CN106257692A - A kind of polarization sensitive photodetector - Google Patents

A kind of polarization sensitive photodetector Download PDF

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Publication number
CN106257692A
CN106257692A CN201610617154.4A CN201610617154A CN106257692A CN 106257692 A CN106257692 A CN 106257692A CN 201610617154 A CN201610617154 A CN 201610617154A CN 106257692 A CN106257692 A CN 106257692A
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metal
active layer
raceway groove
phasmon
phasmon structure
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王琦龙
翟雨生
陈广甸
李晓华
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Southeast University
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Southeast University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by potential barriers, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J1/00Photometry, e.g. photographic exposure meter
    • G01J1/42Photometry, e.g. photographic exposure meter using electric radiation detectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Manufacturing & Machinery (AREA)
  • Light Receiving Elements (AREA)

Abstract

The invention discloses a kind of polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect, including dielectric substrate, metal backing gate electrode, dielectric isolation layer, raceway groove active layer, drain electrode, source electrode and the plasmon resonance phasmon structure to polarization sensitive, the material energy gap of raceway groove active layer is more than the photon energy of incident illumination, and phasmon structure is metal Nano structure;The thermoelectron in phasmon structure is utilized to produce the strong depend-ence characteristic to incident light polarization state to realize the detection of light polarization information.The present invention has the advantage that 1, utilize phasmon structure can realize the miniaturization of the detection of light polarization information, beneficially device and integrated without additional optical element (polarizer/analyzer);2, metal backing gate electrode is utilized both metal backing grid structure and metal nano phasmon structure can be made again to form super surface texture, increase strong light absorption by being biased voltage amplification photoelectric current, improve Photoresponse.

Description

A kind of polarization sensitive photodetector
Technical field
The present invention relates to a kind of polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect, use In the polarization characteristic of light is carried out highly sensitive detection.
Background technology
Polarization is one of intrinsic important characteristic of light, although be widely used, but the acquisition of its information is the most highly difficult.This Be because most of optical pickocff insensitive to the polarization characteristic of light, and the polarization characteristic of light can not as light intensity that Sample can directly record, so the polarization characteristic obtaining light needs, by polarizer, light wave is carried out polarization analysis.By many The light intensity that secondary measurement is relevant to polarization information could release the polarization information of incident beam, and detection process is the most loaded down with trivial details, and system is divided It is vertical numerous, so that Polarization Detection system develops into inexorable trend to integrated high sensitivity direction is miniaturized.
Surface phasmon as emerging research topic, developing rapidly of last decade, rapidly and other field Cross slot interference, New research contents constantly occurs.When the interface of electromagnetic wave incident to metal-insulator, electromagnetic wave and metal surface freely electricity Son interacts and makes it vibrate along with the vibration of electromagnetic wave, when the frequency of electromagnetic wave is equal to the intrinsic frequency of electronics collective oscillation During rate, electromagnetic wave will be intensively absorbed or scatter, here it is the surface plasmon resonance generally said.And metal nano The plasmon resonance of structure, except incident electromagnetic wave is had wavelength-dependent behavior, there is also polarization independent characteristic.Only special Fixed incident polarized light could form plasmon resonance, and produce thermoelectron and be injected into adjacent materials, it is achieved opto-electronic conversion, institute Detect with polarization information to utilize phasmon structure can realize wavelength information detection, and being easily integrated, and traditional Polarization Detection system compares the photodetection realizing the polarization characteristic to light more easily.
Meanwhile, realizing polarization information detection for by phasmon structure, foreign study mechanism has made some attempts And obtain certain progress, such as 2015, the Jason Velentine seminar of Vanderbilt university utilized chirality phasmon Structure achieves the detection to left circularly polarized light and right-circularly polarized light.But realize polarization letter by phasmon structure at present The correlational study of breath detection is seldom.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the present invention combines phasmon structure and metal backing The advantage of grid field effect transistor, devises a kind of novel Polarization-Sensitive photodetector, utilizes metal backing gate electrode both may be used With by being biased voltage amplification photoelectric current, metal backing grid structure and metal nano phasmon structure can be made again to form super table Face structure, increases strong light absorption, improves Photoresponse.
Technical scheme: for achieving the above object, the technical solution used in the present invention is:
A kind of polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect, including insulation lining The end, metal backing gate electrode, dielectric isolation layer, raceway groove active layer, drain electrode, source electrode and plasmon resonance to polarization sensitive etc. From excimer structure, the material energy gap of described raceway groove active layer is more than the photon energy of incident illumination, and phasmon structure is gold Belong to nanostructured;Described dielectric substrate, metal backing gate electrode, dielectric isolation layer and raceway groove active layer set gradually from the bottom to top, Drain electrode and source electrode are arranged on the left and right sides of raceway groove active layer upper surface, and phasmon structure is arranged on raceway groove active layer upper surface And between drain electrode and source electrode;The thermoelectron in phasmon structure is utilized to produce the strong depend-ence to incident light polarization state special Property realizes the detection of light polarization information.When incident illumination is mapped to phasmon structure, owing to the grade of phasmon structure is from swashing There is polarization independent characteristic in unit's resonant excitation, and the photon energy of incident illumination is less than the material energy gap of raceway groove active layer, Cannot directly excite raceway groove active layer to produce electron hole pair and form light stream;Therefore phasmon mesomerism can only be excited to produce The specific incident polarized light of thermoelectron (this thermoelectron can be injected in raceway groove active layer) could form light stream, so utilization etc. Can realize the detection of light polarization information from excimer structure without additional optical element (polarizer/analyzer), be conducive to The miniaturization of device and integrated.
Described metal backing gate electrode both can realize the enlarging function of field-effect transistor by being biased voltage, in order to put Big photoelectric current;Super surface texture can be formed again, in order to strengthen absorbance, to improve Photoresponse with phasmon structure. Preferably, the material of metal backing gate electrode is gold, silver or aluminum etc..
Preferably, so that form super surface texture reliably between metal backing gate electrode and phasmon structure, Ask the gross thickness of described dielectric isolation layer and raceway groove active layer less than 100nm.
Concrete, surface utilizes the techniques such as thin film to prepare metal backing gate electrode on an insulating substrate, at metal backing gate electrode Upper surface utilizes the techniques such as magnetron sputtering, plasma reinforced chemical vapour deposition or electron beam evaporation to prepare dielectric isolation layer, Dielectric isolation layer upper surface utilizes the techniques such as semiconductive thin film to prepare raceway groove active layer, in the left and right two of raceway groove active layer upper surface Side utilizes technique preparation drain electrode and the source electrodes such as thin film, at raceway groove active layer upper surface, utilizes the works such as micro-nano between drain electrode and source electrode Skill prepares phasmon structure;Described micro-nano technique includes chemical gaseous phase deposition, ald, focused-ion-beam lithography, electricity The techniques such as son bundle photoetching.
Preferably, the material of described dielectric substrate is quartz or sapphire.
Preferably, described phasmon structural periodicity metal grating, periodically ╋ shape structure, periodically zero shape structure or Periodically shape structures etc., the material of phasmon structure is gold, silver or aluminum etc..
In general, raceway groove active layer can material selection various, but to difference detect wavelength, selected the selection of material forbidden band width Degree will more than incident illumination photon energy for example: when incident illumination is visible ray, the material of raceway groove active layer be ZnO or TiO2Deng;When incident illumination light is infrared light, the material of raceway groove active layer is silicon or germanium etc..
Beneficial effect: the polarization sensitive light electrical resistivity survey based on metal phasmon structure thermoelectronic effect that the present invention provides Survey device, have the advantage that 1, utilize phasmon structure can get final product in fact without additional optical element (polarizer/analyzer) The miniaturization of the detection of existing light polarization information, beneficially device and integrated;2, metal backing gate electrode is utilized both can to pass through to have added Bias voltage amplifies photoelectric current, and metal backing grid structure and metal nano phasmon structure can be made again to form super surface texture, Increase strong light absorption, improve Photoresponse.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Label in figure: 1-dielectric substrate, 2-metal backing gate electrode, 3-dielectric isolation layer, 4-raceway groove active layer, 5-drains, 6-source electrode, the 7-plasmon resonance phasmon structure to polarization sensitive.
Fig. 2 is the fundamental diagram of the present invention;
Fig. 3 is the circuit connection diagram of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawings the present invention is further described.
It is illustrated in figure 1 a kind of polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect, Including dielectric substrate 1, metal backing gate electrode 2, dielectric isolation layer 3, raceway groove active layer 4, drain electrode 5, source electrode 6 and plasmon resonance Phasmon structure 7 to polarization sensitive, the material energy gap of described raceway groove active layer 4 is more than the photon energy of incident illumination Amount, phasmon structure 7 is metal Nano structure;Described dielectric substrate 1, metal backing gate electrode 2, dielectric isolation layer 3 and raceway groove Active layer 4 sets gradually from the bottom to top, and drain electrode 5 and source electrode 6 are arranged on the left and right sides of raceway groove active layer 4 upper surface, waits from swashing Meta structure 7 is arranged on raceway groove active layer 4 upper surface and between drain electrode 5 and source electrode 6;Utilize the heat in phasmon structure 7 Electronics produces the strong depend-ence characteristic to incident light polarization state and realizes the detection of light polarization information.
The manufacturing process of said structure is as follows: utilize thin-film technique to prepare metal backing gate electrode at dielectric substrate 1 upper surface 2, utilize magnetron sputtering, plasma reinforced chemical vapour deposition or electron beam evaporation process system at metal backing gate electrode 2 upper surface Standby dielectric isolation layer 3, utilizes SEMICONDUCTING THIN FILM TECHNOLOGY to prepare raceway groove active layer 4 at dielectric isolation layer 3 upper surface, active at raceway groove The left and right sides of layer 4 upper surface utilizes thin-film technique preparation drain electrode 5 and source electrode 6, in raceway groove active layer 4 upper surface, drain electrode 5 and source Micro-nano technique is utilized to prepare phasmon structure 7 between pole 6.
Concrete: when incident illumination is visible ray, the material of raceway groove active layer 4 is ZnO or TiO2;When incident illumination light is red Outer smooth time, the material of raceway groove active layer 4 is silicon or germanium;The gross thickness of dielectric isolation layer 3 and raceway groove active layer 4 is 50-100nm; Design optimization phasmon structure 7 is emphasis, and different phasmon structures 7 is different to different polarized light Effect on Detecting, than As, detection line polarisation can design cycle property metal grating, can be with design optimization structure to realize integrated to different polarization light Detection.
As in figure 2 it is shown, polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect work is former Reason is: when incident illumination is mapped to phasmon structure 7, owing to phasmon structure 7 resonant excitation exists polarization independent characteristic, and And the photon energy of incident illumination is less than the material energy gap of raceway groove active layer 4, it is impossible to directly excite raceway groove active layer 4 to produce electricity Sub-hole is to forming photoelectric current;Phasmon structure 7 resonance the most only can be excited to produce thermoelectron, and (this thermoelectron can be noted Enter in raceway groove active layer 4) specific incident polarized light could form photoelectric current.
Thermionic generation is owing to phasmon structure 7 resonance will decay, and decay has two ways: one is radiation Decay forms photon, and one is non-radiative decay.In phasmon structure 7 material conduction band, electronics obtains energy and raises formation heat Electronics, the suitable thermoelectron of energy will be diffused into metal and interface and be injected in adjacent semiconductor active layer, At this moment outside have circuit collection just to have photoelectric current generation.By being biased voltage, electronics is made to concentrate bottom raceway groove active layer 4 Transmission, amplifies photoelectric current, improves Photoresponse.The thermoelectron utilizing the non-radiative decay of phasmon structure to produce realizes light Electrical resistivity survey is surveyed, and this kind is relatively low for the energy requirement of incident photon, only needs incident photon energy to be more than shape between metal and quasiconductor The schottky barrier height become, and without photoelectric current can be formed higher than the energy gap of quasiconductor.Metal backing gate electrode 2 simultaneously Both can improve Photoresponse by being biased voltage amplification photoelectric current, metal backing gate electrode 2 and phasmon can be made again Structure 7 forms super surface texture, increases strong light absorption, improves Photoresponse.
Embodiment one
For realizing a kind of polarization sensitive photodetector being applicable to visible region Polarization Detection, select quartz as lining The end, magnetron sputtering is utilized to prepare aluminum thin film back gate electrode on its surface;The side of electron beam evaporation is utilized at back-gate electrode upper surface Method prepares SiO2Dielectric spacer layer;Utilizing ZnO films grown by magnetron sputtering active layer on dielectric spacer layer surface, thickness is about 100nm;Thermal evaporation coating process is used to prepare gold thin film drain electrode and source electrode in active layer surface afterwards;Between source drain, Beamwriter lithography and lift-off technique manufacturing cycle metal grating phasmon structure is utilized on semiconductor active layer.
The line polarized light of visible region incides on periodicity metal grating, and after exciting plasmon resonance, decay produces Thermoelectron, energy suitable thermoelectron diffusion transport to golden light grid and ZnO interface, and be injected in ZnO, in source electrode and drain electrode Between bias field effect under, thermoelectron to source electrode motion formed photoelectric current.Metal back grid structure and metal nano phasmon Structure forms super surface texture, increases strong light absorption, improves Photoresponse.Utilize field-effect transistor characteristic, by adding simultaneously Bias voltage amplifies photoelectric current, thus can improve response time and the responsiveness of sensitive detection parts.
Embodiment two
For realizing a kind of polarization sensitive photodetector being applicable near infrared region Polarization Detection, select quartz as lining The end, thermal evaporation coating process is utilized to prepare gold thin film back-gate electrode;In the method system that back-gate electrode upper surface utilizes magnetron sputtering Standby SiO2Dielectric spacer layer;Dielectric spacer layer surface utilize plasma enhanced chemical vapor deposition prepare Si active layer; Thermal evaporation coating process is used to prepare gold thin film drain electrode and source electrode in active layer surface afterwards;Between source drain, quasiconductor Active layer utilizes beamwriter lithography and lift-off technique manufacturing cycle metal grating phasmon structure.
The line polarized light of near infrared region incides in periodicity metal grating phasmon structure, excites plasmon resonance Decay afterwards produces thermoelectron, energy suitable thermoelectron diffusion transport to golden light grid and Si interface, and is injected in Si, in source Under bias field effect between pole and drain electrode, thermoelectron forms photoelectric current to source electrode motion.Metal back grid structure is received with metal Rice phasmon structure forms super surface texture, increases strong light absorption, improves Photoresponse.Utilize field-effect transistor special simultaneously Property, by being biased voltage amplification photoelectric current, response time and the responsiveness of sensitive detection parts thus can be improved.
The above is only the preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (7)

1. a polarization sensitive photodetector based on metal phasmon structure thermoelectronic effect, it is characterised in that: bag Include dielectric substrate (1), metal backing gate electrode (2), dielectric isolation layer (3), raceway groove active layer (4), drain electrode (5), source electrode (6) and etc. From the plasmon resonance phasmon structure (7) to polarization sensitive, the material energy gap of described raceway groove active layer (4) be more than into Penetrating the photon energy of light, phasmon structure (7) is metal Nano structure;Described dielectric substrate (1), metal backing gate electrode (2), Dielectric isolation layer (3) and raceway groove active layer (4) set gradually from the bottom to top, and drain electrode (5) and source electrode (6) are arranged on raceway groove active layer (4) left and right sides of upper surface, phasmon structure (7) is arranged on raceway groove active layer (4) upper surface and is positioned at drain electrode (5) and source Between pole (6);Utilize the thermoelectron in phasmon structure (7) to produce the strong depend-ence characteristic to incident light polarization state to realize The detection of light polarization information.
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: the material of described metal backing gate electrode (2) is gold, silver or aluminum.
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: the gross thickness of described dielectric isolation layer (3) and raceway groove active layer (4) is less than 100nm.
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: utilize thin-film technique to prepare metal backing gate electrode (2) at dielectric substrate (1) upper surface, at metal backgate electricity Pole (2) upper surface utilizes magnetron sputtering, plasma reinforced chemical vapour deposition or electron beam evaporation process to prepare dielectric isolation layer (3), SEMICONDUCTING THIN FILM TECHNOLOGY is utilized to prepare raceway groove active layer (4) at dielectric isolation layer (3) upper surface, in raceway groove active layer (4) The left and right sides of upper surface utilizes thin-film technique preparation drain electrode (5) and source electrode (6), in raceway groove active layer (4) upper surface, drain electrode (5) micro-nano technique and is utilized to prepare phasmon structure (7) between source electrode (6).
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: the material of described dielectric substrate (1) is quartz or sapphire.
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: described phasmon structure (7) periodically metal grating, periodically ╋ shape structure, periodically zero shape structure Or periodicity shape structure, the material of phasmon structure (7) is gold, silver or aluminum.
Polarization sensitive photodetection based on metal phasmon structure thermoelectronic effect the most according to claim 1 Device, it is characterised in that: when incident illumination is visible ray, the material of raceway groove active layer (4) is ZnO or TiO2;When incident illumination light is During infrared light, the material of raceway groove active layer (4) is silicon or germanium.
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WO2018209654A1 (en) * 2017-05-18 2018-11-22 中国科学院半导体研究所 Monochromatic light wavelenth recognition device, system and method
CN109888051A (en) * 2019-03-08 2019-06-14 中国科学院物理研究所 A kind of X-ray detector and its manufacturing method
CN110364581A (en) * 2019-06-06 2019-10-22 浙江大学 The conductivity type photodetector structure of asymmetrical beam up and down based on field-effect
CN110459632A (en) * 2019-08-20 2019-11-15 中国科学院半导体研究所 Flexible polarization optical detector and preparation method based on core-shell nano line
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WO2018209654A1 (en) * 2017-05-18 2018-11-22 中国科学院半导体研究所 Monochromatic light wavelenth recognition device, system and method
CN109888051B (en) * 2019-03-08 2020-11-27 中国科学院物理研究所 X-ray detector and manufacturing method thereof
CN109888051A (en) * 2019-03-08 2019-06-14 中国科学院物理研究所 A kind of X-ray detector and its manufacturing method
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Application publication date: 20161228