Pending CN107793602A (en) | 2017-12-07 | 2017-12-07 | High-strength transparence glass rubber and its manufacture craft |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107793602A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4804028A (en) * | 1986-03-05 | 1989-02-14 | The Goodyear Tire & Rubber Company | Non-staining vulcanized elastomeric composition and tires having sidewalls comprising said composition |
| CN102924767A (en) * | 2012-11-22 | 2013-02-13 | 广州市邦尔福鞋材有限公司 | Transparent shoe sole and making method thereof |
| CN106280035A (en) * | 2016-08-30 | 2017-01-04 | 浙江中瑞橡胶高分子材料股份有限公司 | The formula of high transparency rubber sole and preparation method |
-
2017
- 2017-12-07 CN CN201711282591.6A patent/CN107793602A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4804028A (en) * | 1986-03-05 | 1989-02-14 | The Goodyear Tire & Rubber Company | Non-staining vulcanized elastomeric composition and tires having sidewalls comprising said composition |
| CN102924767A (en) * | 2012-11-22 | 2013-02-13 | 广州市邦尔福鞋材有限公司 | Transparent shoe sole and making method thereof |
| CN106280035A (en) * | 2016-08-30 | 2017-01-04 | 浙江中瑞橡胶高分子材料股份有限公司 | The formula of high transparency rubber sole and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105400087A (en) | Long-service-life tire curing bladder and production technology thereof | |
| CN104861318B (en) | A kind of rubber foaming sole material material of reproducible utilization and preparation method thereof | |
| CN102276882B (en) | Tread rubber with high-cutting and tearing resistant performance and low-dynamic heat generation | |
| CN101440176A (en) | Giant engineering tire tread rubber and giant engineering tyre using the same | |
| CN101932459A (en) | Pneumatic tire | |
| CN103435858B (en) | Tyre inner liner rubber and preparation method thereof | |
| CN106167568A (en) | The manufacture method of rubber composition | |
| CN102924772A (en) | Rubber composition used for anti-fire shoes and manufacturing method thereof | |
| WO2013069342A1 (en) | Pneumatic tire | |
| CN109438787A (en) | A kind of collateral support rubber of run-flat tire, preparation method and tire construction | |
| CN102971369A (en) | Rubber blend | |
| CN104829885A (en) | Wear-resistant insulation outsole compounded rubber and preparation method thereof | |
| CN108137866A (en) | Tyre assembly elastic composition and the tire for including them | |
| CN102964640A (en) | Special rubber welt for rubber double-density shoes and preparation method thereof | |
| CN103214705A (en) | Anti-roller-sticking chloroprene rubber and preparation method thereof | |
| CN101774246A (en) | Method for manufacturing sulfur bridge transparent rubber sole | |
| CN107793602A (en) | High-strength transparence glass rubber and its manufacture craft | |
| CN102367294A (en) | Rubber with high thermal ageing resistance and preparation method thereof | |
| CN103214699A (en) | Wear resistant rubber bottom suitable for outdoor use and preparation method thereof | |
| CN113429649A (en) | Inner and outer layer rubber composition for commercial vehicle air spring leather bag and preparation method thereof | |
| CN105017595A (en) | Microporous foamed tire and preparation method thereof | |
| CN106046434B (en) | Sidewall or rim strip rubber composition and pneumatic tire | |
| CN106117669A (en) | A kind of All-steel radial tire sidewall rubber and the production technology of tyre side rubber sheet | |
| CN104403159A (en) | Rubber and preparation method thereof | |
| CN110483882B (en) | Composition for transparent wear-resistant sole and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180313 |
|
| RJ01 | Rejection of invention patent application after publication |