CN106221534A - A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method - Google Patents
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method Download PDFInfo
- Publication number
- CN106221534A CN106221534A CN201610565315.XA CN201610565315A CN106221534A CN 106221534 A CN106221534 A CN 106221534A CN 201610565315 A CN201610565315 A CN 201610565315A CN 106221534 A CN106221534 A CN 106221534A
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- CN
- China
- Prior art keywords
- environmental protection
- automatically cleaning
- protection coating
- flame
- timber buildings
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to functional environment-friendly paint field, be specifically related to a kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method thereof.The present invention is with polyaminoester emulsion as film forming matter, with hydroxyl fluorine silicon additive for the hydrophobic auxiliary agent of low-surface-energy, halogen-free flame-retardant system is constituted with APP, aluminium hydroxide and zinc oxide, and add titanium dioxide, sericite, wetting agent, thickening agent, defoamer, dispersant and coalescents, it is prepared for may be used to the automatically cleaning flame-proof environmental protection coating of timber buildings.Prepared coating has automatically cleaning, the function such as fire-retardant, can be widely used for timber buildings, protects building, improves the live and work environment of people.
Description
Technical field
The invention belongs to field of functional coatings, be specifically related to a kind of automatically cleaning flame-proof environmental protection coating for timber buildings
And preparation method.
Background technology
Timber has the features such as lightweight, intensity is high, attractive in appearance, good processability, is the most just had a preference for by people, is
The construction material that one class is important.Compared with armored concrete or brick structure house, wooden frame structure have raw material renewable,
Recoverable, the advantage of environmental protection.Meanwhile, timber structure destroys for moment impact and Cyclic fatigue and has good supporting
Anti-ability, this makes timber buildings can preferably resist the natural disasters such as earthquake.It addition, use wooden frame structure to protect
Protecting soil, and the construction time of timber buildings is short, easy to maintenance, equipment required when keeping in repair or transform is relatively easy, personnel
The most less.Low-carbon (LC), the requirement of energy-saving and environmental protection that timber buildings is currently advocated with China are extremely consistent, and demand is
Increase year by year.
It is noted that timber buildings there is also the defects such as inflammable, therefore the fire prevention of wooden frame structure is very
Necessary.In modern project, most widely used, the suitability is the strongest, construction is fireproof coating the most easily.APP, hydroxide
The flame-retardant system that aluminum, zinc oxide are constituted has good flameproof effect, will not release hydrogen halide during burning simultaneously, thus can
Think that people provide a safe and reliable living environment.Meanwhile, in order to reduce further timber buildings use during because of
The energy consumption clearing up metope and produce, exploitation plate for timber-construction self-cleaning coating tool is of great significance.It addition, aqueous ring
Friendly coating is without low VOC (Volatile Organic Compounds, VOC), and environmentally safe, to people
Body health does not injure, it is possible to reaches green truly, environmental protection, is increasingly subject to people's attention and likes.Wood knot
Build build the complete composite green of automatically cleaning anti-flaming dope, the Times ' Demand of environmental protection, can be people provide one comfortable, safe,
Healthy living environment.
Summary of the invention
It is an object of the invention to provide a kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method.
It is an object of the invention to, using polyaminoester emulsion as film forming matter, dredge using hydroxyl fluorine silicon additive as low-surface-energy
Water auxiliary agent, is constituted flame-retardant system with APP, aluminium hydroxide, zinc oxide, is compounded with the filler such as titanium dioxide, sericite, and adds
Add wetting agent, thickening agent, defoamer, dispersant and coalescents, be prepared for the timber buildings with automatically cleaning, anti-flaming function
Use environmental protection coating material.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings that the present invention proposes, this kind of plate for timber-construction is certainly
The raw material composition of cleaning flame-proof environmental protection coating, is calculated as with mass fraction:
Raw materials quality number
Polyaminoester emulsion 30 ~ 60
The hydrophobic auxiliary agent of low-surface-energy 3 ~ 9
APP 3 ~ 20
Aluminium hydroxide 1 ~ 15
Zinc oxide 1 ~ 5
Titanium dioxide 5 ~ 20
Sericite 2 ~ 15
Wetting agent 1 ~ 2
Thickening agent 0.5 ~ 2
Defoamer 0.1 ~ 1
Dispersant 0.2 ~ 1.5
Coalescents 1 ~ 3
Remaining is deionized water, and its gross mass number meets 100 parts.
In the present invention, the hydrophobic auxiliary agent of described low-surface-energy is hydroxyl fluorine silicon additive.
In the present invention, described fire retardant is the halogen-free flame-retardant system that APP, aluminium hydroxide and zinc oxide are constituted.
In the present invention, described thickening agent is hydroxyethyl cellulose.
In the present invention, described dispersant is silanol class nonionic surfactant.
In the present invention, described coalescents is ethylene glycol phenyl ether.
The preparation method of a kind of automatically cleaning flame-proof environmental protection coating for timber buildings that the present invention proposes, concrete steps
As follows:
(1) first each raw material is weighed according to parts by weight;
(2) rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersant, defoamer, low-surface-energy hydrophobic
Auxiliary agent;
(3) after agitated, then add APP, aluminium hydroxide, zinc oxide, titanium dioxide, sericite, and high speed dispersor is turned
Velocity modulation carries out high speed dispersion to 8000 revs/min;
(4) reduce high speed dispersor rotating speed to 500 revs/min, add polyaminoester emulsion, coalescents, then regulate with thickening agent
System viscosity;
(5) performance detection;
(6) detect qualified after be packaged into finished product.
It is an advantage of the current invention that:
(1) the Product Green environmental protection of the present invention.The product of this invention is adopted and is used water as solvent, is provided without organic solvent, use
Raw material is all environment-friendly type, will not damage environment and human body.
(2) product of the present invention has good automatically cleaning, flame retardant effect, can be widely used for timber buildings, thus is
People provide comfortable, a safe and healthy living environment.
Detailed description of the invention
Embodiment 1
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion | 40 |
The hydrophobic auxiliary agent of low-surface-energy | 5 |
APP | 9 |
Aluminium hydroxide | 4 |
Zinc oxide | 1 |
Titanium dioxide | 9 |
Sericite | 3 |
Wetting agent | 1.5 |
Thickening agent | 1 |
Defoamer | 0.5 |
Dispersant | 1.2 |
Coalescents | 2 |
Deionized water | 22.8 |
The preparation method of above-mentioned coating, it comprises the following steps that:
It is that 100 kg carry out dispensing by gross weight, the rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersion
Agent, defoamer, the hydrophobic auxiliary agent of low-surface-energy;After agitated, then add APP, aluminium hydroxide, zinc oxide, titanium dioxide, thin,tough silk
Muscovitum, and high speed dispersor rotating speed is adjusted to 8000 revs/min carries out high speed dispersion;Reduce rotor speed to 500 revs/min,
Add polyaminoester emulsion, coalescents, then by hydroxyethyl cellulose regulation system viscosity to construction requirement.
Embodiment 2
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion | 40 |
The hydrophobic auxiliary agent of low-surface-energy | 4 |
APP | 10 |
Aluminium hydroxide | 3 |
Zinc oxide | 1 |
Titanium dioxide | 10 |
Sericite | 3 |
Wetting agent | 1 |
Thickening agent | 0.8 |
Defoamer | 0.6 |
Dispersant | 1 |
Coalescents | 1.5 |
Deionized water | 24.1 |
The preparation method of above-mentioned coating is same as in Example 1.
Embodiment 3
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings, its formula for raw stock is following (according to the mass fraction):
Polyaminoester emulsion | 40 |
The hydrophobic auxiliary agent of low-surface-energy | 7 |
APP | 8 |
Aluminium hydroxide | 5 |
Zinc oxide | 2 |
Titanium dioxide | 8 |
Sericite | 3 |
Wetting agent | 1.2 |
Thickening agent | 0.9 |
Defoamer | 0.5 |
Dispersant | 1 |
Coalescents | 1.6 |
Deionized water | 21.8 |
The preparation method of above-mentioned coating is same as in Example 1.
Claims (7)
1. the automatically cleaning flame-proof environmental protection coating for timber buildings, it is characterised in that this kind of plate for timber-construction automatically cleaning
The raw material composition of flame-proof environmental protection coating, is calculated as with mass fraction:
Raw materials quality number
Polyaminoester emulsion 30 ~ 60
The hydrophobic auxiliary agent of low-surface-energy 3 ~ 9
APP 3 ~ 20
Aluminium hydroxide 1 ~ 15
Zinc oxide 1 ~ 5
Titanium dioxide 5 ~ 20
Sericite 2 ~ 15
Wetting agent 1 ~ 2
Thickening agent 0.5 ~ 2
Defoamer 0.1 ~ 1
Dispersant 0.2 ~ 1.5
Coalescents 1 ~ 3
Remaining is deionized water, and its gross mass number meets 100 parts.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: low
Surface can hydrophobic auxiliary agent be hydroxyl fluorine silicon additive.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: resistance
Combustion agent is the halogen-free flame-retardant system that APP, aluminium hydroxide and zinc oxide are constituted.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: increase
Thick dose is hydroxyethyl cellulose.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: point
Powder is silanol class nonionic surfactant.
A kind of automatically cleaning flame-proof environmental protection coating for timber buildings the most according to claim 1, it is characterised in that: become
Film auxiliary agent is ethylene glycol phenyl ether.
7. a preparation method for a kind of automatically cleaning flame-proof environmental protection coating for timber buildings as claimed in claim 1,
It is characterized in that specifically comprising the following steps that
(1) each raw material is weighed by raw materials quality number;
(2) rotating speed of high speed dispersor is adjusted to 500 revs/min, is sequentially added into water, dispersant, defoamer and low-surface-energy and dredges
Water auxiliary agent;
(3) after agitated, then APP, aluminium hydroxide, zinc oxide, titanium dioxide and sericite are added, and by high speed dispersor
Rotating speed is adjusted to 8000 revs/min and carries out high speed dispersion;
(4) reduce high speed dispersor rotating speed to 500 revs/min, add polyaminoester emulsion, coalescents, then regulate with thickening agent
System viscosity;
(5) performance detection;
(6) detect qualified after be packaged into finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610565315.XA CN106221534A (en) | 2016-07-19 | 2016-07-19 | A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method |
Applications Claiming Priority (1)
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CN201610565315.XA CN106221534A (en) | 2016-07-19 | 2016-07-19 | A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method |
Publications (1)
Publication Number | Publication Date |
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CN106221534A true CN106221534A (en) | 2016-12-14 |
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CN201610565315.XA Pending CN106221534A (en) | 2016-07-19 | 2016-07-19 | A kind of automatically cleaning flame-proof environmental protection coating for timber buildings and preparation method |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107313245A (en) * | 2017-07-25 | 2017-11-03 | 东莞市荣腾纳米科技有限公司 | A kind of flame retardant type fog-proof wet towel and its processing method |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101143988A (en) * | 2006-09-14 | 2008-03-19 | 刘炳义 | Water-based flame-retardant fireproof wood paint |
CN101818017A (en) * | 2010-04-02 | 2010-09-01 | 北京工业大学 | Self-cleaning coating and preparation method thereof |
CN103881550A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof |
CN104356841A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Self-cleaning acrylic coating |
-
2016
- 2016-07-19 CN CN201610565315.XA patent/CN106221534A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101143988A (en) * | 2006-09-14 | 2008-03-19 | 刘炳义 | Water-based flame-retardant fireproof wood paint |
CN101818017A (en) * | 2010-04-02 | 2010-09-01 | 北京工业大学 | Self-cleaning coating and preparation method thereof |
CN103881550A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Water-based expansive type heat-insulated flame-retardant smoke-suppression dope for wooden products and coating method thereof |
CN104356841A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Self-cleaning acrylic coating |
Non-Patent Citations (1)
Title |
---|
郭秉臣: "《非织造技术产品开发》", 31 July 2009, 中国纺织出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107313245A (en) * | 2017-07-25 | 2017-11-03 | 东莞市荣腾纳米科技有限公司 | A kind of flame retardant type fog-proof wet towel and its processing method |
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