CN106277710A - A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof - Google Patents
A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof Download PDFInfo
- Publication number
- CN106277710A CN106277710A CN201610622253.1A CN201610622253A CN106277710A CN 106277710 A CN106277710 A CN 106277710A CN 201610622253 A CN201610622253 A CN 201610622253A CN 106277710 A CN106277710 A CN 106277710A
- Authority
- CN
- China
- Prior art keywords
- disposal
- friendly type
- dispersant
- water
- oily sludge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/365—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/04—Surfactants, used as part of a formulation or alone
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Treatment Of Sludge (AREA)
Abstract
The present invention relates to oilfield chemical technical field, concrete open a kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof, its raw material contains following component by mass percentage: cationic surfactant 5wt% 20wt%, silicate 5wt% 33wt%, inorganic salt 1.5wt% 10wt%, water 37wt% 88.5wt%, the most each constituent content sum is 100wt%;Method comprises the steps:, by described cationic surfactant, silicate, inorganic salt and water mix homogeneously, to obtain sludge dispersant.It is an advantage of the invention that dispersion effect is good, oil recovery rate is high, production cost is low, environmental protection, and preparation method is easy, applied range.
Description
Technical field
The present invention relates to oilfield chemical technical field, concrete open a kind of disposal of oily sludge with environment-friendly type dispersant and
Preparation method.
Background technology
Oil exploitation, collect defeated, refining and oily waste water treatment during all to produce the black of a large amount of oil-containing solid
Body, semisolid waste, i.e. oily sludge, be called for short greasy filth, and its main component is oil, Ni Heshui.Solid particle chi in greasy filth
Very little can be from not enough micron to several inches, great majority are between 1 to 100 micron, and oil composition depends on that crude oil kind, oil plant are tied
Structure and operating condition, the composition of mud may change over and change.Preliminary survey shows, the annual oily sludge of China increases newly
Yield reaches about 800,000 tons, owing to containing water, silt, sulfide, benzene homologues, phenols, hydro carbons etc., not only land occupation in greasy filth
And space, and severe contamination air, soil and groundwater, constrain the development that oil field at home produces to a certain extent.Mesh
Before, oily sludge is classified as dangerous solid waste (HW08) by country, it can be seen that, when to the process of oil field sludge being
In generation, is become.
At present both at home and abroad conventional oily sludge medicament processing method is broadly divided into: surfactant eluting oil removing, broken
Compounding oil removing between Emulsion breaking milk and removing oil, soda lye wash oil removing, flocculant flocculation deoiling, various medicament.Five kinds of methods are necessarily
Oily sludge can be obtained preferable treatment effect in degree, but every kind of method has respective pluses and minuses and range.
Such as, although surfactant eluting oil removing shows higher oil removal rate, but higher concentration and treatment temperature, this meeting are needed
Make You Heshui dissolve each other, in emulsified state, be not easy to former oil recovery;And biological degradability is poor, there is certain toxicity, seriously
Have impact on Environment-Ecosystem.In order to ensure the sustainable development of environment for human survival, exploitation contains ecological environment is free of contamination
Greasy dirt treatment agent is imperative.
Summary of the invention
It is an object of the invention to provide a kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof, this greasy filth divides
Powder dispersion effect is good, oil recovery rate is high, production cost is low, environmental protection, and preparation method is easy, applied range.
To achieve these goals, present invention employs following technical scheme: its raw material contains such as by mass percentage
Lower component: cationic surfactant 5wt%-20wt%, silicate 5wt%-33wt%, inorganic salt 1.5wt%-10wt%,
Water 37wt%-88.5wt%, the most each constituent content sum is 100wt%;Method comprises the steps: described cation form
Face activating agent, silicate, inorganic salt and water mix homogeneously, obtain sludge dispersant.
Wherein, described cationic active agent is a cationoid polymeric surfactant, and its Main Ingredients and Appearance is phenol
Amine aldehyde resin polyoxyethylene polyoxypropylene ether.
Wherein, described silicate is mainly derived from sodium silicate or the sodium silicate solution of solid powdery.
Wherein, described inorganic salt is one or more in sodium chloride, potassium chloride, sodium sulfate or potassium sulfate.
Preferably, by cationic surfactant, silicate, inorganic salt and water mix homogeneously in certain proportion, obtain
Sludge dispersant;Wherein incorporation time is 30-60 minute, and mixing temperature is 50-90 DEG C.
Wherein, greasy filth is mixed homogeneously with water in blending tank, be subsequently adding sludge dispersant, be stirred, after dispersion
Product in oil-sludge separation device, carry out the separation of oil, water, mud.
Preferably, described greasy filth is 1: 3-1: 5 with the mass ratio of water, and the addition of sludge dispersant accounts for the quality hundred of greasy filth
Proportion by subtraction is 1%-6%;Whipping temp is 70-90 DEG C, and mixing time is 60-120 minute.
The beneficial effects of the present invention is: use that above-mentioned dispersant is effective, biological degradability good, oil recovery rate
Height, is particularly well-suited to the high greasy filth of oil content and the impact on environment is little, environmental protection, and production cost is low, and preparation method is easy,
Applied widely, there is bigger industrial applications prospect.
Detailed description of the invention
Embodiment 1
By phenol amine aldehyde resin polyoxyethylene polyoxypropylene ether 6g, sodium silicate 7g, potassium chloride 1.6g, water 85.4g in temperature are
The reactor of 60 DEG C mixes 30 minutes, obtains sludge dispersant.
Embodiment 2
By phenol amine aldehyde resin polyoxyethylene polyoxypropylene ether 15g, sodium silicate 20g, sodium chloride 1.5g, water 63.5g is in temperature
It is that the reactor of 70 DEG C mixes 40 minutes, obtains sludge dispersant.
Embodiment 3
By phenol amine aldehyde resin polyoxyethylene polyoxypropylene ether 18g, sodium silicate 20g, potassium sulfate 2.5g, water 59.5g is in temperature
It is that the reactor of 85 DEG C mixes 30 minutes, obtains sludge dispersant.
Embodiment 4
Certain refinery's tank bottom oil sludge character is as follows: oil-containing 57.76%, and aqueous 20.29%, solid matter content is 21.95%
(percentage composition is on the basis of weight).
Being sent by pumping in blending tank by tank bottom oil sludge, making the solid-to-liquid ratio of greasy filth and water in tank is 1: 5, through strong stirring 5
Minute, make greasy filth mix homogeneously with water.In blending tank, the greasy filth dispersion that embodiment 3 obtains is added according to the 5% of greasy filth weight
Agent, reaction temperature maintains 70-90 DEG C, mixing time 30 minutes.Reacted product carry out in oil-sludge separation device oil,
Water, the separation of mud, by isolated for top recovery of oil, carry out settlement separate by the mud of bottom and the mixture of water, and final oil returns
Yield is 97.8%.
Embodiment 5
Comparative example 1
Selected greasy filth is with embodiment 4
Being sent by pumping in blending tank by tank bottom oil sludge, making the solid-to-liquid ratio of greasy filth and water in tank is 1: 5, through strong stirring 5
Minute, make greasy filth mix homogeneously with water.In blending tank, sodium lauryl sulphate dispersant is added according to the 5% of greasy filth weight,
Reaction temperature maintains 70-90 DEG C, mixing time 30 minutes.Reacted product carries out oil, water, mud in oil-sludge separation device
Separation, by isolated for top recovery of oil, the mud of bottom and the mixture of water are carried out settlement separate.Final oil recovery rate is
73.5%.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (6)
1. a disposal of oily sludge environment-friendly type dispersant, it is characterised in that: its raw material contains following group by mass percentage
Point: cationic surfactant 5wt%-20wt%, silicate 5wt%-33wt%, inorganic salt 1.5wt%-10wt%, water
37wt%-88.5wt%, the most each constituent content sum is 100wt%.
A kind of disposal of oily sludge environment-friendly type dispersant, it is characterised in that: described cation
Activating agent is a cationoid polymeric surfactant, and its Main Ingredients and Appearance is phenol amine aldehyde resin polyoxyethylene polyoxypropylene
Ether.
A kind of disposal of oily sludge environment-friendly type dispersant, it is characterised in that: described silicate
It is mainly derived from sodium silicate or the sodium silicate solution of solid powdery.
A kind of disposal of oily sludge environment-friendly type dispersant, it is characterised in that: described inorganic salt
For one or more in sodium chloride, potassium chloride, sodium sulfate or potassium sulfate.
5. one kind is used for preparing the method for disposal of oily sludge environment-friendly type described in any one of claim 1-4, it is characterised in that:
Comprise the following steps:
1) by cationic surfactant, silicate, inorganic salt and water mix homogeneously in certain proportion, wherein incorporation time is
30-60 minute, mixing temperature was 50-90 DEG C;
2) being mixed homogeneously in blending tank with water by greasy filth, be subsequently adding sludge dispersant, be stirred, the product after dispersion exists
Oil-sludge separation device carries out the separation of oil, water, mud;Whipping temp is 70-90 DEG C, and mixing time is 60-120 minute, obtains
Sludge dispersant.
A kind of preparation method of disposal of oily sludge environment-friendly type dispersant, it is characterised in that: oil
Mud is 1: 3-1: 5 with the mass ratio of water, and it is 1%-6% that the addition of sludge dispersant accounts for the mass percent of greasy filth.
Priority Applications (2)
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CN201610622253.1A CN106277710A (en) | 2016-07-20 | 2016-07-20 | A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof |
CN201710110950.3A CN106966559B (en) | 2016-07-20 | 2017-02-28 | Oil sludge treatment dispersant, preparation method and application thereof |
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CN201610622253.1A CN106277710A (en) | 2016-07-20 | 2016-07-20 | A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof |
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CN201610622253.1A Pending CN106277710A (en) | 2016-07-20 | 2016-07-20 | A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof |
CN201710110950.3A Active CN106966559B (en) | 2016-07-20 | 2017-02-28 | Oil sludge treatment dispersant, preparation method and application thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106966559A (en) * | 2016-07-20 | 2017-07-21 | 西安华诺环保股份有限公司 | A kind of oil-sludge treatment dispersant and its preparation method and application |
CN115703962A (en) * | 2021-08-16 | 2023-02-17 | 中国石油化工股份有限公司 | Blocking remover and construction method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113072258B (en) * | 2021-04-16 | 2023-04-07 | 江苏博大环保股份有限公司 | Enhanced biochemical treatment process for oilfield wastewater |
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JP2001340846A (en) * | 2000-05-30 | 2001-12-11 | Shuichi Nakayama | Method for treating wastewater containing fats and oils |
CN103466908B (en) * | 2013-09-07 | 2015-08-05 | 鞍钢股份有限公司 | A kind of steel rolling greasy filth sorting agent and classifying method |
CN104152279A (en) * | 2014-07-16 | 2014-11-19 | 湖南城市学院 | Water-based cleanser for glass of smart phone and preparation method thereof |
CN106277710A (en) * | 2016-07-20 | 2017-01-04 | 西安华诺环保股份有限公司 | A kind of disposal of oily sludge environment-friendly type dispersant and preparation method thereof |
CN106277709A (en) * | 2016-07-20 | 2017-01-04 | 西安华诺环保股份有限公司 | A kind of disposal of oily sludge environment-friendly cleaning agent and preparation method thereof |
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2016
- 2016-07-20 CN CN201610622253.1A patent/CN106277710A/en active Pending
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106966559A (en) * | 2016-07-20 | 2017-07-21 | 西安华诺环保股份有限公司 | A kind of oil-sludge treatment dispersant and its preparation method and application |
CN115703962A (en) * | 2021-08-16 | 2023-02-17 | 中国石油化工股份有限公司 | Blocking remover and construction method thereof |
CN115703962B (en) * | 2021-08-16 | 2024-01-23 | 中国石油化工股份有限公司 | Blocking remover and construction method thereof |
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CN106966559A (en) | 2017-07-21 |
CN106966559B (en) | 2020-04-28 |
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