CN106221331B - A kind of inner wall mold-proof paint and preparation method thereof - Google Patents

A kind of inner wall mold-proof paint and preparation method thereof Download PDF

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Publication number
CN106221331B
CN106221331B CN201610776707.0A CN201610776707A CN106221331B CN 106221331 B CN106221331 B CN 106221331B CN 201610776707 A CN201610776707 A CN 201610776707A CN 106221331 B CN106221331 B CN 106221331B
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parts
proof paint
wall mold
mixture
water
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CN106221331A (en
Inventor
金立民
赵广庆
董娜
闫爱军
刘栋
冯云青
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Zhangjiakou Kaibo Feng Real Estate Development Co Ltd
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Zhangjiakou Kaibo Feng Real Estate Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of inner wall mold-proof paint and preparation method thereof, inner wall mold-proof paint is prepared from the following raw materials in parts by weight:20 30 parts of butyl acrylate, 15 25 parts of dibutyl phthalate, 20 30 parts of elastic emulsion, 10 20 parts of NPE, 20 30 parts of titanium dioxide, 10 20 parts of thickener, 10 30 parts of foaming agent, 20 30 parts of mould inhibitor, 10 20 parts of water-soluble silicon oil, 20 30 parts of deionized water.After coating of the present invention is applied, the coated film of formation has the advantages that tensile strength and fracture elongation are high, coated film flat smooth, exquisite in texture, with silk gloss, high covering power, strong adhesive force, splendid antibacterial and fungicidal properties, excellent water-alkali resistance performance, film can be scrubbed, and printing resistance is strong, and gloss is lasting, the present invention is applied to indoor interior wall, play waterproof, prevent blending mould proof effect, and with high durable, stain resistance, manufacturing cost is relatively low, toxic is relatively low, is adapted to promote the use of.

Description

A kind of inner wall mold-proof paint and preparation method thereof
Technical field
The present invention relates to a kind of inner wall mold-proof paint and preparation method thereof, belong to building coating field.
Background technology
The generation of mould not only declines the coating surface dicoration weathered, but also can cause paint film cracking or stripping Fall.The moist place of darkness of improper ventilation, material or production environment especially rich in microbial nutrition source, such as beer, beans system The industries such as product, plastic products, the breeding and growth of all very suitable mould of temperature and humidity and bacterium.If applied using general decor Material, will occur the erosion of mould in various degree, can gradually be faded, stain so that coming off by the later coating of mold corrosion.Have Machine antimildew disinfectant antimycotic antiseptic efficiency high, but there is long-term effect, heat resistance, the disadvantage of security difference, inorganic antimildew disinfectant It is mould proof to kill just on the contrary, its antimycotic antiseptic long-term effect, heat-resist and germicidal efficiency is lower slightly.
The content of the invention
The technical problem to be solved in the present invention is to overcome existing defect there is provided a kind of inner wall mold-proof paint and its preparation Method, the inner wall mold-proof paint can be coated in the building surface of humidity, and will not go mouldy.
In order to solve the above-mentioned technical problem, the invention provides following technical scheme:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:20-30 parts of butyl acrylate, O-phthalic 15-25 parts of dibutyl phthalate, 20-30 parts of elastic emulsion, 10-20 parts of NPE, 20-30 parts of titanium dioxide, thickener 10-20 parts, 10-30 parts of foaming agent, 20-30 parts of mould inhibitor, 10-20 parts of water-soluble silicon oil, 20-30 parts of deionized water.
In such scheme preferably, the thickener be polyacrylate, hydroxyethyl cellulose, methylcellulose, One or more in gelatin and guar gum.
In any of the above-described scheme preferably, the mould inhibitor is BIT, 2- (4- thiazoles Base) benzimidazole, double thiocarbamates, chloro- 2-N- octyl groups -3 (the 2H)-isothiazolones of 4,5- bis- and 2- octyl groups -3 (2H) - One or more in isothiazolone.
In any of the above-described scheme preferably, the foaming agent is N, N dinitrosopentamethlyene tetramines, benzene sulfonyl hydrazide With the one or more in azodicarbonamide.
The preparation method of inner wall mold-proof paint of the present invention, including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 5-10min is stirred under alkene ether, 1500-2000r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, thickener, foaming agent, mould inhibitor, water-soluble silicon oil and deionized water are added, 10-20min is stirred under 3000-4000r/min rotating speeds, mixture B is obtained;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Beneficial effects of the present invention:After coating of the present invention is applied, the coated film of formation has tensile strength and extension The high advantage of rate, coated film flat smooth, exquisite in texture, with silk gloss, high covering power, strong adhesive force, splendid antibacterial and Fungicidal properties, excellent water-alkali resistance performance, film can be scrubbed, and printing resistance is strong, and persistently, the present invention is applied in indoor gloss Wall, plays waterproof, prevents blending mould proof effect, and with high durable, stain resistance, manufacturing cost is relatively low, and toxic is relatively low, It is adapted to promote the use of.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:26 parts of butyl acrylate, phthalic acid two 20 parts of butyl ester, 24 parts of elastic emulsion, 17 parts of NPE, 23 parts of titanium dioxide, 14 parts of guar gum, azodicarbonamide 26 parts, 22 parts of 1,2- benzisothiazole-3-ketones, 14 parts of water-soluble silicon oil, 24 parts of deionized water.
The preparation method of the inner wall mold-proof paint, it is characterised in that:Including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 8min is stirred under alkene ether, 1800r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water are added Dissolubility silicone oil and deionized water, 15min is stirred under 3500r/min rotating speeds, obtains mixture B;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Embodiment 2:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:20 parts of butyl acrylate, phthalic acid two 15 parts of butyl ester, 20 parts of elastic emulsion, 10 parts of NPE, 20 parts of titanium dioxide, 10 parts of guar gum, azodicarbonamide 10 parts, 20 parts of 1,2- benzisothiazole-3-ketones, 10 parts of water-soluble silicon oil, 20 parts of deionized water.
The preparation method of the inner wall mold-proof paint, it is characterised in that:Including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 8min is stirred under alkene ether, 1800r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water are added Dissolubility silicone oil and deionized water, 15min is stirred under 3500r/min rotating speeds, obtains mixture B;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Embodiment 3:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:30 parts of butyl acrylate, phthalic acid two 25 parts of butyl ester, 30 parts of elastic emulsion, 20 parts of NPE, 30 parts of titanium dioxide, 20 parts of guar gum, azodicarbonamide 30 parts, 30 parts of 1,2- benzisothiazole-3-ketones, 20 parts of water-soluble silicon oil, 30 parts of deionized water.
The preparation method of the inner wall mold-proof paint, it is characterised in that:Including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 8min is stirred under alkene ether, 1800r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water are added Dissolubility silicone oil and deionized water, 15min is stirred under 3500r/min rotating speeds, obtains mixture B;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Embodiment 4:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:30 parts of butyl acrylate, phthalic acid two 25 parts of butyl ester, 30 parts of elastic emulsion, 20 parts of NPE, 30 parts of titanium dioxide, 20 parts of methylcellulose, N, N bis- are sub- 30 parts of five methine tetramine of nitro, 30 parts of 2- (4- thiazolyls) benzimidazole, 20 parts of water-soluble silicon oil, 30 parts of deionized water.
The preparation method of the inner wall mold-proof paint, it is characterised in that:Including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 5min is stirred under alkene ether, 1500r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water are added Dissolubility silicone oil and deionized water, 10min is stirred under 3000r/min rotating speeds, obtains mixture B;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Embodiment 5:
A kind of inner wall mold-proof paint, is prepared from the following raw materials in parts by weight:30 parts of butyl acrylate, phthalic acid two 25 parts of butyl ester, 30 parts of elastic emulsion, 20 parts of NPE, 30 parts of titanium dioxide, 20 parts of polyacrylate, benzene sulfonyl hydrazide 30 parts, 30 parts of double thiocarbamates, 20 parts of water-soluble silicon oil, 30 parts of deionized water.
The preparation method of the inner wall mold-proof paint, it is characterised in that:Including following steps:
(1) in Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and polyoxyethylene nonyl phenyl second are added 10min is stirred under alkene ether, 2000r/min rotating speeds, mixture A is obtained;
(2) in Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water are added Dissolubility silicone oil and deionized water, 20min is stirred under 4000r/min rotating speeds, obtains mixture B;
(3) the mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
Embodiment 1-5 product passes through performance measurement, the results are shown in Table 1.
Table 1, performance measurement
The test of sterilizing rate is as follows:Bacterium solution (Escherichia coli, black-koji mould) is spread evenly across to the load for scribbling above-mentioned coating On glass side, it is placed in through 0, after 4,12,24,48,100 hours in physiological saline with picking bacterium solution, takes 0.5ml in culture dish, plus Enter culture medium, cultivated 48 hours in incubator, take out number clump count, sterilizing rate is calculated according to formula:Sterilizing rate=(initial bacterium Fall clump count after number-sterilization)/initial clump count × 100%, it the results are shown in Table 2.
The bactericidal property of table 2 is tested
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic. Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention's Within protection domain.

Claims (2)

1. a kind of inner wall mold-proof paint, it is characterised in that:It is prepared from the following raw materials in parts by weight:26 parts of butyl acrylate, neighbour 20 parts of dibatyl phithalate, 24 parts of elastic emulsion, 17 parts of NPE, 23 parts of titanium dioxide, 14 parts of guar gum, idol 26 parts of nitrogen diformamide, 22 parts of 1,2- benzisothiazole-3-ketones, 14 parts of water-soluble silicon oil, 24 parts of deionized water.
2. the preparation method of inner wall mold-proof paint according to claim 1, it is characterised in that:Including following steps:
(1)In Scattered Kettle, butyl acrylate, dibutyl phthalate, elastic emulsion and NPE are added, 5-10min is stirred under 1500-2000r/min rotating speeds, mixture A is obtained;
(2)In Scattered Kettle, titanium dioxide, guar gum, azodicarbonamide, BIT, water solubility are added Silicone oil and deionized water, stir 10-20min under 3000-4000 r/min rotating speeds, obtain mixture B;
(3)The mixture A and mixture B mixing, obtains the inner wall mold-proof paint.
CN201610776707.0A 2016-08-31 2016-08-31 A kind of inner wall mold-proof paint and preparation method thereof Active CN106221331B (en)

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CN109880413A (en) * 2019-01-15 2019-06-14 河北晨阳工贸集团有限公司 A kind of disinsection mold-proof interior wall coating and preparation method thereof
CN112430403A (en) * 2020-10-19 2021-03-02 江苏汉卫环境安全科技有限公司 Antibacterial coating for mobile laboratory

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CN105086539A (en) * 2015-09-01 2015-11-25 天长市开林化工有限公司 Formaldehyde-removal health emulsion paint with addition of adsorbing filler and preparation method thereof

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