CN106221034A - A kind of Halogen thermoplastic flame-proof cable material - Google Patents

A kind of Halogen thermoplastic flame-proof cable material Download PDF

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Publication number
CN106221034A
CN106221034A CN201610747443.6A CN201610747443A CN106221034A CN 106221034 A CN106221034 A CN 106221034A CN 201610747443 A CN201610747443 A CN 201610747443A CN 106221034 A CN106221034 A CN 106221034A
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parts
ethylene
maleic anhydride
copolymer
mixture
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雷开明
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Sichuan Jinkai Specialty Wire And Cable Co Ltd
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Sichuan Jinkai Specialty Wire And Cable Co Ltd
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Priority to CN201610747443.6A priority Critical patent/CN106221034A/en
Publication of CN106221034A publication Critical patent/CN106221034A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses the cable material in a kind of wire cable material field, particularly to a kind of Halogen thermoplastic flame-proof cable material, it includes by weight: (1), ethylene and copolymer 20 parts thereof；(2), thermoplastic elastomer (TPE) 60 parts；(3), polyethylene/propylene 7 parts；(4), compatilizer 5 parts；(5), 3 parts of modified polyphenylene ether resin powder；(6), fire retardant 100 parts；(7), auxiliary agent 2 parts；(8), ethylene propylene diene rubber 100 parts；(9), SEBS503 and/or maleic anhydride-g-SBS 150 parts；(10), plasticising softening agent 150 parts；(11), pigment 2 parts；(12), cross-linking agent 6 parts；(13), liquid strengthens softened rubber 88 parts；(14), reinforcing agent 99 parts.The cable that the cable material of the present invention is produced has the features such as the combustion-supporting property of excellence, pliability, resistance to impact, environmental stress resistance, does not haves crackle so that ftractureing.With the addition of filler, make cable sheath thermal stability good.

Description

A kind of Halogen thermoplastic flame-proof cable material
Technical field
The present invention relates to the cable material in a kind of wire cable material field, particularly to a kind of Halogen thermoplastic flame-proof cable material.
Background technology
Along with global economy fast development, the understanding of people's initiation fire aging to electric wire accident is constantly strengthened, right The environment friendly of electric wire requires more and more higher.The harm of human body and environment is by the poison gas that halogen burning produces Well-known.So, the mortality rate when occurrence index caused by electric wire and breaking out of fire how is reduced？Low cigarette, Halogen, fire-retardant, environmental protection, the developing direction becoming wires and cables industry such as high temperature resistant.Halogen-free flame-retardant wire cable, it is possible to well Solve the contaminative to environment and the person is produced the problem of injury, but being to meet Flame Retardancy and physical and mechanical properties Balance, adds antimony oxide sometimes in halogen-free flame-retardant system, and antimony oxide, during production and processing and using, connects Touch after human body skin, human body can be produced certain harm (skin pruritus, redness), more seriously causing death, at present Electric wire containing antimony oxide is the most clearly prohibitted the use of by some terminal clients.
At present, existing CABLE MATERIALS uses Low Density Polyethylene (LDPE) and ethylene-vinyl acetate copolymer (EVA) to be base Quasi-raw material adds fire retardant and auxiliary agent is plasticated and made.Product hardness, between 90-93 degree A, uses middle inconvenience to move, bend.Resistance Combustion type Plastic-sheathed Cable material uses neoprene (CR) and chlorinated polyethylene (CPE), and flame-retardant system uses antimony oxide, ten bromines two Phenylate, chlorinated paraffin, phosphate ester, i.e. antimony-chloro-bromo-phosphorus flame-retardant system.Because of in a large amount of halogens and rubber itself containing a large amount of chlorine from Son, will necessarily produce a large amount of hydrogen halide during burning and be fire-retardant, forms strong the suffocating and to ring to life entity The severe contamination in border.Further, in the production process of existing domestic production technique, need to add the sulfuration of certain toxic side effect Auxiliary agent is (steam pipeline) sulfuration under high temperature, condition of high voltage, and equipment is complicated, and capital intensive, in raw and auxiliary material and reaction by-product There is a large amount of poisonous and harmful substances, in production process there is serious hidden danger in high temperature, high pressure；Produce simultaneously and consume greatly, useless Product rate is high, causes production cost to improve；And there is a large amount of " three wastes " discharge, form rugged environment and pollute.It can be said that existing work Skill belongs to the handicraft product of " high energy consumption, maximum discharge, high pollution ", does not meets current national product, industrial policy and development completely Long-term interest.Therefore, halogen-free stibium-free high fire-retardance thermoplastic cable material is the development trend of current wires and cables industry.
Summary of the invention
It is an object of the invention to overcome the above-mentioned deficiency in the presence of prior art, it is provided that a kind of Halogen thermoplastic flame-proof Cable material.
In order to realize foregoing invention purpose, the invention provides techniques below scheme: a kind of Halogen thermoplastic flame-proof cable Expecting, it includes by weight:
(1), ethylene and copolymer 20 parts, described ethylene and copolymer thereof are ethylene-vinyl acetate copolymer, ethylene-the third One or more mixture of olefin(e) acid methacrylate copolymers or ethylene-methyl acrylate copolymer；
(2), thermoplastic elastomer (TPE) 60 parts, described thermoplastic elastomer (TPE) be styrene isoprene styrene block copolymer (SIS), One or more are mixed for styrene butadiene styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymers Compound；
(3), polyethylene/propylene 7 parts, described polyethylene/propylene is Low Density Polyethylene, linear low density polyethylene, high density One or more mixture in polyethylene, metallocene PE, polypropylene；
(4), compatilizer 5 parts, described compatilizer be maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride grafting second Alkene-octene copolymer, maleic anhydride grafted ethene-methyl acrylate copolymer, maleic anhydride grafted linear low density polyethylene, One or more mixture in maleic anhydride inoculated polypropylene；
(5), 3 parts of modified polyphenylene ether resin powder, described modified polyphenylene ether resin powder be intrinsic viscosity at 30 DEG C in chloroform survey It is set to the modified polyphenylene ether resin powder of 0.3-0.55dl/g；
(6), fire retardant 100 parts, described fire retardant is in hydroxide, organic hypophosphite fire retardant, melamine compound One or more compounding form；
(7), auxiliary agent 2 parts, described auxiliary agent is zinc stearate, stearic acid, Tissuemat E, antioxidant, UV absorbent, hydroxide Magnesium, aluminium hydroxide, Firebrake ZB, lubricant, antioxidant, one or more mixture of crosslinking coagent TAIC；
(8), ethylene propylene diene rubber 100 parts, ethylene propylene diene rubber be du pont company produce 4725P and 3722P in one Plant or two kinds；
(9), SEBS503 and/or maleic anhydride-g-SBS 150 parts；
(10), plasticising softening agent 150 parts, described plasticising softening agent one or several in naphthenic oil, 26# white oil, the 32# white oil Kind；
(11), pigment 2 parts, described pigment be selected from titanium dioxide, fluorescent whitening agent, pthalocyanine blue, phthalocyanine green, lithol rubine, lithol You are bright red, one or more in permanent yellow, benzidine yellow, white carbon black；
Also include: cross-linking agent 6 parts, described cross-linking agent selected from double (t-butylperoxyisopropyl) benzene and 2,5-dimethyl-2,5 One or both in (dual-tert-butyl peroxidating) hexane；
Liquid strengthens softened rubber 88 parts, and it is in liquid polyisobutene and liquid polybutadiene that described liquid strengthens softened rubber One or both；
Reinforcing agent 99 parts, described reinforcing agent selected from polypropylene, the maleic anhydride inoculated polypropylene of percent grafting 2wt%-9wt%, third Alkene nitrile-BS, percent grafting 9wt%-15wt% maleic anhydride grafted polystyrene in one or several Kind.
Described wherein hydroxide is one or both mixture in magnesium hydroxide, aluminium hydroxide；
Organic hypophosphite fire retardant is methyl hypo-aluminum orthophosphate, Methylethyl hypo-aluminum orthophosphate, phenyl hypo-aluminum orthophosphate, divinyl One or more mixture in aluminum phosphate, divinyl zinc hypophosphite fire retardant；
Melamine compound is the one in melamine cyanurate, melamine pyrophosphate, polyphosphoric acid melamine or many Plant mixture.
Compared with prior art, beneficial effects of the present invention: the cable that the cable material of the present invention is produced has excellence The features such as combustion-supporting property, pliability, resistance to impact, environmental stress resistance, do not have crackle so that ftractureing, simultaneously in order to overcome it easy The shortcoming of combustion, with the addition of a series of auxiliary agent such as aluminium hydroxide, magnesium hydroxide.Improve the flame-retarding characteristic of cable sheath, be both not Add the material of halide, make cable sheath Halogen.With the addition of filler, make cable sheath thermal stability good.
Detailed description of the invention
Below in conjunction with test example and detailed description of the invention, the present invention is described in further detail.But this should not understood Scope for the above-mentioned theme of the present invention is only limitted to below example, and all technology realized based on present invention belong to this The scope of invention.
Embodiment 1
A kind of Halogen thermoplastic flame-proof cable material, it includes by weight:
(1), ethylene and copolymer 20 parts, described ethylene and copolymer thereof are ethylene-vinyl acetate copolymer, ethylene-the third Two kinds of mixture of olefin(e) acid methacrylate copolymers, ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer are respectively 8 parts With 12 parts；
(2), thermoplastic elastomer (TPE) 60 parts, described thermoplastic elastomer (TPE) be styrene isoprene styrene block copolymer (SIS), Styrene butadiene styrene block copolymer (SBS), three kinds of mixture of hydrogenated styrene-butadiene-styrene block copolymers, Described thermoplastic elastomer (TPE) be styrene isoprene styrene block copolymer (SIS), s-B-S block altogether Polymers, three kinds of mixture of hydrogenated styrene-butadiene-styrene block copolymers are respectively 21 parts, 22 parts and 17 parts；
(3), polyethylene/propylene 7 parts, described polyethylene/propylene is Low Density Polyethylene, linear low density polyethylene, high density Polyethylene, four kinds of mixture of metallocene PE, described polyethylene/propylene be Low Density Polyethylene, linear low density polyethylene, High density polyethylene (HDPE), metallocene PE are respectively 1 part, 2 parts, 1 part, 3 parts；
(4), compatilizer 5 parts, described compatilizer be maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride grafting second Two kinds of mixture of alkene-octene copolymer, described maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride grafted ethene- Two kinds of mixture of octene copolymer are respectively 2 parts and 3 parts；
(5), 3 parts of modified polyphenylene ether resin powder, described modified polyphenylene ether resin powder be intrinsic viscosity at 30 DEG C in chloroform survey It is set to the modified polyphenylene ether resin powder of 0.3-0.55dl/g；
(6), fire retardant 100 parts, described fire retardant is hydroxide, organic hypophosphite fire retardant two kinds is compounding forms, described Hydroxide, organic hypophosphite fire retardant are respectively 42 parts and 58 parts；
(7), auxiliary agent 2 parts, described auxiliary agent is magnesium hydroxide, two kinds of mixture of aluminium hydroxide, is respectively 1 part；
(8), ethylene propylene diene rubber 100 parts, ethylene propylene diene rubber be du pont company produce 4725P；
(9), SEBS503 and/or maleic anhydride-g-SBS 150 parts；
(10), plasticising softening agent 150 parts, described plasticising softening agent be selected from naphthenic oil；
(11), pigment 2 parts, described pigment be selected from titanium dioxide, fluorescent whitening agent two kinds, respectively 1 part；
Also including: cross-linking agent 6 parts, described cross-linking agent is selected from double (t-butylperoxyisopropyl) benzene；
Liquid strengthens softened rubber 88 parts, and it is liquid polyisobutene that described liquid strengthens softened rubber；
Reinforcing agent 99 parts, described reinforcing agent selected from polypropylene, acrylonitrile-butadiene-styrene copolymer, two kinds, respectively 32 Part and 67 parts.
Described wherein hydroxide is magnesium hydroxide, two kinds of mixture of aluminium hydroxide；
Organic hypophosphite fire retardant is methyl hypo-aluminum orthophosphate, Methylethyl hypo-aluminum orthophosphate, phenyl hypo-aluminum orthophosphate, divinyl Three kinds of mixture of aluminum phosphate；
Melamine compound is melamine cyanurate, two kinds of mixture of melamine pyrophosphate.

Claims (2)

1. a Halogen thermoplastic flame-proof cable material, it is characterised in that: it includes by weight:
(1), ethylene and copolymer 20 parts, described ethylene and copolymer thereof are ethylene-vinyl acetate copolymer, ethylene-the third One or more mixture of olefin(e) acid methacrylate copolymers or ethylene-methyl acrylate copolymer；
(2), thermoplastic elastomer (TPE) 60 parts, described thermoplastic elastomer (TPE) be styrene isoprene styrene block copolymer (SIS), One or more are mixed for styrene butadiene styrene block copolymer (SBS), hydrogenated styrene-butadiene-styrene block copolymers Compound；
(3), polyethylene/propylene 7 parts, described polyethylene/propylene is Low Density Polyethylene, linear low density polyethylene, high density One or more mixture in polyethylene, metallocene PE, polypropylene；
(4), compatilizer 5 parts, described compatilizer be maleic anhydride grafted ethene-acetate ethylene copolymer, maleic anhydride grafting second Alkene-octene copolymer, maleic anhydride grafted ethene-methyl acrylate copolymer, maleic anhydride grafted linear low density polyethylene, One or more mixture in maleic anhydride inoculated polypropylene；
(5), 3 parts of modified polyphenylene ether resin powder, described modified polyphenylene ether resin powder be intrinsic viscosity at 30 DEG C in chloroform survey It is set to the modified polyphenylene ether resin powder of 0.3-0.55dl/g；
(6), fire retardant 100 parts, described fire retardant is in hydroxide, organic hypophosphite fire retardant, melamine compound One or more compounding form；
(7), auxiliary agent 2 parts, described auxiliary agent is magnesium hydroxide, aluminium hydroxide, Firebrake ZB, lubricant, antioxidant, crosslinking coagent TAIC One or more mixture；
(8), ethylene propylene diene rubber 100 parts, ethylene propylene diene rubber be du pont company produce 4725P and 3722P in one Plant or two kinds；
(9), SEBS503 and/or maleic anhydride-g-SBS 150 parts；
(10), plasticising softening agent 150 parts, described plasticising softening agent one or several in naphthenic oil, 26# white oil, the 32# white oil Kind；
(11), pigment 2 parts, described pigment be selected from titanium dioxide, fluorescent whitening agent, pthalocyanine blue, phthalocyanine green, lithol rubine, lithol You are bright red, one or more in permanent yellow, benzidine yellow, white carbon black.
A kind of Halogen thermoplastic flame-proof cable material the most according to claim 1, it is characterised in that:
Also include: cross-linking agent 6 parts, described cross-linking agent selected from double (t-butylperoxyisopropyl) benzene and 2,5-dimethyl-2,5 One or both in (dual-tert-butyl peroxidating) hexane；
Liquid strengthens softened rubber 88 parts, and it is in liquid polyisobutene and liquid polybutadiene that described liquid strengthens softened rubber One or both；
Reinforcing agent 99 parts, described reinforcing agent selected from polypropylene, the maleic anhydride inoculated polypropylene of percent grafting 2wt%-9wt%, third Alkene nitrile-BS, percent grafting 9wt%-15wt% maleic anhydride grafted polystyrene in one or several Kind；One or more in zinc stearate, stearic acid, Tissuemat E, antioxidant, UV absorbent of described auxiliary agent；
Described wherein hydroxide is one or both mixture in magnesium hydroxide, aluminium hydroxide；
Organic hypophosphite fire retardant is methyl hypo-aluminum orthophosphate, Methylethyl hypo-aluminum orthophosphate, phenyl hypo-aluminum orthophosphate, divinyl One or more mixture in aluminum phosphate, divinyl zinc hypophosphite fire retardant；
Melamine compound is the one in melamine cyanurate, melamine pyrophosphate, polyphosphoric acid melamine or many Plant mixture.
CN201610747443.6A 2016-08-29 2016-08-29 A kind of Halogen thermoplastic flame-proof cable material Pending CN106221034A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880378A (en) * 2017-12-27 2018-04-06 常熟市中联光电新材料有限责任公司 A kind of small line footpath phosphorus flame retardant etc. and preparation method thereof
CN108384126A (en) * 2018-02-07 2018-08-10 合肥安力电力工程有限公司 A kind of CABLE MATERIALS and preparation method thereof with flame retarding function
CN108485011A (en) * 2018-03-09 2018-09-04 安徽中意胶带有限责任公司 A kind of green energy conservation abrasion-proof and cold-resistant flame retarded thermoplastic's rubber and preparation method thereof
CN108530764A (en) * 2018-03-09 2018-09-14 安徽中意胶带有限责任公司 A kind of thermoplastic elastomer (TPE) of halogen-free flame-retardant and preparation method thereof
CN114292461A (en) * 2021-12-24 2022-04-08 太仓迎聚新材料科技有限公司 Irradiation crosslinking halogen-free flame-retardant polyolefin material for new energy automobile line and preparation method and application thereof
WO2022135271A1 (en) * 2020-12-24 2022-06-30 金发科技股份有限公司 Ultra-soft b1-level low-smoke halogen-free flame-retardant sheath material and preparation method therefor

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880378A (en) * 2017-12-27 2018-04-06 常熟市中联光电新材料有限责任公司 A kind of small line footpath phosphorus flame retardant etc. and preparation method thereof
CN108384126A (en) * 2018-02-07 2018-08-10 合肥安力电力工程有限公司 A kind of CABLE MATERIALS and preparation method thereof with flame retarding function
CN108485011A (en) * 2018-03-09 2018-09-04 安徽中意胶带有限责任公司 A kind of green energy conservation abrasion-proof and cold-resistant flame retarded thermoplastic's rubber and preparation method thereof
CN108530764A (en) * 2018-03-09 2018-09-14 安徽中意胶带有限责任公司 A kind of thermoplastic elastomer (TPE) of halogen-free flame-retardant and preparation method thereof
CN108485011B (en) * 2018-03-09 2020-11-17 安徽中意胶带有限责任公司 Green energy-saving wear-resistant cold-resistant flame-retardant thermoplastic rubber and preparation method thereof
CN108530764B (en) * 2018-03-09 2020-12-15 安徽中意胶带有限责任公司 Halogen-free flame-retardant thermoplastic elastomer and preparation method thereof
WO2022135271A1 (en) * 2020-12-24 2022-06-30 金发科技股份有限公司 Ultra-soft b1-level low-smoke halogen-free flame-retardant sheath material and preparation method therefor
CN114292461A (en) * 2021-12-24 2022-04-08 太仓迎聚新材料科技有限公司 Irradiation crosslinking halogen-free flame-retardant polyolefin material for new energy automobile line and preparation method and application thereof
CN114292461B (en) * 2021-12-24 2023-11-24 太仓迎聚新材料科技有限公司 Irradiation crosslinking halogen-free flame-retardant polyolefin material for new energy automobile wires and preparation method and application thereof

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Application publication date: 20161214