CN106255488A - 污染织物倾向性降低的防晒制剂i - Google Patents
污染织物倾向性降低的防晒制剂i Download PDFInfo
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- CN106255488A CN106255488A CN201580023449.2A CN201580023449A CN106255488A CN 106255488 A CN106255488 A CN 106255488A CN 201580023449 A CN201580023449 A CN 201580023449A CN 106255488 A CN106255488 A CN 106255488A
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- triazine
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Abstract
本发明涉及一种化妆品制剂,其含有a)2,4‑双‑{[4‑(2‑乙基‑己氧基)‑2‑羟基]‑苯基}‑6‑(4‑甲氧基苯基)‑1,3,5‑三嗪(INCI:双‑乙基己氧苯酚甲氧苯基三嗪)和b)一种或多种选自带有少于两个氮原子的膦酸、磷酸和羧酸,和/或其碱金属盐和/或其胺N‑氧化物的组的络合剂。
Description
技术领域
本发明涉及一种化妆品制剂,其含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)和一种或多种选自带有少于两个氮原子的膦酸、磷酸和羧酸,和/或其碱金属盐和/或其胺N-氧化物的组的络合剂。
背景技术
从精致的白皮肤到“健康、运动型的褐色皮肤”的潮流经年未断。为了获得这样的肤色,人们将其皮肤暴露于太阳辐射,因为这从形成黑素方面导致了色素的形成。然而,太阳光的紫外辐射也对皮肤具有损害作用。除了急性损害(晒伤)以外,还发生长期的损害,例如在用来自UVB区域(波长:280-320nm)的光过度照射的情况下提高的皮肤癌发病风险。UVB和UVA(波长:320-400nm)辐射的过度作用此外还导致结缔组织的弹性纤维和胶原纤维的弱化。这导致很多光中毒和光过敏反应并导致过早的皮肤老化。
因此,为了保护皮肤,开发了一系列可以用于化妆品制剂中的防晒滤光物质。这些UVA和UVB滤光剂在多数工业国以正面清单的形式汇总,例如化妆品法规的附录7(Anlage 7der Kosmetikverordnung)。
然而,市售防晒剂的多样性不应当掩盖现有技术的制剂具有一系列缺点这一事实。
施加于皮肤上的化妆品制剂例如防晒制剂经常(有意或无意地)与衣物和洗涤用品(例如毛巾)发生接触,它们在其上部分地保持粘附(例如由于“擦蹭”或者由于它们被纤维材料“吸收”)。根据成分的类型,以这种方式尤其在浅色织物上产生污点和变色。变色尤其通过非水溶性的UVA和宽带滤光剂引起。这种污染非常难以通过用常规洗涤剂的洗涤去除,并且由于与洗涤水的离子的相互作用在洗涤过程中甚至进一步加重。
虽然本领域技术人员已知文献WO 2011/101250,然而该文献没有教导本发明的路径。
文献WO 2012078961说明了一种螯合聚合物,其用于阿伏苯宗的光稳定以及减少在硬水中洗涤时的有色络合物的形成,然而该文献同样没能教导本发明的路径。
此外,本领域技术人员原则上已知含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)和络合剂EDTA的化妆品制剂。然而EDTA的减少污染的作用限于在碱性介质中,如在洗涤水中所存在的那样。
发明内容
因此,本发明的任务是消除现有技术的缺点,并且开发一种含有非水溶性的宽带滤光剂如双-乙基己氧苯酚甲氧苯基三嗪的化妆品制剂(尤其是防晒剂),其能够容易地从被该制剂污染的织物上洗去。
该任务令人惊讶地通过一种化妆品制剂解决,其含有a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪),
b)一种或多种选自带有少于两个氮原子的膦酸、磷酸和羧酸,和/或其碱金属盐和/或其胺N-氧化物的组的络合剂。
根据本发明有利的是,根据本发明的制剂以相对于制剂的总重量的0.01至10重量%的量含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪。
根据本发明有利的是,根据本发明的制剂以相对于制剂的总重量的2至5重量%的量含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪。
在本发明的意义上有利的是,根据本发明的制剂以相对于制剂的总重量的0.1至3重量%的总量含有一种或多种络合剂b)。
在本发明的意义上有利的是,根据本发明的制剂以相对于制剂的总重量的0.5至1.5重量%的总量含有一种或多种络合剂b)。
根据本发明,本发明的优选实施方式的特征在于,络合剂b)选自化合物氨基聚羧酸盐、聚膦酸盐、聚磷酸盐和络合酸的组。
在这种情况下根据本发明优选的是,使用选自以下组的一种或多种化合物作为络合剂b):
-1-羟基乙烷-(1,1-二膦酸)/HEDP
-氨基三亚甲基膦酸/ATMP
-二亚乙基三胺五(亚甲基膦酸)/DTPMP
-乙二胺四(亚甲基膦酸)/EDTMP
-膦酸丁烷三羧酸/PBTC
-亚氨基二琥珀酸盐
-多聚磷酸钠
-焦磷酸四钠
-异羟肟酸
-聚半乳糖醛酸
-琥珀酸
-甲酸
-苹果酸
和/或其碱金属盐。
根据本发明,本发明的特别优选的实施方式的特征在于,使用选自以下组的一种或多种化合物作为络合剂b):
-二亚乙基三胺五(亚甲基膦酸)/DTPMP
-乙二胺四(亚甲基膦酸)/EDTMP
-氨基三亚甲基膦酸/ATMP
-亚氨基二琥珀酸盐
-多聚磷酸钠
-焦磷酸四钠
-琥珀酸
和/或其碱金属盐。
在这种情况下钠盐和钾盐作为根据本发明有利的碱金属盐,其中根据本发明优选的是钠盐。
根据本发明,本发明的有利的实施方式的特征在于,2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪与b)组络合剂总量的重量比例为5:1至5:3。
根据本发明有利的是,根据本发明的制剂以乳液的形式存在。在这种情况下根据本发明优选的是,制剂以水包油乳液(O/W乳液)的形式存在。
在这种情况下,本发明的根据本发明的有利实施方式的特征在于,制剂含有选自化合物甘油硬脂酸酯柠檬酸酯、鲸蜡硬脂醇、鲸蜡硬脂醇硫酸酯钠、甘油硬脂酸酯、鲸蜡硬脂醇磺基琥珀酸酯、硬脂酰谷氨酸钠、聚甘油-3甲基葡糖二硬脂酸酯、聚甘油-3甲基葡糖二硬脂酸酯、硬脂酸、鲸蜡醇磷酸酯钾的组的一种或多种乳化剂。
对本发明而言有利的是,该化妆品制剂的特征在于该制剂含有一种或多种UV滤光剂,该滤光剂选自以下化合物的组:2-苯基苯并咪唑-5-磺酸和/或其盐;亚苯基-1,4-双-(2-苯并咪唑基)-3,3'-5,5'-四磺酸盐;1,4-二(2-氧代-10-磺基-3-亚冰片基甲基)-苯及其盐;4-(2-氧代-3-亚冰片基甲基)苯磺酸盐;2-甲基-5-(2-氧代-3-亚冰片基甲基)磺酸盐;2,2'-亚甲基-双-(6-(2H-苯并三唑-2-基)-4-(1,1,3,3-四甲基丁基)-苯酚);2-(2H-苯并三唑-2-基)-4-甲基-6-[2-甲基-3-[1,3,3,3-四甲基-1-[(三甲基甲硅烷基)氧基]二硅氧烷基]丙基]-苯酚;3-(4-甲基亚苄基)樟脑;3-亚苄基樟脑亚苄基樟脑;水杨酸乙基己酯;对苯二亚甲基二樟脑磺酸;2-乙基己基-2-氰基-3,3-二苯基丙烯酸酯;4-(二甲基氨基)-苯甲酸(2-乙基己基)酯;4-(二甲基氨基)苯甲酸戊酯;4-甲氧基亚苄基丙二酸二(2-乙基己基)酯;4-甲氧基肉桂酸(2-乙基己基)酯;4-甲氧基肉桂酸异戊酯;2-羟基-4-甲氧基二苯甲酮;2-羟基-4-甲氧基-4'-甲基二苯甲酮;2,2'-二羟基-4-甲氧基二苯甲酮;水杨酸高酯;2-乙基己基-2-羟基苯甲酸酯;聚二甲基硅氧烷二乙基亚苄基丙二酸酯;3-(4-(2,2-双乙氧基羰基乙烯基)-苯氧基)丙烯基)-甲氧基硅氧烷/二甲基硅氧烷共聚物;2-(4'-二乙基氨基-2'-羟基苯甲酰基)-苯甲酸己酯;二辛基丁基酰氨基三嗪酮(INCI:二乙基己基丁酰氨基三嗪酮);2,4-双-[5-1(二甲基丙基)苯并噁唑-2-基-(4-苯基)-亚氨基]-6-(2-乙基己基)-亚氨基-1,3,5-三嗪(CAS号288254-16-0);4-(叔丁基)-4'-甲氧基二苯甲酰基甲烷;4,4',4”-(1,3,5-三嗪-2,4,6-三基三亚氨基)-三苯甲酸三(2-乙基己酯)(也称为:2,4,6-三-[苯胺基-(p-碳-2'-乙基-1'-己氧基)]-1,3,5-三嗪(INCI:乙基己基三嗪酮));2,4,6-三联苯-4-基-1,3,5-三嗪;部花青;二氧化钛;氧化锌。
在这种情况下根据本发明特别优选的是根据本发明的组合物没有3-(4-甲基亚苄基)樟脑和2-羟基-4-甲氧基二苯甲酮(氧苯酮)。
根据本发明有利的实施方式可以通过以下方式获得,即,使制剂含有乙基己基甘油、聚甘油-2癸酸酯、丙二醇、丁二醇、2-甲基-1,3-丙二醇、1,2-戊二醇、1,2-己二醇、1,2-辛二醇和/或1,2-癸二醇。
根据本发明有利的是制剂含有苯氧乙醇和/或对羟基苯甲酸甲酯。
在这种情况下根据本发明优选的是,制剂没有对羟基苯甲酸丙酯和对羟基苯甲酸丁酯、3-碘-2-丙炔基丁基氨基甲酸酯。
根据本发明有利的实施方式的特征还在于,制剂含有一种或多种选自化合物木兰提取物、甘草次酸、尿素、牛蒡苷、α-硫辛酸、叶酸、八氢番茄红素、D-生物素、辅酶Q10、α-葡糖基芸香苷、肉碱、肌肽、咖啡因、天然和/或合成异黄酮、葡萄糖基甘油酯、肌酸、肌酸酐、牛磺酸、生育酚、生育酚乙酸酯、β-丙氨酸和/或甘草查尔酮A的组的有效物质。
根据本发明的制剂还可以有利地含有甘油和/或乙醇。在这种情况下,根据本发明有利的是,甘油浓度为相对于制剂的总重量的0.01至10重量%。针对乙醇,根据本发明的使用范围相对于制剂的总重量在0.01与10重量%之间。
此外,根据本发明的制剂的油相还可以含有其他的油、脂或蜡成分,例如选自以下组的极性油:卵磷脂或化合物,譬如椰油酸甘油酯、辛酸/癸酸甘油三酯、橄榄油、葵花籽油、霍霍巴油、大豆油、花生油、菜籽油、杏仁油、棕榈油、椰子油、蓖麻油、小麦胚芽油、葡萄籽油、红花油、月见草油、澳洲坚果油等。也可以使用化合物如苯甲酸苯乙酯、2-苯甲酸苯乙酯、月桂酰肌氨酸异丙酯、苯基三甲基聚硅氧烷、环甲基聚硅氧烷、己二酸二丁酯、棕榈酸辛酯、椰油酸辛酯、异硬脂酸辛酯、辛基十二醇肉豆蔻酸酯、辛基十二烷醇、鲸蜡硬脂醇异壬酸酯、肉豆蔻酸异丙酯、硬脂酸异丙酯、油酸异丙酯、硬脂酸正丁酯、月桂酸正己酯、油酸正癸酯、硬脂酸异辛酯、硬脂酸异壬酯、异壬酸异壬酯、2-乙基己基棕榈酸酯、2-乙基己基月桂酸酯、2-己基癸基硬脂酸、2-辛基十二烷基棕榈酸酯、硬脂醇庚酸酯、油醇油酸酯、油醇芥酸酯、瓢儿菜醇油酸酯、瓢儿菜醇芥酸酯、十三烷醇硬脂酸酯、十三烷醇偏苯三酸酯。
此外根据本发明有利的是动物或植物来源的天然蜡,譬如蜂蜡和其它昆虫蜡,以及浆果蜡、牛油树脂和/或羊毛脂(羊毛蜡)
此外,油相可以有利地选自二烷基醚和二烷基碳酸酯的组,例如有利的是二辛醚(Cetiol OE)和/或碳酸二辛酯,其例如能以商品名Cetiol CC从Cognis公司获得。
此外有利的是,一种或多种油成分选自以下组:异二十烷、新戊二醇二庚酸酯、丙二醇二辛酸酯/二癸酸酯、辛酸/癸酸/二甘油琥珀酸酯、丁二醇二辛酸酯/二癸酸酯、C12-13烷基乳酸酯、二C12-13烷基酒石酸酯、三异硬脂精、二聚季戊四醇六辛酸酯/六癸酸酯、丙二醇单异硬脂酸酯、三辛精、异山梨醇二甲醚。特别有利的是,根据本发明的配制物的油相具有C12-15烷基苯甲酸酯组分。
此外,有利的油成分例如是棕榈酸异丙酯、肉豆蔻酸肉豆蔻酯、丁基辛基水杨酸酯(例如以商品名Hallbrite BHB从CP Hall公司获得)、十三烷醇水杨酸酯(其例如以商品名Cosmacol ESI从Sasol公司获得)、C12-15烷醇水杨酸酯(其例如以商品名Dermol NS从Alzo公司获得)、十六烷基苯甲酸酯和丁基辛基苯甲酸酯以及它们的混合物(Hallstar AB)。
在本发明的意义上,使用这些油成分和蜡成分的任意混合物也是有利的。
同样,油相还有利地可以含有非极性的油,例如选自支链或非支链的烃或烃蜡的组,尤其是矿物油、凡士林(矿脂)、石蜡油、角鲨烷和角鲨烯、聚烯烃、氢化聚异丁烯、C13-16异链烷烃和异十六烷。对于聚烯烃,聚癸烯是优选物质。
根据本发明,本发明的有利的实施方式的特征还在于,乳液含有聚二甲基硅氧烷和/或环聚二甲基硅氧烷。
作为用于提高耐水性的聚合物成膜剂,根据本发明的制剂根据本发明可以有利地含有乙烯基吡咯烷酮/十六碳烯共聚物。此外,添加剂根据本发明有利地是木薯淀粉。
根据本发明的制剂尤其是可以有利地作为日用护理产品或防晒剂使用。
根据本发明,还涉及了一种使含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)的化妆品制剂从织物的可洗出性变容易的方法,其特征在于,向该化妆品添加一种或多种根据本发明的络合剂。
还涉及了一种减少由含有UV防晒滤光剂(尤其是2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪))的化妆品制剂引起的织物污染的方法,其特征在于,化妆品根据本发明添加有一种或多种络合剂。
根据本发明,还涉及了根据本发明的络合剂在含有2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)的化妆品制剂中用于使UV防晒滤光剂从被所述制剂污染的织物的可洗出性变容易的用途,以及根据本发明的络合剂在含有UV防晒滤光剂(尤其是2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪))的化妆品制剂中用于减少由所述制剂引起的织物污染的用途。
具体实施方式
对比实验
用下面的实验可以示例性地证明本发明的效果:
分别将1%的根据本发明的助剂添加到含有双-乙基己氧苯酚甲氧苯基三嗪的配制物中,并借助所描述的方法确定与没有根据本发明的络合剂的配制剂相比的污染降低效果(减少b*)。
作为根据本发明的制剂的改善的可洗出性和污点的形成减少的证明,进行离体研究,其结果示于图1和表1中。
针对在一个离体施加周期/洗涤周期中黄色污点的形成,研究了不同的防晒乳液。在这里使用白色的经过预洗的棉质监视样(Monitore)(100%棉)。为此,将每25mg测试配制剂均匀地分布在PMMA 板上(5.0×5.0cm)并直接通过按压转移到测试织物上。随后将有污染的棉质试样在实验条件下在空气中干燥12小时。
在干燥后通过用色度计spectro-color(Dr.Lange)进行黄度测量来进行所产生的初始污染的色度表征;色度软件:spectral-QC,测量几何版本:d/8°,排除闪光组件,光类型:D65(相当于平均日光),校准标准:LZM 268,测量孔:10mm,试样背景:没有光学增亮剂的衬纸,检测条件:21℃(±1℃),41%(±4%)相对空气湿度。
为了计值,使用来自CIE-Lab颜色测量系统的b值的变化。B轴在CIE-Lab系统中表示黄/蓝颜色印象,其中正的b值表示黄色分量增加。b值越高,黄色印象越大。
在测量过程之后,进行测试布料在颜色和洗涤牢度仪Linitest Plus(Atlas)中分别的洗涤(60℃,1小时,20rpm,Ariel Compact洗衣粉,10个金属球作为额外加载),随后进行漂洗过程(20℃,15分钟,自来水)。
在实验条件下干燥12小时后,重新通过用色度计spectro-color(Dr.Lange)如上所述进行色值测量来进行所产生的污染的色度表征。
CIE-Lab系统或者L*a*b*颜色空间是一种三维测量空间,其中包含了所有可感知的颜色。该颜色空间基于互补色理论构建。L*a*b*颜色模型的最重要的性质是其不依赖于仪器,也就是说颜色独立于其产生和再现技术的类型进行定义。
相应的EU指令为DIN EN ISO 11664-4“比色-第4部分:CIE 1976L*a*b*颜色空间”。CIELAB平面的坐标由红/绿值a和黄/蓝值b形成。亮度轴L垂直于该平面。根据DIN6174L、a和b以*描绘,以区别其他的例如“Hunter-Lab”系统。
表1:测试的制剂和其污染的黄色值降低状况–b*[%]
结果表明,通过使用络合剂与没有根据本发明的络合剂的配制物(实施例7)相比较污染明显减少。
实施例
下面的实施例用于解释本发明,而不对其构成限制。如无相反说明,所有的用量信息、份额以及百分比基于制剂的重量和总量或者基于总重量。
Claims (15)
1.一种化妆品制剂,其含有
a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪),
b)一种或多种选自带有少于两个氮原子的膦酸、磷酸和羧酸,和/或其碱金属盐和/或其胺N-氧化物的组的络合剂。
2.根据权利要求1所述的化妆品制剂,其特征在于,所述制剂以相对于制剂的总重量的0.01至10.0重量%的量含有a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)。
3.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂以相对于制剂的总重量的0.1至3重量%的总量含有一种或多种络合剂b)。
4.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,络合剂b)选自化合物氨基聚羧酸盐、聚膦酸盐、聚磷酸盐和络合酸的组。
5.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)与b)组络合剂总量的重量比例为5:1至5:3。
6.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,使用选自以下组的一种或多种化合物作为络合剂b):
-1-羟基乙烷-(1,1-二膦酸)/HEDP
-氨基三亚甲基膦酸/ATMP
-二亚乙基三胺五(亚甲基膦酸)/DTPMP
-乙二胺四(亚甲基膦酸)/EDTMP
-膦酸丁烷三羧酸/PBTC
-亚氨基二琥珀酸盐
-多聚磷酸钠
-焦磷酸四钠
-异羟肟酸
-聚半乳糖醛酸
-琥珀酸
-甲酸
-苹果酸
和/或其碱金属盐。
7.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,使用选自以下组的一种或多种化合物作为络合剂b):
-二亚乙基三胺五(亚甲基膦酸)/DTPMP
-氨基三亚甲基膦酸/ATMP
-乙二胺四(亚甲基膦酸)/EDTMP
-亚氨基二琥珀酸盐
-多聚磷酸钠
-焦磷酸四钠
-琥珀酸
和/或其碱金属盐。
8.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂以水包油乳液(O/W乳液)的形式存在。
9.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂含有选自化合物甘油硬脂酸酯柠檬酸酯、鲸蜡硬脂醇、鲸蜡硬脂醇硫酸酯钠+甘油硬脂酸酯、鲸蜡硬脂醇磺基琥珀酸酯、硬脂酰谷氨酸钠、聚甘油-3甲基葡糖二硬脂酸酯、聚甘油-3甲基葡糖二硬脂酸酯、硬脂酸、鲸蜡醇磷酸酯钾的组的一种或多种乳化剂。
10.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂含有一种或多种UV滤光剂,所述滤光剂选自以下化合物的组:2-苯基苯并咪唑-5-磺酸和/或其盐;亚苯基-1,4-双-(2-苯并咪唑基)-3,3'-5,5'-四磺酸盐;1,4-二(2-氧代-10-磺基-3-亚冰片基甲基)-苯及其盐;4-(2-氧代-3-亚冰片基甲基)苯磺酸盐;2-甲基-5-(2-氧代-3-亚冰片基甲基)磺酸盐;2,2'-亚甲基-双-(6-(2H-苯并三唑-2-基)-4-(1,1,3,3-四甲基丁基)-苯酚);2-(2H-苯并三唑-2-基)-4-甲基-6-[2-甲基-3-[1,3,3,3-四甲基-1-[(三甲基甲硅烷基)氧基]二硅氧烷基]丙基]-苯酚;3-(4-甲基亚苄基)樟脑;3-亚苄基樟脑;水杨酸乙基己酯;对苯二亚甲基二樟脑磺酸;2-乙基己基-2-氰基-3,3-二苯基丙烯酸酯;4-(二甲基氨基)-苯甲酸(2-乙基己基)酯;4-(二甲基氨基)苯甲酸戊酯;4-甲氧基亚苄基丙二酸二(2-乙基己基)酯;4-甲氧基肉桂酸(2-乙基己基)酯;4-甲氧基肉桂酸异戊酯;2-羟基-4-甲氧基二苯甲酮;2-羟基-4-甲氧基-4'-甲基二苯甲酮;2,2'-二羟基-4-甲氧基二苯甲酮;水杨酸高酯;2-乙基己基-2-羟基苯甲酸酯;聚二甲基硅氧烷二乙基亚苄基丙二酸酯;3-(4-(2,2-双乙氧基羰基乙烯基)-苯氧基)丙烯基)-甲氧基硅氧烷/二甲基硅氧烷共聚物;2-(4'-二乙基氨基-2'-羟基苯甲酰基)-苯甲酸己酯;二辛基丁基酰氨基三嗪酮(INCI:二乙基己基丁酰氨基三嗪酮);2,4-双-[5-1(二甲基丙基)苯并噁唑-2-基-(4-苯基)-亚氨基]-6-(2-乙基己基)-亚氨基-1,3,5-三嗪(CAS号288254-16-0);2,4-双{[4-(2-乙基己氧基)-2-羟基]-苯基}-6-(4-甲氧苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪);4-(叔丁基)-4'-甲氧基二苯甲酰基甲烷;4,4',4”-(1,3,5-三嗪-2,4,6-三基三亚氨基)-三苯甲酸三(2-乙基己酯)(也称为:2,4,6-三-[苯胺基-(p-碳-2'-乙基-1'-己氧基)]-1,3,5-三嗪(INCI:乙基己基三嗪酮));2,4,6-三联苯-4-基-1,3,5-三嗪;部花青;二氧化钛;氧化锌。
11.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂含有选自以下组的一种或多种化合物:乙基己基甘油、聚甘油-2癸酸酯、丙二醇、丁二醇、2-甲基-1,3-丙二醇、1,2-戊二醇、1,2-己二醇、1,2-辛二醇和/或1,2-癸二醇。
12.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,所述制剂含有苯氧乙醇和/或对羟基苯甲酸甲酯。
13.根据前述权利要求中任意一项所述的化妆品制剂,其特征在于,乳液含有一种或多种选自化合物木兰提取物、甘草次酸、尿素、牛蒡苷、α-硫辛酸、叶酸、八氢番茄红素、D-生物素、辅酶Q10、α-葡糖基芸香苷、肉碱、肌肽、咖啡因、天然和/或合成异黄酮、葡萄糖基甘油酯、肌酸、肌酸酐、牛磺酸、生育酚、生育酚乙酸酯、β-丙氨酸和/或甘草查尔酮A的组的有效物质。
14.一种使含有a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)的化妆品制剂从织物的可洗出性变容易的方法,其特征在于,向化妆品添加一种或多种根据前述权利要求中任意一项所述的络合剂。
15.根据前述权利要求中任意一项所述的络合剂在含有a)2,4-双-{[4-(2-乙基-己氧基)-2-羟基]-苯基}-6-(4-甲氧基苯基)-1,3,5-三嗪(INCI:双-乙基己氧苯酚甲氧苯基三嗪)的化妆品制剂中使UV防晒滤光剂从被所述制剂污染的织物的可洗出性变容易的用途。
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DE102014207919.5A DE102014207919A1 (de) | 2014-04-28 | 2014-04-28 | Sonnenschutzmittel mit reduzierter Neigung zur Textilverfleckung I |
PCT/EP2015/057808 WO2015165711A1 (de) | 2014-04-28 | 2015-04-10 | Sonnenschutzmittel mit reduzierter neigung zur textilverfleckung i |
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DE102016211239A1 (de) * | 2016-06-23 | 2017-12-28 | Beiersdorf Ag | Neustes Sonnenschutzmittel mit reduzierter Neigung zur Textilverfleckung |
DE102016211238A1 (de) * | 2016-06-23 | 2017-12-28 | Beiersdorf Ag | Sonnenschutzmittel mit reduzierter Textilverfleckung |
DE102016220547A1 (de) * | 2016-10-20 | 2018-04-26 | Beiersdorf Ag | Ethanolisches Sonnenschutzmittel mit reduzierter Neigung zur Textilverfleckung |
DE102017201235A1 (de) | 2017-01-26 | 2018-07-26 | Beiersdorf Ag | Verwendung von Dimethylaminohydroxybenzoylhexylbenzoat in kosmetischen Sonnenschutzmitteln |
WO2020070194A1 (en) | 2018-10-05 | 2020-04-09 | Basf Se | Methylene bis-benzotriazolyl tetramethylbutylphenol for fabric staining reduction |
KR20210072035A (ko) | 2018-10-05 | 2021-06-16 | 바스프 에스이 | 직물 착색을 감소시키기 위한 드로메트리졸 트리실록산을 포함하는 선스크린 조성물 |
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DE10356187A1 (de) * | 2003-12-02 | 2005-07-21 | Beiersdorf Ag | Wirkstoffkombinationen aus Phytosterolen und/oder Cholesterin und Licochalcon A oder einem wäßrigen Extrakt aus Radix Glycyrrhizae inflatae, enthaltend Licochalcon A |
JP4339136B2 (ja) * | 2004-01-20 | 2009-10-07 | 株式会社資生堂 | 皮膚外用剤 |
DE102004014615A1 (de) * | 2004-03-23 | 2005-10-13 | Beiersdorf Ag | Taurinhaltige Zubereitungen zur Verbesserung der Hautbarriere |
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