CN106229327A - A kind of flexible large area perovskite solar module and preparation method thereof - Google Patents

A kind of flexible large area perovskite solar module and preparation method thereof Download PDF

Info

Publication number
CN106229327A
CN106229327A CN201610630348.8A CN201610630348A CN106229327A CN 106229327 A CN106229327 A CN 106229327A CN 201610630348 A CN201610630348 A CN 201610630348A CN 106229327 A CN106229327 A CN 106229327A
Authority
CN
China
Prior art keywords
layer
tumble
paddle
flexible
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610630348.8A
Other languages
Chinese (zh)
Inventor
陈培专
牛萍娟
于莉媛
张炜
杜阳阳
张建军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Polytechnic University
Original Assignee
Tianjin Polytechnic University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Polytechnic University filed Critical Tianjin Polytechnic University
Priority to CN201610630348.8A priority Critical patent/CN106229327A/en
Publication of CN106229327A publication Critical patent/CN106229327A/en
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
    • H10K77/10—Substrates, e.g. flexible substrates
    • H10K77/111—Flexible substrates
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/50—Photovoltaic [PV] devices
    • H10K30/57—Photovoltaic [PV] devices comprising multiple junctions, e.g. tandem PV cells
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80—Constructional details
    • H10K30/81—Electrodes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80—Constructional details
    • H10K30/88—Passivation; Containers; Encapsulations
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/60—Forming conductive regions or layers, e.g. electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention relates to a kind of flexible large area perovskite solar module and preparation method thereof.This perovskite solar module includes that one stacks gradually electrode, transparent enclosure glue, flexible transparent plastic cover plate before metal backing reflecting layer on flexible substrate, electron transfer layer, perovskite absorbed layer, hole transmission layer, electrically conducting transparent, and light is incident by flexible transparent plastic cover plate direction；The paddle-tumble that before metal backing reflecting layer, electron transfer layer, perovskite absorbed layer, hole transmission layer, electrically conducting transparent, electrode is predetermined separates and forms multiple sub-battery being in series.The present invention, to the permeability of substrate and electric conductivity no requirement (NR), can use the flexible substrate of conventional low cost, significantly reduce cost；Preparation method technique is simple; yield rate is high, it is easy to accomplish large-scale production, on the basis of not affecting perovskite solar cell performance; the extraneous factor adverse effects to perovskite solar cell such as steam, chemical attack, external carbuncle can be avoided, improve the reliability of battery.

Description

A kind of flexible large area perovskite solar module and preparation method thereof
Technical field
The invention belongs to titanium ore technical field of solar cells, be specifically related to a kind of flexible large area perovskite solar panel Part and preparation method thereof.
Background technology
Increasingly serious along with global ecological environment and energy shortage problem, cleans reproducible solar energy power generating and is subject to Most attention to various countries.Perovskite solar cell, since within 2009, being in the news first, has just attracted a large amount of researcher Interest.Through the development of a few years, its device efficiency just rises to 22% from 3.8%.Perovskite solar cell is by complete The reason that world's photovoltaic art pays high attention to, reaches the high efficiency level of first generation crystal silicon cell at short notice except it, The more important thing is the preparation method of its low cost, this is that the photovoltaic industry in depression brings dawn.
Type according to substrate is different, and perovskite solar cell can be divided into rigid substrate perovskite solar cell and flexible liner End perovskite solar cell.Compared to rigid substrate structure, flexible substrate perovskite solar cell is lighter, and quality is than power more Little and rollable, therefore can be widely applied to power station, roof, BIPV, movable power source etc..In industry metaplasia In product, flexible substrate solar cell can use volume to volume manufacturing process, and preparation cost is greatly reduced.
Flexible substrate perovskite solar cell generally uses following structure at present: on flexible and transparent conductive substrate, order is heavy Long-pending electron transfer layer (or hole transmission layer), perovskite absorbed layer, hole transmission layer (or electron transfer layer), finally deposit metal Back electrode.Flexible and transparent conductive substrate is made up of PET or the PEN plastic sheeting of high transmission and the ito film being deposited on.Due to light Being incident from flexible and transparent conductive substrate direction, the most this structure is called upper substrat structure.Flexible perovskite solar cell mesh Before be mostly in the little area experimentation stage, how to realize large area assembly, reduce cost and finally to realize industrialization be it Inevitable development trend.
But, in the middle of the process of Industrialization, the large area flexible perovskite solar cell of substrat structure in employing Can there is following problems in assembly: (1) prepares the transparency conducting layer technology of high conductance in PET or the PEN plastic of high transmission Difficulty is relatively big, and yield rate is low, and therefore the highest (1 square metre of cost surpasses flexible and transparent conductive substrate price based on PET or PEN Cross 10,000 yuan), the large area assembly cost that industrialization thus can be caused to produce remains high；(2) the large area perovskite sun is prepared During battery component, need that area battery is divided into baby battery and connect, to promote open-circuit voltage and the power of battery.By In perovskite absorbed layer not resistant against high temperatures, therefore can not use laser scribing, machinery line can only be used.If using above-mentioned Flexible and transparent conductive substrat structure, then easily lead to be previously deposited in flexible substrates when machinery scribing perovskite absorbed layer On ITO conductive layer fracture, thus cause battery failure.Therefore, no matter from cost angle or from technical standpoint consideration, above-mentioned Structural flexibility substrate perovskite solar cell is difficult to industrialization.
Summary of the invention
It is an object of the invention to solve above-mentioned technical problem and a kind of flexible large area perovskite solar cell is provided Assembly and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of flexible large area perovskite solar module, anti-including the metal backing stacked gradually on flexible substrate Before penetrating layer, electron transfer layer, perovskite absorbed layer, hole transmission layer, electrically conducting transparent, electrode, transparent enclosure glue, flexible and transparent are moulded Material cover plate, light is incident by flexible transparent plastic cover plate direction；Described metal backing reflecting layer, electron transfer layer, perovskite absorbed layer, The paddle-tumble that before hole transmission layer, electrically conducting transparent, electrode is predetermined separates and forms multiple sub-battery being in series；
Described metal backing reflecting layer and electron transfer layer are cut off and in this P1 paddle-tumble by perovskite by the P1 paddle-tumble at N number of interval Absorbed layer is filled up completely with；Described perovskite absorbed layer, hole transmission layer, electron transfer layer are cut off by the P2 paddle-tumble at N number of interval, institute Before stating electrically conducting transparent, electrode is connected with the metal backing reflecting layer of adjacent subcell by this P2 paddle-tumble；Described transparent enclosure glue is filled In this P2 paddle-tumble and with electrically conducting transparent before electrode this P2 paddle-tumble is filled up completely with；Described P1 paddle-tumble and P2 paddle-tumble share a limit It is provided adjacent to；
Described flexible substrate is dielectric substrate or is previously deposited one layer of insulating barrier for metal backing reflective layer deposition Metal substrate.
Described P1 paddle-tumble uses laser grooving and scribing method to prepare, and width is 30-300 μm.
Described P2 paddle-tumble uses mechanical scribing method to prepare, and width is 2-4 times of P1 paddle-tumble.
Described metal backing reflecting layer is the alloy between the one or two kinds of in Au, Ag or Al.
Described metal substrate is opaque flexible stainless steel substrate or titanium substrate；Described dielectric substrate is poly-naphthalene two Formic acid glycol ester thin film, polycarbonate film, polyacrylate film, Polyethersulfone membranes, polysulphone film or polyimides PI Plastic film substrate, or PET or PEN plastic film substrate.
Described transparent enclosure glue is mixed by A glue and B glue, and crosslinked at low temperature solidify to form.
Before described metal backing reflecting layer, electron transfer layer, perovskite absorbed layer, hole transmission layer and electrically conducting transparent, electrode is adopted Deposit by all solid state vacuum technology.
Described metal backing reflecting layer uses magnetically controlled DC sputtering or thermal evaporation method to prepare；Described electron transfer layer uses heat Prepared by the method for evaporation, electron beam evaporation or magnetron sputtering；Described perovskite absorbed layer uses thermal evaporation method to prepare；Described sky Cave transport layer uses thermal evaporation, electron beam evaporation or radio frequency magnetron sputtering method to prepare；Before described electrically conducting transparent, electrode uses heat Prepared by the method for evaporation or electron beam evaporation or rf magnetron sputtering.
The present invention also aims to provide a kind of flexible large area perovskite solar module preparation method, including such as Lower step:
Flexible substrate, preparation is provided to stack gradually the metal backing reflecting layer in described flexible substrate, electron transfer layer, and The P1 paddle-tumble that metal backing reflecting layer, electron transfer layer are cut off by rear preparation；
Preparation stacks gradually the perovskite absorbed layer on described electron transfer layer and hole transmission layer, the most adjacent described The P2 paddle-tumble that perovskite absorbed layer, hole transmission layer, electron transfer layer are cut off by the preparation of P1 paddle-tumble；
Preparation is laminated in electrode before the electrically conducting transparent on described hole transmission layer, and before making electrically conducting transparent, electrode is drawn at described P2 In connecting with the metal backing reflecting layer of adjacent subcell in groove and making described P2 paddle-tumble, region filled by reserved transparent enclosure glue, and this is saturating Bright packaging plastic is filled region and is separated with P1 paddle-tumble by electrode before the electrically conducting transparent in P2 paddle-tumble；
Electrode surface coating transparent enclosure glue before described electrically conducting transparent, and make transparent enclosure glue be filled in described P2 paddle-tumble Interior reserved transparent enclosure glue is filled in region；
Cover flexible transparent plastic cover plate on described packaging plastic surface, then carry out crosslinked at low temperature solidification, obtain flexible big Area perovskite solar module.
Described packaging plastic is mixed by A glue and B glue, and ratio is 1:1；After mix homogeneously, under coarse vacuum, room temperature state Bleed, the air being mixed in discharging glue；After aerofluxus, more mixed packaging plastic is uniformly coated on electricity before electrically conducting transparent Surface, pole；After having coated, flexible transparent plastic cover plate is laid on packaging plastic, then carries out crosslinked at low temperature solidification.
Flexible large area perovskite solar module of the present invention uses lower substrat structure, and light does not enters from substrate direction Penetrate, therefore can use cheap flexible substrate, it is not necessary to use expensive flexible and transparent conductive substrate, significantly reduce cost；
And the preparation method technique of the flexible large area perovskite solar module of the present invention is simple, yield rate is high, easily In accomplishing scale production, and on the basis of not affecting perovskite solar cell performance, can avoid steam, chemical attack, The extraneous factors such as the external carbuncle adverse effect to perovskite solar cell, improves the reliability of battery.
The two step scribing process taked can realize the series connection of sub-battery, promotes the open-circuit voltage of battery, and has The advantage that dead zone area is little, will not damage film layer.
Owing to before electrically conducting transparent, electrode (transparent conducting film) finally deposits, therefore P1 groove and the P2 groove of early stage is delineated also Before will not leading electrically conducting transparent, the film of electrode ruptures, and promotes yield rate.
The method using the coating encapsulation of A, B glue, technique is simple, and equipment requirements is low, will not introduce bubble, and can realize Crosslinked at low temperature solidifies, it is to avoid curing process temperature causes perovskite absorbed layer to decompose.
Accompanying drawing explanation
Fig. 1 illustrates the structural representation of the flexible large area perovskite solar module of the present invention；
In figure: 1-flexible substrate；2-metal backing reflecting layer；3-electron transfer layer；4-perovskite absorbed layer；5-hole transport Layer；Electrode before 6-electrically conducting transparent；7-transparent enclosure glue；8-flexible transparent plastic cover plate.
Detailed description of the invention
Below, in conjunction with example, substantive distinguishing features and the advantage of the present invention are further described, but the present invention not office It is limited to listed embodiment.
Embodiment 1:
Referring to shown in Fig. 1, a kind of flexible large area perovskite solar module, including stacking gradually in polyimides (PI) metal backing reflecting layer Ag on flexible substrate, electron transfer layer Al-Doped ZnO (AZO), perovskite absorbed layer CH3NH3PbI3, hole transmission layer CuI, electrode ITO, transparent enclosure glue, flexible transparent plastic cover plate before electrically conducting transparent, light is by soft Property transparent plastic cover plate direction incident.
By two step scoring procedure, this large area assembly is divided into the most sub-battery.The metal backing of adjacent subcell Reflecting layer Ag is cut off by P1 paddle-tumble, by P2 paddle-tumble, and electrode ITO and next sub-battery before the electrically conducting transparent of previous sub-battery Metal backing reflecting layer Ag be connected, thus by each sub-battery inline formation cascaded structure.
Embodiment 2:
The preparation method of a kind of flexible large area perovskite solar module, comprises the steps:
Polyimides (PI) flexible plastic substrate is cleaned.
The method using pulsed dc magnetron sputtering deposits metal backing reflecting layer Ag: base reservoir temperature 25-100 in substrate DEG C, sputtering pressure 0.1-10Pa, sputtering power 50-300W, Ag film thickness 50-300nm.
The method using rf magnetron sputtering deposits electron transfer layer AZO: depositing temperature on Ag film and is 25-100 DEG C, spatters Pressure of emanating 0.1-10Pa, sputtering power 50-300W, AZO film thickness 30-100nm；
The method using laser scribing prepares P1 paddle-tumble, and width is 50-300 μm.Described P1 paddle-tumble draws disconnected AZO and Ag electricity Pole, touches PI substrate.
The method using two step order coarse vacuum depositions deposits CH on the electron transport layer3NH3PbI3Absorbed layer: first exist Thermal evaporation PbI under low vacuum environment2Powder, then thermal evaporation CH3NH3I powder, carries out annealing on hot plate and is formed after taking-up Perovskite absorbed layer, thermal evaporation vacuum is 0.01-10Pa, and annealing temperature is 50-200 DEG C, and thickness is 100-500nm.
Use method deposition of hole transport layer CuI on perovskite absorbed layer of thermal evaporation: electric current is 20-60A, film thickness Degree is 20-100nm.
Using mechanical scribe process to prepare P2 paddle-tumble, width is 2-3 times of P1 paddle-tumble, and P2 paddle-tumble draws disconnected hole transmission layer CuI, perovskite absorbed layer and electron transfer layer AZO, touch metal backing reflecting layer Ag.
The method using thermal evaporation indium stannum alloy deposits ITO: temperature 100-400 DEG C, oxygen pressure on hole transmission layer 0.1-10Pa, thicknesses of layers 50-300nm.
Draw positive and negative electrode；
Electrode and P2 paddle-tumble surface-coated packaging plastic before electrically conducting transparent.Described packaging plastic is mixed by A glue and B glue, Ratio is 1:1；After mix homogeneously, at coarse vacuum, room temperature state lower pumping, the air being mixed in discharging glue, vacuum is 1-102 Handkerchief, the time is 100-200min；After aerofluxus, then being coated by mixed packaging plastic, thickness is 1-5mm；
The flexible transparent plastic substrate of high transmission is laid in packaging plastic surface, solidifies in coarse vacuum low temperature laminated, layer Pressure temperature is 120 DEG C.
Complete flexible large area perovskite solar module to prepare.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (10)

1. a flexible large area perovskite solar module, it is characterised in that include stacking gradually on flexible substrate Metal backing reflecting layer, electron transfer layer, perovskite absorbed layer, hole transmission layer, electrode before electrically conducting transparent, transparent enclosure glue, Flexible transparent plastic cover plate, light is incident by flexible transparent plastic cover plate direction；Described metal backing reflecting layer, electron transfer layer, calcium The paddle-tumble that before titanium ore absorbed layer, hole transmission layer, electrically conducting transparent, electrode is predetermined separates and forms multiple sub-battery being in series；
Described metal backing reflecting layer and electron transfer layer are cut off by the P1 paddle-tumble at N number of interval and are absorbed by perovskite in this P1 paddle-tumble Layer is filled up completely with；Described perovskite absorbed layer, hole transmission layer, electron transfer layer are cut off by the P2 paddle-tumble at N number of interval, described Before bright conduction, electrode is connected with the metal backing reflecting layer of adjacent subcell by this P2 paddle-tumble；Described transparent enclosure glue is filled in this In P2 paddle-tumble and with electrically conducting transparent before electrode this P2 paddle-tumble is filled up completely with；Described P1 paddle-tumble and P2 paddle-tumble share a limit and adjoin Arrange；
Described flexible substrate is dielectric substrate or is previously deposited one layer of metal for the insulating barrier of metal backing reflective layer deposition Substrate.
The most flexible large area perovskite solar module, it is characterised in that described P1 paddle-tumble uses Prepared by laser grooving and scribing method, width is 30-300 μm.
The most flexible large area perovskite solar module, it is characterised in that described P2 paddle-tumble uses Prepared by mechanical scribing method, width is 2-4 times of P1 paddle-tumble.
4. according to large area perovskite solar module flexible described in any one of claim 1-3, it is characterised in that described gold Belonging to back reflection layer is the alloy between the one or two kinds of in Au, Ag or Al.
The most flexible large area perovskite solar module, it is characterised in that described metal substrate is Opaque flexible stainless steel substrate or titanium substrate；Described dielectric substrate is PEN thin film, poly-carbon Acid esters thin film, polyacrylate film, Polyethersulfone membranes, polysulphone film or polyimides PI plastic film substrate, or PET or PEN plastic film substrate.
The most flexible large area perovskite solar module, it is characterised in that described transparent enclosure glue Being mixed by A glue and B glue, crosslinked at low temperature solidify to form.
The most flexible large area perovskite solar module, it is characterised in that described metal backing reflects Before layer, electron transfer layer, perovskite absorbed layer, hole transmission layer and electrically conducting transparent, electrode uses all solid state vacuum technology deposition.
The most flexible large area perovskite solar module, it is characterised in that described metal backing reflects Layer uses magnetically controlled DC sputtering or thermal evaporation method to prepare；Described electron transfer layer uses thermal evaporation, electron beam evaporation or magnetic control Prepared by the method for sputtering；Described perovskite absorbed layer uses thermal evaporation method to prepare；Described hole transmission layer uses thermal evaporation, electricity Prepared by sub-beam evaporation or radio frequency magnetron sputtering method；Before described electrically conducting transparent, electrode uses thermal evaporation or electron beam evaporation or radio frequency Prepared by the method for magnetron sputtering.
9. a flexible large area perovskite solar module preparation method, it is characterised in that comprise the steps:
Flexible substrate, preparation is provided to stack gradually the metal backing reflecting layer in described flexible substrate, electron transfer layer, then make The standby P1 paddle-tumble that metal backing reflecting layer, electron transfer layer are cut off；
Preparation stacks gradually the perovskite absorbed layer on described electron transfer layer and hole transmission layer, and the most adjacent described P1 draws The P2 paddle-tumble that perovskite absorbed layer, hole transmission layer, electron transfer layer are cut off by groove preparation；
Preparation is laminated in electrode before the electrically conducting transparent on described hole transmission layer, and before making electrically conducting transparent, electrode is in described P2 paddle-tumble In connecting with the metal backing reflecting layer of adjacent subcell and making described P2 paddle-tumble, reserved transparent enclosure glue fills region, this transparent envelope Dress glue is filled region and is separated with P1 paddle-tumble by electrode before the electrically conducting transparent in P2 paddle-tumble；
Electrode surface coating transparent enclosure glue before described electrically conducting transparent, and it is pre-to make transparent enclosure glue be filled in described P2 paddle-tumble Transparent enclosure glue is stayed to fill in region；
Cover flexible transparent plastic cover plate on described packaging plastic surface, then carry out crosslinked at low temperature solidification, obtain flexible large area Perovskite solar module.
The most flexible large area perovskite solar module preparation method, it is characterised in that described Packaging plastic is mixed by A glue and B glue, and ratio is 1:1；After mix homogeneously, at coarse vacuum, room temperature state lower pumping, discharge glue The air being inside mixed into；After aerofluxus, more mixed packaging plastic is uniformly coated on electrode surface before electrically conducting transparent；Coating After completing, flexible transparent plastic cover plate is laid on packaging plastic, then carries out crosslinked at low temperature solidification.
CN201610630348.8A 2016-08-02 2016-08-02 A kind of flexible large area perovskite solar module and preparation method thereof Pending CN106229327A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610630348.8A CN106229327A (en) 2016-08-02 2016-08-02 A kind of flexible large area perovskite solar module and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610630348.8A CN106229327A (en) 2016-08-02 2016-08-02 A kind of flexible large area perovskite solar module and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106229327A true CN106229327A (en) 2016-12-14

Family

ID=57536583

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610630348.8A Pending CN106229327A (en) 2016-08-02 2016-08-02 A kind of flexible large area perovskite solar module and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106229327A (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106981574A (en) * 2017-04-18 2017-07-25 陈胜红 A kind of long-life perovskite photovoltaic cell and preparation method thereof
CN108389975A (en) * 2018-04-10 2018-08-10 常州大学 A kind of preparation method of perovskite solar module
CN108461632A (en) * 2017-02-21 2018-08-28 华邦电子股份有限公司 Perovskite composite construction
WO2018156987A1 (en) * 2017-02-24 2018-08-30 Epic Battery Inc. Stable perovskite solar cell
CN108987585A (en) * 2017-06-02 2018-12-11 姚冀众 A kind of the perovskite solar cell module and its packaging method of encapsulation
CN109216550A (en) * 2017-06-30 2019-01-15 松下电器产业株式会社 Solar battery and solar cell module
CN109713129A (en) * 2018-12-28 2019-05-03 蜂巢能源科技有限公司 Perovskite thin film solar components and preparation method thereof
CN110061136A (en) * 2019-03-26 2019-07-26 西南石油大学 A kind of back-contact perovskite solar cell and preparation method thereof
CN110246909A (en) * 2019-07-23 2019-09-17 绵阳金能移动能源有限公司 A kind of flexible intraconnected solar cell encapsulation structure of low cost and method
CN110246965A (en) * 2018-03-09 2019-09-17 中国科学院大连化学物理研究所 A kind of large area perovskite solar cell component and preparation method thereof
JP2019175909A (en) * 2018-03-27 2019-10-10 積水化学工業株式会社 Flexible solar cell and manufacturing method therefor
US10587221B2 (en) 2017-04-03 2020-03-10 Epic Battery Inc. Modular solar battery
JP2020053454A (en) * 2018-09-25 2020-04-02 積水化学工業株式会社 Solar battery and method of manufacturing the same
US20200176196A1 (en) * 2017-07-24 2020-06-04 University Of Pittsburgh-Of The Commonwealth System Of Higher Education Perovskite solar cell configurations
CN111403436A (en) * 2020-03-16 2020-07-10 武汉理工大学 Perovskite solar cell and O L ED integrated device and preparation method
CN111403608A (en) * 2020-03-16 2020-07-10 武汉理工大学 Preparation method of perovskite solar cell series connection component
CN111463351A (en) * 2020-05-06 2020-07-28 武汉理工大学 Lead leakage prevention packaging structure of perovskite solar cell and packaging method thereof
TWI709257B (en) * 2017-07-27 2020-11-01 國立臺灣大學 Flexible perovskite solar cell and manufacturing method thereof
CN112670416A (en) * 2020-12-22 2021-04-16 常州亚玛顿股份有限公司 Packaging structure and packaging method of perovskite battery component
CN113380957A (en) * 2020-03-10 2021-09-10 杭州纤纳光电科技有限公司 Perovskite photoelectric component and packaging process thereof
CN113823745A (en) * 2021-11-10 2021-12-21 浙江晶科能源有限公司 Solar cell module, preparation method thereof and photovoltaic module
CN114156370A (en) * 2021-12-03 2022-03-08 华能新能源股份有限公司 Solar cell device and manufacturing method thereof
CN114335360A (en) * 2022-01-10 2022-04-12 华能新能源股份有限公司 Preparation method of scribing-free large-area perovskite solar cell
US11489082B2 (en) 2019-07-30 2022-11-01 Epic Battery Inc. Durable solar panels
EP4266378A4 (en) * 2022-01-24 2024-03-06 Contemporary Amperex Technology Co Ltd Solar cell and preparation method therefor, photovoltaic module and electric device
CN117750849A (en) * 2024-02-20 2024-03-22 西安电子科技大学 Preparation method of large-area flexible perovskite solar cell and cell

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102800734A (en) * 2012-09-04 2012-11-28 上海中科高等研究院 Solar power generation and storage integrated device
CN102832262A (en) * 2011-06-14 2012-12-19 通用电气公司 Photovoltaic device with reflection enhancing layer
US20140313574A1 (en) * 2013-01-14 2014-10-23 South Dakota State University Nanoparticle films for use as solar cell back reflectors and other applications
CN104521010A (en) * 2012-06-04 2015-04-15 瑞士材料试验研究所 Method for production of a photovoltaic device in substrate configuration

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102832262A (en) * 2011-06-14 2012-12-19 通用电气公司 Photovoltaic device with reflection enhancing layer
CN104521010A (en) * 2012-06-04 2015-04-15 瑞士材料试验研究所 Method for production of a photovoltaic device in substrate configuration
CN102800734A (en) * 2012-09-04 2012-11-28 上海中科高等研究院 Solar power generation and storage integrated device
US20140313574A1 (en) * 2013-01-14 2014-10-23 South Dakota State University Nanoparticle films for use as solar cell back reflectors and other applications

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FABIO MATTEOCCI 等: ""High efficiency photovoltaic module based on mesoscopic organometal halide perovskite"", 《PROGRESS IN PHOTOVOLTAICS》 *
FRANCESCO DI GIACOMO 等: ""Flexible Perovskite Photovoltaic Modules and Solar Cells Based on Atomic Layer Deposited Compact Layers and UV-Irradiated TiO 2 Scaffolds on Plastic Substrates"", 《ADVANCED ENERGY MATERIALS》 *
MINWOO PARK 等: ""High-performance flexible and air-stable perovskite solar cells with a large active area based on poly(3-hexylthiophene) nanofibrils"", 《JOURNAL OF MATERIALS CHEMISTRY A》 *

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108461632A (en) * 2017-02-21 2018-08-28 华邦电子股份有限公司 Perovskite composite construction
WO2018156987A1 (en) * 2017-02-24 2018-08-30 Epic Battery Inc. Stable perovskite solar cell
US10587221B2 (en) 2017-04-03 2020-03-10 Epic Battery Inc. Modular solar battery
CN106981574B (en) * 2017-04-18 2019-07-05 浙江蓝绿新材料科技有限公司 A kind of long-life perovskite photovoltaic cell and preparation method thereof
CN106981574A (en) * 2017-04-18 2017-07-25 陈胜红 A kind of long-life perovskite photovoltaic cell and preparation method thereof
CN108987585A (en) * 2017-06-02 2018-12-11 姚冀众 A kind of the perovskite solar cell module and its packaging method of encapsulation
CN109216550B (en) * 2017-06-30 2023-09-01 松下控股株式会社 Solar cell and solar cell module
CN109216550A (en) * 2017-06-30 2019-01-15 松下电器产业株式会社 Solar battery and solar cell module
US11764001B2 (en) * 2017-07-24 2023-09-19 University Of Pittsburgh-Of The Commonwealth System Of Higher Education Perovskite solar cell configurations
US20200176196A1 (en) * 2017-07-24 2020-06-04 University Of Pittsburgh-Of The Commonwealth System Of Higher Education Perovskite solar cell configurations
TWI709257B (en) * 2017-07-27 2020-11-01 國立臺灣大學 Flexible perovskite solar cell and manufacturing method thereof
CN110246965A (en) * 2018-03-09 2019-09-17 中国科学院大连化学物理研究所 A kind of large area perovskite solar cell component and preparation method thereof
JP2019175909A (en) * 2018-03-27 2019-10-10 積水化学工業株式会社 Flexible solar cell and manufacturing method therefor
JP7112225B2 (en) 2018-03-27 2022-08-03 積水化学工業株式会社 FLEXIBLE SOLAR CELL AND METHOD FOR MANUFACTURING FLEXIBLE SOLAR CELL
CN108389975A (en) * 2018-04-10 2018-08-10 常州大学 A kind of preparation method of perovskite solar module
JP2020053454A (en) * 2018-09-25 2020-04-02 積水化学工業株式会社 Solar battery and method of manufacturing the same
CN109713129A (en) * 2018-12-28 2019-05-03 蜂巢能源科技有限公司 Perovskite thin film solar components and preparation method thereof
WO2020135739A1 (en) * 2018-12-28 2020-07-02 蜂巢能源科技有限公司 Perovskite film solar module and manufacturing method therefor
CN109713129B (en) * 2018-12-28 2021-02-26 无锡极电光能科技有限公司 Perovskite thin-film solar module and preparation method thereof
CN110061136B (en) * 2019-03-26 2022-03-11 西南石油大学 Back contact type perovskite solar cell and preparation method thereof
CN110061136A (en) * 2019-03-26 2019-07-26 西南石油大学 A kind of back-contact perovskite solar cell and preparation method thereof
CN110246909B (en) * 2019-07-23 2024-01-30 绵阳皓华光电科技有限公司 Low-cost flexible inline solar cell packaging structure and method
CN110246909A (en) * 2019-07-23 2019-09-17 绵阳金能移动能源有限公司 A kind of flexible intraconnected solar cell encapsulation structure of low cost and method
US11489082B2 (en) 2019-07-30 2022-11-01 Epic Battery Inc. Durable solar panels
CN113380957A (en) * 2020-03-10 2021-09-10 杭州纤纳光电科技有限公司 Perovskite photoelectric component and packaging process thereof
CN111403608B (en) * 2020-03-16 2022-04-15 武汉理工大学 Preparation method of perovskite solar cell series connection component
CN111403608A (en) * 2020-03-16 2020-07-10 武汉理工大学 Preparation method of perovskite solar cell series connection component
CN111403436A (en) * 2020-03-16 2020-07-10 武汉理工大学 Perovskite solar cell and O L ED integrated device and preparation method
CN111463351A (en) * 2020-05-06 2020-07-28 武汉理工大学 Lead leakage prevention packaging structure of perovskite solar cell and packaging method thereof
CN112670416A (en) * 2020-12-22 2021-04-16 常州亚玛顿股份有限公司 Packaging structure and packaging method of perovskite battery component
CN113823745A (en) * 2021-11-10 2021-12-21 浙江晶科能源有限公司 Solar cell module, preparation method thereof and photovoltaic module
US11676774B2 (en) 2021-11-10 2023-06-13 Zhejiang Jinko Solar Co., Ltd. Solar cell module, manufacturing method thereof, and photovoltaic module
CN114156370A (en) * 2021-12-03 2022-03-08 华能新能源股份有限公司 Solar cell device and manufacturing method thereof
CN114335360A (en) * 2022-01-10 2022-04-12 华能新能源股份有限公司 Preparation method of scribing-free large-area perovskite solar cell
EP4266378A4 (en) * 2022-01-24 2024-03-06 Contemporary Amperex Technology Co Ltd Solar cell and preparation method therefor, photovoltaic module and electric device
CN117750849A (en) * 2024-02-20 2024-03-22 西安电子科技大学 Preparation method of large-area flexible perovskite solar cell and cell

Similar Documents

Publication Publication Date Title
CN106229327A (en) A kind of flexible large area perovskite solar module and preparation method thereof
JP2013509706A (en) Solar cell and manufacturing method thereof
US8779282B2 (en) Solar cell apparatus and method for manufacturing the same
CN107658366A (en) The film plating process and PVD support plates and coating apparatus of a kind of hetero-junction solar cell
CN106340570A (en) Film plating device for preparing TCO (Transparent Conductive Oxide) film and film plating method
CN101752453A (en) Preparation method of glass-substrate double-side CIGS thin film solar cell module
CN113178501A (en) Flexible photovoltaic module and preparation method thereof
CN103426943A (en) Laminated structure of copper-zinc-tin-sulfur film solar cell and preparation method thereof
KR20180098492A (en) Solar cell and process of preparing the same
CN101615640B (en) Zinc oxide based solar battery and preparation method thereof
KR102174537B1 (en) Solar cell and process of preparing the same
CN105742402A (en) Preparation method of laminated solar battery, and structure of lamination solar battery
CN112103271A (en) Double-sided light-receiving laminated solar cell module and preparation method thereof
CN101728460B (en) Solar battery for solar mobile phone battery and preparation method thereof
CN101556973B (en) Film photovoltaic device and composite electrode thereof
CN103187481A (en) Conductive substrate, method for manufacturing same, and solar cell
CN105720199A (en) Large-area organic thin-film solar battery and preparation method thereof
CN202033491U (en) Reflective strip and solar cell assembly using the same
CN103597610B (en) Solar module and manufacture method thereof
CN104067398B (en) Solar cell and manufacture method thereof
CN101820004A (en) Photo-electro separated solar cell back reflector
CN202324421U (en) Photovoltaic building component of solar battery
CN106711284B (en) A kind of cadmium telluride diaphragm solar battery method of manufacturing technology of binodal lamination parallel connection
US9660113B2 (en) Solar cell apparatus and method of fabricating the same
CN105206693A (en) Flexible thin-film solar cell structure and preparation method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20161214