CN106221534A - A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method - Google Patents

A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method Download PDF

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Publication number
CN106221534A
CN106221534A CN201610565315.XA CN201610565315A CN106221534A CN 106221534 A CN106221534 A CN 106221534A CN 201610565315 A CN201610565315 A CN 201610565315A CN 106221534 A CN106221534 A CN 106221534A
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CN
China
Prior art keywords
environmental protection
automatically cleaning
protection coating
flame
timber buildings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610565315.XA
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Chinese (zh)
Inventor
袁伟忠
邹辉
陈相南
陆叶强
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Tongji University
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Tongji University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University filed Critical Tongji University
Priority to CN201610565315.XA priority Critical patent/CN106221534A/en
Publication of CN106221534A publication Critical patent/CN106221534A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to functional environment-friendly paint field, be specifically related to a kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method thereof.The present invention is with polyaminoester emulsion as film forming matter, with hydroxyl fluorine silicon additive for the hydrophobic auxiliary agent of low-surface-energy, halogen-free flame-retardant system is constituted with APP, aluminium hydroxide and zinc oxide, and add titanium dioxide, sericite, wetting agent, thickening agent, defoamer, dispersant and coalescents, it is prepared for may be used to the automatically cleaning flame-proof environmental protection coating of timber buildings.Prepared coating has automatically cleaning, the function such as fire-retardant, can be widely used for timber buildings, protects building, improves the live and work environment of people.

Description

A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method
Technical field
The invention belongs to field of functional coatings, be specifically related to a kind of automatically cleaning flame-proof environmental protection coating for timber buildings And preparation method.
Background technology
Timber has the features such as lightweight, intensity is high, attractive in appearance, good processability, is the most just had a preference for by people, is The construction material that one class is important.Compared with armored concrete or brick structure house, wooden frame structure have raw material renewable, Recoverable, the advantage of environmental protection.Meanwhile, timber structure destroys for moment impact and Cyclic fatigue and has good supporting Anti-ability, this makes timber buildings can preferably resist the natural disasters such as earthquake.It addition, use wooden frame structure to protect Protecting soil, and the construction time of timber buildings is short, easy to maintenance, equipment required when keeping in repair or transform is relatively easy, personnel The most less.Low-carbon (LC), the requirement of energy-saving and environmental protection that timber buildings is currently advocated with China are extremely consistent, and demand is Increase year by year.
It is noted that timber buildings there is also the defects such as inflammable, therefore the fire prevention of wooden frame structure is very Necessary.In modern project, most widely used, the suitability is the strongest, construction is fireproof coating the most easily.APP, hydroxide The flame-retardant system that aluminum, zinc oxide are constituted has good flameproof effect, will not release hydrogen halide during burning simultaneously, thus can Think that people provide a safe and reliable living environment.Meanwhile, in order to reduce further timber buildings use during because of The energy consumption clearing up metope and produce, exploitation plate for timber-construction self-cleaning coating tool is of great significance.It addition, aqueous ring Friendly coating is without low VOC (Volatile Organic Compounds, VOC), and environmentally safe, to people Body health does not injure, it is possible to reaches green truly, environmental protection, is increasingly subject to people's attention and likes.Wood knot Build build the complete composite green of automatically cleaning anti-flaming dope, the Times ' Demand of environmental protection, can be people provide one comfortable, safe, Healthy living environment.
Summary of the invention
It is an object of the invention to provide a kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method.
It is an object of the invention to, using polyaminoester emulsion as film forming matter, dredge using hydroxyl fluorine silicon additive as low-surface-energy Water auxiliary agent, is constituted flame-retardant system with APP, aluminium hydroxide, zinc oxide, is compounded with the filler such as titanium dioxide, sericite, and adds Add wetting agent, thickening agent, defoamer, dispersant and coalescents, be prepared for the timber buildings with automatically cleaning, anti-flaming function Use environmental protection coating material.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings that the present invention proposes, this kind of plate for timber-construction is certainly The raw material composition of cleaning flame-proof environmental protection coating, is calculated as with mass fraction:
Raw materials quality number
Polyaminoester emulsion 30 ~ 60
The hydrophobic auxiliary agent of low-surface-energy 3 ~ 9
APP 3 ~ 20
Aluminium hydroxide 1 ~ 15
Zinc oxide 1 ~ 5
Titanium dioxide 5 ~ 20
Sericite 2 ~ 15
Wetting agent 1 ~ 2
Thickening agent 0.5 ~ 2
Defoamer 0.1 ~ 1
Dispersant 0.2 ~ 1.5
Coalescents 1 ~ 3
Remaining is deionized water, and its gross mass number meets 100 parts.
In the present invention, the hydrophobic auxiliary agent of described low-surface-energy is hydroxyl fluorine silicon additive.
In the present invention, described fire retardant is the halogen-free flame-retardant system that APP, aluminium hydroxide and zinc oxide are constituted.
In the present invention, described thickening agent is hydroxyethyl cellulose.
In the present invention, described dispersant is silanol class nonionic surfactant.
In the present invention, described coalescents is ethylene glycol phenyl ether.
The preparation method of a kind of automatically cleaning flame-proof environmental protection coating for timber buildings that the present invention proposes, concrete steps As follows:
(1) first each raw material is weighed according to parts by weight;
(2) rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersant, defoamer, low-surface-energy hydrophobic Auxiliary agent;
(3) after agitated, then add APP, aluminium hydroxide, zinc oxide, titanium dioxide, sericite, and high speed dispersor is turned Velocity modulation carries out high speed dispersion to 8000 revs/min;
(4) reduce high speed dispersor rotating speed to 500 revs/min, add polyaminoester emulsion, coalescents, then regulate with thickening agent System viscosity;
(5) performance detection;
(6) detect qualified after be packaged into finished product.
It is an advantage of the current invention that:
(1) the Product Green environmental protection of the present invention.The product of this invention is adopted and is used water as solvent, is provided without organic solvent, use Raw material is all environment-friendly type, will not damage environment and human body.
(2) product of the present invention has good automatically cleaning, flame retardant effect, can be widely used for timber buildings, thus is People provide comfortable, a safe and healthy living environment.
Detailed description of the invention
Embodiment 1
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion 40
The hydrophobic auxiliary agent of low-surface-energy 5
APP 9
Aluminium hydroxide 4
Zinc oxide 1
Titanium dioxide 9
Sericite 3
Wetting agent 1.5
Thickening agent 1
Defoamer 0.5
Dispersant 1.2
Coalescents 2
Deionized water 22.8
The preparation method of above-mentioned coating, it comprises the following steps that:
It is that 100 kg carry out dispensing by gross weight, the rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersion Agent, defoamer, the hydrophobic auxiliary agent of low-surface-energy;After agitated, then add APP, aluminium hydroxide, zinc oxide, titanium dioxide, thin,tough silk Muscovitum, and high speed dispersor rotating speed is adjusted to 8000 revs/min carries out high speed dispersion;Reduce rotor speed to 500 revs/min, Add polyaminoester emulsion, coalescents, then by hydroxyethyl cellulose regulation system viscosity to construction requirement.
Embodiment 2
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion 40
The hydrophobic auxiliary agent of low-surface-energy 4
APP 10
Aluminium hydroxide 3
Zinc oxide 1
Titanium dioxide 10
Sericite 3
Wetting agent 1
Thickening agent 0.8
Defoamer 0.6
Dispersant 1
Coalescents 1.5
Deionized water 24.1
The preparation method of above-mentioned coating is same as in Example 1.
Embodiment 3
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion 40
The hydrophobic auxiliary agent of low-surface-energy 7
APP 8
Aluminium hydroxide 5
Zinc oxide 2
Titanium dioxide 8
Sericite 3
Wetting agent 1.2
Thickening agent 0.9
Defoamer 0.5
Dispersant 1
Coalescents 1.6
Deionized water 21.8
The preparation method of above-mentioned coating is same as in Example 1.

Claims (7)

1. the automatically cleaning flame-proof environmental protection coating for timber buildings, it is characterised in that this kind of plate for timber-construction automatically cleaning The raw material composition of flame-proof environmental protection coating, is calculated as with mass fraction:
Raw materials quality number
Polyaminoester emulsion 30 ~ 60
The hydrophobic auxiliary agent of low-surface-energy 3 ~ 9
APP 3 ~ 20
Aluminium hydroxide 1 ~ 15
Zinc oxide 1 ~ 5
Titanium dioxide 5 ~ 20
Sericite 2 ~ 15
Wetting agent 1 ~ 2
Thickening agent 0.5 ~ 2
Defoamer 0.1 ~ 1
Dispersant 0.2 ~ 1.5
Coalescents 1 ~ 3
Remaining is deionized water, and its gross mass number meets 100 parts.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: low Surface can hydrophobic auxiliary agent be hydroxyl fluorine silicon additive.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: resistance Combustion agent is the halogen-free flame-retardant system that APP, aluminium hydroxide and zinc oxide are constituted.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: increase Thick dose is hydroxyethyl cellulose.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: point Powder is silanol class nonionic surfactant.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: become Film auxiliary agent is ethylene glycol phenyl ether.
7. a preparation method for a kind of automatically cleaning flame-proof environmental protection coating for timber buildings as claimed in claim 1, It is characterized in that specifically comprising the following steps that
(1) each raw material is weighed by raw materials quality number;
(2) rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersant, defoamer and low-surface-energy and dredges Water auxiliary agent;
(3) after agitated, then APP, aluminium hydroxide, zinc oxide, titanium dioxide and sericite are added, and by high speed dispersor Rotating speed is adjusted to 8000 revs/min and carries out high speed dispersion;
(4) reduce high speed dispersor rotating speed to 500 revs/min, add polyaminoester emulsion, coalescents, then regulate with thickening agent System viscosity;
(5) performance detection;
(6) detect qualified after be packaged into finished product.
CN201610565315.XA 2016-07-19 2016-07-19 A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method Pending CN106221534A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610565315.XA CN106221534A (en) 2016-07-19 2016-07-19 A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610565315.XA CN106221534A (en) 2016-07-19 2016-07-19 A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method

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Publication Number Publication Date
CN106221534A true CN106221534A (en) 2016-12-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107313245A (en) * 2017-07-25 2017-11-03 东莞市荣腾纳米科技有限公司 A kind of flame retardant type fog-proof wet towel and its processing method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101143988A (en) * 2006-09-14 2008-03-19 刘炳义 Water-based flame-retardant fireproof wood paint
CN101818017A (en) * 2010-04-02 2010-09-01 北京工业大学 Self-cleaning coating and preparation method thereof
CN103881550A (en) * 2014-02-26 2014-06-25 金甲化工企业(中山)有限公司 Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof
CN104356841A (en) * 2014-10-23 2015-02-18 安徽省金盾涂料有限责任公司 Self-cleaning acrylic coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101143988A (en) * 2006-09-14 2008-03-19 刘炳义 Water-based flame-retardant fireproof wood paint
CN101818017A (en) * 2010-04-02 2010-09-01 北京工业大学 Self-cleaning coating and preparation method thereof
CN103881550A (en) * 2014-02-26 2014-06-25 金甲化工企业(中山)有限公司 Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof
CN104356841A (en) * 2014-10-23 2015-02-18 安徽省金盾涂料有限责任公司 Self-cleaning acrylic coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭秉臣: "《非织造技术产品开发》", 31 July 2009, 中国纺织出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107313245A (en) * 2017-07-25 2017-11-03 东莞市荣腾纳米科技有限公司 A kind of flame retardant type fog-proof wet towel and its processing method

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Application publication date: 20161214

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