CN106245880A - Super-thin plastic floor - Google Patents

Super-thin plastic floor Download PDF

Info

Publication number
CN106245880A
CN106245880A CN201610612837.0A CN201610612837A CN106245880A CN 106245880 A CN106245880 A CN 106245880A CN 201610612837 A CN201610612837 A CN 201610612837A CN 106245880 A CN106245880 A CN 106245880A
Authority
CN
China
Prior art keywords
bed
parts
super
plastic floor
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610612837.0A
Other languages
Chinese (zh)
Inventor
戴会斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG JINGTONG PLASTICS CO Ltd
Original Assignee
ZHEJIANG JINGTONG PLASTICS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG JINGTONG PLASTICS CO Ltd filed Critical ZHEJIANG JINGTONG PLASTICS CO Ltd
Priority to CN201610612837.0A priority Critical patent/CN106245880A/en
Publication of CN106245880A publication Critical patent/CN106245880A/en
Pending legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The present invention provides a kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer, the described middle bed of material includes in first the bed of material in the bed of material and second, described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film and wearing layer set gradually in second, the described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 98 106 parts, DOTP 30 35 parts, calcium-zinc composite stabilizing agent 1 2.2 parts, white carbon black 0.2 0.5 parts, calcium carbonate 450 455 parts.Super-thin plastic floor of the present invention, owing to adding fiberglass layer, and have adjusted the formula of the middle bed of material so that product pliability substantially increases, and shrinkage factor drops to less than 0.08%, and hardness reduces, and for extra-thin product, performance is more preferable.And fiberglass layer is arranged in two-layer between the bed of material, then product does not haves the phenomenon of warpage, and product stability is more preferable, more durable.

Description

Super-thin plastic floor
Technical field
The present invention relates to plastic floor field, particularly relate to a kind of super-thin plastic floor.
Background technology
Plastic floor i.e. PVC floor, it is mainly composed of pvc material.PVC floor is enriched due to its pattern, Color is various and is widely used in each side of house and business.Plastic floor is that in the world today, popular one is novel Light body floor decorative material, also referred to as " light body ground material ", be a kind of product very popular in American-European and Asia Japan and Korea S, fashionable Abroad, initially entering Chinese market from the beginning of the eighties, big and medium-sized cities the most at home have obtained universal accreditation, use non- Often extensively, the various fields such as such as indoor family, hospital, school, office building, factory, public place, supermarket, business, stadiums Institute.
In existing plastic floor, in order to control expansion rate and the shrinkage factor of product, add substantial amounts of inorganic filler (carbonic acid Calcium), but add substantial amounts of inorganic filler and can bring new problem: and along with the increase of inorganic flavoring agent, the density of product, hardness are also Meeting is along with increase, and toughness can decline, then the edge of product easily becomes fragile, and easily causes damage during processing and transport Bad, and it is susceptible to warpage.
Summary of the invention
The invention aims to solve the above-mentioned problems in the prior art, it is provided that a kind of super-thin plastic ground Plate, adds fiberglass layer in the product, and toughness is preferable, and warpage will not occur.
In order to achieve the above object, the present invention provides a kind of super-thin plastic floor, including initial bed, the middle bed of material, glass Layer, printing film and wearing layer, the described middle bed of material includes in first the bed of material in the bed of material and second, described initial bed, expects in first Layer, fiberglass layer, the bed of material, printing film and wearing layer set gradually in second, and the described middle bed of material is by the raw material system of following weight portion Become: polrvinyl chloride 98-106 part, DOTP 30-35 part, calcium-zinc composite stabilizing agent 1-2.2 part, white carbon black 0.2-0.5 Part, calcium carbonate 450-455 part.
In one embodiment of the invention, the described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 98 parts, to benzene Dioctyl phthalate dioctyl ester 30 parts, calcium-zinc composite stabilizing agent 1 part, white carbon black 0.2 part, calcium carbonate 450 parts.
In one embodiment of the invention, the described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 100 parts, right Dioctyl phthalate 32 parts, calcium-zinc composite stabilizing agent 1.5 parts, white carbon black 0.3 part, calcium carbonate 452 parts.
In one embodiment of the invention, the thickness of described fiberglass layer is 0.2mm-0.6mm.
In one embodiment of the invention, the thickness of described fiberglass layer is 0.3mm.
In one embodiment of the invention, described fiberglass layer is latticed glass fibre.
In one embodiment of the invention, in described first, the bed of material is identical with the thickness of the bed of material in described second.
In one embodiment of the invention, in described first, the thickness of the bed of material is 0.6-0.8mm.
In one embodiment of the invention, in described second, the thickness of the bed of material is 0.6-0.8mm.
Compared with prior art, the technical program provides the benefit that:
Super-thin plastic floor of the present invention, owing to adding fiberglass layer, and have adjusted the formula of the middle bed of material so that product is soft Toughness substantially increases, and shrinkage factor declines, and hardness reduces, and for extra-thin product, performance is more preferable.And fiberglass layer is arranged on In two-layer between the bed of material, then product does not haves the phenomenon of warpage, and product stability is more preferable, more durable.
Accompanying drawing explanation
Fig. 1 is the structural representation on super-thin plastic floor of the present invention.
Detailed description of the invention
Below in conjunction with the accompanying drawings, by specific embodiment, technical scheme is carried out clear, complete description.
Refer to shown in Fig. 1, the present invention provides a kind of super-thin plastic floor, including initial bed 1, the middle bed of material, fiberglass layer 3, printing film 5 and wearing layer 6.The described middle bed of material includes in first the bed of material 4, the bed of material 2 and second in first in the bed of material 2 and second The composition of raw materials of the middle bed of material 4 is identical.The bed of material 4, printing film 5 and in the bed of material 2, fiberglass layer 3, second in described initial bed 1, first Wearing layer 6 sets gradually.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 98-106 part, p-phthalic acid Dioctyl ester 30-35 part, calcium-zinc composite stabilizing agent 1-2.2 part, white carbon black 0.2-0.5 part, calcium carbonate 450-455 part.
The middle bed of material is prepared by the following method: material pvc, DOTP, calcium-zinc composite stabilizing agent Mix according to aforementioned proportion with white carbon black, add calcium carbonate after mix homogeneously and continue mixing, after mix homogeneously, add closed refining glue In machine, internal rubber mixer controls temperature and is 170-180 DEG C, discharging after banburying 5 minutes, regulation thickness in open mill Degree, controls slice temperature and is 40-50 DEG C, rolling out film, the i.e. available middle bed of material.
Stack successively initial bed, the middle bed of material, fiberglass layer, the middle bed of material, printing film and wearing layer and carry out hot pressing be combined, i.e. Available described super-thin plastic floor.
Owing to this plastic floor adds fiberglass layer, and have adjusted the formula of the middle bed of material so that product pliability substantially increases Adding, shrinkage factor declines, and hardness reduces, and for extra-thin product, performance is more preferable.The thickness of described fiberglass layer 3 is 0.2mm-0.6mm, it is possible to provide preferably pliability, and reduce product hardness.The bed of material in the bed of material 2 and described second in described first The thickness of 3 is identical, then fiberglass layer 3 is located between the middle bed of material that two layers of thickness is identical, then product does not haves the phenomenon of warpage.
Embodiment 1
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 98 parts, p-phthalic acid two is pungent Ester 30 parts, calcium-zinc composite stabilizing agent 1 part, white carbon black 0.2 part, calcium carbonate 450 parts.The middle bed of material is prepared by the following method: raw material Polrvinyl chloride, DOTP, calcium-zinc composite stabilizing agent and white carbon black mix according to aforementioned proportion, add after mix homogeneously Calcium carbonate continues mixing, adds in internal rubber mixer after mix homogeneously, and it is 180 DEG C that internal rubber mixer controls temperature, banburying 5 Discharging after minute, regulates thickness in open mill, and controlling slice temperature is 40 DEG C, rolling out film, i.e. available middle material Layer.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.3mm, and in described first, the thickness of the bed of material is 0.6mm, in described second, the thickness of the bed of material is 0.6mm.
Embodiment 2
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 100 parts, p-phthalic acid two Monooctyl ester 32 parts, calcium-zinc composite stabilizing agent 1.5 parts, white carbon black 0.3 part, calcium carbonate 452 parts.The middle bed of material uses same as in Example 1 Prepared by method.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.4mm, the bed of material in described first Thickness is 0.75mm, and in described second, the thickness of the bed of material is 0.75mm.
Embodiment 3
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 102 parts, p-phthalic acid two Monooctyl ester 33 parts, calcium-zinc composite stabilizing agent 1.8 parts, white carbon black 0.3 part, calcium carbonate 453 parts.The middle bed of material uses same as in Example 1 Prepared by method.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.4mm, the bed of material in described first Thickness is 0.8mm, and in described second, the thickness of the bed of material is 0.8mm.
Embodiment 4
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 104 parts, p-phthalic acid two Monooctyl ester 34 parts, calcium-zinc composite stabilizing agent 2 parts, white carbon black 0.4 part, calcium carbonate 455 parts.The middle bed of material uses side same as in Example 1 Prepared by method.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.5mm, the thickness of the bed of material in described first Degree is 0.75mm, and in described second, the thickness of the bed of material is 0.75mm.
Embodiment 5
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 105 parts, p-phthalic acid two Monooctyl ester 35 parts, calcium-zinc composite stabilizing agent 2 parts, white carbon black 0.5 part, calcium carbonate 450 parts.The middle bed of material uses side same as in Example 1 Prepared by method.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.6mm, the thickness of the bed of material in described first Degree is 0.8mm, and in described second, the thickness of the bed of material is 0.8mm.
Embodiment 6
A kind of super-thin plastic floor, including initial bed, the middle bed of material, fiberglass layer, printing film and wearing layer.Described middle material Layer includes in first the bed of material in the bed of material and second.Described initial bed, the bed of material in first, fiberglass layer, the bed of material, printing film in second Set gradually with wearing layer.The described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 106 parts, p-phthalic acid two Monooctyl ester 35 parts, calcium-zinc composite stabilizing agent 2.2 parts, white carbon black 0.5 part, calcium carbonate 455 parts.The middle bed of material uses same as in Example 1 Prepared by method.Described fiberglass layer is latticed glass fibre.The thickness of described fiberglass layer is 0.3mm, the bed of material in described first Thickness is 0.7mm, and in described second, the thickness of the bed of material is 0.7mm.
The shrinkage factor on super-thin plastic floor, hardness and the pliability of detection embodiment 1-6.
Shrinkage factor: use precision high temperature roaster HQ-WG-550 to be measured.
Hardness: use Shore durometer SLX-D to be measured.
Pliability: use scratch resistance tester RZ-706 to measure pliability, product bends rotating around 4cm cylinder and 2cm cylinder, Check product crack conditions.
Testing result is as shown in table 1.
Table 1
Existing super-thin plastic floor, is not provided with fiberglass layer in the middle bed of material, the shrinkage factor of product is about 0.1%, hardness Being about 65HD, pliability is poor, does not ruptures around 4cm cylinder, but ruptures around 2cm cylinder.And as shown in Table 1, the present invention surpasses Slim plastic floor, for existing super-thin plastic floor, its shrinkage factor is substantially reduced, and hardness reduces, pliability Also significantly improving, properties of product are more excellent.
Although the present invention is open as above with preferred embodiment, but it is not for limiting the present invention, any this area Technical staff without departing from the spirit and scope of the present invention, may be by the method for the disclosure above and technology contents to this Bright technical scheme makes possible variation and amendment, therefore, every content without departing from technical solution of the present invention, according to the present invention Technical spirit any simple modification, equivalent variations and modification that above example is made, belong to technical solution of the present invention Protection domain.

Claims (9)

1. a super-thin plastic floor, it is characterised in that include initial bed, the middle bed of material, fiberglass layer, printing film and wear-resisting Layer, the described middle bed of material includes in first the bed of material in the bed of material and second, described initial bed, the bed of material in first, fiberglass layer, expects in second Layer, printing film and wearing layer set gradually, and the described middle bed of material is made up of the raw material of following weight portion: polrvinyl chloride 98-106 Part, DOTP 30-35 part, calcium-zinc composite stabilizing agent 1-2.2 part, white carbon black 0.2-0.5 part, calcium carbonate 450-455 Part.
Super-thin plastic floor the most according to claim 1, it is characterised in that former by following weight portion of the described middle bed of material Material is made: polrvinyl chloride 98 parts, DOTP 30 parts, calcium-zinc composite stabilizing agent 1 part, white carbon black 0.2 part, calcium carbonate 450 parts.
Super-thin plastic floor the most according to claim 1, it is characterised in that former by following weight portion of the described middle bed of material Material is made: polrvinyl chloride 100 parts, DOTP 32 parts, calcium-zinc composite stabilizing agent 1.5 parts, white carbon black 0.3 part, carbonic acid Ca45 2 parts.
Super-thin plastic floor the most according to claim 1, it is characterised in that the thickness of described fiberglass layer is 0.2mm- 0.6mm。
Super-thin plastic floor the most according to claim 4, it is characterised in that the thickness of described fiberglass layer is 0.3mm.
Super-thin plastic floor the most according to claim 1, it is characterised in that described fiberglass layer is latticed glass fibers Dimension.
Super-thin plastic floor the most according to claim 1, it is characterised in that in described first in the bed of material and described second The thickness of the bed of material is identical.
Super-thin plastic floor the most according to claim 1, it is characterised in that in described first, the thickness of the bed of material is 0.6- 0.8mm。
Super-thin plastic floor the most according to claim 1, it is characterised in that in described second, the thickness of the bed of material is 0.6- 0.8mm。
CN201610612837.0A 2016-07-29 2016-07-29 Super-thin plastic floor Pending CN106245880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610612837.0A CN106245880A (en) 2016-07-29 2016-07-29 Super-thin plastic floor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610612837.0A CN106245880A (en) 2016-07-29 2016-07-29 Super-thin plastic floor

Publications (1)

Publication Number Publication Date
CN106245880A true CN106245880A (en) 2016-12-21

Family

ID=57606102

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610612837.0A Pending CN106245880A (en) 2016-07-29 2016-07-29 Super-thin plastic floor

Country Status (1)

Country Link
CN (1) CN106245880A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110103437A (en) * 2018-01-05 2019-08-09 无锡市博宇塑机有限公司 Plastic floor stratiform reinforced structure and its manufacturing equipment and forming method
CN114278047A (en) * 2021-12-22 2022-04-05 浙江巨美家科技有限公司 Super wear-resistant PVC (polyvinyl chloride) wrapper and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09207292A (en) * 1996-02-02 1997-08-12 Misawa Homes Co Ltd Wooden style plate material and its manufacture
CN202265992U (en) * 2011-10-25 2012-06-06 泰州市华丽塑料有限公司 Composite plastic floor
CN203531317U (en) * 2013-08-16 2014-04-09 浙江晶通塑胶有限公司 Fracture-resistant composite floor
CN104109321A (en) * 2014-07-31 2014-10-22 浙江晶通塑胶有限公司 Middle layer material for latching floors and preparation method thereof
CN105178561A (en) * 2015-10-09 2015-12-23 浙江晶通塑胶有限公司 Glass fiber glue-free floor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09207292A (en) * 1996-02-02 1997-08-12 Misawa Homes Co Ltd Wooden style plate material and its manufacture
CN202265992U (en) * 2011-10-25 2012-06-06 泰州市华丽塑料有限公司 Composite plastic floor
CN203531317U (en) * 2013-08-16 2014-04-09 浙江晶通塑胶有限公司 Fracture-resistant composite floor
CN104109321A (en) * 2014-07-31 2014-10-22 浙江晶通塑胶有限公司 Middle layer material for latching floors and preparation method thereof
CN105178561A (en) * 2015-10-09 2015-12-23 浙江晶通塑胶有限公司 Glass fiber glue-free floor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
潘旺林: "《最新建筑材料手册》", 30 April 2014, 安徽科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110103437A (en) * 2018-01-05 2019-08-09 无锡市博宇塑机有限公司 Plastic floor stratiform reinforced structure and its manufacturing equipment and forming method
CN114278047A (en) * 2021-12-22 2022-04-05 浙江巨美家科技有限公司 Super wear-resistant PVC (polyvinyl chloride) wrapper and preparation method thereof

Similar Documents

Publication Publication Date Title
CA2939954C (en) A high strength stone plastic floor and manufacturing method thereof
CN105315521B (en) High damping material suitable for composite high temperature co-curing and preparation method thereof
WO2022127215A1 (en) Scratch-resistant wear-resistant self-repairing composite board, and manufacturing method therefor and application thereof
CN109895472A (en) A kind of Self-sinking type plastic floor and preparation method thereof
CN106245880A (en) Super-thin plastic floor
CN106243559A (en) The middle bed of material of plastic floor and plastic floor
CN102086349B (en) Non-curing waterproof glue with double character
CN106910788B (en) A kind of high resistant water type solar energy backboard polyester film and preparation method thereof
CN109653060A (en) A kind of plane plastic cement race track and preparation method thereof
CN105237914A (en) PVC waterproof roll
CN107207814A (en) Flooring board hyaline membrane, its preparation method and the flooring board including it
JP2016175409A (en) Flexible laminate film
CN106284919A (en) Plastic floor
CN109680508A (en) A kind of high-polymer modified pitch and preparation method thereof and polymer modified bituminous waterproof sheet material
CN106639248A (en) Light VCP floor and preparation method thereof
CN109653057A (en) A kind of mixed type plastic track and preparation method thereof
EP3645280B1 (en) Composite with direct bonding between rubber and foam
CN106243557A (en) Environment-friendly type plastic adhesive floor
CN106554581B (en) A kind of PVC waterproof roll and preparation method thereof
CN109849473A (en) A kind of PVC hard composite floor board and its manufacture craft that negative oxygen ion is modified
CN106243556B (en) The middle bed of material and plastic floor of environment-friendly type plastic adhesive floor
CN106065700A (en) High durable plastic floor
CN107740554A (en) Solid wood stone plastic floor and preparation method thereof
CN113958085A (en) High-elasticity high-aging-resistance three-layer rubber floor tile
CN104962669B (en) Inorganic nano leather repairing agent and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161221

RJ01 Rejection of invention patent application after publication