CN106221489A - A kind of automatically cleaning ornament materials for floor - Google Patents

A kind of automatically cleaning ornament materials for floor Download PDF

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Publication number
CN106221489A
CN106221489A CN201610717727.0A CN201610717727A CN106221489A CN 106221489 A CN106221489 A CN 106221489A CN 201610717727 A CN201610717727 A CN 201610717727A CN 106221489 A CN106221489 A CN 106221489A
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CN
China
Prior art keywords
parts
floor
antibacterial
calcium carbonate
ornament materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610717727.0A
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Chinese (zh)
Inventor
黄雄关
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu City Tian Xiong New Material Science And Technology Ltd
Original Assignee
Wuhu City Tian Xiong New Material Science And Technology Ltd
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Publication date
Application filed by Wuhu City Tian Xiong New Material Science And Technology Ltd filed Critical Wuhu City Tian Xiong New Material Science And Technology Ltd
Priority to CN201610717727.0A priority Critical patent/CN106221489A/en
Publication of CN106221489A publication Critical patent/CN106221489A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32—Modified amine-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Architecture (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of automatically cleaning ornament materials for floor, component including following mass fraction: cyanurotriamide modified resin 50 80 parts, epoxy resin 68 parts, acrylic resin 25 parts, cetyl trimethylammonium bromide 0.3 0.5 parts, dodecylbenzene sodium sulfonate 0.4 0.6 parts, the waterglass 0.2 0.4 parts of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.2 0.4 parts, sodium metaaluminate 0.05 0.07 parts, preservative 0.12 0.15 parts, ferrous acid four butyl ester 0.03 0.05 parts etc..The present invention is antibacterial, antibacterial effect is excellent, long-acting, safety, and do not affect decorated material physical properties, surface decoration material is made to have high-temperature stability, antibacterial surface decorative material can be given with resistance to elevated temperatures, raw material plays synergism, make the material prepared give full play to adsorption, alleviate the pollution of harmful gas in environment.

Description

A kind of automatically cleaning ornament materials for floor
Technical field
The invention belongs to building material technical field, particularly relate to a kind of automatically cleaning ornament materials for floor.
Background technology
After timber floor purchase installation is in place, during life-time service, operational maintenance is most important, directly influences The service life on floor.Although consolidated floor has wear-resisting, corrosion-resistant, resistance to compression, shock resistance, it is simple to clean, nurse, dimensionally stable Property the plurality of advantages such as good, but the most still can not ignore scientific maintenance.Because having considerable problem all because floor uses Safeguard improper and cause.Often keep the dry and comfortable of floor and cleaning, do not rinse with substantial amounts of water, note avoiding local, floor long Phase soaks.If there have been oil stain and spot in floor, it should be noted that remove in time, can enter by domestic soft mild detergent warm water Row processes, and cleans preferably with the special floor-cleaning protection liquid supporting with floor.Not with aqueous alkali, oxalic acid, suds etc. Corrosive liquids contact floor surface, does not more come wiping floor with the inflammable articles such as gasoline and other high-temp liquids.Solid wood ground Plate, multi-layer solid wood floor is often waxed and can be kept gloss, reduces lacquer painting senile abrasion.In inorganic antiseptic, four needle-like oxygen Changing zinc crystal whisker materials is the class novel antibacterial material occurred in recent years, has zinc ion active antibacterial, ZnOw needle point Nano active is antibacterial, ZnOw elemental oxygen is antibacterial and the multiple antibacterial mechanism such as photo-catalytic antibacterial, fills at antimicrobial surface Application in exterior material.
Floor is the ornament materials of more environmental protection, but still suffers from trace formaldehyde residual, Er Qieren in the spray of floor Other building materials in habitat environment, such as various sheet materials etc., owing to employing Lauxite, melamine resin and phenolic resin Continuing release formaldehyde in surrounding Deng the binding agent with formaldehyde as raw material, cause room air pollution, harmful to human is good for Health.
In order to eliminate the pollution of indoor formaldehyde, prior art has been disclosed for multiple formaldehyde scavenger, by brushing, coating Or the method such as spraying is coated in pollutant surface and reaches to remove the purpose of formaldehyde.But, due to floor and other building materials continue, Release formaldehyde in air lentamente, needs periodically or non-periodically to use formaldehyde scavenger, operates comparatively laborious.And, formaldehyde Scavenger is generally Strong oxdiative reducing agent, is applied directly to floor or other building material surfaces can destroy U.S.s of floor and other building materials See.Therefore, how to produce a kind of ornament materials being applied to floor surface, there is the advantages such as antibacterial, environmental protection, practicality, can extensively answer For human settlement, it it is the technical problem to be solved in the present invention.
Summary of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposition one is antibacterial, antibacterial effect is excellent, long-acting, peace Entirely, and do not affect decorated material physical properties, make surface decoration material have high-temperature stability, antimicrobial surface can be given Ornament materials plays synergism with resistance to elevated temperatures, raw material, makes the material prepared give full play to adsorption, alleviate in environment The automatically cleaning ornament materials for floor of the pollution of harmful gas.
Technical scheme: a kind of automatically cleaning ornament materials for floor of the present invention, including following mass fraction Component:
Cyanurotriamide modified resin 50-80 part, epoxy resin 6-8 part, acrylic resin 2-5 part, cetyl trimethyl Ammonium bromide 0.3-0.5 part, dodecylbenzene sodium sulfonate 0.4-0.6 part, waterglass 0.2-0.4 part of silicon dioxide, four Needle-shape zinc oxide crystal whisker antibacterial 0.2-0.4 part, sodium metaaluminate 0.05-0.07 part, preservative 0.12-0.15 part, ferrum Acid four butyl ester 0.03-0.05 parts, calcium carbonate 0.2-0.4 part, surfactant 0.3-0.5 part, calcium carbonate 5-40 part, Medical stone powder 5-30 part, long fibre 0.1-1.5 part, chopped fiber 0.3-1.5 part, attapulgite 4.5-40 part, hydroxypropyl Ylmethyl cellulose 2-20 part.
Further, including the component of following mass fraction:
Cyanurotriamide modified resin 60-80 part, epoxy resin 6-8 part, acrylic resin 3-5 part, cetyl trimethyl Ammonium bromide 0.4-0.5 part, dodecylbenzene sodium sulfonate 0.5-0.6 part, waterglass 0.3-0.4 part of silicon dioxide, four Needle-shape zinc oxide crystal whisker antibacterial 0.3-0.4 part, sodium metaaluminate 0.06-0.07 part, preservative 0.13-0.15 part, ferrum Acid four butyl ester 0.04-0.05 parts, calcium carbonate 0.3-0.4 part, surfactant 0.4-0.5 part, calcium carbonate 20-40 Part, medical stone powder 10-30 part, long fibre 0.5-1.5 part, chopped fiber 0.5-1.5 part, attapulgite 20-40 part, hydroxyl Propyl methocel 10-20 part.
Further, including the component of following mass fraction:
Cyanurotriamide modified resin 70 parts, epoxy resin 7 parts, acrylic resin 4 parts, cetyl trimethylammonium bromide 0.4 Part, dodecylbenzene sodium sulfonate 0.5 part, the waterglass 0.3 part of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.3 Part, sodium metaaluminate 0.06 part, preservative 0.14 part, ferrous acid four butyl ester 0.04 part, calcium carbonate 0.3 part, surfactant 0.4 part, calcium carbonate 30 parts, medical stone powder 20 parts, long fibre 1 part, chopped fiber 1 part, attapulgite 30 parts, hydroxypropyl Methylcellulose 15 parts.
Further, described preservative be methyl parahydroxybenzoate and propyl p-hydroxybenzoate according to mol ratio 1: The mixture of 1-2 composition.
Further, described surfactant be dioctyl sulfosuccinate and fatty alcohol-polyoxyethylene ether according to mole Mixture than 1-2: 1 composition.
Beneficial effect: the present invention is antibacterial, antibacterial effect is excellent, long-acting, safety, and does not affect decorated Material Physics Matter, makes surface decoration material have high-temperature stability, can give antibacterial surface decorative material and send out with resistance to elevated temperatures, raw material Wave synergism, make the material prepared give full play to adsorption, alleviate the pollution of harmful gas in environment.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
A kind of automatically cleaning ornament materials for floor, including the component of following mass fraction:
Cyanurotriamide modified resin 50 parts, epoxy resin 6 parts, acrylic resin 2 parts, cetyl trimethylammonium bromide 0.3 part, dodecylbenzene sodium sulfonate 0.4 part, the waterglass 0.2 part of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.2 part, sodium metaaluminate 0.05 part, preservative 0.12 part, ferrous acid four butyl ester 0.03 part, calcium carbonate 0.2 part, surface activity Agent 0.3 part, calcium carbonate 5 parts, medical stone powder 5 parts, long fibre 0.1 part, chopped fiber 0.3 part, attapulgite 4.5 parts, hydroxyl Propyl methocel 2 parts.
Described preservative is methyl parahydroxybenzoate and propyl p-hydroxybenzoate forms according to mol ratio 1: 1 Mixture.
Described surfactant is that dioctyl sulfosuccinate and fatty alcohol-polyoxyethylene ether are according to mol ratio 1: 1 group The mixture become.
Embodiment 2
A kind of automatically cleaning ornament materials for floor, including the component of following mass fraction:
Cyanurotriamide modified resin 80 parts, epoxy resin 8 parts, acrylic resin 5 parts, cetyl trimethylammonium bromide 0.5 part, dodecylbenzene sodium sulfonate 0.6 part, the waterglass 0.4 part of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.4 part, sodium metaaluminate 0.07 part, preservative 0.15 part, ferrous acid four butyl ester 0.05 part, calcium carbonate 0.4 part, surface Activating agent 0.5 part, calcium carbonate 40 parts, medical stone powder 30 parts, long fibre 1.5 parts, chopped fiber 1.5 parts, attapulgite 40 parts of soil, hydroxypropyl methyl cellulose 20 parts.
Described preservative be methyl parahydroxybenzoate and propyl p-hydroxybenzoate according to mol ratio 1: 2 form mixed Compound.
Described surfactant is that dioctyl sulfosuccinate and fatty alcohol-polyoxyethylene ether are according to mol ratio 2: 1 groups The mixture become.
Embodiment 3
A kind of automatically cleaning ornament materials for floor, including the component of following mass fraction:
Cyanurotriamide modified resin 70 parts, epoxy resin 7 parts, acrylic resin 4 parts, cetyl trimethylammonium bromide 0.4 Part, dodecylbenzene sodium sulfonate 0.5 part, the waterglass 0.3 part of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.3 Part, sodium metaaluminate 0.06 part, preservative 0.14 part, ferrous acid four butyl ester 0.04 part, calcium carbonate 0.3 part, surfactant 0.4 part, calcium carbonate 30 parts, medical stone powder 20 parts, long fibre 1 part, chopped fiber 1 part, attapulgite 30 parts, hydroxypropyl Methylcellulose 15 parts.
Described preservative is that methyl parahydroxybenzoate and propyl p-hydroxybenzoate form according to mol ratio 1: 1 .5 Mixture.
Described surfactant is that dioctyl sulfosuccinate and fatty alcohol-polyoxyethylene ether are according to mol ratio 1.5: 1 The mixture of composition.
The present invention is antibacterial, antibacterial effect is excellent, long-acting, safety, and does not affect decorated material physical properties, makes surface fill Exterior material has high-temperature stability, can give antibacterial surface decorative material and play synergism with resistance to elevated temperatures, raw material, Make the material prepared give full play to adsorption, alleviate the pollution of harmful gas in environment.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.

Claims (5)

1. the automatically cleaning ornament materials for floor, it is characterised in that: include the component of following mass fraction:
Cyanurotriamide modified resin 50-80 part, epoxy resin 6-8 part, acrylic resin 2-5 part, cetyl trimethyl Ammonium bromide 0.3-0.5 part, dodecylbenzene sodium sulfonate 0.4-0.6 part, waterglass 0.2-0.4 part of silicon dioxide, four Needle-shape zinc oxide crystal whisker antibacterial 0.2-0.4 part, sodium metaaluminate 0.05-0.07 part, preservative 0.12-0.15 part, ferrum Acid four butyl ester 0.03-0.05 parts, calcium carbonate 0.2-0.4 part, surfactant 0.3-0.5 part, calcium carbonate 5-40 part, Medical stone powder 5-30 part, long fibre 0.1-1.5 part, chopped fiber 0.3-1.5 part, attapulgite 4.5-40 part, hydroxypropyl Ylmethyl cellulose 2-20 part.
A kind of automatically cleaning ornament materials for floor the most according to claim 1, it is characterised in that: include following quality The component of number:
Cyanurotriamide modified resin 60-80 part, epoxy resin 6-8 part, acrylic resin 3-5 part, cetyl trimethyl Ammonium bromide 0.4-0.5 part, dodecylbenzene sodium sulfonate 0.5-0.6 part, waterglass 0.3-0.4 part of silicon dioxide, four Needle-shape zinc oxide crystal whisker antibacterial 0.3-0.4 part, sodium metaaluminate 0.06-0.07 part, preservative 0.13-0.15 part, ferrum Acid four butyl ester 0.04-0.05 parts, calcium carbonate 0.3-0.4 part, surfactant 0.4-0.5 part, calcium carbonate 20-40 Part, medical stone powder 10-30 part, long fibre 0.5-1.5 part, chopped fiber 0.5-1.5 part, attapulgite 20-40 part, hydroxyl Propyl methocel 10-20 part.
A kind of automatically cleaning ornament materials for floor the most according to claim 1, it is characterised in that: include following quality The component of number:
Cyanurotriamide modified resin 70 parts, epoxy resin 7 parts, acrylic resin 4 parts, cetyl trimethylammonium bromide 0.4 Part, dodecylbenzene sodium sulfonate 0.5 part, the waterglass 0.3 part of silicon dioxide, four acicular type zinc oxide crystal whisker antibacterial 0.3 Part, sodium metaaluminate 0.06 part, preservative 0.14 part, ferrous acid four butyl ester 0.04 part, calcium carbonate 0.3 part, surfactant 0.4 part, calcium carbonate 30 parts, medical stone powder 20 parts, long fibre 1 part, chopped fiber 1 part, attapulgite 30 parts, hydroxypropyl Methylcellulose 15 parts.
A kind of automatically cleaning ornament materials for floor the most according to claim 1, it is characterised in that: described preservative is The mixture that methyl parahydroxybenzoate and propyl p-hydroxybenzoate form according to mol ratio 1: 1-2.
A kind of automatically cleaning ornament materials for floor the most according to claim 1, it is characterised in that: described surface activity Agent be dioctyl sulfosuccinate and fatty alcohol-polyoxyethylene ether according to mol ratio 1-2: the mixture of 1 composition.
CN201610717727.0A 2016-08-25 2016-08-25 A kind of automatically cleaning ornament materials for floor Pending CN106221489A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011744A (en) * 2017-05-23 2017-08-04 龚伟 Bright anti-fouling and self-cleaning paint of a kind of nanometer and preparation method thereof
CN107556791A (en) * 2017-08-31 2018-01-09 巢湖鹏远金属焊管有限公司 A kind of preparation technology of automatically cleaning pipeline external erosion shield
CN112892488A (en) * 2021-01-20 2021-06-04 常州大学 Honeycomb attapulgite clay material, preparation method and application
WO2022013076A1 (en) * 2020-07-15 2022-01-20 Nass Joerg Use of silicone to fill joints
CN115838556A (en) * 2022-12-16 2023-03-24 山东新升实业发展有限责任公司 Metal support anti-corrosion treatment material and production process thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000104016A (en) * 1998-09-28 2000-04-11 Gengen Kagaku Kogyo Kk Coating composition for flooring
CN104030611A (en) * 2014-05-30 2014-09-10 沈承舟 Diatom ooze environment-friendly decorating material
CN104194592A (en) * 2014-07-30 2014-12-10 青岛吉顺隆商贸有限公司 Long-acting wear-resisting floor paint
CN104710897A (en) * 2013-12-17 2015-06-17 郝明先 Decoration material coated on surface of floor
CN104962400A (en) * 2015-06-30 2015-10-07 青岛精石通精密机械制造有限公司 Cleanser special for wood floor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000104016A (en) * 1998-09-28 2000-04-11 Gengen Kagaku Kogyo Kk Coating composition for flooring
CN104710897A (en) * 2013-12-17 2015-06-17 郝明先 Decoration material coated on surface of floor
CN104030611A (en) * 2014-05-30 2014-09-10 沈承舟 Diatom ooze environment-friendly decorating material
CN104194592A (en) * 2014-07-30 2014-12-10 青岛吉顺隆商贸有限公司 Long-acting wear-resisting floor paint
CN104962400A (en) * 2015-06-30 2015-10-07 青岛精石通精密机械制造有限公司 Cleanser special for wood floor

Non-Patent Citations (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107011744A (en) * 2017-05-23 2017-08-04 龚伟 Bright anti-fouling and self-cleaning paint of a kind of nanometer and preparation method thereof
CN107556791A (en) * 2017-08-31 2018-01-09 巢湖鹏远金属焊管有限公司 A kind of preparation technology of automatically cleaning pipeline external erosion shield
WO2022013076A1 (en) * 2020-07-15 2022-01-20 Nass Joerg Use of silicone to fill joints
CN112892488A (en) * 2021-01-20 2021-06-04 常州大学 Honeycomb attapulgite clay material, preparation method and application
CN115838556A (en) * 2022-12-16 2023-03-24 山东新升实业发展有限责任公司 Metal support anti-corrosion treatment material and production process thereof
CN115838556B (en) * 2022-12-16 2024-01-23 山东新升实业发展有限责任公司 Metal support anti-corrosion treatment material and production process thereof

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Application publication date: 20161214