CN106205859A - The preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire - Google Patents
The preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire Download PDFInfo
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- CN106205859A CN106205859A CN201610480406.3A CN201610480406A CN106205859A CN 106205859 A CN106205859 A CN 106205859A CN 201610480406 A CN201610480406 A CN 201610480406A CN 106205859 A CN106205859 A CN 106205859A
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- terbium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
- C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
- C23C18/2073—Multistep pretreatment
- C23C18/2086—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
Abstract
The invention belongs to wearable electronic technical field, relate to the preparation method of a kind of terbium tin-nickel alloy/bamboo fibre electronic wire.The preparation method of this electronic wire include bamboo fibre clean, surface modification, catalytic activation and chemical plating terbium tin-nickel alloy.The advantage of preparation method of the present invention is: through 180 days simulated body fluid corrosion tests, metal ion flood rate had high biotic environment reliability less than 1ppm, i.e. this material；The electrical conductivity of electronic wire is higher than copper, reaches 8 × 107More than S/m.Terbium tin-nickel alloy/bamboo fibre electronic wire can be used for intelligent clothing, and application prospect is bright and clear, and market potential is huge.
Description
Technical field
The invention belongs to wearable electronic technical field, relate to the preparation of a kind of terbium tin-nickel alloy/bamboo fibre electronic wire
Method.
Background technology
Wearable intelligent clothing is to use sensing device to obtain physiology signal, is sent to backstage electricity by bluetooth module
It is analyzed on brain, record.The combination development of information technology and sensor technology at present so that wearable smart machine becomes
One popular developing direction of health-care.By these Wearable, use noninvasive detection mode, it is possible to old age
The health status of people carries out real-time monitoring, timely prophylactic generation.There is the advantages such as easy to detect, with low cost, especially
It is that the detection to chronic disease has the effect do not replaced.On acute illness prevents, there is danger at wearer in intelligent clothing
And during the physiological reaction of life, it is possible to decrease the probability of sudden death.In chronic disease context of detection, the U.S. develops one i.e.
Time monitoring of physiologic health status intelligent clothing, data are processed and send the result to hospital after interpretation to doctor by system
Diagnosis, can grasp wearer's body health status in time, additionally, obtain the HRV analysis of electrocardiosignal for intelligent clothing, right
In slight or serious depression, chronic obstructive pulmonary disease, the medical diagnosis on disease such as children with attention deficit hyperactivity disorder has bright
Aobvious help.
Bamboo fibre is the cellulose fibre that extracts from the bamboo of growth naturally, the fifth-largest after cotton, fiber crops, hair, silk
Natural fiber.Bamboo fiber yarn is used for garment material, bed-mat for summer, sheet, curtain, scarf etc., as used the method with polyvinyl blending
Frivolous garment material can be produced.Carry out blending with cotton, hair, fiber crops, thin,tough silk and chemical fibre, for woven or knitting, produce various rule
The woven fabric of lattice and knitting fabric.Woven fabric can be used for making curtain, jacket, easy dress, Western-style clothes suit, shirt, bed
List and towel, bath towel etc..Knitting fabric suitable for making underwear, undershirt, T-shirt, socks etc..Bamboo fiber content less than 30%
Bamboo cotton blending yarn is more suitable for underwear, socks, it is also possible to be used for making medical treatment and nursing articles for use.
For the electronic wire of wearable garment, due to health Long contact time, there is risk in safety problem, special always
It not the application containing metal electron conduction, in human sweat's environment, the spilling of electronic wire metal ion, unfavorable to human body.
The present invention is to be coated with terbium tin-nickel alloy layer on bamboo surface, and core process is under copper cobalt composite catalyzing activates, in chemical plating
In solution, rare earth element terbium enters in the lattice of tin-nickel alloy, forms more form compact and stable alloy-layer, simulates people through 180 days
Body corrosion in body fluid is tested, and the metal ion flood rate of terbium tin-nickel alloy/bamboo fibre electronic wire is less than 1/1000000th (1ppm),
Illustrate that this material has high biotic environment reliability；The electrical conductivity of terbium tin-nickel alloy/bamboo fibre electronic wire is higher than copper, reaches
To 8 × 107More than S/m, is best in current all conduction bamboo composites.In sum, the terbium stannum nickel that the present invention proposes
The preparation method of alloy/bamboo fibre electronic wire has prominent substantive distinguishing features and significantly progress, i.e. possesses creativeness.
Summary of the invention
The invention belongs to wearable electronic field, relate to the preparation method of a kind of terbium tin-nickel alloy/bamboo fibre electronic wire.
The step of this preparation method is as follows:
1) by bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionization
Water is cleaned, is dried；
2) clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven that to be dried 3 in 60 DEG C little
Time, it is cooled to room temperature, obtains modified bamboo fiber；Wherein the formula of modifier solution be solvent be deionized water, various molten in solution
Matter concentration is respectively as follows: chitosan concentration 3～6g/L, methyl methacrylate concentration 9～12g/L, performic acid concentration 1～3g/L,
Oxolane concentration 100～200g/L.
3) modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in
Weight percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre；Wherein activator
The formula of solution be solvent be deionized water, in solution, various solute concentrations are respectively as follows: cobaltic chloride concentration 20～30g/L, sulfur
Acid copper concentration 20～30g/L, sodium tartrate potassium concn 20～30g/L.
4) activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Obtain terbium tin-nickel alloy/bamboo fibre electronic wire.Wherein the formula of terbium stannum nickel chemical plating solution be solvent be deionized water, in solution
Various solute concentrations are respectively as follows: Terbium nitrate (Tb(NO3)3) concentration 20～30g/L；Concentration of nickel sulfate 20～30g/L；Stannous chloride concentration 40～
60g/L；Sodium bicarbonate concentration 30～60g/L；Sodium tartrate potassium concn 60～90g/L；Dimethylamino borane concentration 3～6g/L；
Ammonium succinate concentration 6～9g/L.
5) terbium tin-nickel alloy/bamboo fibre electronic wire test characterizes.Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in mould
Intend, in human body fluid, placing 180 days in 37 DEG C, take out, with the unit of Energy Dispersive X-ray detector (EDX) test electronic wire
Cellulose content, calculates terbium, stannum, the flood rate of nickel ion；Electrical conductivity with four-point probe test electronic wire.Wherein simulate people
The each component content of body body fluid: NaCl 8g/L, KCl 0.4g/L, NaHCO30.35g/L, CaCl20.14g/L, Na2HPO4
0.06g/L, KH2PO40.06g/L, MgSO4.7H2O 0.2g/L, glucose 1g/L.
Terbium tin-nickel alloy/bamboo fibre electronic wire can be used for wearable garment, and application prospect is bright and clear, and market potential is huge.
Detailed description of the invention
The invention is further illustrated by the following examples
Embodiment 1
By bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionized water
Clean, dry.
By 3.5g chitosan, 9.6g methyl methacrylate, 2.7g performic acid is dissolved in 168g oxolane, add go from
Sub-water, is made into the modifier solution that volume is 1L.
Clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C,
It is cooled to room temperature, obtains modified bamboo fiber.
By 23.2g cobaltic chloride, 26.5g copper sulfate, 29.5g potassium sodium tartrate is dissolved in 500mL deionized water, then dilutes
Becoming volume is the activator solution of 1L.
Modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Amount percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre.
By 21.5g Terbium nitrate (Tb(NO3)3), 23.5g nickel sulfate, 45.5g stannous chloride, 57.5g sodium bicarbonate, 79.5g sodium tartrate
Potassium, 4.1g dimethylamino borine, 8.1g ammonium succinate is dissolved in 500mL deionized water, then is diluted to the terbium stannum nickel that volume is 1L
Chemical plating solution.
Activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Terbium tin-nickel alloy/bamboo fibre electronic wire.
By 8g NaCl, 0.4g KCl, 0.35g NaHCO3, 0.14g CaCl2, 0.06g Na2HPO4, 0.06g KH2PO4,
0.2g MgSO4.7H2O, 1g glucose is dissolved in 500mL deionized water, then is diluted to the simulated body fluid that volume is 1L.
Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in simulated body fluid, places 180 days in 37 DEG C, take out, with
The constituent content of Energy Dispersive X-ray detector (EDX) test electronic wire, calculating terbium, stannum, the flood rate of nickel ion are respectively
0.11ppm、0.35ppm、0.15ppm；The electrical conductivity of electronic wire is tested for 8.7 × 10 with four-point probe7S/m。
Embodiment 2
By bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionized water
Clean, dry.
By 4.4g chitosan, 10.2g methyl methacrylate, 2.6g performic acid is dissolved in 155g oxolane, and interpolation is gone
Ionized water, is made into the modifier solution that volume is 1L.
Clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C,
It is cooled to room temperature, obtains modified bamboo fiber.
By 21.5g cobaltic chloride, 24.1g copper sulfate, 27.1g potassium sodium tartrate is dissolved in 500mL deionized water, then dilutes
Becoming volume is the activator solution of 1L.
Modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Amount percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre.
By 26.8g Terbium nitrate (Tb(NO3)3), 24.9g nickel sulfate, 52.4g stannous chloride, 56.2g sodium bicarbonate, 89.6g sodium tartrate
Potassium, 4.8g dimethylamino borine, 6.7g ammonium succinate is dissolved in 500mL deionized water, then is diluted to the terbium stannum nickel that volume is 1L
Chemical plating solution.
Activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Terbium tin-nickel alloy/bamboo fibre electronic wire.
By 8g NaCl, 0.4g KCl, 0.35g NaHCO3, 0.14g CaCl2, 0.06g Na2HPO4, 0.06g KH2PO4,
0.2g MgSO4.7H2O, 1g glucose is dissolved in 500mL deionized water, then is diluted to the simulated body fluid that volume is 1L.
Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in simulated body fluid, places 180 days in 37 DEG C, take out, with
The constituent content of Energy Dispersive X-ray detector (EDX) test electronic wire, calculating terbium, stannum, the flood rate of nickel ion are respectively
0.11ppm、0.14ppm、0.27ppm；The electrical conductivity of electronic wire is tested for 8.5 × 10 with four-point probe7S/m。
Embodiment 3
By bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionized water
Clean, dry.
By 6g chitosan, 12g methyl methacrylate, 3g performic acid is dissolved in 200g oxolane, adds deionized water,
It is made into the modifier solution that volume is 1L.
Clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C,
It is cooled to room temperature, obtains modified bamboo fiber.
By 30g cobaltic chloride, 30g copper sulfate, 30g potassium sodium tartrate is dissolved in 500mL deionized water, then is diluted to volume
Activator solution for 1L.
Modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Amount percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre.
By 30g Terbium nitrate (Tb(NO3)3), 30g nickel sulfate, 60g stannous chloride, 60g sodium bicarbonate, 90g potassium sodium tartrate, 6g diformazan ammonia
Base borine, 9g ammonium succinate is dissolved in 500mL deionized water, then is diluted to the terbium stannum nickel chemical plating solution that volume is 1L.
Activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Terbium tin-nickel alloy/bamboo fibre electronic wire.
By 8g NaCl, 0.4g KCl, 0.35g NaHCO3, 0.14g CaCl2, 0.06g Na2HPO4, 0.06g KH2PO4,
0.2g MgSO4.7H2O, 1g glucose is dissolved in 500mL deionized water, then is diluted to the simulated body fluid that volume is 1L.
Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in simulated body fluid, places 180 days in 37 DEG C, take out, with
The constituent content of Energy Dispersive X-ray detector (EDX) test electronic wire, calculating terbium, stannum, the flood rate of nickel ion are respectively
0.15ppm、0.26ppm、0.31ppm；The electrical conductivity of electronic wire is tested for 8.3 × 10 with four-point probe7S/m。
Embodiment 4
By bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionized water
Clean, dry.
By 3.1g chitosan, 10.3g methyl methacrylate, 2.5g performic acid is dissolved in 181g oxolane, and interpolation is gone
Ionized water, is made into the modifier solution that volume is 1L.
Clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C,
It is cooled to room temperature, obtains modified bamboo fiber.
By 24.2g cobaltic chloride, 25.8g copper sulfate, 28.2g potassium sodium tartrate is dissolved in 500mL deionized water, then dilutes
Becoming volume is the activator solution of 1L.
Modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Amount percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre.
By 25.1g Terbium nitrate (Tb(NO3)3), 23.3g nickel sulfate, 41.5g stannous chloride, 59.7g sodium bicarbonate, 77.2g sodium tartrate
Potassium, 5.1g dimethylamino borine, 7.1g ammonium succinate is dissolved in 500mL deionized water, then is diluted to the terbium stannum nickel that volume is 1L
Chemical plating solution.
Activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Terbium tin-nickel alloy/bamboo fibre electronic wire.
By 8g NaCl, 0.4g KCl, 0.35g NaHCO3, 0.14g CaCl2, 0.06g Na2HPO4, 0.06g KH2PO4,
0.2g MgSO4.7H2O, 1g glucose is dissolved in 500mL deionized water, then is diluted to the simulated body fluid that volume is 1L.
Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in simulated body fluid, places 180 days in 37 DEG C, take out, with
The constituent content of Energy Dispersive X-ray detector (EDX) test electronic wire, calculating terbium, stannum, the flood rate of nickel ion are respectively
0.32ppm、0.11ppm、0.21ppm；The electrical conductivity of electronic wire is tested for 8.1 × 10 with four-point probe7S/m。。
Embodiment 5
By bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionized water
Clean, dry.
By 3g chitosan, 9g methyl methacrylate, 1g performic acid is dissolved in 100g oxolane, adds deionized water,
It is made into the modifier solution that volume is 1L.
Clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C,
It is cooled to room temperature, obtains modified bamboo fiber.
By 20g cobaltic chloride, 20g copper sulfate, 20g potassium sodium tartrate is dissolved in 500mL deionized water, then is diluted to volume
Activator solution for 1L.
Modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Amount percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, clean, obtain activation bamboo fibre.
By 20g Terbium nitrate (Tb(NO3)3), 20g nickel sulfate, 40g stannous chloride, 30g sodium bicarbonate, 60g potassium sodium tartrate, 3g diformazan ammonia
Base borine, 6g ammonium succinate is dissolved in 500mL deionized water, then is diluted to the terbium stannum nickel chemical plating solution that volume is 1L.
Activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry,
Terbium tin-nickel alloy/bamboo fibre electronic wire.
By 8g NaCl, 0.4g KCl, 0.35g NaHCO3, 0.14g CaCl2, 0.06g Na2HPO4, 0.06g KH2PO4,
0.2g MgSO4.7H2O, 1g glucose is dissolved in 500mL deionized water, then is diluted to the simulated body fluid that volume is 1L.
Terbium tin-nickel alloy/bamboo fibre electronic wire is placed in simulated body fluid, places 180 days in 37 DEG C, take out, with
The constituent content of Energy Dispersive X-ray detector (EDX) test electronic wire, calculating terbium, stannum, the flood rate of nickel ion are respectively
0.22ppm、0.11ppm、0.21ppm；The electrical conductivity of electronic wire is tested for 8.3 × 10 with four-point probe7S/m。
Claims (4)
1. the preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire, it is characterised in that:
1) by bamboo fibre successively with the ammonia spirit that weight percent concentration is 10%, the hydrogen peroxide solution of 5%, deionization washing
Only, dry；
2) clean bamboo fibre is placed in modifier solution 30 minutes, takes out, be placed in baking oven and be dried 3 hours in 60 DEG C, cold
But to room temperature, modified bamboo fiber is obtained；
3) modified bamboo fiber is placed in activator solution 30 minutes, takes out, be washed with deionized water clean, dry, then be placed in weight
Percent concentration be 5% potassium borohydride aqueous solution in 10 minutes, take out, be washed with deionized water clean, obtain activation bamboo fibre；
4) activation bamboo fibre is placed in terbium stannum nickel chemical plating solution, in 25 DEG C of chemical platings 3 hours, takes out and clean, dry, obtain terbium
Tin-nickel alloy/bamboo fibre electronic wire.
2. the preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire as claimed in claim 1, it is characterised in that described changes
The formula of property agent solution be solvent be deionized water, in solution, various solute concentrations are respectively as follows:
Chitosan concentration 3 ~ 6 g/L；
Methyl methacrylate concentration 9 ~ 12 g/L；
Performic acid concentration 1 ~ 3 g/L；
Oxolane concentration 100 ~ 200 g/L.
3. the preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire as claimed in claim 1, it is characterised in that described work
The formula of agent solution be solvent be deionized water, in solution, various solute concentrations are respectively as follows:
Cobaltic chloride concentration 20 ~ 30g/L；
Concentration of copper sulfate 20 ~ 30g/L；
Sodium tartrate potassium concn 20 ~ 30g/L.
4. the preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire as claimed in claim 1, it is characterised in that described terbium
The formula of stannum nickel chemical plating solution be solvent be deionized water, in solution, various solute concentrations are respectively as follows:
Terbium nitrate (Tb(NO3)3) concentration 20 ~ 30g/L；
Concentration of nickel sulfate 20 ~ 30g/L；
Stannous chloride concentration 40 ~ 60g/L；
Sodium bicarbonate concentration 30 ~ 60g/L；
Sodium tartrate potassium concn 60 ~ 90g/L；
Dimethylamino borane concentration 3 ~ 6g/L；
Ammonium succinate concentration 6 ~ 9g/L.
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| CN201610480406.3A CN106205859A (en) | 2016-06-27 | 2016-06-27 | The preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire |
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| CN201610480406.3A CN106205859A (en) | 2016-06-27 | 2016-06-27 | The preparation method of terbium tin-nickel alloy/bamboo fibre electronic wire |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101446037A (en) * | 2008-12-29 | 2009-06-03 | 中国科学院长春应用化学研究所 | Preparation method of electric-conducting polyimide fiber |
| CN102041492A (en) * | 2011-01-06 | 2011-05-04 | 中国人民解放军第二炮兵工程学院 | Method for carrying out surface modification on plating layer of chemical-plating nickel-cobalt-ferrum alloy fabric by utilizing rare-earth metal salt |
| CN103060779A (en) * | 2012-12-04 | 2013-04-24 | 复旦大学 | Preparation method of copper/modal fiber composite material |
-
2016
- 2016-06-27 CN CN201610480406.3A patent/CN106205859A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101446037A (en) * | 2008-12-29 | 2009-06-03 | 中国科学院长春应用化学研究所 | Preparation method of electric-conducting polyimide fiber |
| CN102041492A (en) * | 2011-01-06 | 2011-05-04 | 中国人民解放军第二炮兵工程学院 | Method for carrying out surface modification on plating layer of chemical-plating nickel-cobalt-ferrum alloy fabric by utilizing rare-earth metal salt |
| CN103060779A (en) * | 2012-12-04 | 2013-04-24 | 复旦大学 | Preparation method of copper/modal fiber composite material |
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