CN106221612A - A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent - Google Patents
A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent Download PDFInfo
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- CN106221612A CN106221612A CN201610725853.0A CN201610725853A CN106221612A CN 106221612 A CN106221612 A CN 106221612A CN 201610725853 A CN201610725853 A CN 201610725853A CN 106221612 A CN106221612 A CN 106221612A
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- parts
- ageing
- binding agent
- woven fabrics
- resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of ageing-resistant butyronitrile latex binding agent of non-woven fabrics, including the raw material of following weight portion: nitrile rubber 24～50 parts, ethylene propylene diene rubber 8～10 parts, phenolic resin 16～25 parts, ethanol 50～80 parts, Borax 8～15 parts, white carbon black 10～15 parts, triphenyl phosphate 8～15 parts, zinc oxide 6～12 parts, oleic acid 0.8～1.8 parts, age resistor 3～8 parts, coupling agent 2～8 parts.A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, bonding strength is high, there is good insulation, ageing-resistant performance, the triphenyl phosphate added in formula effectively raising can prepare the stability of binding agent, anti-flammability and antioxygen property, and there is excellent light stabilization function and toughness, the invention allows for a kind of non-woven fabrics preparation method with ageing-resistant butyronitrile latex binding agent, raw materials used safety non-pollution, technological operation is simple, production process is environmentally friendly, preparation cost is low, can obtain and extensively apply.
Description
Technical field
The present invention relates to adhesive field, particularly relate to a kind of ageing-resistant butyronitrile latex binding agent of non-woven fabrics.
Background technology
Non-woven fabrics, also known as adhesive-bonded fabric, is to be made up of that orient or random fiber, is a new generation's environment-friendly materials, has anti-
Damp, ventilative, pliable and tough, light weight, decomposition the most combustion-supporting, easy, nontoxic nonirritant, rich color, cheap, capable of circulation use again
Feature.It is raw material as used polypropylene (pp material) pellet more, batches continuous one-step through high-temperature fusion, spray webbing, paving guiding principle, hot pressing
Produce, be called cloth because having the outward appearance of cloth and some performance.Along with developing rapidly, to binding agent of non-woven fabrics industry
Propose new requirement, i.e. must make non-woven fabrics during using, keep certain adhesion strength, those are had biology
The non-woven fabrics that the fiber of capacity of decomposition is made, selects suitable binding agent to seem particular importance.Nonwoven the most conventional
Cloth binding agent kind mainly has acrylate copolymer emulsion, interpolymer latex of polystyrene and acrylic ester, vinyl acetate-acrylate
Copolymer emulsion, prepared non-woven fabric adhesive cost is high, and wherein environment can be caused certain dirt by styrene and vinyl acetate
Dye, so, it is badly in need of the new technique of composite adhesives.Based on the problems referred to above, the present invention proposes a kind of ageing-resistant fourth of non-woven fabrics
Nitrile emulsion binder.
Summary of the invention
The invention aims to solve shortcoming present in prior art, and a kind of non-woven fabrics proposed is with ageing-resistant
Butyronitrile latex binding agent.
A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: nitrile rubber 24～50
Part, ethylene propylene diene rubber 8～10 parts, phenolic resin 16～25 parts, ethanol 50～80 parts, Borax 8～15 parts, white carbon black 10～15
Part, triphenyl phosphate 8～15 parts, zinc oxide 6～12 parts, oleic acid 0.8～1.8 parts, age resistor 3～8 parts, coupling agent 2～8 parts.
Preferably, described a kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: fourth
Nitrile rubber 27～50 parts, ethylene propylene diene rubber 9～10 parts, phenolic resin 18～25 parts, ethanol 60～70 parts, Borax 10～12
Part, white carbon black 12～14 parts, triphenyl phosphate 10～14 parts, zinc oxide 8～10 parts, oleic acid 1～1.5 parts, age resistor 4～6 parts, idol
Connection agent 3～6 parts.
Preferably, described a kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: fourth
Nitrile rubber 40 parts, ethylene propylene diene rubber 9 parts, 20 parts of phenolic resin, ethanol 65 parts, Borax 12 parts, white carbon black 14 parts, triphenyl phosphate
12 parts, zinc oxide 10 parts, oleic acid 1.4 parts, 5 parts of age resistor, coupling agent 4 parts.
Preferably, the weight ratio of described nitrile rubber, ethylene propylene diene rubber and phenolic resin is 3～5:1:2～2.5.
Preferably, the particle diameter of described Borax is 10～500 μm.
Preferably, described age resistor is 2,6 ditertiary butyl p cresol.
Preferably, described coupling agent is isopropyl three stearic acid acyloxy titanate esters.
The invention allows for a kind of non-woven fabrics preparation method with ageing-resistant butyronitrile latex binding agent, including following step
Rapid:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 160～190 DEG C of sulfurations 4～6h, obtain mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, coupling agent and age resistor,
With the rotating speed of 80～100r/min, at the uniform velocity stirring 20～40min, is cooled to room temperature, obtains mixture B；
S3, the mixture B of gained in step S2 and the Borax of described proportion, phenolic resin and ethanol are joined high-speed stirred
In machine, with the rotating speed of 600～800r/min, high-speed stirred 1～3h, after uniform one-tenth pasty state to be mixed, pack and get final product.
A kind of non-woven fabrics that the present invention proposes with ageing-resistant butyronitrile latex binding agent, bonding strength height, have good exhausted
Edge, ageing-resistant performance, fabulous with oil resistivity, wearability is higher, and thermostability is preferable, and the nitrile rubber that bonding force is strong is the most former
Material, the triphenyl phosphate added in formula effectively raising can be prepared the stability of binding agent, anti-flammability and antioxygen property, and have
There are excellent light stabilization function and toughness, the invention allows for the preparation with ageing-resistant butyronitrile latex binding agent of a kind of non-woven fabrics
Method, by after nitrile rubber and ethylene propylene diene rubber are vulcanized in addition auxiliary agent be dissolved in ethanol make paste with phenolic resin and Borax
Shape binding agent, raw materials used safety non-pollution, technological operation is simple, production process is environmentally friendly, and preparation cost is low, can obtain extensively
General application.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: butyronitrile rubber
40 parts of glue, ethylene propylene diene rubber 9 parts, 20 parts of phenolic resin, ethanol 70 parts, Borax 14 parts, white carbon black 10 parts, triphenyl phosphate 9 parts,
Zinc oxide 9 parts, oleic acid 1 part, 2,6 ditertiary butyl p cresol 4 parts, isopropyl three stearic acid acyloxy titanate esters 4 parts.
Its preparation method, comprises the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 170 DEG C sulfuration 5.5h, obtains mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, isopropyl three stearic acid
Acyloxy titanate esters and 2,6 ditertiary butyl p cresol, with the rotating speed of 80r/min, at the uniform velocity stir 35min, be cooled to room temperature,
Mixture B；
S3, it is that 350 μm Boraxs, phenolic resin and ethanol add by the mixture B of gained in step S2 with the particle diameter of described proportion
Enter in homogenizer, with the rotating speed of 700r/min, high-speed stirred 2h, after uniform one-tenth pasty state to be mixed, pack and get final product.
Embodiment two
A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: butyronitrile rubber
48 parts of glue, ethylene propylene diene rubber 10 parts, 22 parts of phenolic resin, ethanol 68 parts, Borax 12 parts, white carbon black 14 parts, triphenyl phosphate 12
Part, zinc oxide 10 parts, oleic acid 1.2 parts, 2,6 ditertiary butyl p cresol 5 parts, isopropyl three stearic acid acyloxy titanate esters 6 parts.
Its preparation method, comprises the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 180 DEG C sulfuration 4.5h, obtains mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, isopropyl three stearic acid
Acyloxy titanate esters and 2,6 ditertiary butyl p cresol, with the rotating speed of 100r/min, at the uniform velocity stir 25min, be cooled to room temperature,
Mixture B；
S3, it is that 20 μm Boraxs, phenolic resin and ethanol add by the mixture B of gained in step S2 and the particle diameter of described proportion
In homogenizer, with the rotating speed of 650r/min, high-speed stirred 2.5h, after uniform one-tenth pasty state to be mixed, pack and get final product.
Embodiment three
A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: butyronitrile rubber
28 parts of glue, ethylene propylene diene rubber 8 parts, 18 parts of phenolic resin, ethanol 60 parts, Borax 15 parts, white carbon black 12 parts, triphenyl phosphate 10
Part, zinc oxide 12 parts, oleic acid 1.5 parts, 2,6 ditertiary butyl p cresol 6 parts, isopropyl three stearic acid acyloxy titanate esters 8 parts.
Its preparation method, comprises the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 165 DEG C sulfuration 6h, obtains mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, isopropyl three stearic acid
Acyloxy titanate esters and 2,6 ditertiary butyl p cresol, with the rotating speed of 85r/min, at the uniform velocity stir 30min, be cooled to room temperature,
Mixture B；
S3, it is that 400 μm Boraxs, phenolic resin and ethanol add by the mixture B of gained in step S2 with the particle diameter of described proportion
Enter in homogenizer, with the rotating speed of 800r/min, high-speed stirred 1h, after uniform one-tenth pasty state to be mixed, pack and get final product.
Embodiment four
A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: butyronitrile rubber
50 parts of glue, ethylene propylene diene rubber 10 parts, 24 parts of phenolic resin, ethanol 80 parts, Borax 8 parts, white carbon black 13 parts, triphenyl phosphate 15
Part, zinc oxide 8 parts, oleic acid 1.8 parts, 2,6 ditertiary butyl p cresol 7 parts, isopropyl three stearic acid acyloxy titanate esters 5 parts.
Its preparation method, comprises the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 175 DEG C sulfuration 5h, obtains mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, isopropyl three stearic acid
Acyloxy titanate esters and 2,6 ditertiary butyl p cresol, with the rotating speed of 95r/min, at the uniform velocity stir 40min, be cooled to room temperature,
Mixture B；
S3, it is that 100 μm Boraxs, phenolic resin and ethanol add by the mixture B of gained in step S2 with the particle diameter of described proportion
Enter in homogenizer, with the rotating speed of 750r/min, high-speed stirred 1.5h, after uniform one-tenth pasty state to be mixed, pack i.e.
?.
Embodiment five
A kind of non-woven fabrics that the present invention proposes is with ageing-resistant butyronitrile latex binding agent, including the raw material of following weight portion: butyronitrile rubber
30 parts of glue, ethylene propylene diene rubber 8 parts, 16 parts of phenolic resin, ethanol 50 parts, Borax 10 parts, white carbon black 15 parts, triphenyl phosphate 14
Part, zinc oxide 6 parts, oleic acid 0.8 part, 2,6 ditertiary butyl p cresol 8 parts, isopropyl three stearic acid acyloxy titanate esters 3 parts.
Its preparation method, comprises the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 185 DEG C sulfuration 4h, obtains mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, isopropyl three stearic acid
Acyloxy titanate esters and 2,6 ditertiary butyl p cresol, with the rotating speed of 90r/min, at the uniform velocity stir 20min, be cooled to room temperature,
Mixture B；
S3, it is that 80 μm Boraxs, phenolic resin and ethanol add by the mixture B of gained in step S2 and the particle diameter of described proportion
In homogenizer, with the rotating speed of 600r/min, high-speed stirred 3h, after uniform one-tenth pasty state to be mixed, pack and get final product.
The binding agent prepared in the five groups of embodiments present invention proposed carries out Performance comparision and understands, and makes in embodiment three
Best for the binding agent bonding effect gone out, insulation effect is optimal, and the binding agent combination property prepared in embodiment two is best.This
A kind of non-woven fabrics that invention proposes with ageing-resistant butyronitrile latex binding agent, bonding strength height, there is good insulation, resistance to ag(e)ing
Can, fabulous with oil resistivity, wearability is higher, and thermostability is preferable, and the nitrile rubber that bonding force is strong is primary raw material, adds in formula
Triphenyl phosphate effectively raising can prepare the stability of binding agent, anti-flammability and antioxygen property, and it is steady to have excellent light
Determine function and toughness, the invention allows for a kind of non-woven fabrics preparation method with ageing-resistant butyronitrile latex binding agent, by inciting somebody to action
After nitrile rubber and ethylene propylene diene rubber sulfuration, in addition auxiliary agent is dissolved in ethanol makes paste adhesive with phenolic resin and Borax, institute
Pollution-free with materials safety, technological operation is simple, production process is environmentally friendly, and preparation cost is low, can obtain and extensively apply.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. a non-woven fabrics is with ageing-resistant butyronitrile latex binding agent, it is characterised in that include the raw material of following weight portion: butyronitrile rubber
Glue 24～50 parts, ethylene propylene diene rubber 8～10 parts, phenolic resin 16～25 parts, ethanol 50～80 parts, Borax 8～15 parts, white carbon black
10～15 parts, triphenyl phosphate 8～15 parts, zinc oxide 6～12 parts, oleic acid 0.8～1.8 parts, age resistor 3～8 parts, coupling agent 2
～8 parts.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that include following
The raw material of weight portion: nitrile rubber 27～50 parts, ethylene propylene diene rubber 9～10 parts, phenolic resin 18～25 parts, ethanol 60～70
Part, Borax 10～12 parts, white carbon black 12～14 parts, triphenyl phosphate 10～14 parts, zinc oxide 8～10 parts, oleic acid 1～1.5 parts, anti-
Old agent 4～6 parts, coupling agent 3～6 parts.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that include following
The raw material of weight portion: nitrile rubber 40 parts, ethylene propylene diene rubber 9 parts, 20 parts of phenolic resin, ethanol 65 parts, Borax 12 parts, white carbon black
14 parts, triphenyl phosphate 12 parts, zinc oxide 10 parts, oleic acid 1.4 parts, 5 parts of age resistor, coupling agent 4 parts.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that described butyronitrile
The weight ratio of rubber, ethylene propylene diene rubber and phenolic resin is 3～5:1:2～2.5.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that described Borax
Particle diameter be 10～500 μm.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that described anti-always
Agent is 2,6 ditertiary butyl p cresol.
A kind of non-woven fabrics the most according to claim 1 is with ageing-resistant butyronitrile latex binding agent, it is characterised in that described coupling
Agent is isopropyl three stearic acid acyloxy titanate esters.
8. the non-woven fabrics preparation method of ageing-resistant butyronitrile latex binding agent, it is characterised in that comprise the following steps:
S1, the nitrile rubber by described proportion, ethylene propylene diene rubber, white carbon black, zinc oxide, oleic acid join in rubber vulcanizing tank,
High temperature 160～190 DEG C of sulfurations 4～6h, obtain mixture A；
In S2, holding step S1, mixture A's is temperature-resistant, adds the triphenyl phosphate of described proportion, coupling agent and age resistor,
With the rotating speed of 80～100r/min, at the uniform velocity after stirring 20～40min, it is cooled to room temperature, obtains mixture B；
S3, the mixture B of gained in step S2 and the Borax of described proportion, phenolic resin and ethanol are joined high-speed stirred
In machine, with the rotating speed of 600～800r/min, high-speed stirred 1～3h, after uniform one-tenth pasty state to be mixed, pack and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610725853.0A CN106221612A (en) | 2016-08-26 | 2016-08-26 | A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610725853.0A CN106221612A (en) | 2016-08-26 | 2016-08-26 | A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221612A true CN106221612A (en) | 2016-12-14 |
Family
ID=57555279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610725853.0A Pending CN106221612A (en) | 2016-08-26 | 2016-08-26 | A kind of non-woven fabrics is with ageing-resistant butyronitrile latex binding agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN106221612A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1178237A (en) * | 1997-10-23 | 1998-04-08 | 湖北省化学研究所 | Heat-resistant fireproof adhesive for flexible printing circuit and preparation thereof |
| CN102108274A (en) * | 2011-01-27 | 2011-06-29 | 安徽安大中鼎橡胶技术开发有限公司 | Phenolic-nitrile rubber hot vulcanized adhesive and preparation method thereof |
-
2016
- 2016-08-26 CN CN201610725853.0A patent/CN106221612A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1178237A (en) * | 1997-10-23 | 1998-04-08 | 湖北省化学研究所 | Heat-resistant fireproof adhesive for flexible printing circuit and preparation thereof |
| CN102108274A (en) * | 2011-01-27 | 2011-06-29 | 安徽安大中鼎橡胶技术开发有限公司 | Phenolic-nitrile rubber hot vulcanized adhesive and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 * |
| 阎春绵等: "《制鞋与皮革胶黏剂》", 31 March 2009, 化学工业出版社 * |
| 韦军等: "《高分子合成工艺学》", 28 February 2011, 华南理工大学出版社 * |
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Application publication date: 20161214 |
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