CN106221833A - A kind of nanometer diesel fuel additives - Google Patents

A kind of nanometer diesel fuel additives Download PDF

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Publication number
CN106221833A
CN106221833A CN201610722651.0A CN201610722651A CN106221833A CN 106221833 A CN106221833 A CN 106221833A CN 201610722651 A CN201610722651 A CN 201610722651A CN 106221833 A CN106221833 A CN 106221833A
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CN
China
Prior art keywords
parts
diesel fuel
fuel additives
piba
cycloalkane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610722651.0A
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Chinese (zh)
Inventor
蒋俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guilin Weimeiyuan Restaurant Management Co Ltd
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Guilin Weimeiyuan Restaurant Management Co Ltd
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Publication date
Application filed by Guilin Weimeiyuan Restaurant Management Co Ltd filed Critical Guilin Weimeiyuan Restaurant Management Co Ltd
Priority to CN201610722651.0A priority Critical patent/CN106221833A/en
Publication of CN106221833A publication Critical patent/CN106221833A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/106—Liquid carbonaceous fuels containing additives mixtures of inorganic compounds with organic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1275—Inorganic compounds sulfur, tellurium, selenium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2366—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amine groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2381—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds polyamides; polyamide-esters; polyurethane, polyureas

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention relates to a kind of nanometer diesel fuel additives, including: weight ratio is nanocatalyst and the soluble lignin of 1:10, wherein, nanocatalyst parts by weights divides and includes: polyurethane 5 15 parts, PIBA 8 12 parts, 0.5 1 parts of cycloalkane, 13 parts of zinc sulfate.The nanometer diesel fuel additives extracting method of the present invention is simple, and equipment requirements is low, and productivity is high, and the cycle is short, provides support for industrialization synthesis；It is added in diesel oil to improve diesel oil efficiency and reduce waste gas discharge.

Description

A kind of nanometer diesel fuel additives
Technical field
The present invention relates to energy-conserving and environment-protective technical field, specifically, relate to a kind of nanometer diesel fuel additives.
Background technology
Diesel oil is one of non-renewable energy resources, along with the minimizing of natural oil storage capacity, improves diesel oil cleanliness factor and makes Diesel oil fully burns and is current chemical field and problem that auto industry is extremely paid close attention to, the diesel oil particularly used at present in China In, catalytic cracking diesel oil proportion is the most at a relatively high, and therefore the problem of diesel oil oxidation generation colloid, paint film and deposit also compares Seriously, therefore, environment protection diesel oil additive is the focus of research at present.Electromotor operating time, atomizer temperature at about 100 DEG C, Intake valve temperature is between 200-300 DEG C.At such temperatures, the labile element in diesel oil, easily produce oxidative condensation Reaction, generates colloid and carbon distribution, is deposited on intake valve and atomizer, and advanced high blower engine and use GDI diesel oil are straight The electromotor of spray technique is more prone to carbon distribution.The deposit being deposited on intake valve, can cause inlet channel sectional area to reduce, Intake efficiency reduces, and power drop can make valve event slow, be not closed completely time serious.Atomizer carbon distribution, can make oil spout not Freely, diesel oil atomization quality declines, and after causing diesel oil to enter combustor, it is difficult to burn completely, causes engine start difficulty, idling Shakiness, and oil consumption increasing, exhaust emissions deteriorates, and especially in winter, these situations become apparent from.
Summary of the invention
The technical problem to be solved is to provide the nanometer diesel fuel additives of a kind of energy-conserving and environment-protective.
The technical scheme is that
A kind of nanometer diesel fuel additives, including: weight ratio is nanocatalyst and the soluble lignin of 1:10, wherein, Nanocatalyst parts by weights divides and includes:
Polyurethane 5-15 part, PIBA 8-12 part, cycloalkane 0.5-1 part, zinc sulfate 1-3 part.
Further, described soluble lignin includes: ethanol lignin, alkali lignin, nitric acid lignin, phenol lignin In one or more.
Further, described nanocatalyst parts by weights divides and includes:
Polyurethane 5 parts, PIBA 12 parts, 0.5 part of cycloalkane, 3 parts of zinc sulfate.
Further, described nanocatalyst parts by weights divides and includes:
Polyurethane 15 parts, PIBA 8 parts, 1 part of cycloalkane, 1 part of zinc sulfate.
Further, described nanocatalyst parts by weights divides and includes:
Polyurethane 10 parts, PIBA 10 parts, 0.8 part of cycloalkane, 2 parts of zinc sulfate.
Further, described nanometer diesel fuel additives is prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 5-15 part, PIBA 8-12 part, cycloalkane 0.5-1 part, zinc sulfate 1-3 part；
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
Further, described polyurethane, PIBA, cycloalkane, zinc sulfate and water-soluble lignin all use nanoscale Material.
The invention has the beneficial effects as follows: the nanometer diesel fuel additives extracting method of the present invention is simple, and equipment requirements is low, productivity Height, the cycle is short, provides support for industrialization synthesis；It is added in diesel oil to improve diesel oil efficiency and reduce waste gas row Put.
Detailed description of the invention
Principle and feature to the present invention are described below, and example is served only for explaining the present invention, is not intended to limit Determine the scope of the present invention.
The nanometer diesel fuel additives of the present invention is prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 5-15 part, PIBA 8-12 part, cycloalkane 0.5-1 part, zinc sulfate 1-3 part；
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
Described polyurethane, PIBA, cycloalkane, zinc sulfate and water-soluble lignin all use nanometer materials.
Embodiment 1
A kind of nanometer diesel fuel additives, including: weight ratio is nanocatalyst and the soluble lignin of 1:10, wherein, Nanocatalyst parts by weights divides and includes:
Polyurethane 5 parts, PIBA 12 parts, 0.5 part of cycloalkane, 3 parts of zinc sulfate.
Described nanometer diesel fuel additives is prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 5 parts, PIBA 12 parts, 0.5 part of cycloalkane, 3 parts of zinc sulfate.
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
Embodiment 2
A kind of nanometer diesel fuel additives, including: weight ratio is nanocatalyst and the soluble lignin of 1:10, wherein, Nanocatalyst parts by weights divides and includes:
Polyurethane 15 parts, PIBA 8 parts, 1 part of cycloalkane, 1 part of zinc sulfate.
Described nanometer diesel fuel additives is prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 15 parts, PIBA 8 parts, 1 part of cycloalkane, 1 part of zinc sulfate.
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
Embodiment 3
A kind of nanometer diesel fuel additives, including: weight ratio is nanocatalyst and the soluble lignin of 1:10, wherein, Nanocatalyst parts by weights divides and includes:
Polyurethane 10 parts, PIBA 10 parts, 0.8 part of cycloalkane, 2 parts of zinc sulfate.
Described nanometer diesel fuel additives is prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 10 parts, PIBA 10 parts, 0.8 part of cycloalkane, 2 parts of zinc sulfate.
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
With respectively by the nanometer diesel fuel additives in embodiment of the present invention 1-3 and commercially available ordinary diesel oil additive (contrast Example) add in diesel oil with same ratio, it improves diesel oil efficiency and minimizing discharge amount of exhaust gas is as shown in table 1.(with without diesel oil The diesel combustion efficiency of additive and exhaust emissions amount are 100%).
Table 1
Efficiency of combustion (%) Exhaust emissions amount (%)
Embodiment 1 133 46
Embodiment 2 135 44
Embodiment 3 133 46
Comparative example 104 94
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (7)

1. a nanometer diesel fuel additives, it is characterised in that including: weight ratio be the nanocatalyst of 1:10 and solubility wooden Element, wherein, nanocatalyst parts by weights divides and includes:
Polyurethane 5-15 part, PIBA 8-12 part, cycloalkane 0.5-1 part, zinc sulfate 1-3 part.
2. a kind of interior close diesel fuel additives as claimed in claim 1, it is characterised in that described soluble lignin includes: One or more in ethanol lignin, alkali lignin, nitric acid lignin, phenol lignin.
3. a kind of interior close diesel fuel additives as claimed in claim 2, it is characterised in that described nanocatalyst graduation by weight Divide and include:
Polyurethane 5 parts, PIBA 12 parts, 0.5 part of cycloalkane, 3 parts of zinc sulfate.
4. a kind of interior close diesel fuel additives as claimed in claim 2, it is characterised in that described nanocatalyst graduation by weight Divide and include:
Polyurethane 15 parts, PIBA 8 parts, 1 part of cycloalkane, 1 part of zinc sulfate.
5. a kind of interior close diesel fuel additives as claimed in claim 2, it is characterised in that described nanocatalyst graduation by weight Divide and include:
Polyurethane 10 parts, PIBA 10 parts, 0.8 part of cycloalkane, 2 parts of zinc sulfate.
6. the nanometer diesel fuel additives as described in claim 1-5 is arbitrary, it is characterised in that described nanometer diesel fuel additives passes through Prepared by following steps:
(1) raw material prepares: take various raw material by weight, and the parts by weight of various raw materials are as follows:
Polyurethane 5-15 part, PIBA 8-12 part, cycloalkane 0.5-1 part, zinc sulfate 1-3 part；
(2) stirring mixing: each raw material mixes with the lignin of its 10 times of weight, and adds water and stir；
(3) pelletize: the mixture in step 2 is used screw extruder extruding pelletization.
7. the nanometer diesel fuel additives as described in claim 1-5 is arbitrary, it is characterised in that described polyurethane, PIBA, Cycloalkane, zinc sulfate and water-soluble lignin all use nanometer materials.
CN201610722651.0A 2016-08-25 2016-08-25 A kind of nanometer diesel fuel additives Pending CN106221833A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1041387A (en) * 1989-10-12 1990-04-18 占小玲 Universal additive for substitute fuel oils
CN101333467A (en) * 2007-06-28 2008-12-31 詹姆士·肯尼思·桑德斯 Nano-sized metal and metal oxide particles for more complete fuel combustion
CN103265983A (en) * 2013-06-08 2013-08-28 江苏大学 High-efficiency nanometer fuel oil
CN103387857A (en) * 2013-08-16 2013-11-13 重庆车伴侣科技有限公司 Nanometer fuel oil catalytic additive
CN104629830A (en) * 2013-11-09 2015-05-20 西安润达化工科技有限公司 Diesel oil additive
CN104629827A (en) * 2015-01-20 2015-05-20 深圳市厚和科技有限公司 Chemical fuel oil additive and compound fuel oil additive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1041387A (en) * 1989-10-12 1990-04-18 占小玲 Universal additive for substitute fuel oils
CN101333467A (en) * 2007-06-28 2008-12-31 詹姆士·肯尼思·桑德斯 Nano-sized metal and metal oxide particles for more complete fuel combustion
CN103265983A (en) * 2013-06-08 2013-08-28 江苏大学 High-efficiency nanometer fuel oil
CN103387857A (en) * 2013-08-16 2013-11-13 重庆车伴侣科技有限公司 Nanometer fuel oil catalytic additive
CN104629830A (en) * 2013-11-09 2015-05-20 西安润达化工科技有限公司 Diesel oil additive
CN104629827A (en) * 2015-01-20 2015-05-20 深圳市厚和科技有限公司 Chemical fuel oil additive and compound fuel oil additive

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