CN106223109A - Paper softening agent is used in a kind of braiding - Google Patents

Paper softening agent is used in a kind of braiding Download PDF

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Publication number
CN106223109A
CN106223109A CN201610579325.9A CN201610579325A CN106223109A CN 106223109 A CN106223109 A CN 106223109A CN 201610579325 A CN201610579325 A CN 201610579325A CN 106223109 A CN106223109 A CN 106223109A
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Prior art keywords
paper
braiding
softening agent
minutes
mixture
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Granted
Application number
CN201610579325.9A
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Chinese (zh)
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CN106223109B (en
Inventor
刘维金
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Linyi Tailai Plastics Co ltd
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Fu'nan Jinwei Arts & Crafts Co Ltd
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Priority to CN201610579325.9A priority Critical patent/CN106223109B/en
Publication of CN106223109A publication Critical patent/CN106223109A/en
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/11—Halides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper

Landscapes

  • Paper (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of braiding paper softening agent, be made up of following raw material: Oleum Gossypii semen, microcrystalline Cellulose, chitosan quaternary ammonium salt, cocamido propyl betaine, Aloe extract, allantoin, sodium carboxymethyl cellulose, isopropyl myristate, candelilla wax, triclosan.The braiding paper softening agent that the present invention provides, preparation is simple, cheap, can carry out large-scale production, safety non-toxic, environmental protection, will not be detrimental to health；Through ultrasonic and vacuum stirring, making all raw material mix homogeneously, in homogeneous latex emulsion state, addition is few, use simple, be directly added into paper pulp or spray paper, soften uniformly, without vestige, folding rate and percentage elongation are remarkably reinforced, and the persistent period is long, improve paper brightness and smoothness；Braiding breakage rate reduces 13.6%, and braiding speed improves 10.2%, and knitting intensity improves 17.3%, hence it is evident that improve knitting property, improves quality and the class of knitting.

Description

Paper softening agent is used in a kind of braiding
Technical field
The invention mainly relates to softening technology field, particularly relate to a kind of braiding paper softening agent.
Background technology
Paper is seen everywhere, and may be used for industry, office, culture and life, and the waste and old paper therefore produced is also a lot, greatly How all can throw away after crushing, only fraction can recycle, and for improving the value of waste and old paper, reduces environment dirty Dye, is woven into life appliance or the art work by waste and old paper, has the highest use and enjoying value, and can protection ring Border, improves income.
At present, the paper softening agent in market is of a great variety, but is typically only used for the softening of paper pulp or paper, does not possesses Dual-use function, bating effect is uneven, and effect duration is short, all containing toxic reagent, is detrimental to health, the waste water severe contamination of generation Environment.
Summary of the invention
In order to make up the defect of prior art, it is an object of the invention to provide a kind of braiding paper softening agent.
Paper softening agent is used in a kind of braiding, is made up of the raw material of following weight portion: Oleum Gossypii semen 32 ~ 34, microcrystalline Cellulose 27 ~ 29, chitosan quaternary ammonium salt 26 ~ 28, cocamido propyl betaine 22 ~ 24, Aloe extract 18 ~ 20, allantoin 13 ~ 15, carboxylic first Base sodium cellulosate 10 ~ 12, isopropyl myristate 6 ~ 8, candelilla wax 6 ~ 8, triclosan 5 ~ 7.
A kind of preparation method woven with paper softening agent, specifically includes following steps:
(1) Oleum Gossypii semen is heated to 110 ~ 120 DEG C, keeps temperature 5 ~ 10 minutes, be cooled to 65 ~ 70 DEG C, add myristic acid different Propyl ester and candelilla wax, 48 ~ 50 revs/min are stirred 18 ~ 20 minutes, and mix homogeneously obtains mixture A；
(2) adding the water of chitosan quaternary ammonium salt weight 2 ~ 3 times amount in chitosan quaternary ammonium salt, stirring, to being completely dissolved, adds cocos nucifera oil Amido propyl betaine, Aloe extract, allantoin and sodium carboxymethyl cellulose, ultrasonic 15 ~ 20 minutes of 32 ~ 34kHz, obtain mixing Thing B；
(3) in microcrystalline Cellulose, add the sodium hydroxide solution that mass fraction is 3 ~ 4% of microcrystalline Cellulose weight 2 ~ 3 times amount, 52 ~ 54 revs/min are stirred 8 ~ 10 minutes, add triclosan, ultrasonic 20 ~ 25 minutes of 34 ~ 36kHz, obtain mixture C；
(4) mixture A, mixture B and mixture C are mixed, in 65 ~ 70 DEG C, ultrasonic 25 ~ 30 minutes of 30 ~ 32kHz, in 110 ~ 120kW, 160 ~ 180 revs/min of vacuum stirring 30 ~ 35 minutes, quickly form emulsion state, it is simple to uses, obtains braiding paper Softening agent；
(5) vacuum packaging, obtains finished product.
The using method of described braiding paper softening agent, weighs paper pulp or the 0.4 ~ 0.6% of paper dry weight, adds distilled water Dilute 100 ~ 150 times, after adding paper pulp, carry out the preparation of follow-up paper, or even application is after paper surface, paper is placed in 12 ~ 14 DEG C, air humidity be 63 ~ 65% environment in be dried to water content be 5 ~ 6%, waste and old paper can be softened.
The invention have the advantage that a kind of braiding paper softening agent that the present invention provides, preparation is simple, cheap, can To carry out large-scale production, safety non-toxic, environmental protection, will not be detrimental to health；Through ultrasonic and vacuum stirring, make all former Material mix homogeneously, in homogeneous latex emulsion state, addition is few, uses simple, is directly added into paper pulp or sprays paper, can make Standby brand-new braiding paper, it is also possible to carrying out the improvement of waste and old paper, soften uniformly, without vestige, folding rate and percentage elongation are obvious Strengthening, the persistent period is long, improves paper brightness and smoothness；Braiding breakage rate reduces 13%, and braiding speed improves 10.2%, braiding Product intensity improves 6.8%, hence it is evident that improve knitting property, improves quality and the class of knitting, and income improves 21.3%.
Detailed description of the invention
With specific embodiment, the present invention is described below.
Embodiment 1
Paper softening agent is used in a kind of braiding, is made up of the raw material of following weight portion: Oleum Gossypii semen 32, microcrystalline Cellulose 27, chitosan Quaternary ammonium salt 26, cocamido propyl betaine 22, Aloe extract 18, allantoin 13, sodium carboxymethyl cellulose 10, myristic acid Isopropyl ester 6, candelilla wax 6, triclosan 5.
A kind of preparation method woven with paper softening agent, specifically includes following steps:
(1) Oleum Gossypii semen is heated to 115 DEG C, keeps temperature 8 minutes, be cooled to 65 ~ 70 DEG C, add isopropyl myristate and little Candle vegetable wax, 50 revs/min are stirred 18 minutes, and mix homogeneously obtains mixture A；
(2) adding the water of chitosan quaternary ammonium salt weight 3 times amount in chitosan quaternary ammonium salt, stirring, to being completely dissolved, adds cocos nucifera oil acyl Amine CAB, Aloe extract, allantoin and sodium carboxymethyl cellulose, ultrasonic 20 minutes of 32kHz, obtain mixture B；
(3) sodium hydroxide solution that mass fraction is 4% of addition microcrystalline Cellulose weight 3 times amount in microcrystalline Cellulose, 52 Rev/min stirring 10 minutes, add triclosan, ultrasonic 25 minutes of 35kHz, obtain mixture C；
(4) mixture A, mixture B and mixture C are mixed, in 65 DEG C, ultrasonic 25 minutes of 30kHz, in 115kW, 170 revs/min Clock vacuum stirring 30 minutes, quickly forms emulsion state, it is simple to uses, obtains braiding paper softening agent；
(5) vacuum packaging, obtains finished product.
The using method of described braiding paper softening agent, weighs paper pulp or the 0.5% of paper dry weight, adds distilled water diluting 150 times, after adding paper pulp, carry out the preparation of follow-up paper, or even application is after paper surface, paper is placed in 12 DEG C, sky Air humidity degree be 65% environment in be dried to water content be 5%, waste and old paper can be softened.
Embodiment 2
Paper softening agent is used in a kind of braiding, is made up of the raw material of following weight portion: Oleum Gossypii semen 33, microcrystalline Cellulose 28, chitosan Quaternary ammonium salt 27, cocamido propyl betaine 23, Aloe extract 19, allantoin 14, sodium carboxymethyl cellulose 11, myristic acid Isopropyl ester 7, candelilla wax 7, triclosan 6.
Preparation and application, with embodiment 1.
Embodiment 3
Paper softening agent is used in a kind of braiding, is made up of the raw material of following weight portion: Oleum Gossypii semen 34, microcrystalline Cellulose 29, chitosan Quaternary ammonium salt 28, cocamido propyl betaine 24, Aloe extract 20, allantoin 15, sodium carboxymethyl cellulose 12, myristic acid Isopropyl ester 8, candelilla wax 8, triclosan 7.
Preparation and application, with embodiment 1.
Comparative example
Existing paper softening agent.
Embodiment and the index evaluation of comparative example softening agent:
Processing identical paper with the softening agent of comparative example by embodiment respectively, matched group is not handled by, and is disposed Rear detecting respectively, the index evaluation of embodiment and comparative example softening agent is shown in Table 1.
Table 1: embodiment and the index evaluation of comparative example softening agent
Project Embodiment group Comparative example group Matched group
Abnormal flavour Nothing Have Nothing
Toxicity Nothing Have Nothing
Brightness/(%) 82 67 73
Suppleness improves/(%) 13.4 — —
Folding rate improves/(%) 5.8 — —
Braiding breakage rate/(%) 2~3 5~6 16~17
Braiding speed improves/(%) 10.2 — —
Income improves/(%) 21.2 — —
Note: " " indicate without.
The result of table 1 shows, paper softening agent is used in embodiment braiding, the paper after process relative to comparative example, free from extraneous odour, Safety non-toxic, brightness is suitable, and suppleness and folding rate significantly improve, and breakage rate during braiding substantially reduces, and improves braiding speed, Work efficiency significantly improves, and increases income, illustrates that the braiding paper softening agent that the present invention provides has preferably softening Effect.

Claims (3)

1. paper softening agent is used in a braiding, it is characterised in that be made up of the raw material of following weight portion: Oleum Gossypii semen 32 ~ 34, crystallite Cellulose 27 ~ 29, chitosan quaternary ammonium salt 26 ~ 28, cocamido propyl betaine 22 ~ 24, Aloe extract 18 ~ 20, allantoin 13 ~ 15, sodium carboxymethyl cellulose 10 ~ 12, isopropyl myristate 6 ~ 8, candelilla wax 6 ~ 8, triclosan 5 ~ 7.
The braiding preparation method of paper softening agent the most according to claim 1, it is characterised in that specifically include following step Rapid:
(1) Oleum Gossypii semen is heated to 110 ~ 120 DEG C, keeps temperature 5 ~ 10 minutes, be cooled to 65 ~ 70 DEG C, add myristic acid different Propyl ester and candelilla wax, 48 ~ 50 revs/min are stirred 18 ~ 20 minutes, and mix homogeneously obtains mixture A；
(2) adding the water of chitosan quaternary ammonium salt weight 2 ~ 3 times amount in chitosan quaternary ammonium salt, stirring, to being completely dissolved, adds cocos nucifera oil Amido propyl betaine, Aloe extract, allantoin and sodium carboxymethyl cellulose, ultrasonic 15 ~ 20 minutes of 32 ~ 34kHz, obtain mixing Thing B；
(3) in microcrystalline Cellulose, add the sodium hydroxide solution that mass fraction is 3 ~ 4% of microcrystalline Cellulose weight 2 ~ 3 times amount, 52 ~ 54 revs/min are stirred 8 ~ 10 minutes, add triclosan, ultrasonic 20 ~ 25 minutes of 34 ~ 36kHz, obtain mixture C；
(4) mixture A, mixture B and mixture C are mixed, in 65 ~ 70 DEG C, ultrasonic 25 ~ 30 minutes of 30 ~ 32kHz, in 110 ~ 120kW, 160 ~ 180 revs/min of vacuum stirring 30 ~ 35 minutes, obtain braiding paper softening agent；
(5) vacuum packaging, obtains finished product.
3. according to the braiding using method of paper softening agent described in claim 1 ~ 2, it is characterised in that weigh paper pulp or paper The 0.4 ~ 0.6% of dry weight, adds distilled water diluting 100 ~ 150 times, after adding paper pulp, carries out the preparation of follow-up paper, or even application After paper surface, paper is placed in 12 ~ 14 DEG C, air humidity be 63 ~ 65% environment in be dried to water content be 5 ~ 6%, can So that waste and old paper is softened.
CN201610579325.9A 2016-07-22 2016-07-22 A kind of braiding paper softening agent Active CN106223109B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610579325.9A CN106223109B (en) 2016-07-22 2016-07-22 A kind of braiding paper softening agent

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CN106223109B CN106223109B (en) 2018-08-24

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103109019A (en) * 2010-09-30 2013-05-15 凯米罗总公司 Degrading agent compositions for temporary wet strength systems in tissue products
CN104085008A (en) * 2014-06-10 2014-10-08 安徽华宇工艺品集团有限公司 A mildew-resistant bamboo softener and a preparing method thereof
CN104264530A (en) * 2014-09-24 2015-01-07 陈嗳 Production process of antibacterial paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103109019A (en) * 2010-09-30 2013-05-15 凯米罗总公司 Degrading agent compositions for temporary wet strength systems in tissue products
CN104085008A (en) * 2014-06-10 2014-10-08 安徽华宇工艺品集团有限公司 A mildew-resistant bamboo softener and a preparing method thereof
CN104264530A (en) * 2014-09-24 2015-01-07 陈嗳 Production process of antibacterial paper

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Effective date of registration: 20221208

Address after: 276000 Tuan Lin Zhen Xu Jia Huang Suo Cun, Lingang Economic Development Zone, Linyi City, Shandong Province

Patentee after: Linyi Tailai Plastics Co.,Ltd.

Address before: 236300 Liu Tai Village, Gao Tai Township, Funan County, Fuyang, Anhui

Patentee before: FUNAN JINWEI CRAFTS CO.,LTD.