CN106243505A - A kind of polypropylene regenerated plastics and the preparation method of flat filament thereof - Google Patents

A kind of polypropylene regenerated plastics and the preparation method of flat filament thereof Download PDF

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Publication number
CN106243505A
CN106243505A CN201610705453.3A CN201610705453A CN106243505A CN 106243505 A CN106243505 A CN 106243505A CN 201610705453 A CN201610705453 A CN 201610705453A CN 106243505 A CN106243505 A CN 106243505A
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China
Prior art keywords
polypropylene
regenerated plastics
flat filament
parts
polypropylene regenerated
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610705453.3A
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Chinese (zh)
Inventor
厉艳荣
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Tianjin Xuhuihengyuan Plastic Packaging Corp
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Tianjin Xuhuihengyuan Plastic Packaging Corp
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Priority to CN201610705453.3A priority Critical patent/CN106243505A/en
Publication of CN106243505A publication Critical patent/CN106243505A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/728Measuring data of the driving system, e.g. torque, speed, power, vibration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The present invention is a kind of polypropylene regenerated plastics, it is characterised in that components by weight percent is: waste and old polypropylene 85~89 parts;Inorganic powder material 40 parts;Linear low density polyethylene 15~22 parts;Antioxidant 0.8~1.2 parts;Compatilizer 14~20 parts;Tissuemat E 1~1.7 parts;UV absorbent 4~10 parts;Preparation method is, first adds in continuous mixer by said components, mixes as uniform jelly;The pulpous state batch mixing of above-mentioned steps gained is sent in flat filament drawing machine, is cooled to room temperature sizing after being extruded into thin film, then cuts into embryo silk through blade, wire drawing machine is drawn into flat filament.The present invention is inorganic powder material by using Pulvis Talci, the polypropylene regenerated plastics flat filament prepared has a certain degree of improvement on it is pliable and tough, by adding UV absorbent in the polypropylene regenerated plastics being prepared as, it is effective against the destruction of ultraviolet, therefore adds the service life of polypropylene regenerated plastics.

Description

A kind of polypropylene regenerated plastics and the preparation method of flat filament thereof
Technical field
The present invention relates to a kind of waste plastic regeneration processing technique field, particularly relate to a kind of polypropylene regenerated plastics and The preparation method of flat filament.
Background technology
Plastic product while meet people's daily life and social development, is caused owing to plastic refuse increases severely Society and environmental problem that " white pollution " causes are the most serious, and therefore the research to regenerated plastics is extremely urgent, the most again It is poor generally to there is pliability in the flat filament that raw plastics prepare, and opposing UV resistance is weak, the most aging, and the shortcomings such as service life is short make All there is certain restriction effect in the scope that must recycle it and field.
Summary of the invention
Present invention seek to address that the deficiencies in the prior art, and a kind of polypropylene regenerated plastics and the preparation side of flat filament thereof are provided Method.
The present invention for achieving the above object, by the following technical solutions: a kind of polypropylene regenerated plastics, it is characterised in that It is made up of the raw material of following parts by weight:
As preferably, described inorganic powder material is Pulvis Talci.
As preferably, described antioxidant refers to one or both in antioxidant 1010 and antioxidant 168.
As preferably, described compatilizer is polyolefin-maleic anhydride graft copolymer.
The preparation method of a kind of polypropylene regenerated plastics flat filament that the present invention provides, it is characterised in that comprise the following steps:
(1) by waste and old polypropylene, inorganic powder material, linear low density polyethylene, antioxidant, compatilizer, polyethylene Wax and UV absorbent add in continuous mixer, and rotating speed is 300~600 turns/min, and mixing time is 15~25 minutes, will Above-mentioned raw materials mixes as uniform jelly;
(2) being sent in flat filament drawing machine by the pulpous state batch mixing of above-mentioned steps (1) gained, plasticization temperature controls 200~210 DEG C, all it being extruded into thin film after having plastified, during extrusion, melt flow is 4.10g/10min;
(3) it is cooled to room temperature sizing after being extruded into thin film, then cuts into embryo silk through blade, finally stretch in wire drawing machine Becoming flat filament, in wire drawing machine, cooling water tank temperature is set to 45~48 DEG C, and oven temperature controls at 200~210 DEG C, and cold roll temperature is set to 25~38 DEG C, draw speed is set to 150~210m/min, and draw ratio is set to 7 times, obtains polypropylene regenerated plastics flat filament.
The invention has the beneficial effects as follows: the present invention is inorganic powder material by using Pulvis Talci, the polypropylene prepared Regenerated plastics flat filament has a certain degree of improvement on it is pliable and tough, by adding ultraviolet in the polypropylene regenerated plastics being prepared as Absorbent, is effective against the destruction of ultraviolet, therefore adds the service life of polypropylene regenerated plastics.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1
A kind of polypropylene regenerated plastics, it is characterised in that be made up of the raw material of following parts by weight:
Preparation method: a kind of polypropylene regeneration provided the present embodiment as a example by preparing polypropylene regenerated plastics flat filament is moulded The preparation method of material flat filament is described below:
(1) by waste and old polypropylene, Pulvis Talci, linear low density polyethylene, antioxidant 1010, polyolefin-maleic anhydride Graft copolymer, Tissuemat E and UV absorbent add in continuous mixer, and rotating speed is 300 turns/min, and mixing time is 15 minutes, above-mentioned raw materials is mixed into uniform jelly;
(2) being sent in flat filament drawing machine by the pulpous state batch mixing of above-mentioned steps (1) gained, plasticization temperature controls, at 200 DEG C, to mould All being extruded into thin film after having changed, during extrusion, melt flow is 4.10g/10min;
(3) it is cooled to room temperature sizing after being extruded into thin film, then cuts into embryo silk through blade, finally stretch in wire drawing machine Becoming flat filament, in wire drawing machine, cooling water tank temperature is set to 45 DEG C, and oven temperature controls at 200 DEG C, and cold roll temperature is set to 25 DEG C, stretching Speed is set to 150m/min, and draw ratio is set to 7 times, obtains polypropylene regenerated plastics flat filament.
Embodiment 2
A kind of polypropylene regenerated plastics, it is characterised in that be made up of the raw material of following parts by weight:
Preparation method: a kind of polypropylene regeneration provided the present embodiment as a example by preparing polypropylene regenerated plastics flat filament is moulded The preparation method of material flat filament is described below:
(1) waste and old polypropylene, Pulvis Talci, linear low density polyethylene, antioxidant 168, polyolefin-maleic anhydride are connect Graft copolymer, Tissuemat E and UV absorbent add in continuous mixer, and rotating speed is 600 turns/min, and mixing time is 25 Minute, above-mentioned raw materials is mixed into uniform jelly;
(2) being sent in flat filament drawing machine by the pulpous state batch mixing of above-mentioned steps (1) gained, plasticization temperature controls, at 210 DEG C, to mould All being extruded into thin film after having changed, during extrusion, melt flow is 4.10g/10min;
(3) it is cooled to room temperature sizing after being extruded into thin film, then cuts into embryo silk through blade, finally stretch in wire drawing machine Becoming flat filament, in wire drawing machine, cooling water tank temperature is set to 48 DEG C, and oven temperature controls at 210 DEG C, and cold roll temperature is set to 38 DEG C, stretching Speed is set to 210m/min, and draw ratio is set to 7 times, obtains polypropylene regenerated plastics flat filament.
Above the present invention is exemplarily described, it is clear that the present invention implements and is not subject to the restrictions described above, As long as have employed method design and the various improvement that carry out of technical scheme of the present invention, or the most improved directly apply to other Close, all within protection scope of the present invention.

Claims (5)

1. polypropylene regenerated plastics, it is characterised in that be made up of the raw material of following parts by weight:
A kind of polypropylene regenerated plastics the most according to claim 1, it is characterised in that described inorganic powder material is for sliding Stone powder.
A kind of polypropylene regenerated plastics the most according to claim 1, it is characterised in that described antioxidant refers to antioxygen One or both in agent 1010 and antioxidant 168.
A kind of polypropylene regenerated plastics the most according to claim 1, it is characterised in that described compatilizer be polyolefin- Maleic anhydride graft copolymer.
5. the preparation method of a polypropylene regenerated plastics flat filament as claimed in claim 1, it is characterised in that include following step Rapid:
(1) by waste and old polypropylene, inorganic powder material, linear low density polyethylene, antioxidant, compatilizer, Tissuemat E and UV absorbent adds in continuous mixer, and rotating speed is 300~600 turns/min, and mixing time is 15~25 minutes, by above-mentioned Raw material mixes as uniform jelly;
(2) being sent in flat filament drawing machine by the pulpous state batch mixing of above-mentioned steps (1) gained, plasticization temperature controls at 200~210 DEG C, All being extruded into thin film after having plastified, during extrusion, melt flow is 4.10g/10min;
(3) it is cooled to room temperature sizing after being extruded into thin film, then cuts into embryo silk through blade, be finally drawn into flat in wire drawing machine Silk, in wire drawing machine, cooling water tank temperature is set to 45~48 DEG C, and oven temperature controls at 200~210 DEG C, cold roll temperature be set to 25~ 38 DEG C, draw speed is set to 150~210m/min, and draw ratio is set to 7 times, obtains polypropylene regenerated plastics flat filament.
CN201610705453.3A 2016-08-23 2016-08-23 A kind of polypropylene regenerated plastics and the preparation method of flat filament thereof Pending CN106243505A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610705453.3A CN106243505A (en) 2016-08-23 2016-08-23 A kind of polypropylene regenerated plastics and the preparation method of flat filament thereof

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107082952A (en) * 2017-05-05 2017-08-22 安徽国登管业科技有限公司 Modified polypropene regenerated plastics and preparation method thereof
CN107476099A (en) * 2017-09-04 2017-12-15 界首市宏利塑料有限公司 A kind of preparation technology of wear-resisting UV resistant plastic ties
CN107881588A (en) * 2017-10-09 2018-04-06 福建三宏再生资源科技有限公司 A kind of regeneration polypropylene yarn line and its process for producing with anti-degradability
CN108690268A (en) * 2018-05-30 2018-10-23 温州鑫泰新材料股份有限公司 A kind of anticracking PP black reworked materials and preparation method thereof
CN110029513A (en) * 2019-04-18 2019-07-19 宝应县科达电缆料有限公司 A kind of preparation method of the wire and cable netted gasket for packing of PP
CN111808394A (en) * 2020-07-15 2020-10-23 浙江塑博特包装有限公司 Plastic compatilizer composition, thermoplastic regenerated plastic and processing method thereof
CN115256902A (en) * 2022-06-10 2022-11-01 江西亚美达环保再生资源股份有限公司 Woven bag wire drawing machine and production method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1986627A (en) * 2005-12-22 2007-06-27 吴永刚 Composite polypropylene material and its preparing method
CN101914240A (en) * 2010-08-11 2010-12-15 丁飞鹏 Regenerated wire drawing modified material of waste polypropylene woven bags and preparation method thereof
CN103113662A (en) * 2011-11-17 2013-05-22 上海金发科技发展有限公司 Low-odor ultrahigh-toughness polypropylene compound and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1986627A (en) * 2005-12-22 2007-06-27 吴永刚 Composite polypropylene material and its preparing method
CN101914240A (en) * 2010-08-11 2010-12-15 丁飞鹏 Regenerated wire drawing modified material of waste polypropylene woven bags and preparation method thereof
CN103113662A (en) * 2011-11-17 2013-05-22 上海金发科技发展有限公司 Low-odor ultrahigh-toughness polypropylene compound and preparation method thereof

Non-Patent Citations (1)

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合成树脂及塑料技术全书编委会编著: "《合成树脂及塑料技术全书》", 30 April 2006, 中国石化出版社 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107082952A (en) * 2017-05-05 2017-08-22 安徽国登管业科技有限公司 Modified polypropene regenerated plastics and preparation method thereof
CN107476099A (en) * 2017-09-04 2017-12-15 界首市宏利塑料有限公司 A kind of preparation technology of wear-resisting UV resistant plastic ties
CN107881588A (en) * 2017-10-09 2018-04-06 福建三宏再生资源科技有限公司 A kind of regeneration polypropylene yarn line and its process for producing with anti-degradability
CN108690268A (en) * 2018-05-30 2018-10-23 温州鑫泰新材料股份有限公司 A kind of anticracking PP black reworked materials and preparation method thereof
CN110029513A (en) * 2019-04-18 2019-07-19 宝应县科达电缆料有限公司 A kind of preparation method of the wire and cable netted gasket for packing of PP
CN111808394A (en) * 2020-07-15 2020-10-23 浙江塑博特包装有限公司 Plastic compatilizer composition, thermoplastic regenerated plastic and processing method thereof
CN115256902A (en) * 2022-06-10 2022-11-01 江西亚美达环保再生资源股份有限公司 Woven bag wire drawing machine and production method thereof
CN115256902B (en) * 2022-06-10 2023-04-18 江西亚美达环保再生资源股份有限公司 Woven bag wire drawing machine and production method thereof

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