CN107603379A - A kind of fluorescent paint with fire protecting performance - Google Patents

A kind of fluorescent paint with fire protecting performance Download PDF

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Publication number
CN107603379A
CN107603379A CN201710968607.2A CN201710968607A CN107603379A CN 107603379 A CN107603379 A CN 107603379A CN 201710968607 A CN201710968607 A CN 201710968607A CN 107603379 A CN107603379 A CN 107603379A
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CN
China
Prior art keywords
fire protecting
protecting performance
fluorescent paint
performance according
agent
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Pending
Application number
CN201710968607.2A
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Chinese (zh)
Inventor
邓雪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gold Blue Collar Education And Science Co Ltd Of Foshan City
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Gold Blue Collar Education And Science Co Ltd Of Foshan City
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Gold Blue Collar Education And Science Co Ltd Of Foshan City filed Critical Gold Blue Collar Education And Science Co Ltd Of Foshan City
Priority to CN201710968607.2A priority Critical patent/CN107603379A/en
Publication of CN107603379A publication Critical patent/CN107603379A/en
Pending legal-status Critical Current

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Abstract

The present invention provides a kind of fluorescent paint with fire protecting performance, and it includes the raw material of following degree:30%~40% organosilicon-modified acrylic emulsion, 10%~20% fluorescent pigment emulsion, 10%~20% APP, 8%~15% pentaerythrite, 5%~10% melamine, 5%~10% titanium dioxide, 2%~8% aluminium hydroxide, 1%~5% Firebrake ZB, 1%~5% chlorinated paraffin, 0.05%~0.2% anticorrosion and bactericidal agent, 0.1%~0.2% dispersant, 0.3%~1.0% coalescents, 0.1%~0.5% thickener, 0.5%~2.0% defoamer, 0.5%~2.0% anti-settling agent and appropriate amount of deionized water.The fluorescent paint belongs to green environmental protection coating, and environment and human health will not be damaged;Also there is the advantages such as fire protecting performance is good, the resistance to combustion time is long, fluorescence is strong, coating performance is excellent.

Description

A kind of fluorescent paint with fire protecting performance
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of fluorescent paint with fire protecting performance.
Background technology
Coating refers to be applied to body surface and can form the general name of the material of tough and tensile diaphragm.With the development of society, For coating in occupation of increasingly consequence in the life of people, application is also more and more extensive, and at present, people are in concern coating
Health environment-friendly performance and decoration performance beyond, also more and more paid close attention to the feature of coating.Fire protecting performance The development of fluorescent paint necessarily turns into future market trend.
The content of the invention
It is an object of the invention to provide a kind of fluorescent paint with fire protecting performance, the fluorescent paint belongs to green Property coating, not only with the alkaline-resisting time grow, decoration performance it is good, water resistance is excellent, and ageing-resistant performance is excellent, and the brush of resistance to Xian is good, is also free of The metallic compound such as mercury, not leaded or chromium, does not contain free formaldehyde toxic gas, and environment and human health will not be caused to endanger Evil;Also there is the advantages such as fire protecting performance is good, the resistance to combustion time is long, fluorescence is strong, coating performance is excellent.It can be widely applied to hotel, big The building decorations such as tall building, airport, station.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of fluorescence with fire protecting performance applies Material, it includes the raw material of following degree:30%~40% organosilicon-modified acrylic emulsion, 10%~20% Fluorescent pigment emulsion, 10%~20% APP, 8%~15% pentaerythrite, 5%~10% melamine, 5%~10% titanium dioxide, 2%~8% aluminium hydroxide, 1%~5% Firebrake ZB, 1%~5% chlorinated paraffin, 0.05%~0.2% anticorrosion and bactericidal agent, 0.1%~0.2% dispersant, 0.3%~1.0% coalescents, 0.1% ~0.5% thickener, 0.5%~2.0% defoamer, 0.5%~2.0% anti-settling agent and appropriate amount of deionized water.
Further, the titanium dioxide uses rutile titanium dioxide.
Further, the anticorrosion and bactericidal agent is OIT, chloromethyl OIT, benzisothiazole Ketone, 1,2 '-two bromo- 2,4- dicyanobutanes, the bromo- 2- bromomethyls glutaronitriles of 2- or 2- benzimidazole aminocarbamic acid first One or more in ester.
Further, the dispersant is one kind in acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt Or more than one mixtures.
Further, the coalescents are 2- amino -2- methyl isophthalic acids-propyl alcohol, alcohol ester 12, butyl glycol ether, third One or more kinds of mixtures in glycol butyl ether, phenmethylol, propane diols phenylate.
Further, the thickener be one kind in carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol or A variety of mixtures.
Further, the defoamer is organic silicon defoamer, mineral oil defoaming agent or its combination.
Further, the anti-settling agent is aerosil.
Beneficial effects of the present invention:The present invention introduces fire retardant polyphosphoric acid using organosilicon-modified acrylic emulsion as base-material Ammonium, pentaerythrite, melamine, aluminium hydroxide, Firebrake ZB are compound existing with obtained flame-proof type polyalcohol emulsion waterproofing paint Good mechanical property, there is good fire resistance again, the materials'use is convenient, green, safety and stability, and at it In also added the fluorescent paint that fluorescent pigment emulsion is directly scattered in the fire protecting performance being prepared in base-material, there is fluorescence The advantages such as by force, good weatherability, coating performance be excellent, it can be widely used for can be widely applied to the building such as hotel, mansion, airport, station Decoration.
Embodiment
In order that present disclosure is more likely to be clearly understood, below according to the specific embodiment of the present invention, to this Invention is described in further detail.
Embodiment 1
A kind of fluorescent paint with fire protecting performance, it includes the raw material of following degree:30% it is organic-silicon-modified Acrylic emulsion, 20% fluorescent pigment emulsion, 10% APP, 8% pentaerythrite, 5% melamine, 5% Titanium dioxide, 2% aluminium hydroxide, 1% Firebrake ZB, 1% chlorinated paraffin, 0.05% anticorrosion and bactericidal agent, 0.1% it is scattered Agent, 0.3% coalescents, 0.1% thickener, 0.5% defoamer, 0.5% anti-settling agent and appropriate amount of deionized water.
The titanium dioxide uses rutile titanium dioxide.
The anticorrosion and bactericidal agent is OIT.
The dispersant is acrylic copolymer ammonium salt.
The coalescents are 2- amino -2- methyl isophthalic acids-propyl alcohol.
The thickener is carboxymethyl cellulose.
The defoamer is organic silicon defoamer.
The anti-settling agent is aerosil.
Embodiment 2
A kind of fluorescent paint with fire protecting performance, it includes the raw material of following degree:40% it is organic-silicon-modified Acrylic emulsion, 20% fluorescent pigment emulsion, 10%% APP, 8%% pentaerythrite, 5% melamine, 5% titanium dioxide, 2% aluminium hydroxide, 1% Firebrake ZB, 1% chlorinated paraffin, 0.2% anticorrosion and bactericidal agent, 00.2% Dispersant, 1.0% coalescents, 0.5% thickener, 2.0% defoamer, 2.0% anti-settling agent and appropriate deionization Water.
The titanium dioxide uses rutile titanium dioxide.
The anticorrosion and bactericidal agent is OIT, chloromethyl OIT arbitrarily matches mixture.
The dispersant is acrylic copolymer ammonium salt and ammonium polyacrylate salt mixture.
The coalescents be 2- amino -2- methyl isophthalic acids-propyl alcohol, alcohol ester 12, butyl glycol ether, propandiol butyl ether, The a variety of mixture of phenmethylol, propane diols phenylate.
The thickener is the mixture of carboxymethyl cellulose, hydroxyethyl cellulose.
The defoamer is the combination of organic silicon defoamer, mineral oil defoaming agent.
The anti-settling agent is aerosil.
Embodiment 3
A kind of fluorescent paint with fire protecting performance, it includes the raw material of following degree:35% it is organic-silicon-modified Acrylic emulsion, 15% fluorescent pigment emulsion, 15% APP, 12% pentaerythrite, 6% melamine, 6% Titanium dioxide, 5% aluminium hydroxide, 3% Firebrake ZB, 3% chlorinated paraffin, 0.08% anticorrosion and bactericidal agent, 0.2% it is scattered Agent, 0.6% coalescents, 0.3% thickener, 0.6% defoamer, 0.8% anti-settling agent and appropriate amount of deionized water.
The titanium dioxide uses rutile titanium dioxide.
The anticorrosion and bactericidal agent be OIT, chloromethyl OIT, BIT, 1,2 '- Two bromo- 2,4- dicyanobutanes, the mixture arbitrarily matched.
The dispersant is acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt arbitrarily match mixture.
The coalescents be 2- amino -2- methyl isophthalic acids-propyl alcohol, alcohol ester 12, butyl glycol ether, propandiol butyl ether, Phenmethylol, the mixture arbitrarily matched.
The thickener is hydroxyethyl cellulose.
The defoamer is mineral oil defoaming agent.
The anti-settling agent is aerosil.
Table 1 is the environmental-protecting performance check table for the fluorescent paint that this kind has fire protecting performance
Table 2 is the technical performance check table for the fluorescent paint that this kind has fire protecting performance.
By Tables 1 and 2 it can be seen that the fluorescent paint with fire protecting performance of the present invention, the fluorescent paint belong to green Property coating, not only with the alkaline-resisting time grow, decoration performance it is good, water resistance is excellent, and ageing-resistant performance is excellent, and the brush of resistance to Xian is good, is also free of The metallic compound such as mercury, not leaded or chromium, does not contain free formaldehyde toxic gas, and environment and human health will not be caused to endanger Evil;Also there is the advantages such as fire protecting performance is good, the resistance to combustion time is long, fluorescence is strong, coating performance is excellent.

Claims (8)

  1. A kind of 1. fluorescent paint with fire protecting performance, it is characterised in that:It includes the raw material of following degree:
    30%~40% organosilicon-modified acrylic emulsion, 10%~20% fluorescent pigment emulsion, 10%~20% it is poly- Ammonium phosphate, 8%~15% pentaerythrite, 5%~10% melamine, 5%~10% titanium dioxide, 2%~8% Aluminium hydroxide, 1%~5% Firebrake ZB, 1%~5% chlorinated paraffin, 0.05%~0.2% anticorrosion and bactericidal agent, 0.1%~0.2% dispersant, 0.3%~1.0% coalescents, 0.1%~0.5% thickener, 0.5%~ 2.0% defoamer, 0.5%~2.0% anti-settling agent and appropriate amount of deionized water.
  2. 2. a kind of fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the titanium dioxide is adopted Use rutile titanium dioxide.
  3. A kind of 3. fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the antisepsis and sterilization Agent be OIT, chloromethyl OIT, BIT, 1,2 '-two bromo- 2,4- dicyanobutanes, One or more in the bromo- 2- bromomethyls glutaronitriles of 2- or 2- benzimidazole ylcarbamic acid methyl esters.
  4. 4. a kind of fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the dispersant is One or more kinds of mixtures in acrylic copolymer ammonium salt, ammonium polyacrylate salt, polycarboxylic acids ammonium salt.
  5. A kind of 5. fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the coalescents For in 2- amino -2- methyl isophthalic acids-propyl alcohol, alcohol ester 12, butyl glycol ether, propandiol butyl ether, phenmethylol, propane diols phenylate One or more kinds of mixtures.
  6. 6. a kind of fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the thickener is For one or more kinds of mixtures in carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol.
  7. 7. a kind of fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the defoamer is Organic silicon defoamer, mineral oil defoaming agent or its combination.
  8. 8. a kind of fluorescent paint with fire protecting performance according to claim 1, it is characterised in that the anti-settling agent is Aerosil.
CN201710968607.2A 2017-10-18 2017-10-18 A kind of fluorescent paint with fire protecting performance Pending CN107603379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710968607.2A CN107603379A (en) 2017-10-18 2017-10-18 A kind of fluorescent paint with fire protecting performance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710968607.2A CN107603379A (en) 2017-10-18 2017-10-18 A kind of fluorescent paint with fire protecting performance

Publications (1)

Publication Number Publication Date
CN107603379A true CN107603379A (en) 2018-01-19

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109554081A (en) * 2018-11-15 2019-04-02 株洲飞鹿高新材料技术股份有限公司 A kind of aqueous scumbling type aluminium alloy fireproof coating and preparation method thereof
CN116396644A (en) * 2023-03-03 2023-07-07 贵州大学 Luminous paint with flame retardant effect and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675992A (en) * 2011-03-07 2012-09-19 嘉宝莉化工集团股份有限公司 Expanded type aqueous facing fireproof coating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675992A (en) * 2011-03-07 2012-09-19 嘉宝莉化工集团股份有限公司 Expanded type aqueous facing fireproof coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曹优明等: ""有机硅改性丙烯酸树脂荧光涂料的研究"", 《新型建筑材料》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109554081A (en) * 2018-11-15 2019-04-02 株洲飞鹿高新材料技术股份有限公司 A kind of aqueous scumbling type aluminium alloy fireproof coating and preparation method thereof
CN116396644A (en) * 2023-03-03 2023-07-07 贵州大学 Luminous paint with flame retardant effect and preparation method thereof

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Application publication date: 20180119