CN108726594A - A kind of environment-friendly type inorganic agent for treated sewage - Google Patents
A kind of environment-friendly type inorganic agent for treated sewage Download PDFInfo
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- CN108726594A CN108726594A CN201810526520.4A CN201810526520A CN108726594A CN 108726594 A CN108726594 A CN 108726594A CN 201810526520 A CN201810526520 A CN 201810526520A CN 108726594 A CN108726594 A CN 108726594A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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Abstract
The present invention relates to a kind of environment-friendly type inorganic agent for treated sewage, weight meter is prepared using following raw material:25-30 parts of diatom ooze, 3-5 parts of polyacrylamide, 8-10 parts of wingceltis hide fiber, 1.8-2.5 parts of diallyl dimethyl ammoniumchloride, 16-22 parts of flyash.Environment-friendly type inorganic agent prepared by the present invention is safe, new pollutant will not be introduced in processing procedure, new pollution will not be generated to water body, the primary raw material ingredient in the application is diatomite, flyash etc., and cost of material is relatively low, and flyash itself is a kind of rubbish, processing of its new function for sewage is assigned after treatment, greatly reduces the cost of inorganic agent, simultaneously, waste is recycled, economic benefit is improved.
Description
Technical field
The invention belongs to field of environment protection, are related to the process field of sewage, and in particular to a kind of environmental protection for treated sewage
Type inorganic agent.
Background technology
Sewage disposal is that the water quality requirement for draining a certain water body to make sewage reach or reusing purifies it
Process.It is each that sewage disposal is widely used in building, agricultural, traffic, the energy, petrochemical industry, environmental protection, urban landscape, medical treatment, food and drink etc.
The daily life of common people is also come into a field more and more.
Present sewage water treatment method is broadly divided into chemical decomposition method, microorganism decomposition method and several classes of physisorphtion, for
Different sewage can also select the combination of these types of method to handle sewage, for the sewage containing heavy metal ion,
It is mainly removed using complexometry, the cost of complexing agent is often higher, and the range that the effect removed is more general, applicable
Also more single.
Invention content
The present invention provides a kind of for treated sewage to solve the defect of existing sewage disposal process inorganic agent
Environment-friendly type inorganic agent greatly promotes treatment effect of the inorganic agent to sewage by being compounded to inorganic agent, can be dirty to life
Water, paper waste and dyeing waste water all have good treatment effect.
The invention is realized by the following technical scheme:
A kind of environment-friendly type inorganic agent for treated sewage is prepared using following raw material by weight:25-30 parts of diatom ooze gathers
3-5 parts of acrylamide, 8-10 parts of wingceltis hide fiber, 1.8-2.5 parts of diallyl dimethyl ammoniumchloride, 16-22 parts of flyash.
The diatom ooze is modified processing using following methods:
(1), diatomite cleaned up using clear water, the isothermal holding 45-50min at 450-500 DEG C, at this temperature, to
Dextrin, polyvinyl alcohol, sodium citrate, water are sprayed above diatomite by weight 3.5:6:1.2:Mixture made of 10, then
It is naturally cooling to room temperature, the weight ratio of diatomite and mixture is 80-90:1;
(2), by step(1)The phosphoric acid solution immersion treatment 3-5min for the diatomite use quality score 20% handled well, impregnated
In journey frequency of use be 25kHz ultrasonic echography handle, then by diatomite at 55-60 DEG C drying and processing 35-40min;
(3), by step(2)The diatomite handled well is with chitosan by weight 13-15:1 ratio mixing, uses height after mixing
Fast mixing machine is handled, and diatomite is made to be sufficiently mixed uniformly with chitosan;
(4), by step(3)The diatomite handled well pressurize under 2Mpa pressure handles 2h, obtains modification infusorial earth.
The flyash passes through modification, and the specific method is as follows:(1), flyash be broken into grain size be not more than 10mm
Particle, by fly ash grain use quality score be 20% phosphoric acid, mass fraction 60% sulfuric acid by volume 2:3 preparations
Acid soak handles 3-5min;
(2), by step(1)The flyash handled well makes 2-3 times wash with distilled water, is then dried at 50-60 DEG C, then will
In the sulfuric acid solution that flyash is put into 10-15 times of its weight, mass fraction is 3%, using blender with the speed of 50-60r/min
Stirring, and the ultrasonication that frequency of use is 20kHz, it is that 1.5% aluminium hydroxide is molten that mass fraction is added constantly into mixture
Liquid, the addition volume of aluminum hydroxide solution are the 1/3 of sulfuric acid solution, and being continuing with blender after the completion of being added stirs and surpassed
Sonication 15-20min;
(3), by step(2)The flyash handled well is cleaned, and surface impurity is removed, and is then placed in the phosphorus that mass fraction is 5%
In acid dihydride sodium solution, the ultrasonic oscillation that frequency of use is 25kHz handles 30-40min, takes out, drying, obtains modified fine coal
Ash.
The wingceltis hide fiber is modified processing using following steps:(1), annual early June late May-, selection is green
Wingceltis peeling, by the lignin sulfonic acid sodium solution immersion treatment 120-150min of wingceltis use quality score 1.2%;
(2), by step(1)The wingceltis handled well carries out roller process, when first time roll-in, the roller of roll squeezer using roll squeezer
Spacing is the 2/3 of wingceltis maximum gauge, and the roller spacing of roll squeezer is reduced 2mm by roller process every time later, until roll squeezer
Roller stop roller process when being smaller than 1.2mm, after each roll-in, the wingceltis after roll-in is used into sodium carbonate-
Sodium bicarbonate buffer system, dodecyl sodium sulfate, water are by weight 5:1:200 solution prepared impregnate 8-10min, then again
It is further processed;
(3), by step(2)The wingceltis handled well uses compound soak immersion treatment 60-75min at 42-50 DEG C, then
It is stirred using blender, fiber is made to disperse in compound soak, then removed the residue of offscum and floating, then will remain
Remaining fiber is combed, and the compound soak is made using following raw material by weight:1.2 parts of trihydroxy ethylamine oleate soap,
30 parts of 15 parts of ethanol solution, the water of 1.2 parts of dodecyl sodium sulfate, 0.4 part of triethanolamine, volume fraction 78%;
(4), by step(3)The sodium citrate solution that the fiber handled well is 2% with mass fraction is by weight 1:2 ratio is mixed
It closes, fiber is then broken into the staple fiber that length is 2-15mm using crusher, obtains modified wingceltis hide fiber.
The pH9.2-10.8 of the sodium carbonate-bicarbonate buffer system.
A kind of preparation method of environment-friendly type inorganic agent for papermaking wastewater, includes the following steps:(1), by diatom ooze, powder
Coal ash is added blender and stirs 30-40min, the activation process 12-15min at 600-650 DEG C, and wingceltis hide fiber is then added,
Continue to stir 25-30min, above-mentioned raw materials is made to be sufficiently mixed;
(2), by step(1)Polyacrylamide and diallyl dimethyl ammoniumchloride are added in the raw material handled well, using turning
Drum granulator, obtains inorganic agent.
A kind of preparation method of environment-friendly type inorganic agent for papermaking wastewater, the diatom ooze are changed using following methods
Property processing:
(1), diatomite cleaned up using clear water, the isothermal holding 45-50min at 450-500 DEG C, at this temperature, to
Dextrin, polyvinyl alcohol, sodium citrate, water are sprayed above diatomite by weight 3.5:6:1.2:Mixture made of 10, then
It is naturally cooling to room temperature, the weight ratio of diatomite and mixture is 80-90:1;
(2), by step(1)The phosphoric acid solution immersion treatment 3-5min for the diatomite use quality score 20% handled well, impregnated
In journey frequency of use be 25kHz ultrasonic echography handle, then by diatomite at 55-60 DEG C drying and processing 35-40min;
(3), by step(2)The diatomite handled well is with chitosan by weight 13-15:1 ratio mixing, uses height after mixing
Fast mixing machine is handled, and diatomite is made to be sufficiently mixed uniformly with chitosan;
(4), by step(3)The diatomite handled well pressurize under 2Mpa pressure handles 2h, obtains modification infusorial earth.
In the preparation method, the flyash passes through modification, and the specific method is as follows:(1), flyash is broken into
Grain size is not more than the particle of 10mm, and the sulfuric acid of phosphoric acid, mass fraction 60% that fly ash grain use quality score is 20% is pressed
Volume ratio 2:3 acid soaks prepared handle 10-15min;
(2), by step(1)The flyash handled well makes 2-3 times wash with distilled water, is then dried at 50-60 DEG C, then will
In the sulfuric acid solution that flyash is put into 10-15 times of its weight, mass fraction is 3%, using blender with the speed of 50-60r/min
Stirring, and the ultrasonication that frequency of use is 20kHz, it is that 1.5% aluminium hydroxide is molten that mass fraction is added constantly into mixture
Liquid, the addition volume of aluminum hydroxide solution are the 1/3 of sulfuric acid solution, and being continuing with blender after the completion of being added stirs and surpassed
Sonication 15-20min;
(3), by step(2)The flyash handled well is cleaned, and surface impurity is removed, and is then placed in the phosphorus that mass fraction is 5%
In acid dihydride sodium solution, the ultrasonic oscillation that frequency of use is 25kHz handles 30-40min, takes out, drying, obtains modified fine coal
Ash.
In the preparation method, the wingceltis hide fiber is modified processing using following steps:(1), annual 5 below the moon
Early June in ten days-selects wingceltis peeling, by the lignin sulfonic acid sodium solution immersion treatment of wingceltis use quality score 1.2%
120-150min;
(2), by step(1)The wingceltis handled well carries out roller process, when first time roll-in, the roller of roll squeezer using roll squeezer
Spacing is the 2/3 of wingceltis maximum gauge, and the roller spacing of roll squeezer is reduced 2mm by roller process every time later, until roll squeezer
Roller stop roller process when being smaller than 1.2mm, after each roll-in, the wingceltis after roll-in is used into sodium carbonate-
Sodium bicarbonate buffer system, dodecyl sodium sulfate, water are by weight 5:1:200 solution prepared impregnate 8-10min, then again
It is further processed;
(3), by step(2)The wingceltis handled well uses compound soak immersion treatment 60-75min at 42-50 DEG C, then
It is stirred using blender, fiber is made to disperse in compound soak, then removed the residue of offscum and floating, then will remain
Remaining fiber is combed, and the compound soak is made using following raw material by weight:1.2 parts of trihydroxy ethylamine oleate soap,
30 parts of 15 parts of ethanol solution, the water of 1.2 parts of dodecyl sodium sulfate, 0.4 part of triethanolamine, volume fraction 78%;
(4), by step(3)The sodium citrate solution that the fiber handled well is 2% with mass fraction is by weight 1:2 ratio is mixed
It closes, fiber is then broken into the staple fiber that length is 2-15mm using crusher, obtains modified wingceltis hide fiber.
Beneficial effects of the present invention:The environment-friendly type inorganic agent for treated sewage in the application uses diatom ooze, fine coal
Ash is prepared by primary raw material, and relative to directly being adsorbed using activated carbon, the cost of processing significantly reduces, due to fine coal
It is grey this as dead meal, it is difficult to handle, cost is extremely low, by being modified to flyash in the application, promotes its absorption property,
And after modification, flyash can be made to keep good form and performance, make its equal energy under a variety of use environments
Keep good performance;Wingceltis hide fiber is added in the application in the feed, on the one hand utilizes plant fiber good flexible
Property, the hinge between each raw material as connection promotes the stability of inorganic agent form, on the other hand, changes by the application method
Property processing wingceltis, there is certain complex performance, in sewage microparticle and generate after being complexed with other compositions
Sediment has the function of certain cohesion, gathers, and promotes the effect to pollutant removal in sewage, meanwhile, wingceltis hide fiber
After the modification of the present invention, there can be good dispersion effect in sewage, have for the treatment effect of sewage
It is obviously improved.
Environment-friendly type inorganic agent prepared by the present invention is safe, and new pollutant will not be introduced in processing procedure, will not
New pollution is generated to water body, the primary raw material ingredient in the application is diatomite, flyash etc., and cost of material is relatively low, and
Flyash itself is a kind of rubbish, assigns processing of its new function for sewage after treatment, greatly reduces inorganic agent
Cost, meanwhile, waste is recycled, economic benefit is improved.
Specific implementation mode
Embodiment 1
A kind of environment-friendly type inorganic agent for treated sewage is prepared using following raw material by weight:28 parts of diatom ooze, polypropylene
4.2 parts of amide, 8.5 parts of wingceltis hide fiber, 2.2 parts of diallyl dimethyl ammoniumchloride, 19 parts of flyash.
The diatom ooze is modified processing using following methods:
(1), diatomite cleaned up using clear water, the isothermal holding 45-50min at 450-500 DEG C, at this temperature, to
Dextrin, polyvinyl alcohol, sodium citrate, water are sprayed above diatomite by weight 3.5:6:1.2:Mixture made of 10, then
It is naturally cooling to room temperature, the weight ratio of diatomite and mixture is 85:1;
(2), by step(1)The phosphoric acid solution immersion treatment 4min for the diatomite use quality score 20% handled well, soaking process
Middle frequency of use be 25kHz ultrasonic echography handle, then by diatomite at 58-60 DEG C drying and processing 40min;
(3), by step(2)The diatomite handled well is with chitosan by weight 14.5:1 ratio mixing, uses height after mixing
Fast mixing machine is handled, and diatomite is made to be sufficiently mixed uniformly with chitosan;
(4), by step(3)The diatomite handled well pressurize under 2Mpa pressure handles 2h, obtains modification infusorial earth.
A kind of preparation method of environment-friendly type inorganic agent for papermaking wastewater, includes the following steps:(1), by diatom ooze, powder
Coal ash is added blender and stirs 30-40min, the activation process 13-15min at 630-645 DEG C, and wingceltis hide fiber is then added,
Continue to stir 25-30min, above-mentioned raw materials is made to be sufficiently mixed;
(2), by step(1)Polyacrylamide and diallyl dimethyl ammoniumchloride are added in the raw material handled well, using turning
Drum granulator, obtains inorganic agent.
Embodiment 2
A kind of environment-friendly type inorganic agent for treated sewage is prepared using following raw material by weight:28 parts of diatom ooze, polypropylene
4.2 parts of amide, 8.5 parts of wingceltis hide fiber, 2.2 parts of diallyl dimethyl ammoniumchloride, 19 parts of flyash.
The diatom ooze is modified processing using following methods:
(1), diatomite cleaned up using clear water, the isothermal holding 45-50min at 450-500 DEG C, at this temperature, to
Dextrin, polyvinyl alcohol, sodium citrate, water are sprayed above diatomite by weight 3.5:6:1.2:Mixture made of 10, then
It is naturally cooling to room temperature, mixture is 85 with diatomaceous weight ratio:1;
(2), by step(1)The phosphoric acid solution immersion treatment 4min for the diatomite use quality score 20% handled well, soaking process
Middle frequency of use be 25kHz ultrasonic echography handle, then by diatomite at 58-60 DEG C drying and processing 40min;
(3), by step(2)The diatomite handled well is with chitosan by weight 14.5:1 ratio mixing, uses height after mixing
Fast mixing machine is handled, and diatomite is made to be sufficiently mixed uniformly with chitosan;
(4), by step(3)The diatomite handled well pressurize under 2Mpa pressure handles 2h, obtains modification infusorial earth.
The flyash passes through modification, and the specific method is as follows:(1), flyash be broken into grain size be not more than 10mm
Particle, by fly ash grain use quality score be 20% phosphoric acid, mass fraction 60% sulfuric acid by volume 2:3 preparations
Acid soak handles 3min;
(2), by step(1)The flyash handled well makes 3 times wash with distilled water, is then dried at 57 DEG C, then by fine coal
In the sulfuric acid solution that ash is put into 12 times of its weight, mass fraction is 3%, stirred with the speed of 58r/min using blender, and make
The ultrasonication for being 20kHz with frequency, it is 1.5% aluminum hydroxide solution, hydroxide that mass fraction is added constantly into mixture
The addition volume of aluminum solutions is the 1/3 of sulfuric acid solution, and being continuing with blender after the completion of being added stirs and be ultrasonically treated
18min;
(3), by step(2)The flyash handled well is cleaned, and surface impurity is removed, and is then placed in the phosphorus that mass fraction is 5%
In acid dihydride sodium solution, the ultrasonic oscillation that frequency of use is 25kHz handles 35min, takes out, and drying obtains modified coal ash.
The wingceltis hide fiber is modified processing using following steps:(1), annual early June late May-, selection is green
Wingceltis peeling, by the lignin sulfonic acid sodium solution immersion treatment 135min of wingceltis use quality score 1.2%;
(2), by step(1)The wingceltis handled well carries out roller process, when first time roll-in, the roller of roll squeezer using roll squeezer
Spacing is the 2/3 of wingceltis maximum gauge, and the roller spacing of roll squeezer is reduced 2mm by roller process every time later, until roll squeezer
Roller stop roller process when being smaller than 1.2mm, after each roll-in, the wingceltis after roll-in is used into sodium carbonate-
Sodium bicarbonate buffer system, dodecyl sodium sulfate, water are by weight 5:1:200 solution prepared impregnate 8-10min, then again
It is further processed;
(3), by step(2)The wingceltis handled well uses compound soak immersion treatment 70min at 48 DEG C, then using stirring
The machine of mixing is stirred, and fiber is made to disperse in compound soak, the residue of offscum and floating is then removed, then by remaining fibre
Dimension is combed, and the compound soak is made using following raw material by weight:1.2 parts of trihydroxy ethylamine oleate soap, dodecane
30 parts of 15 parts of ethanol solution, the water of 1.2 parts of base sodium sulfonate, 0.4 part of triethanolamine, volume fraction 78%;
(4), by step(3)The sodium citrate solution that the fiber handled well is 2% with mass fraction is by weight 1:2 ratio is mixed
It closes, fiber is then broken into the staple fiber that length is 2-15mm using crusher, obtains modified wingceltis hide fiber.
The pH9.2-10.8 of the sodium carbonate-bicarbonate buffer system.
Embodiment 3
A kind of environment-friendly type inorganic agent for treated sewage is prepared using following raw material by weight:30 parts of diatom ooze, polypropylene
4.2 parts of amide, 8.5 parts of wingceltis hide fiber, 2.3 parts of diallyl dimethyl ammoniumchloride, 20 parts of flyash.
The preparation method of raw material and product is the same as embodiment 2 in the embodiment.
Embodiment 4
A kind of environment-friendly type inorganic agent for treated sewage is prepared using following raw material by weight:26 parts of diatom ooze, polypropylene
4.2 parts of amide, 8.9 parts of wingceltis hide fiber, 2.3 parts of diallyl dimethyl ammoniumchloride, 22 parts of flyash.
The preparation method of raw material and product is the same as embodiment 2 in the embodiment.
Comparative example 1
The inorganic agent is prepared using following raw material by weight:28 parts of diatom ooze, 4.2 parts of polyacrylamide, wingceltis hide fiber
8.5 parts, 2.2 parts of diallyl dimethyl ammoniumchloride, 19 parts of flyash.But the diatom ooze in raw material is without using the present invention's
Method is modified processing, other compositions processing method such as embodiment 1.
Comparative example 2
The inorganic agent is prepared using following raw material by weight:28 parts of diatom ooze, 4.2 parts of polyacrylamide, polydiene propyl two
2.2 parts of ammonio methacrylate, 19 parts of flyash.The application does not use wingceltis hide fiber relative to the scheme in embodiment 1, other
The ratio and processing mode of ingredient are consistent with embodiment 2.
Comparative example 3
The inorganic agent is prepared using following raw material by weight:28 parts of diatom ooze, 4.2 parts of polyacrylamide, wingceltis hide fiber
8.5 parts, 2.2 parts of diallyl dimethyl ammoniumchloride.Flyash, other compositions processing mode are added without in the embodiment raw material
Such as embodiment 2.
Comparative example 4
The inorganic agent is prepared using following raw material by weight:28 parts of diatom ooze, 4.2 parts of polyacrylamide, wingceltis hide fiber
8.5 parts, 2.2 parts of diallyl dimethyl ammoniumchloride, 19 parts of flyash, wherein diatom ooze without using embodiment 2 method into
Row processing, other treatment process are consistent with embodiment 2.
The applicant carries out the treatment effect of each group inorganic agent by the way that comparative example is arranged to verify the effect of the application
Verification, verifies the treatment effect of the inorganic agent of different ratio ingredient and preparation method, and the sewage of processing uses paper grade (stock)
Sewage is handled using same batch sewage, and every group of inorganic agent handles 500ml sewage, and the inorganic agent added in every group is
7.5g when processing, makes inorganic agent be uniformly dispersed in sewage, major pollutants content in sewage before and after statistical disposition, specific number
According to such as table 1.
Table 1.
Paper waste in table 1 is that sulfate reed reed starches bleaching effluent.As shown in Table 1, when located using matching for the application
Inorganic agent prepared by reason method has more significant effect, waste water after treatment for the suspended matter and BOD5 of papermaking wastewater
Meet discharging standards.
The applicant is handled electroplating sewerage using inorganic agent, is handled using same batch sewage, at every group
It manages agent and handles 500ml sewage, the inorganic agent added in every group is 8g, when processing, so that inorganic agent is uniformly dispersed in sewage, stands
Handle 30min, major pollutants content in sewage before and after statistical disposition, specific data such as table 2.
Table 2.
Table 3.
The removal effect of chromium in the lower waste water of chrome content in table 3, when processing, per 500ml waste water in inorganic agent make
Dosage is 8g.
By table 2,3 it is found that the inorganic agent using the embodiment of the present invention handles electroplating sewerage, and by processing
The ratio of agent prescription is adjusted verification processing as a result, the results show that can reach to the absorption of chromium using the formula in the present invention
One preferably horizontal, and the chromate waste water of high concentration can almost reach the standard of discharge, for containing after single treatment
The lower sewage of chromium content, single treatment can reach discharge standard, greatly reduce the cost of sewage disposal.
In order to verify during diatomite modified, the influence of different diatomite and chitosan ratio to adsorption effect,
The applicant verify, specific as follows.
Embodiment 5
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 13:1, other compositions and
Processing method is identical.
Embodiment 6
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 14:1, other compositions and
Processing method is identical.
Embodiment 7
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 15:1, other compositions and
Processing method is identical.
Comparative example 5
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 12.5:1, other compositions
And processing method is identical.
Comparative example 6
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 12:1, other compositions and
Processing method is identical.
Comparative example 7
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 11:1, other compositions and
Processing method is identical.
Comparative example 8
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 10:1, other compositions and
Processing method is identical.
Comparative example 9
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 15.5:1, other compositions
And processing method is identical.
Comparative example 10
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 16:1, other compositions and
Processing method is identical.
Comparative example 11
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 17:1, other compositions and
Processing method is identical.
Comparative example 12
Compared with Example 2, in diatomite modified processing, the weight ratio of diatomite and chitosan is 18:1, other compositions and
Processing method is identical.
Table 4.
As shown in Table 4, in inorganic agent preparation process, the ratio of diatomite and chitosan compares inorganic agent to heavy metal etc.
The treatment effect of ion has significant impact, is 13-15 in the weight ratio of diatomite and chitosan:In the range of 1, processing
Best results.
Claims (4)
1. a kind of environment-friendly type inorganic agent for treated sewage, which is characterized in that prepared by weight using following raw material:Diatom
25-30 parts of mud, 3-5 parts of polyacrylamide, 8-10 parts of wingceltis hide fiber, 1.8-2.5 parts of diallyl dimethyl ammoniumchloride, powder
16-22 parts of coal ash;The diatom ooze is modified processing using following methods:
(1), diatomite cleaned up using clear water, the isothermal holding 45-50min at 450-500 DEG C, at this temperature, to
Dextrin, polyvinyl alcohol, sodium citrate, water are sprayed above diatomite by weight 3.5:6:1.2:Mixture made of 10, then
It is naturally cooling to room temperature, the weight ratio of diatomite and mixture is 80-90:1;
(2), by step(1)The phosphoric acid solution immersion treatment 3-5min for the diatomite use quality score 20% handled well, impregnated
In journey frequency of use be 25kHz ultrasonic echography handle, then by diatomite at 55-60 DEG C drying and processing 35-40min;
(3), by step(2)The diatomite handled well is with chitosan by weight 13-15:1 ratio mixing, uses height after mixing
Fast mixing machine is handled, and diatomite is made to be sufficiently mixed uniformly with chitosan;
(4), by step(3)The diatomite handled well pressurize under 2Mpa pressure handles 2h, obtains modification infusorial earth.
2. a kind of environment-friendly type inorganic agent for treated sewage according to claim 1, it is characterised in that:The flyash
By modification, the specific method is as follows:(1), flyash is broken into the particle that grain size is not more than 10mm, by fly ash grain
The sulfuric acid by volume 2 of phosphoric acid, mass fraction 60% that use quality score is 20%:3 acid soaks prepared handle 3-5min;
(2), by step(1)The flyash handled well makes 2-3 times wash with distilled water, is then dried at 50-60 DEG C, then will
In the sulfuric acid solution that flyash is put into 10-15 times of its weight, mass fraction is 3%, using blender with the speed of 50-60r/min
Stirring, and the ultrasonication that frequency of use is 20kHz, it is that 1.5% aluminium hydroxide is molten that mass fraction is added constantly into mixture
Liquid, the addition volume of aluminum hydroxide solution are the 1/3 of sulfuric acid solution, and being continuing with blender after the completion of being added stirs and surpassed
Sonication 15-20min;
(3), by step(2)The flyash handled well is cleaned, and surface impurity is removed, and is then placed in the phosphorus that mass fraction is 5%
In acid dihydride sodium solution, the ultrasonic oscillation that frequency of use is 25kHz handles 30-40min, takes out, drying, obtains modified fine coal
Ash.
3. a kind of environment-friendly type inorganic agent for treated sewage according to claim 1, it is characterised in that:The wingceltis
Fiber is modified processing using following steps:(1), annual early June late May-, select wingceltis peeling, wingceltis made
With the lignin sulfonic acid sodium solution immersion treatment 120-150min of mass fraction 1.2%;
(2), by step(1)The wingceltis handled well carries out roller process, when first time roll-in, the roller of roll squeezer using roll squeezer
Spacing is the 2/3 of wingceltis maximum gauge, and the roller spacing of roll squeezer is reduced 2mm by roller process every time later, until roll squeezer
Roller stop roller process when being smaller than 1.2mm, after each roll-in, the wingceltis after roll-in is used into sodium carbonate-
Sodium bicarbonate buffer system, dodecyl sodium sulfate, water are by weight 5:1:200 solution prepared impregnate 8-10min, then again
It is further processed;
(3), by step(2)The wingceltis handled well uses compound soak immersion treatment 60-75min at 42-50 DEG C, then
It is stirred using blender, fiber is made to disperse in compound soak, then removed the residue of offscum and floating, then will remain
Remaining fiber is combed, and the compound soak is made using following raw material by weight:1.2 parts of trihydroxy ethylamine oleate soap,
30 parts of 15 parts of ethanol solution, the water of 1.2 parts of dodecyl sodium sulfate, 0.4 part of triethanolamine, volume fraction 78%;
(4), by step(3)The sodium citrate solution that the fiber handled well is 2% with mass fraction is by weight 1:2 ratio is mixed
It closes, fiber is then broken into the staple fiber that length is 2-15mm using crusher, obtains modified wingceltis hide fiber.
4. a kind of environment-friendly type inorganic agent for treated sewage according to claim 3, it is characterised in that:The carbonic acid
The pH9.2-10.8 of sodium-sodium bicarbonate buffer system.
Priority Applications (1)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109574461A (en) * | 2018-12-18 | 2019-04-05 | 安徽中环环保科技股份有限公司 | A kind of mixed flocculation agent and preparation method thereof for Treatment of Sludge |
CN114656127A (en) * | 2022-03-31 | 2022-06-24 | 沧州鹏发生物科技有限公司 | Glucose-based polymeric flocculant for sludge dewatering and preparation method thereof |
-
2018
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109574461A (en) * | 2018-12-18 | 2019-04-05 | 安徽中环环保科技股份有限公司 | A kind of mixed flocculation agent and preparation method thereof for Treatment of Sludge |
CN114656127A (en) * | 2022-03-31 | 2022-06-24 | 沧州鹏发生物科技有限公司 | Glucose-based polymeric flocculant for sludge dewatering and preparation method thereof |
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