CN106222535A - A kind of high-chromium wear-resistant ball and preparation method thereof - Google Patents

A kind of high-chromium wear-resistant ball and preparation method thereof Download PDF

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Publication number
CN106222535A
CN106222535A CN201610728359.XA CN201610728359A CN106222535A CN 106222535 A CN106222535 A CN 106222535A CN 201610728359 A CN201610728359 A CN 201610728359A CN 106222535 A CN106222535 A CN 106222535A
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CN
China
Prior art keywords
resistant ball
temperature
chromium wear
wear
chromium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610728359.XA
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Chinese (zh)
Inventor
程福军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Singapore And Malaysia High-Abrasive Material Co Ltd Of Middle Building Materials Ningguo
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Singapore And Malaysia High-Abrasive Material Co Ltd Of Middle Building Materials Ningguo
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Application filed by Singapore And Malaysia High-Abrasive Material Co Ltd Of Middle Building Materials Ningguo filed Critical Singapore And Malaysia High-Abrasive Material Co Ltd Of Middle Building Materials Ningguo
Priority to CN201610728359.XA priority Critical patent/CN106222535A/en
Publication of CN106222535A publication Critical patent/CN106222535A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/36Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for balls; for rollers
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a kind of high-chromium wear-resistant ball and preparation method thereof, each component of wear-resistant ball and percentage by weight thereof be: C:2.50 2.70%, Mn:0.35 0.60%, Cr:18.10 18.50%, Mo:0.02 0.03%, Si :≤1.0%, P :≤0.08%, S :≤0.08%;Surplus is Fe.The present invention provides a kind of high-chromium wear-resistant ball, service life length, hardness is high, wearability is good high chromium casting ball.

Description

A kind of high-chromium wear-resistant ball and preparation method thereof
Technical field
The present invention relates to high-abrasive material technical field, be specifically related to a kind of high-chromium wear-resistant ball and preparation method thereof.
Background technology
High-abrasive material is the new material that a big class has special electricity, magnetic, light, sound, heat, power, chemistry and biological function, It is high-tech sector and the important foundation materials of national defense construction such as information technology, biotechnology, energy technology, simultaneously also to transformation Some conventional industries has a very important role.High-abrasive material is the core of field of new, and the development to new and high technology rises Important promotion and supporting role, in new material research field, the whole world, high-abrasive material accounts for 85%.Along with information-intensive society Arriving, special, wear-resistant material plays important promotion and supporting role to the development of new and high technology, is 21st century information, life The critical material of the high-tech sectors such as thing, the energy, environmental protection, space, becomes the emphasis of countries in the world field of new research and development, Also it is the focus of Strategic Competition in the high technology development of countries in the world.Existing in Chinese Patent Application No.: public in 201210291075 Having opened the manufacture method of a kind of high carbon and chromium high-manganese alloy cast ball, raw material is steel scrap: bearing leftover pieces: C:0.3-1.0%;Si: ≤ 0.4%;Mn :≤0.3%;Cr:0.5-1.5%;High carbon ferro-chrome: Cr:60%;Si :≤1.5;Fe :≤38%;High carbon ferromanganese: Mn:58%;S :≤2%;Fe :≤40%.This technical scheme is low for service life, and hardness, wearability are the most not enough.
Summary of the invention
For the deficiencies in the prior art, the present invention provides a kind of high-chromium wear-resistant ball, service life length, hardness is high, wearability Good high chromium casting ball.
The technical problem to be solved can be to realize by the following technical programs:
A kind of high-chromium wear-resistant ball, each component and percentage by weight thereof be: C:2.50-2.70%, Mn:0.35-0.60%, Cr:18.10-18.50%, Mo:0.02-0.03%, Si :≤1.0%, P :≤0.08%, S :≤0.08%;Surplus is Fe.
Described C:2.50%, Mn:0.35%, Cr:18.10%, Mo:0.02%, Si:0.5%, P :≤0.08%, S: ≤ 0.08%.
Described C:2.70%, Mn:0.60%, Cr:18.50%, Mo:0.03%, Si:1.0%, P :≤0.08%, S: ≤ 0.08%.
Described C:2.6%, Mn:0.45%, Cr:18.30%, Mo:0.025%, Si:0.8%, P :≤0.08%, S: ≤ 0.08%.
The preparation method of high-chromium wear-resistant ball, (1) electric furnace list opens, and swage produces, and uses high-quality wood shavings type steel scrap to produce melting;
(2) tapping temperature 1580 DEG C-1600 DEG C, pouring temperature 1450 DEG C-1480 DEG C;
(3) deoxidized aluminium addition is the 0.03% of molten iron total amount, poly-, slag skimming process;
(4) detection product appearance is not allow for the casting flaws such as serious high stake, high temperature pore, cinder hole, overlap;
(5) heat treatment.
Described heat treatment be linked back by even quenching heat-treatment production line perform heat treatment, heat-treatment quenching high temperature section temperature control At 1050 DEG C, product quenches into oil temperature 100 DEG C-110 DEG C;Temperature: 280 DEG C.
Compared with prior art, the invention have the benefit that
Invention hardness is high, and HRC is 65 70, impact value >=2.9J/cm2, and ball falling impact fatigue life >= 12000 times, core hardness is basically identical with case hardness, and service life is long, and wearability is good, low cost;The actual ball of wear-resistant ball consumes Be 214.1 grams ton ore deposit;Wear-resistant ball uses 500 hours or ore grinding cumulative amount reaches 50,000 ton hour detections, and chip index is less than 1%, loses Circle rate is less than 1%
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making The every other embodiment obtained under creative work premise, broadly falls into the scope of protection of the invention.
A kind of high-chromium wear-resistant ball, each component and percentage by weight thereof be: C:2.50-2.70%, Mn:0.35-0.60%, Cr:18.10-18.50%, Mo:0.02-0.03%, Si :≤1.0%, P :≤0.08%, S :≤0.08%;Surplus is Fe.
The preparation method of high-chromium wear-resistant ball, (1) electric furnace list opens, and swage produces, and uses high-quality wood shavings type steel scrap to produce melting;
(2) tapping temperature 1580 DEG C-1600 DEG C, pouring temperature 1450 DEG C-1480 DEG C;
(3) deoxidized aluminium addition is the 0.03% of molten iron total amount, poly-, slag skimming process;
(4) detection product appearance is not allow for the casting flaws such as serious high stake, high temperature pore, cinder hole, overlap;
(5) heat treatment.
Described heat treatment be linked back by even quenching heat-treatment production line perform heat treatment, heat-treatment quenching high temperature section temperature control At 1050 DEG C, product quenches into oil temperature 100 DEG C-110 DEG C;Temperature: 280 DEG C.
Invention hardness is high, and HRC is 65 70, impact value >=2.9J/cm2, and ball falling impact fatigue life >= 12000 times, core hardness is basically identical with case hardness, and service life is long, and wearability is good, low cost;The actual ball of wear-resistant ball consumes Be 214.1 grams ton ore deposit;Wear-resistant ball uses 500 hours or ore grinding cumulative amount reaches 50,000 ton hour detections, and chip index is less than 1%, loses Circle rate is less than 1%
It should be noted that in this article, such as term " includes ", " comprising " or its any other variant are intended to Comprising of nonexcludability, so that include that the process of a series of key element, method, article or equipment not only include that those are wanted Element, but also include other key elements being not expressly set out, or also include for this process, method, article or equipment Intrinsic key element.In the case of there is no more restriction, statement " including ... " key element limited, it is not excluded that Including process, method, article or the equipment of described key element there is also other identical element.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a high-chromium wear-resistant ball, it is characterised in that: each component and percentage by weight thereof be: C:2.50-2.70%, Mn:0.35- 0.60%, Cr:18.10-18.50%, Mo:0.02-0.03%, Si :≤1.0%, P :≤0.08%, S :≤0.08%;Surplus For Fe.
2. high-chromium wear-resistant ball as claimed in claim 1, it is characterised in that described C:2.50%, Mn:0.35%, Cr: 18.10%, Mo:0.02%, Si:0.5%, P :≤0.08%, S :≤0.08%.
3. high-chromium wear-resistant ball as claimed in claim 1, it is characterised in that described C:2.70%, Mn:0.60%, Cr: 18.50%, Mo:0.03%, Si:1.0%, P :≤0.08%, S :≤0.08%.
4. high-chromium wear-resistant ball as claimed in claim 1, it is characterised in that described C:2.6%, Mn:0.45%, Cr: 18.30%, Mo:0.025%, Si:0.8%, P :≤0.08%, S :≤0.08%.
5. the preparation method of high-chromium wear-resistant ball as claimed in claim 1, it is characterised in that
(1) electric furnace list leaves, and swage produces, and uses high-quality wood shavings type steel scrap to produce melting;
(2) tapping temperature 1580 DEG C-1600 DEG C, pouring temperature 1450 DEG C-1480 DEG C;
(3) deoxidized aluminium addition is the 0.03% of molten iron total amount, poly-, slag skimming process;
(4) detection product appearance is not allow for the casting flaws such as serious high stake, high temperature pore, cinder hole, overlap;
(5) heat treatment.
6. the preparation method of high-chromium wear-resistant ball as claimed in claim 1, it is characterised in that described heat treatment is linked back by even quenching Heat-treatment production line performs heat treatment, and heat-treatment quenching high temperature section temperature controls at 1050 DEG C, and product quenches into oil temperature 100 ℃-110℃;Temperature: 280 DEG C.
CN201610728359.XA 2016-08-25 2016-08-25 A kind of high-chromium wear-resistant ball and preparation method thereof Pending CN106222535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610728359.XA CN106222535A (en) 2016-08-25 2016-08-25 A kind of high-chromium wear-resistant ball and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610728359.XA CN106222535A (en) 2016-08-25 2016-08-25 A kind of high-chromium wear-resistant ball and preparation method thereof

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU494427A1 (en) * 1974-05-16 1975-12-05 Институт Проблем Литья Ан Украинской Сср Cast iron
DE2413521A1 (en) * 1974-03-21 1976-01-15 Wahl Verschleiss Tech Perforated sieve plates with high wear resistance - obtd by making the plates from ledeburitic chromium steel
JPS5159007A (en) * 1974-11-21 1976-05-22 Komatsu Mfg Co Ltd TAISHOKUTAIMA MOSEI HAKUSEN CHUTETSU
CN1053267A (en) * 1991-01-16 1991-07-24 河北工学院 Casting-state troostite grinding ball
CN103981426A (en) * 2014-05-07 2014-08-13 中建材宁国新马耐磨材料有限公司 High-chromium alloy cast ball
CN103981429A (en) * 2014-05-07 2014-08-13 中建材宁国新马耐磨材料有限公司 High-chromium wear resistant lining board and making method thereof
CN105369160A (en) * 2015-10-19 2016-03-02 安徽瑞泰新材料科技有限公司 High-chromium abrasion-resistant ball special for diaspore and preparation method of high-chromium abrasion-resistant ball

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2413521A1 (en) * 1974-03-21 1976-01-15 Wahl Verschleiss Tech Perforated sieve plates with high wear resistance - obtd by making the plates from ledeburitic chromium steel
SU494427A1 (en) * 1974-05-16 1975-12-05 Институт Проблем Литья Ан Украинской Сср Cast iron
JPS5159007A (en) * 1974-11-21 1976-05-22 Komatsu Mfg Co Ltd TAISHOKUTAIMA MOSEI HAKUSEN CHUTETSU
CN1053267A (en) * 1991-01-16 1991-07-24 河北工学院 Casting-state troostite grinding ball
CN103981426A (en) * 2014-05-07 2014-08-13 中建材宁国新马耐磨材料有限公司 High-chromium alloy cast ball
CN103981429A (en) * 2014-05-07 2014-08-13 中建材宁国新马耐磨材料有限公司 High-chromium wear resistant lining board and making method thereof
CN105369160A (en) * 2015-10-19 2016-03-02 安徽瑞泰新材料科技有限公司 High-chromium abrasion-resistant ball special for diaspore and preparation method of high-chromium abrasion-resistant ball

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Application publication date: 20161214