CN106256524A - Flexible plastic plastic material and application thereof - Google Patents

Flexible plastic plastic material and application thereof Download PDF

Info

Publication number
CN106256524A
CN106256524A CN201610637494.3A CN201610637494A CN106256524A CN 106256524 A CN106256524 A CN 106256524A CN 201610637494 A CN201610637494 A CN 201610637494A CN 106256524 A CN106256524 A CN 106256524A
Authority
CN
China
Prior art keywords
plastic material
matrix
flexible plastic
granule
plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610637494.3A
Other languages
Chinese (zh)
Other versions
CN106256524B (en
Inventor
孙倩倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sui Meiqing
Original Assignee
Shanghai Kedou Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Kedou Electronic Technology Co Ltd filed Critical Shanghai Kedou Electronic Technology Co Ltd
Priority to CN201610637494.3A priority Critical patent/CN106256524B/en
Publication of CN106256524A publication Critical patent/CN106256524A/en
Application granted granted Critical
Publication of CN106256524B publication Critical patent/CN106256524B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a general shape other than plane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/02—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica the layer of fibres or particles being impregnated or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/025—Particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/02—Synthetic macromolecular particles
    • B32B2264/0214—Particles made of materials belonging to B32B27/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/101—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/41—Opaque
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV

Abstract

Flexible plastic plastic material and application thereof relate to resin base joint product.Flexible plastic plastic material, including light-cured resin based composites, including a matrix, described matrix includes two film layers, two described film interlayers constitute an interlayer, are provided with at least two granule in described interlayer, are filled with uncured light-cured resin based composites described at least two between granule；In two described film layers, at least one film layer is light transmissive material.Irradiated by light, it is achieved the solidification of uncured light-cured resin based composites, so that position is fixed between granule and granule, and then make base shape be fixed, and then realize the solidification of flexible plastic plastic material.

Description

Flexible plastic plastic material and application thereof
The filing date of the original application of this divisional application: on 04 13rd, 2012, Application No.: 2012101093273, name It is referred to as: particles filled formula photo-curing material and application thereof.
Technical field
The present invention relates to curing materials field, be specifically related to a kind of photo-curing material.
Background technology
Polymer matrix composites product is producing and is being widely used in life.Polymer matrix composites may be used for manufacturing Various products, all bring convenience for producing and living.But owing to these productions are complex, use Person can not arbitrarily design, according to the wish of oneself, the article oneself needed.
It addition, our life has a lot of article because volume is relatively big, not readily transportable and storage.Such as table, chair, basin, The articles for daily uses such as bucket, for another example device housings, strip part of appliance, large-scale lamellar part of appliance etc..Due to shape design Problem, although although these article weight are not the heaviest, but it is big to take up room, and there is transport and the problem of storage inconvenience.
Summary of the invention
It is an object of the invention to provide a kind of flexible plastic plastic material, to solve above-mentioned technical problem.
The present invention also aims to provide a kind of flexible plastic plastic material application, to solve above-mentioned technical problem.
The present invention can realize by the following technical solutions:
Flexible plastic plastic material, including light-cured resin based composites, it is characterised in that include a matrix, described Matrix includes that two film layers, two described film interlayers constitute an interlayer, are provided with at least two granule, at least two in described interlayer Uncured light-cured resin based composites it is filled with between described granule；In two described film layers, at least one film layer is printing opacity Material.Two described film layers are flexible.So that making total present flexibility, allowing for bending and depositing.
Light-cured resin based composites is the polymer matrix composites containing light curing agent, uncured light-cured resin Uncured in based composites is to say that the polymer matrix composites containing light curing agent yet there are no light, is still in non-solid.Logical Cross light to irradiate, it is achieved the solidification of uncured light-cured resin based composites, so that position is consolidated between granule and granule Fixed, and then make base shape be fixed, and then realize the solidification of flexible plastic plastic material.Because significant portion material is Grain, rather than light-cured resin based composites, so cost is relatively low.
Granule can be foam beads, bead, glass microballoon, metallic particles, building stones granule, plastic grain etc..Preferably Bead and glass microballoon.
Two described film interlayers are also provided with microcapsule, are filled with uncured light-cured resin base composite wood in microcapsule Material.To improve mechanical property.
Described granule is flexible, in order to makes total present flexibility, allows for bending and deposit.Preferred foams Grain, flexiplast granule etc..
The distance of two described film interlayers is more than 2 times of described granule average thickness.So that being overlapped mutually between granule, increase Strong mechanical performance.
Described microcapsule wall is flexible.So that making total present flexibility, allowing for bending and depositing.Described microcapsule Thickness could be arranged to the half of the distance less than two described film interlayers.So that being overlapped mutually.
One film layer of described matrix is positioned at lower section, is fixedly arranged above one layer of auxiliary film, and described auxiliary film has been fixed State granule.By being arranged in auxiliary film by granule, make auxiliary film that granule to play certain fixation.And then make granule arrange Cloth will not excessively concentrate at one or excessively disperse.
Two described film interlayers can arrange two-layer or the above additional film layer of two-layer.
Two described film interlayers can be filled with the vesicle of gas in arranging.Thus reduce weight.
Part microcapsule can not be full of by uncured light-cured resin based composites, in remaining space, fill solid Granule or gas, with tuning performance.The solid particle filled can be foam, bead, metallic particles, building stones granule, mould Material granule etc..
Described microcapsule wall is elastomeric material.So that more random carrying out bends, strengthen the randomness deposited and use.
Two film layers of described matrix are respectively elastomeric material, in order to more random carrying out bend, stretch, manufacture recessed Fall into or protruding, strengthen the randomness deposited and use.
It is opaque for having one in two film layers of described matrix, in case penetrating whole base carrying out light irradiation time line Body.
An inner side in two film layers of described matrix is reflective material, in order to by light line reflection, promotes real as early as possible Now solidify, and save light energy.
Flexible plastic plastic material includes that two matrixes, two matrixes be arranged in parallel, is provided with and props up between described matrix and matrix Support member, described support member is flexible pipe body, is filled with uncured light-cured resin based composites in flexible pipe body.Do not having Before solidifying, support member and two matrixes are flexibility, it is allowed to bending, and the distance between matrix and matrix can not get It is fixing, so the thickness of flexible plastic plastic material before curing can be relatively thin.
Two matrix peripheral sealings of described flexible plastic plastic material, and it is provided with an air inlet.When depositing, by two Air between matrix is extracted out, makes support member bend, and then makes two matrixes inwardly close up, thinning, it is simple to deposit.
Before curing, by being filled with air in air inlet space between two matrixes, and then two matrixes are made to separate also Spreading, makes support member stretching open, then carries out photocuring.So that two matrixes and support member solidify respectively, so that institute State flexible plastic plastic material and can possess certain thickness after hardening, and because for hollow structure, so lighter in weight.
Described support member one end is fixed on the matrix of side, forms a summit, is at least further fixed on separately at described apex One end of one support member, i.e. one apex is fixed with at least two support members；Side matrix is total to the support member on summit, Summit no longer it is total on opposite side matrix.Therefore two can constitute a triangular shape structure between support member and matrix, because triangular shape knot Structure has stable feature, can be with the stability of reinforcing material.
One apex can draw two, three or four support members, it is also possible to draws more.But preferably draw three Root, the structure of four support members.
Each apex all draws two, three or four support members, so that stabilized structure.
In two described film layers at least one layer be rupture pressure disc, strengthen fastness.It can also be provided that shellproof film.
In two described film layers wherein one layer be anti-ultraviolet film.Place photocuring middle-ultraviolet lamp to leak outside, and after hardening Also function to completely cut off the effect of ultraviolet.
Described flexible plastic plastic material is lamellar.Can realize carrying out cutting during use, fold, beat in the operations such as money The combination of one or more operations, thus obtain the contoured article needed, then solidify.For complicated structure, Respectively each simple parts can be solidified, assemble after solidification.Can also be combined before curing, combine After solidify, in order to be firmly combined with.
Described flexible plastic plastic material prop up after for component shape to be formed, or be the combination of multiple parts. During use, after taking-up material is propped up, carry out solidifying the parts that i.e. can obtain needing.Described props up operation, can be by one Parts are individually propped up, or by realizing propping up operation after several unit constructions, constitute the article needed.
Described flexible plastic plastic material is ship shape after propping up.Ship is become after solidification.Can be one single described soft Property moldable plastic material prop up after formed, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved after propping up formed.
Described flexible plastic plastic material is house shape after propping up.House is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is device housings shape after propping up.Device housings is become after solidification.Can be one Individual single described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, Realization is formed after propping up.
Described flexible plastic plastic material is table shape after propping up.Desk is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is chair shape after propping up.Chair is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is bed body shape after propping up.Bed is become after solidification.It can be a single institute State and formed after flexible plastic plastic material is propped up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved after propping up Formed.
Described flexible plastic plastic material is cupboard shape after propping up.Cupboard is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is fish jar shape after propping up.Fish jar is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is vase shape after propping up.Vase is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is tea table shape after propping up.Tea table is become after solidification.Can be one individually Described flexible plastic plastic material is formed after propping up, it is also possible to be that multiple flexible plastic plastic material is combined, it is achieved prop up Rear formation.
Described flexible plastic plastic material is gear shape after propping up.Gear is become after solidification.
For with the large components such as ship, house, device housings, required flexible plastic plastic material includes two bases Body, two matrixes be arranged in parallel, are provided with support member between described matrix and matrix, and described support member is flexible pipe body, flexible pipe body Inside it is filled with uncured light-cured resin based composites.So that shrinking the mechanical strength after depositing and strengthen solidification.
In advance the described flexible plastic plastic material after inflation is shaped to the shape of required parts, makes at needs Used time, gas is filled with the shape that can present parts, is solidified the parts that i.e. can obtain needing by light.
Being embedded with fibre reinforced materials in the uncured resin-based materials in light-cured resin based composites, fiber increases Strong material can use one or several in the reinforcing fibers such as glass fibre, Plant fiber, carbon fiber.
It is mixed with pigment in uncured light-cured resin based composites in described microcapsule, colours.To adapt to face Color or patterning requirement.
It is mixed with pigment in the uncured light-cured resin based composites that two film interlayers of described matrix are filled, carries out Coloring, to adapt to color or patterning requirement.
It is mixed with pigment in uncured light-cured resin based composites and is mixed with electroluminescent powder, and be embedded with wire.With Facilitate implementation electroluminescent, thus realize illumination or beautify.
Also including a light-shielding container, described flexible plastic plastic material leaves in described light-shielding container after folding, in order to In longer-term storage.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of the present invention；
Fig. 2 is the another kind of structural representation of the present invention；
Fig. 3 is the another kind of structural representation of the present invention；
Fig. 4 is the another kind of structural representation of the present invention.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Conjunction is specifically illustrating, and the present invention is expanded on further.
With reference to Fig. 1, Fig. 2, Fig. 3 and Fig. 4, flexible plastic plastic material, including a matrix, matrix includes two, two films Constitute an interlayer between layer 11, in interlayer, be provided with at least two granule 12, be filled with uncured light between at least two granule 12 solid Change polymer matrix composites；In two film layers 11, at least one film layer is light transmissive material.Irradiated by light, it is achieved uncured light The solidification of solidification polymer matrix composites, so that position is fixed between granule 12 and granule 12, and then makes base shape obtain With fixing, and then realize the solidification of flexible plastic plastic material.Because significant portion material is granule 12, rather than light-cured resin Based composites, so cost is relatively low.
A light shield layer can be provided with, to avoid it slowly to consolidate during storing outside the film layer that employing light transmissive material is made Change, affect performance.Light shield layer is provided with at least one bonding strength and is prone to the unlatching line 3 at other positions, as bonding strength is relative What other positions were more weak opens line or the bonding strength unlatching line stronger relative to other positions.Owing to opening line 3 and other portions The bonding strength divided is inconsistent, and the place that light shield layer changes readily along bonding strength is torn, thus by opening line 3 side Just remove light shield layer.
Granule 12 can be foam beads, bead, glass microballoon, metallic particles, building stones granule, plastic grain etc..Excellent Select bead and glass microballoon.Plastic grain can also is that recycled plastic granules, and the raw material of recycled plastic granules can be to add Among the process of work virgin material, remaining little corner, or the raw material that quality does not passes a test.Such as: the leftover pieces that do not land, under Corner material, regrinding-material, rubber head material etc..The raw material of recycled plastic granules can also is that the most used virgin material or used repeatedly Discarded plastics.Use recycled plastic granules the most cost-effective.
Two described film layers 11 use flexibility or elastomeric material to make.Flexible material is used to be easy to make total present soft Property, can carry out bending, stretch, manufacture depression or protruding, it is allowed to bending is deposited.Flexible plastic plastic material can be prefabricated into Certain form, employing elastomeric material allows to deposit and carries out part deformation in transportation, to facilitate storage, is easy to multiple during use Originally it was the form being prefabricated into.
Described granule 12 is flexible, in order to makes total present flexibility, allows for bending and deposit.Preferred foams Grain, flexiplast granule etc..
As a kind of preferred version, the distance between two described film layers 11 is more than 2 times of described granule 12 average thickness.With It is easy between granule 12 be overlapped mutually, strengthens mechanical performance.
It is opaque for having one in two film layers 11 of described matrix, in case penetrating whole base carrying out light irradiation time line Body.An inner side in two film layers 11 of described matrix can be reflective material, in order to by light line reflection, promotes real as early as possible Now solidify, and save light energy.
It is provided with the structure of the flexible plastic plastic material of microcapsule 13: between two film layers 11, be also provided with microcapsule 13, microcapsule Uncured light-cured resin based composites it is filled with in 13.To improve mechanical property.Microcapsule wall can use flexible material Make.So that making total present flexibility, allowing for bending and depositing.The thickness of microcapsule 13 could be arranged to less than two The half of the distance between film layer 11.So that being overlapped mutually.Can not be by uncured light-cured resin base in part microcapsule 13 Composite is full of, and fills solid particle or gas, with tuning performance in remaining space.The solid particle filled can be bubble Foam, bead, metallic particles, building stones granule, plastic grain etc..
Pigment can be mixed in uncured light-cured resin based composites in microcapsule 13, colour.To adapt to Color or patterning requirement.Microcapsule wall preferred elastomeric material.So that more random carrying out bends, strengthen and deposit and use Random.
See Fig. 2, be provided with the structure of the filled type photo-curing material of auxiliary film: a film layer of matrix is positioned at lower section, on Side is fixed with one layer of auxiliary, and 14, auxiliary film 14 is fixed with granule 12.By granule 12 is arranged in auxiliary film 14, make auxiliary Help film 14 that granule 12 is played certain fixation.And then make granule 12 arrangement will not excessively concentrate at one or excessively divide Dissipate.In the case of being provided with auxiliary film 14, the thickness of granule 12 can be equal to or slightly less than the distance between two film layers 11, i.e. Grain 12 is monolayer arrangement in auxiliary film.Two-layer or the above additional film layer of two-layer can be set between two film layers 11.Film layer in Fig. 2 Two-layer auxiliary film it is provided with between 11.
It is provided with the structure of the filled type photo-curing material of vesicle 15: the capsule of gas between two film layers 11, in arranging, can be filled with Bubble 15.Thus reduce weight.
See Fig. 3, be provided with the structure of the filled type photo-curing material of support member 16: flexible plastic plastic material includes two Matrix, two matrixes be arranged in parallel, are provided with support member 16 between matrix and matrix, and support member 16 is filled with uncured light in being solid Change the flexible pipe body of polymer matrix composites.Before not solidifying, support member 16 and two matrixes are flexibility, permit Permitted bending, and the distance between matrix and matrix be can not get fixing, so the thickness of flexible plastic plastic material is before curing Can be relatively thin.
As a kind of preferred version, two matrix peripheral sealings, and it is provided with an air inlet 2.Two matrixes of air inlet UNICOM Between space.When depositing, the air between two matrixes is extracted out, makes support member bend, and then make two matrixes inwardly close up, Thinning, it is simple to deposit.
Before curing, by being filled with air in the air inlet 2 space between two matrixes, and then two matrixes are made to separate also Spreading, makes support member 16 stretching open, then carries out photocuring.So that two matrixes and support member 16 solidify respectively, thus Make flexible plastic plastic material can possess certain thickness after hardening, and because for hollow structure, so lighter in weight.
Matrix number can increase as required, and each matrix be arranged in parallel, is provided with support member, each matrix week between matrix and matrix Limit seals, and by internal passage UNICOM, is provided with an air inlet, the space between air inlet UNICOM matrix.When depositing, will Air between matrix is extracted out, makes support member bend, and then makes matrix inwardly close up, thinning, it is simple to deposit.Before curing, pass through Air inlet is filled with air in the space between two matrixes, and then makes two matrixes separate and spreading, makes support member stretching open, so After carry out photocuring.So that two matrixes and support member solidify respectively, so that described granule 12 filled type photocuring material Material can possess certain thickness after hardening, and because for hollow structure, so lighter in weight.This structure is particularly well-suited to soft Property moldable plastic material make brick situation, and do in the granule 12 filled type photo-curing material of brick can arrange more Inside it is filled with the vesicle of gas, to alleviate brick body quality.
Support member one end is fixed on the matrix of side, forms a summit, is at least further fixed on another support member at apex One end, i.e. one apex is fixed with at least two support members；Side matrix is total to the support member on summit, at opposite side base Summit no longer it is total on body.Therefore two can constitute a triangular shape structure between support member and matrix, because triangular shape structure has surely Determine feature, can be with the stability of reinforcing material.Support member can also use elastomeric material to make, such filled type photo-curing material The setting shape of filled type photo-curing material after external pressure removes, can be automatically restored to by the elasticity of support member.
One apex can draw two, three or four support members, it is also possible to draws more.But preferably draw three Root, the structure of four support members.Each apex can be used all to draw the structure of two, three or four support members, so that knot Structure consolidates.
User, can be separately provided microcapsule, auxiliary film, vesicle or support member, it is also possible to as required by microcapsule, auxiliary Film, vesicle or support member are arranged after being combined, and have the characteristic of granule additionally, due to microcapsule and vesicle, therefore can regard as respectively Granule, different according to the implant in microcapsule, the granule with different performance can be regarded as, be filled with in vesicle is gas, can To regard gas particles as.
In order to increase the fastness of the filled type photo-curing material after solidification, in two film layers 11 at least one layer be explosion-proof Film or shellproof film.In order to prevent photocuring middle-ultraviolet lamp from leaking outside, and also function to completely cut off the effect of ultraviolet, two films after hardening Layer 11 in wherein one layer be anti-ultraviolet film.
The described preferred laminated structure of flexible plastic plastic material.Can realize during use carrying out cutting, fold, the behaviour such as bend The combination of one or more operations in work, thus obtain the contoured article needed, then solidify.For complexity Each simple parts can be solidified, assemble after solidification by structure respectively.Can also be combined before curing, Solidify after combining, in order to be firmly combined with.
Seeing Fig. 4, flexible plastic plastic material can also use tubular structure, i.e. matrix to use tubular structure.It is positioned at pipe Film layer 11 outside shape matrix is light transmissive material.Can realize during use carrying out cutting, bend, one in the operation such as stretching or The combination of more than one operations, thus obtain the pipe shape needed, then solidify.Such as: need a straight tube, can be by Flexible plastic plastic material carries out cutting and directly obtains；When the caliber needed is less than the external diameter of matrix, matrix can be carried out Hold, draw etc. operates, and forces flexible plastic plastic material to attenuate, is then inserted into carrying out in the pipe of the caliber uniform internal diameter needed Solidifying and setting；When the caliber needed is more than the external diameter of matrix, an expansion thing can be inserted at matrix, force flexible plastic to be moulded Material material is expanding, then carries out solidifying and setting；When needs bend pipe, it can be bent, obtain the shape needed, enter the most again Row solidification.When making water pipe again, metallic particles preferred aluminum particulate granule.Uncured light-cured resin based composites is contained within Resin-based materials preferably polyethylene, polybutene or polyacrylic resin material.
Flexible plastic plastic material can also use linear structure, and theca externa is tubular structure, and theca interna is reduced to be positioned at Using an enhancing muscle in the theca externa of tubular structure, theca externa is light transmissive material, and described theca interna can use fiber to increase Strong material is made, fibre reinforced materials can use the one in the reinforcing fibers such as glass fibre, Plant fiber, carbon fiber or Several.Can also use another kind of structure, two film layer avris are connected, and constitute a tubular body, and two film layers all use printing opacity material Material is made.
Described flexible plastic plastic material prop up after for component shape to be formed, or be the combination of multiple parts. During use, after taking-up material is propped up, carry out solidifying the parts that i.e. can obtain needing.Described props up operation, can be by one Parts are individually propped up, or by realizing propping up operation after several unit constructions, constitute the article needed.
Described flexible plastic plastic material is hollow tubular after propping up.Pipe fitting or pipe fitting joint is become after solidification.Described soft Property moldable plastic material prop up after for brick shape.Brick is become after solidification.Described flexible plastic plastic material is ship shape after propping up.Solidification After become ship.Described flexible plastic plastic material is house shape after propping up.House is become after solidification.Described flexible plastic plastics Material is device housings shape after propping up.Device housings is become after solidification.Described flexible plastic plastic material is desk after propping up Shape.Desk is become after solidification.Described flexible plastic plastic material is chair shape after propping up.Chair is become after solidification.Described Flexible plastic plastic material is bed body shape after propping up.Bed is become after solidification.Described flexible plastic plastic material is cabinet after propping up Sub-shape.Cupboard is become after solidification.Described flexible plastic plastic material is fish jar shape after propping up.Fish jar is become after solidification.Institute State after flexible plastic plastic material is propped up as vase shape.Described flexible plastic plastic material is tea table shape after propping up.Solidification After become tea table.Described flexible plastic plastic material is gear shape after propping up.Gear is become after solidification.
For with the large components such as ship, house, device housings, required flexible plastic plastic material includes two bases Body, two matrixes be arranged in parallel, are provided with support member between described matrix and matrix, and described support member is flexible pipe body, flexible pipe body Inside it is filled with uncured light-cured resin based composites.So that shrinking the mechanical strength after depositing and strengthen solidification.
In advance the described flexible plastic plastic material after inflation is shaped to the shape of required parts, makes at needs Used time, gas is filled with the shape that can present parts, is solidified the parts that i.e. can obtain needing by light.
Being embedded with fibre reinforced materials in the uncured resin-based materials in light-cured resin based composites, fiber increases Strong material can use one or several in the reinforcing fibers such as glass fibre, Plant fiber, carbon fiber.
It is mixed with pigment in the uncured light-cured resin based composites filled between two film layers 11 of described matrix, enters Row coloring, to adapt to color or patterning requirement.
It is mixed with pigment in uncured light-cured resin based composites and is mixed with electroluminescent powder, and be embedded with wire.With Facilitate implementation electroluminescent, thus realize illumination or beautify.Such as in the case of there is alternating electric field, electroluminescent powder energy Enough luminescences.
Optical fibers can also be filled, at fibre-optic one end or two ends, also in described flexible plastic plastic material Light source can be provided with.If the optical fibers optical fibers that to be body luminous, then can by light source illuminate optical fibers and then Illuminate whole flexible plastic plastic material.Light source can be LED light source.
As a kind of preferred version, flexible plastic plastic material can also use tubular structure, i.e. matrix to use tubulose knot Structure.It is provided with wire or optical fibers, wire or optical fibers in internal membrane layer and can insert tubulose by the way of outside is inserted In film layer inside matrix, it is also possible to be directly embedded in flexible plastic plastic material, i.e. can use and be positioned at inside tubular matrix Film layer as the external insulation layer of wire, can use and be positioned at the film layer inside tubular matrix as retraining fibre-optic bundle The restraint layer of position, optical fibers selects the optical fibers that body is luminous.When the structure that the optical fibers that body is luminous is built-in, it is positioned at Film layer inside tubular matrix can be light transmissive material, and being positioned at the film layer outside tubular matrix can be light screening material, utilizes light Lead the light that fiber sends to be solidified.
With reference to Fig. 4, also including a light-shielding container 4, described flexible plastic plastic material leaves described shading in after folding holds In device 4, in order to longer-term storage.Light-shielding container 4 is provided with the opening 5 that can open.Before using, flexible plastic plastic material is put Put in the light-shielding container 4 with shade function, keep in Dark Place.During use, flexible plastic plastic material is held in shading Take out in device 4.After being fabricated to the shape needed, solidify, Burdick lamp can be opened and help to accelerate curing rate.
It addition, at least one film layer of flexible plastic plastic material can also is that layers of elastomeric film made by elastomeric material, elastic The advantage of film layer has a lot: 1. transport and during storage, can compel it and carry out certain deformation, to build small size, saves Space；2. use time, external force can be removed, utilize the elasticity of himself to carry out certain recovery, it is therefore not necessary to as above that Sample is inflated, but can be by the mode of inflation, accelerates it and restores speed；3. for repair or to need further deformation Place, it is possible to use its elastic force suitably deforms in the case of not changing big profile.This structure is particularly well-suited to film When layer has certain shape, matrix is made as the article that has specific modality in advance.
Such as: matrix is enclosed type, such as spherical, jar, chest, including two film layers, internally positioned film layer is inner membrance Layer, externally-located film layer are theca externa, and theca interna uses elastomeric material to make.Spherical substrate is provided with air-filled pore, transport and During storage, extruded through internal gas by air-filled pore, to reduce volume.During use, external force is removed, enter in air-filled pore Entering gas, theca interna restores gradually, it is also possible to by the way of inflating, and accelerates it and restores speed.If theca externa uses Flexible material, on the one hand the theca externa that flexible material is made during transport and storage, can buffer external pressure and play protection Effect；When on the one hand making, the transmutability of flexible material is utilized can skin patching and embossing etc. to be deformed.
The most such as: matrix is type semienclosed, include two film layers such as bowl, spoon, cup, plate, ashtray etc., be positioned at The film layer in portion be theca interna, externally-located film layer be theca externa, theca interna uses elastomeric material to make, the mistake transported and store Cheng Zhong, external force compels its deformation, to reduce volume.During use, external force being removed, theca interna restores gradually, it is also possible to pinched by hands, The modes such as beating, stretching, accelerate it and restore speed.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (10)

1. flexible plastic plastic material, including light-cured resin based composites, it is characterised in that include a matrix, described base Body includes that two film layers, two described film interlayers constitute an interlayer, is provided with at least two granule, at least two institute in described interlayer State and between granule, be filled with uncured light-cured resin based composites；In two described film layers, at least one film layer is printing opacity material Material.
Flexible plastic plastic material the most according to claim 1, it is characterised in that: granule is foam beads, bead, glass Glass microballon, metallic particles, building stones granule or plastic grain.
Flexible plastic plastic material the most according to claim 1, it is characterised in that: two described film layers are flexible or bullet Property.
Flexible plastic plastic material the most according to claim 1, it is characterised in that: described granule is flexible particle.
Flexible plastic plastic material the most according to claim 1, it is characterised in that: the distance of two described film interlayers is more than 2 times of described granule average thickness.
Flexible plastic plastic material the most as claimed in any of claims 1 to 5, it is characterised in that: two described films Interlayer is also provided with microcapsule, is filled with uncured light-cured resin based composites in microcapsule, and the thickness of described microcapsule can To be set smaller than the half of the distance of two described film interlayers.
Flexible plastic plastic material the most according to claim 6, it is characterised in that: under a film layer of described matrix is positioned at Side, is fixedly arranged above one layer of auxiliary film, described auxiliary film is fixed with described granule.
Flexible plastic plastic material the most according to claim 6, it is characterised in that: two described film interlayers are filled with in arranging The vesicle of gas.
Flexible plastic plastic material the most according to claim 6, it is characterised in that: flexible plastic plastic material includes two Matrix, two matrixes be arranged in parallel, are provided with support member between described matrix and matrix, and described support member is flexible pipe body, flexible pipe Internal it is filled with uncured light-cured resin based composites.
Flexible plastic plastic material the most according to claim 9, it is characterised in that: described support member one end is fixed on one On the matrix of side, forming a summit, be at least further fixed on one end of another support member at described apex, i.e. one apex is fixed There are at least two support members；Side matrix is total to the support member on summit, opposite side matrix is no longer total to summit.
CN201610637494.3A 2012-04-13 2012-04-13 Flexible plastic plastic material and its application Expired - Fee Related CN106256524B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610637494.3A CN106256524B (en) 2012-04-13 2012-04-13 Flexible plastic plastic material and its application

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210109327.3A CN103373026B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material and application thereof
CN201610637494.3A CN106256524B (en) 2012-04-13 2012-04-13 Flexible plastic plastic material and its application

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201210109327.3A Division CN103373026B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material and application thereof

Publications (2)

Publication Number Publication Date
CN106256524A true CN106256524A (en) 2016-12-28
CN106256524B CN106256524B (en) 2019-04-30

Family

ID=49459144

Family Applications (5)

Application Number Title Priority Date Filing Date
CN201610635613.1A Expired - Fee Related CN106239992B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material
CN201210109327.3A Active CN103373026B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material and application thereof
CN201610637724.6A Expired - Fee Related CN106273117B (en) 2012-04-13 2012-04-13 Filled type photo-curing material
CN201610637494.3A Expired - Fee Related CN106256524B (en) 2012-04-13 2012-04-13 Flexible plastic plastic material and its application
CN201610637495.8A Expired - Fee Related CN106273677B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material

Family Applications Before (3)

Application Number Title Priority Date Filing Date
CN201610635613.1A Expired - Fee Related CN106239992B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material
CN201210109327.3A Active CN103373026B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material and application thereof
CN201610637724.6A Expired - Fee Related CN106273117B (en) 2012-04-13 2012-04-13 Filled type photo-curing material

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201610637495.8A Expired - Fee Related CN106273677B (en) 2012-04-13 2012-04-13 Particles filled formula photo-curing material

Country Status (1)

Country Link
CN (5) CN106239992B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106273476B (en) * 2012-04-27 2019-07-05 上海科斗电子科技有限公司 Rapid prototyping material and plastic part quick molding method
CN112976432B (en) * 2021-01-26 2023-03-31 广东千大新材料有限公司 Preparation method of self-shedding and self-repairing type aerogel composite material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004131985A (en) * 2002-10-09 2004-04-30 Central Japan Railway Co Reinforcing prepreg sheet and the reinforcing method of concrete construction
US20040175521A1 (en) * 2001-07-09 2004-09-09 Tetsuya Nakamura Photo-curing hollow structure and method of curing the same
JP2005172180A (en) * 2003-12-15 2005-06-30 Yamagami Material Technologies Inc Method of manufacturing structure of fiber-reinforced plastic
CN102121673A (en) * 2010-01-11 2011-07-13 上海科斗电子科技有限公司 Photocuring lamp

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4709991A (en) * 1983-04-26 1987-12-01 Seiko Epson Kabushiki Kaisha Liquid crystal display with barrier layer to reduce permeability
JPH08258164A (en) * 1995-03-23 1996-10-08 Entoo Kk Fiber-reinforced plastic and molding method therefor
CN202121673U (en) * 2010-11-22 2012-01-18 中山爱科数字科技有限公司 Telephone and telephone system
CN202805772U (en) * 2012-04-13 2013-03-20 上海科斗电子科技有限公司 Functional photocuring material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040175521A1 (en) * 2001-07-09 2004-09-09 Tetsuya Nakamura Photo-curing hollow structure and method of curing the same
JP2004131985A (en) * 2002-10-09 2004-04-30 Central Japan Railway Co Reinforcing prepreg sheet and the reinforcing method of concrete construction
JP2005172180A (en) * 2003-12-15 2005-06-30 Yamagami Material Technologies Inc Method of manufacturing structure of fiber-reinforced plastic
CN102121673A (en) * 2010-01-11 2011-07-13 上海科斗电子科技有限公司 Photocuring lamp

Also Published As

Publication number Publication date
CN103373026A (en) 2013-10-30
CN106273677A (en) 2017-01-04
CN106273677B (en) 2018-12-11
CN106273117A (en) 2017-01-04
CN106239992A (en) 2016-12-21
CN103373026B (en) 2016-12-14
CN106239992B (en) 2018-11-06
CN106256524B (en) 2019-04-30
CN106273117B (en) 2019-04-23

Similar Documents

Publication Publication Date Title
CN101736476A (en) Foam filled stereoscopic reinforced material
CN106256524A (en) Flexible plastic plastic material and application thereof
CN103372937B (en) Micro-capsule photo-curing material and application thereof
CN107526125A (en) A kind of reflective storage light film of microballon exposed type colorful and its manufacturing process
CN202668828U (en) Resin product with supporting piece
CN202862722U (en) Lightweight resin-based product
US8210953B1 (en) Translucent closed-molded fiber-reinforced plastic and method of making the same
CN202805772U (en) Functional photocuring material
CN205438983U (en) Ball is mould for veneer gluing
CN108297457A (en) A kind of preparation method of composite material origami structure energy absorption devices
CN202656548U (en) Resin-based product convenient to transport
CN202805773U (en) High-strength light-curing product
CN208199305U (en) A kind of degradable high mineral type courier bag
CN102121673B (en) Photocuring lamp
CN103373009B (en) Plastic part rapid manufacture special material and use this material to carry out working of plastics to draw a design or the technique of production
CN204172613U (en) Level is exempted to fill integrated tyre
CN206367246U (en) Novel degradable plastic sheeting
WO2011140691A1 (en) Delaminated package type inflatable product with high intensity and compression resistance
CN202781966U (en) Photo-curing tube
CN206465575U (en) A kind of heat reflection vacuum ambetti
CN206327696U (en) A kind of reflective flame retardant woven bag
WO2014198990A1 (en) Method for producing a lightweight textured shower tray and lightweight textured shower tray produced by said method
CN208199252U (en) A kind of biodegrade courier bag
CN104874184A (en) Inflatable toy and production method thereof
CN205871386U (en) Novel packing plastic film

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20201216

Address after: No.36, Chengliu village, Zhongxing Town, Shan county, Heze City, Shandong Province, 274300

Patentee after: Sui Meiqing

Address before: 201111 577, room second, 5500 Yuanjiang Road, Minhang District, Shanghai.

Patentee before: SHANGHAI KE DOU ELECTRONIC TECHNOLOGY Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20190430