CN106238966B - A kind of abrasion-proof overlaying welding flux-cored wire - Google Patents

A kind of abrasion-proof overlaying welding flux-cored wire Download PDF

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Publication number
CN106238966B
CN106238966B CN201610644036.2A CN201610644036A CN106238966B CN 106238966 B CN106238966 B CN 106238966B CN 201610644036 A CN201610644036 A CN 201610644036A CN 106238966 B CN106238966 B CN 106238966B
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Prior art keywords
abrasion
cored wire
flux
medicine core
welding flux
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CN106238966A (en
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杨可
包晔峰
蒋永锋
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Changzhou Campus of Hohai University
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Changzhou Campus of Hohai University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding
    • B23K35/406Filled tubular wire or rods

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The invention belongs to field of welding material, and in particular to a kind of abrasion-proof overlaying welding flux-cored wire wraps up medicinal powder by H08A steel bands, formed through rolling, drawing, medicine core used includes the raw material of following mass percent:Titanium dioxide 5 10%, feldspar 2 8%, ice crystal 1 5%, zircon 2 5%, rare earth silicon 2 8%, ferromanganese 5 10%, crome metal 30 50%, ferrotungsten 8 20%, surplus are iron powder, filling rate 20 40%.Flux-cored wire of the present invention is suitable for CO2Gas Shielded welding, total amount of weld fumes is few, overlay cladding average hardness 50 60, has good intensity, toughness and red hardness, is especially suitable for using under resistance to 600 DEG C of high temperature wear operating modes.

Description

A kind of abrasion-proof overlaying welding flux-cored wire
Technical field
The invention belongs to technical field of welding materials, and in particular to a kind of abrasion-proof overlaying welding flux-cored wire.
Background technology
A kind of economic and quick process of the built-up welding as material surface modifying, more and more widely applied to each During the manufacture of industrial department part is repaired.In order to most effectively play the effect of overlay cladding, it is desirable to the overlaying method of use have compared with Small base material dilution, higher deposition rate and excellent overlay properties, i.e., high-quality, efficient, low dilution rate technique for overlaying.
The hardfacing materials that are commonly used are carbon containing and alloying element is higher, mainly using carbon and chromium, titanium, vanadium, Niobium etc. forms carbide hard particle, to improve the hardness of surfacing layer metal, so as to improve its wear-resisting property.But such welding material Since phosphorus content is high, often anti-weld crack ability is poor, and toughness is relatively low.The study found that reinforcing material surface strength and improvement The effective way of wearability is to provide the case hardness and obdurability of material, and ideal institutional framework is tough and tensile, continuous The good particle of high-melting-point, high rigidity, stability is uniformly distributed on matrix.Existing CO2The letter of gas shielded flux cored wire overlay-operation Just it is, at low cost, production efficiency is high, but the problem of generally existing powder amount is higher.
The content of the invention
In view of the above-mentioned problems, the present invention researchs and develops, a kind of powder amount is small, toughness is high, the CO of resistance to 600 DEG C of high temperature wears2 Gas protects weldering abrasion-proof overlaying welding flux-cored wire.
For solution more than technical problem, the invention is realized by the following technical scheme:
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core includes the raw material of following mass percent:Titanium White powder 5-10%, feldspar 2-8%, ice crystal 1-5%, zircon 2-5%, rare earth silicon 2-8%, ferromanganese 5-10%, crome metal 30-50%, tungsten Iron 8-20%, surplus are iron powder.
Preferably, the medicine core includes the raw material of following mass percent:Titanium dioxide 5-8%, feldspar 3-6%, ice crystal 3- 4%th, zircon 3-4%, rare earth silicon 4-7%, ferromanganese 6-8%, crome metal 35-42%, ferrotungsten 9-16%, surplus are iron powder.
It is furthermore preferred that the medicine core is made of the raw material of following mass percent:Titanium dioxide 7%, feldspar 5%, ice crystal 3%, Zircon 4%, rare earth silicon 5%, ferromanganese 7%, crome metal 40%, ferrotungsten 12%, iron powder 17%.
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 1.6-2.4mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 20-40%.
The content of rare earth of rare earth silicon described above is 30-33wt%, silicone content 30-35wt%.
Each raw material is marketable material in medicine core used in the present invention, and grain size is 100-300 μm, and action principle is as follows:
Titanium dioxide:Contain the TiO more than 98%2, there is good protective effect to the molten drop of overheat, reduce the droplet transfer It evaporates in the process;TiO2Titanate can be combined into FeO and enters slag, reduces iron oxide fumes;Welding is stablized in slag making simultaneously Electric arc, and improve welding technological properties.Feldspar:Arc stabilizer plays an important role of to stablize electric arc, can increase the viscosity of slag, protect Hot melt drop, reduces powder amount.Ice crystal:Simultaneously containing Na, Al stabilising arc element, there is stabilising arc effect, while reduce in weld seam Diffusible hydrogen content improves the anti-crack ability of weld seam.Zircon:It is mainly used for slag making, improves the removability of slag of slag.Rare earth silicon and Ferromanganese:Abundant deoxidation, desulfurization, stablize electric arc, restrain the deoxygenation of carbon, CO gas is avoided to generate, and reduce hair dirt Amount.Rare earth silicon plays an important role of that crystal grain thinning is made, promotes the high hard phase disperse educt of stability simultaneously, hence it is evident that raising toughness and resistance to High temperature grinds performance.Crome metal, ferrotungsten:The transition alloy elements into weld seam form high tenacity matrix+be largely uniformly distributed height The good anti-abrasive hard tissue of temperature stability.Iron powder:Increase weld metal, improve deposition efficiency.
The present invention has following positive beneficial effect:
Wear-resisting welding wire with flux core carbon content of the present invention is low(Hardly carbon containing in drug core component in welding wire, carbon source is only Carbon in H08A steel bands, thus it is extremely low, less than 0.08%), anti-weld crack performance is strong, according to national standard GB1225-76 test sides Method, powder amount reduce more than 30% than commercially available flux-cored wire, have good welding technological properties, can carry out all-position welding, have There is very high deposition efficiency, welding layer case hardness is evenly distributed, and average hardness can be in the range of HRC50~60, impact flexibility There is height good high temperature resistant to grind performance, and high temperature resistant mill performance is 10-20 times of No. 45 steel, is especially suitable for resistance to 600 DEG C of high temperature mill It is used under damage operating mode.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in more detail.It should be appreciated that specific reality described herein It applies example to be only used to explain the present invention, be not intended to limit the present invention.Each raw material is city in medicine core used in following embodiment Sell raw material, grain size is 100-300 μm, and the content of rare earth of the rare earth silicon is 30-33wt%, silicone content 30-35wt%.
Embodiment 1
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core is made of the raw material of following mass percent: Titanium dioxide 5%, feldspar 3%, ice crystal 3%, zircon 3%, rare earth silicon 4%, ferromanganese 6%, crome metal 35%, ferrotungsten 9%, surplus are iron powder 32%。
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 1.6mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 27%, surfacing layer metal average hardness 52HRC, powder amount reduce 37% than commercially available flux-cored wire, and wear-resisting property is 15 times of No. 45 steel at 600 DEG C.
Embodiment 2
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core is made of the raw material of following mass percent: Titanium dioxide 8%, feldspar 6%, ice crystal 4%, zircon 4%, rare earth silicon 7%, ferromanganese 8%, crome metal 42%, ferrotungsten 16%, surplus are iron Powder 5%.
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 2.4mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 33%, surfacing layer metal average hardness 56HRC, powder amount reduce 43% than commercially available flux-cored wire, and wear-resisting property is 12 times of No. 45 steel at 600 DEG C.
Embodiment 3
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core is made of the raw material of following mass percent: Titanium dioxide 5%, feldspar 8%, ice crystal 1%, zircon 5%, rare earth silicon 2%, ferromanganese 10%, crome metal 30%, ferrotungsten 20%, surplus are iron Powder 19%.
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 1.8mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 20%, surfacing layer metal average hardness 50HRC, powder amount reduce 51% than commercially available flux-cored wire, and wear-resisting property is 10 times of No. 45 steel at 600 DEG C.
Embodiment 4
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core is made of the raw material of following mass percent: Titanium dioxide 10%, feldspar 2%, ice crystal 5%, zircon 2%, rare earth silicon 8%, ferromanganese 5%, crome metal 50%, ferrotungsten 8%, surplus are iron Powder 10%.
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 2.2mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 40%, surfacing layer metal average hardness 51HRC, powder amount reduce 39% than commercially available flux-cored wire, and wear-resisting property is 14 times of No. 45 steel at 600 DEG C.
Embodiment 5
A kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, medicine core is made of the raw material of following mass percent: Titanium dioxide 7%, feldspar 5%, ice crystal 3%, zircon 4%, rare earth silicon 5%, ferromanganese 7%, crome metal 40%, ferrotungsten 12%, surplus are iron Powder 17%.
Abrasion-proof overlaying welding flux-cored wire of the present invention is drawn into straight by the uniformly mixed medicine core powder of H08A steel bands package through rolling Footpath be 2.0mm flux-cored wires, filling rate(Medicine core accounts for the percentage of flux-cored wire gross weight)For 30%, surfacing layer metal average hardness 60HRC, powder amount reduce 61% than commercially available flux-cored wire, and wear-resisting property is 20 times of No. 45 steel at 600 DEG C.
The invention is not limited in above-mentioned specific embodiment, those skilled in the art can also make a variety of variations accordingly, It is but any all to cover within the scope of the claims with equivalent or similar variation of the invention.

Claims (7)

1. a kind of abrasion-proof overlaying welding flux-cored wire, including crust and medicine core, it is characterised in that:The medicine core includes following quality percentage The raw material of ratio:Titanium dioxide 5-10%, feldspar 2-8%, ice crystal 1-5%, zircon 2-5%, rare earth silicon 2-8%, ferromanganese 5-10%, metal Chromium 30-50%, ferrotungsten 8-20%, surplus are iron powder.
2. abrasion-proof overlaying welding flux-cored wire according to claim 1, it is characterised in that:The medicine core includes following quality percentage The raw material of ratio:Titanium dioxide 5-8%, feldspar 3-6%, ice crystal 3-4%, zircon 3-4%, rare earth silicon 4-7%, ferromanganese 6-8%, crome metal 35-42%, ferrotungsten 9-16%, surplus are iron powder.
3. abrasion-proof overlaying welding flux-cored wire according to claim 2, it is characterised in that:The medicine core is by following mass percent Raw material composition:Titanium dioxide 7%, feldspar 5%, ice crystal 3%, zircon 4%, rare earth silicon 5%, ferromanganese 7%, crome metal 40%, ferrotungsten 12%th, iron powder 17%.
4. according to claim 1-3 any one of them abrasion-proof overlaying welding flux-cored wires, it is characterised in that:The grain of each material composition Footpath is 100-300 μm.
5. according to claim 1-3 any one of them abrasion-proof overlaying welding flux-cored wires, it is characterised in that:The rare earth of the rare earth silicon Content is 30-33wt%, silicone content 30-35wt%.
6. according to claims 1 to 3 any one of them abrasion-proof overlaying welding flux-cored wire, it is characterised in that:The hardfacing medicine Core welding wire is drawn into a diameter of 1.6-2.4mm flux-cored wires, i.e., by the uniformly mixed medicine core raw material of H08A steel bands package through rolling .
7. abrasion-proof overlaying welding flux-cored wire according to claim 6, it is characterised in that:The abrasion-proof overlaying welding flux-cored wire is filled out Rate is filled for 20-40%.
CN201610644036.2A 2016-08-08 2016-08-08 A kind of abrasion-proof overlaying welding flux-cored wire Active CN106238966B (en)

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CN114523229B (en) * 2021-12-24 2022-11-04 河海大学 Wear-resistant flux-cored wire and preparation method and surfacing process thereof
CN115592296A (en) * 2022-10-13 2023-01-13 山东聚力焊接材料有限公司(Cn) Surfacing flux-cored wire and preparation method and application thereof

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CN1094808C (en) * 2000-12-07 2002-11-27 房爱存 High-temp antiwear surfacing welding electrode
CN101402161B (en) * 2008-11-07 2010-10-13 山东大学 Abrasive wear resistant weld deposit flux-cored wire
JP5198481B2 (en) * 2010-01-09 2013-05-15 株式会社神戸製鋼所 Ni-based alloy flux cored wire
CN102554502B (en) * 2011-12-07 2014-04-16 燕山大学 Special electrode for overlaying and repairing high-chromium cast iron type high-speed rail substructure tamping pick
CN104325232A (en) * 2014-10-29 2015-02-04 李永锋 Wear-resistant overlaying flux-cored wire

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