CN108396399A - A kind of production method of graphene intelligent health-care underwear - Google Patents
A kind of production method of graphene intelligent health-care underwear Download PDFInfo
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- CN108396399A CN108396399A CN201810285554.9A CN201810285554A CN108396399A CN 108396399 A CN108396399 A CN 108396399A CN 201810285554 A CN201810285554 A CN 201810285554A CN 108396399 A CN108396399 A CN 108396399A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41B—SHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
- A41B17/00—Selection of special materials for underwear
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
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- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
Abstract
The invention discloses a kind of production methods of graphene intelligent health-care underwear, are as follows：Graphite powder is added in the concentrated sulfuric acid, graphene concentrated sulfuric acid solution is obtained, concentrated phosphoric acid is added, potassium permanganate and potassium bichromate is added, deionized water is added, hydrogen peroxide obtains modified graphene solution, then modified graphene suspension is prepared；Silk fiber is through degumming, dissolving, dialysis, purification, filtering; obtain pure silk fibroin solution; regenerated silk fiber is made; by modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing; then it is heating and curing to obtain the silk fiber of graphene modification under the protection of inert gas, then makes underwear ontology to obtain the final product.The present invention has anti-microbial property, uv resistance energy and far infrared performance etc., the underwear being prepared has the performances such as the excellent antibacterial, far infrared health care of heat conduction, body blood circulation is helped speed up, increases skin surface temperature, and will not decay by multiple washing effect.
Description
Technical field
The present invention relates to underwear manufacture technology field, the production method of specifically a kind of graphene intelligent health-care underwear.
Background technology
Graphene is a kind of two-dimentional carbon material, is single-layer graphene, bilayer graphene and the general designation for lacking layer graphene.Graphite
Alkene is the nano material that known world is most thin, most hard, it is almost fully transparent, only absorbs 2.3% light；Heat conduction system
Number is up to 5300W/m.K, is higher than carbon nanotube and diamond, its electron mobility is more than 15000cm under room temperature2/ V.s, and compare
Carbon nanotubes or silicon crystal are high, and resistivity about 108Ω .m, it is lower than copper or silver, it is the material of world resistivity minimum.Cause
Its resistivity is extremely low, and the speed of electron transfer is exceedingly fast, therefore is expected to can be used to develop thinner, conductive speed of new generation faster
Electronic component or transistor.Since graphene is substantially a kind of transparent, good conductor, it also is adapted for for manufacturing transparent touch
Screen, tabula rasa, even solar cell.
Graphene is the two dimensional crystal material and structure carbon material the simplest of monoatomic layer.Common graphite material
Material is considered as being formed by graphene stacked in multi-layers, therefore graphene is also considered " mono-layer graphite ".It is known as " 21 century mystery
The graphene of material " is that current known world is most thin, most hard, electric conductivity is best at room temperature and possesses powerful flexibility
Nano material；It thin can arrive the only thickness there are one carbon atom, and 3,000,000 layers of stone can be separated in the graphite flake of 1 millimeters thick
Black alkene；It is very hard, 200 times more taller than steel of intensity；At room temperature, the minimum substance of resistivity is silver, and the electricity of graphene
Resistance rate is also smaller than silver；Various characteristics that it is transparent and airtight ... keep graphene future all in touch screen, sensor, accumulator etc.
Multi-field application is full of the imagination.
China is current graphene research and application and development one of country the most active.Data are shown, in All Countries
In, the graphene patent numbers of China's application are most, more than 2200, account for global 1/3.Currently, Chinese graphene is special
Sharp quantity the first in the world.
Underwear refers to the personal clothing worn, including vest, undershirt, shorts, brassiere etc., is typically to be in direct contact skin,
It is indispensable one of the dress ornament of modern.Underwear has absorbing sweat, rectifys type, set off body, is warming and not by filthy from body
The effect of harm, is considered as sex character sometimes.Underwear is substantially inclusiveness to be had, and could effectively give breast and stern in this way
Portion is with supporting force.Whether underwear has this characteristic, is related to forming the material of underwear and the frame mode of material：With knitting
Mode carrys out organization material, ineffective material be silk, cotton, chemical fibre, it is blended, them can all generated very strong
Contractility, i.e. our traditionally described elasticity；And the knitting fabric of double-layer structure, elasticity are better than single layer again.In some
Clothing is expensive, some underwears come from a master's hand, and once effect is distinguished for some underwears, but regardless of the underwear of sample,
Wear, wash, drying in the air, receive during all can it is fast or slowly lose it is original possessed by function, underwear at this time even can play anti-work
With the amendment bodily form is not only unprofitable to one by one, figure can be distorted instead.
It is preferably natural fibre products to select underwear.It is wherein more suitable with cotton products.Its hygroscopicity and warmth retention property is good
Well, price is also moderate.Their hygroscopicity such as the product of synthetic fibers such as polyamide fibre underpants, terylene shirt are poor, are unfavorable for human sweat
Absorption and distribute, it is difficult to adjust the moist heat between skin and underwear, therefore wear next to the skin often and have sultry feeling.Its
Notable to be synthetic fibers underwear can also cause skin injury, the harm of nylon from remaining monomer phthalein amine in oneself,
It can cause dry skin, it is coarse, thicken, or even occur relatively to split, dermatitis etc..In addition it has antigenicity to skin, so as to cause
Allergic reaction.
Invention content
The purpose of the present invention is to provide a kind of production methods for the graphene intelligent health-care underwear that heat conduction is antibacterial, to solve
The problems mentioned above in the background art.
To achieve the above object, the present invention provides the following technical solutions：
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:The graphite powder of 18-22 is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain stone
The graphene concentrated sulfuric acid solution is stirred 10-15min, and stands 40-60min by black alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution being added in 100-140 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%,
Then 6-10min is stirred, and stands 40-60min；Obtained solution is cooled to 4-8 DEG C again, is then added 2.5-3.5 parts high
Potassium manganate and 2.5-3.5 parts of potassium bichromates stir 6-10min, are then allowed to stand 4-6h；
（3）By above-mentioned steps（2）Obtained solution is heated to 30-35 DEG C, and 45-55 parts of deionized waters are then added, are again heated to
88-92 DEG C, it is then allowed to stand 2-4h, then is cooled to 30 DEG C, 5-10 parts of hydrogen peroxide are then added, stirs 6-10min, stands 1.2-
1.6h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.5-2h, obtains modified graphene solution；
（5）Dispersant, the weight ratio of the modified graphene solution and dispersant are added into the modified graphene solution
It is 1:5-10 disperses to obtain modified graphene suspension using blender, and blender rotating speed is 1500-2500r/min；
（6）By 40-60 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk element is molten
Liquid, which is placed in container to spontaneously dry at room temperature, forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk is made
Spinning solution；
（7）The chitosan of graphene suspension and 10-20 parts of low molecular weights will be added in silk spinning solution, stirs shape
At uniform and stable spinning solution, regenerated silk fiber is obtained through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then lazy
Property gas protection under be heating and curing to obtain the silk fiber of graphene modification；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
As a further solution of the present invention：The dispersant is 3- aminopropyl triethoxysilanes.
As a further solution of the present invention：The step（5）A concentration of 15-20mg/ of middle modified graphene suspension
mL。
As a further solution of the present invention：The mass fraction of fibroin is in silk spinning solution in the step (6)
18-22%.
As further scheme of the invention：The inert gas is nitrogen or argon gas.
Compared with prior art, the beneficial effects of the invention are as follows：
Modified graphene material and silk fiber are blended and improve silk fiber mechanical performance by the present invention, and assign silk fiber
Electric conductivity, so that fabric has anti-microbial property, uv resistance energy and far infrared performance etc., the underwear being prepared has
The performances such as the antibacterial, far infrared health care of excellent heat conduction help speed up body blood circulation, increase skin surface temperature, and
It will not decay by multiple washing effect.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:18 graphite powder is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain graphite
The graphene concentrated sulfuric acid solution is stirred 10min, and stands 40min by alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution is added in 100 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%, then
6min is stirred, and stands 40min；Obtained solution is cooled to 4 DEG C again, 2.5 parts of potassium permanganate and 2.5 parts of weight chromium are then added
Sour potassium stirs 6min, is then allowed to stand 4h；
（3）By above-mentioned steps（2）Obtained solution is heated to 30 DEG C, and 45 parts of deionized waters are then added, are again heated to 88 DEG C, so
After stand 2h, then be cooled to 30 DEG C, 5 parts of hydrogen peroxide be then added, stir 6min, stand 1.2h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.5h, obtains modified graphene solution；
（5）Into the modified graphene solution be added 3- aminopropyl triethoxysilanes, the modified graphene solution with
The weight ratio of 3- aminopropyl triethoxysilanes is 1:5, disperse to obtain modified graphene suspension using blender, what is obtained changes
Property graphene suspension a concentration of 15mg/mL, blender rotating speed be 1500r/min；
（6）By 40 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk fibroin solution is set
It is spontaneously dried at room temperature in container and forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk spinning is made
Liquid, the mass fraction of fibroin is 18% in silk spinning solution；
（7）The chitosan of graphene suspension and 10 parts of low molecular weights will be added in silk spinning solution, stirs to be formed
Uniform and stable spinning solution obtains regenerated silk fiber through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then in nitrogen
It is heating and curing to obtain the silk fiber of graphene modification under the protection of gas；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
Embodiment 2
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:19 graphite powder is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain graphite
The graphene concentrated sulfuric acid solution is stirred 11min, and stands 45min by alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution is added in 110 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%, then
7min is stirred, and stands 45min；Obtained solution is cooled to 5 DEG C again, 2.8 parts of potassium permanganate and 2.8 parts of weight chromium are then added
Sour potassium stirs 7min, is then allowed to stand 4.5h；
（3）By above-mentioned steps（2）Obtained solution is heated to 31 DEG C, and 48 parts of deionized waters are then added, are again heated to 89 DEG C, so
After stand 2.5h, then be cooled to 30 DEG C, 6 parts of hydrogen peroxide be then added, stir 7min, stand 1.3h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.6h, obtains modified graphene solution；
（5）Into the modified graphene solution be added 3- aminopropyl triethoxysilanes, the modified graphene solution with
The weight ratio of 3- aminopropyl triethoxysilanes is 1:6, disperse to obtain modified graphene suspension using blender, what is obtained changes
Property graphene suspension a concentration of 16mg/mL, blender rotating speed be 1800r/min；
（6）By 45 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk fibroin solution is set
It is spontaneously dried at room temperature in container and forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk spinning is made
Liquid, the mass fraction of fibroin is 19% in silk spinning solution；
（7）The chitosan of graphene suspension and 12 parts of low molecular weights will be added in silk spinning solution, stirs to be formed
Uniform and stable spinning solution obtains regenerated silk fiber through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then in argon
It is heating and curing to obtain the silk fiber of graphene modification under the protection of gas；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
Embodiment 3
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:The graphite powder of 18-22 is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain stone
The graphene concentrated sulfuric acid solution is stirred 12min, and stands 50min by black alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution is added in 120 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%, then
8min is stirred, and stands 50min；Obtained solution is cooled to 6 DEG C again, 3 parts of potassium permanganate and 3 parts of dichromic acids are then added
Potassium stirs 8min, is then allowed to stand 5h；
（3）By above-mentioned steps（2）Obtained solution is heated to 32 DEG C, and 50 parts of deionized waters are then added, are again heated to 90 DEG C, so
After stand 3h, then be cooled to 30 DEG C, 8 parts of hydrogen peroxide be then added, stir 8min, stand 1.4h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.8h, obtains modified graphene solution；
（5）Into the modified graphene solution be added 3- aminopropyl triethoxysilanes, the modified graphene solution with
The weight ratio of 3- aminopropyl triethoxysilanes is 1:8, disperse to obtain modified graphene suspension using blender, what is obtained changes
Property graphene suspension a concentration of 18mg/mL, blender rotating speed be 2000r/min；
（6）By 50 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk fibroin solution is set
It is spontaneously dried at room temperature in container and forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk spinning is made
Liquid, the mass fraction of fibroin is 20% in silk spinning solution；
（7）The chitosan of graphene suspension and 15 parts of low molecular weights will be added in silk spinning solution, stirs to be formed
Uniform and stable spinning solution obtains regenerated silk fiber through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then in nitrogen
It is heating and curing to obtain the silk fiber of graphene modification under the protection of gas；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
Embodiment 4
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:21 graphite powder is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain graphite
The graphene concentrated sulfuric acid solution is stirred 14min, and stands 55min by alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution is added in 130 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%, then
9min is stirred, and stands 55min；Obtained solution is cooled to 7 DEG C again, 3.2 parts of potassium permanganate and 3.2 parts of weight chromium are then added
Sour potassium stirs 9min, is then allowed to stand 5.5h；
（3）By above-mentioned steps（2）Obtained solution is heated to 34 DEG C, and 52 parts of deionized waters are then added, are again heated to 91 DEG C, so
After stand 3.5h, then be cooled to 30 DEG C, 9 parts of hydrogen peroxide be then added, stir 9min, stand 1.5h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.9h, obtains modified graphene solution；
（5）Aminopropyl triethoxysilane, the modified graphene solution and ammonia are added into the modified graphene solution
The weight ratio of propyl-triethoxysilicane is 1:9, the modification stone for obtaining modified graphene suspension, obtaining is disperseed using blender
A concentration of 19mg/mL of black alkene suspension, blender rotating speed are 2200r/min；
（6）By 55 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk fibroin solution is set
It is spontaneously dried at room temperature in container and forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk spinning is made
Liquid, the mass fraction of fibroin is 21% in silk spinning solution；
（7）The chitosan of graphene suspension and 18 parts of low molecular weights will be added in silk spinning solution, stirs to be formed
Uniform and stable spinning solution obtains regenerated silk fiber through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then in argon
It is heating and curing to obtain the silk fiber of graphene modification under the protection of gas；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
Embodiment 5
A kind of production method of graphene intelligent health-care underwear, is as follows：
（1）It is 1 by component ratio:22 graphite powder is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain graphite
The graphene concentrated sulfuric acid solution is stirred 15min, and stands 60min by alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution is added in 140 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%, then
10min is stirred, and stands 60min；Obtained solution is cooled to 8 DEG C again, 3.5 parts of potassium permanganate and 3.5 parts of weights are then added
Potassium chromate stirs 10min, is then allowed to stand 6h；
（3）By above-mentioned steps（2）Obtained solution is heated to 35 DEG C, and 55 parts of deionized waters are then added, are again heated to 92 DEG C, so
After stand 4h, then be cooled to 30 DEG C, 10 parts of hydrogen peroxide be then added, stir 10min, stand 1.6h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 2h, obtains modified graphene solution；
（5）Aminopropyl triethoxysilane, the modified graphene solution and ammonia are added into the modified graphene solution
The weight ratio of propyl-triethoxysilicane is 1:10, the modification for obtaining modified graphene suspension, obtaining is disperseed using blender
A concentration of 20mg/mL of graphene suspension, blender rotating speed are 2500r/min；
（6）By 60 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk fibroin solution is set
It is spontaneously dried at room temperature in container and forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk spinning is made
Liquid, the mass fraction of fibroin is 22% in silk spinning solution；
（7）The chitosan of graphene suspension and 20 parts of low molecular weights will be added in silk spinning solution, stirs to be formed
Uniform and stable spinning solution obtains regenerated silk fiber through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then in nitrogen
It is heating and curing to obtain the silk fiber of graphene modification under the protection of gas；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
Modified graphene material and silk fiber are blended and improve silk fiber mechanical performance by the present invention, and assign silk
Filamentary conductive energy, so that fabric has anti-microbial property, uv resistance energy and far infrared performance etc., the underwear being prepared
With performances such as the antibacterial, far infrared health cares of excellent heat conduction, body blood circulation is helped speed up, increases skin surface temperature,
And it will not decay by multiple washing effect.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective
Various changes can be made.
Claims (5)
1. a kind of production method of graphene intelligent health-care underwear, which is characterized in that be as follows：
（1）It is 1 by component ratio:The graphite powder of 18-22 is added in the concentrated sulfuric acid, and a concentration of 98% or more of the concentrated sulfuric acid, obtain stone
The graphene concentrated sulfuric acid solution is stirred 10-15min, and stands 40-60min by black alkene concentrated sulfuric acid solution；
（2）The graphene concentrated sulfuric acid solution being added in 100-140 parts of concentrated phosphoric acid, the concentration of the concentrated phosphoric acid is more than 85%,
Then 6-10min is stirred, and stands 40-60min；Obtained solution is cooled to 4-8 DEG C again, is then added 2.5-3.5 parts high
Potassium manganate and 2.5-3.5 parts of potassium bichromates stir 6-10min, are then allowed to stand 4-6h；
（3）By above-mentioned steps（2）Obtained solution is heated to 30-35 DEG C, and 45-55 parts of deionized waters are then added, are again heated to
88-92 DEG C, it is then allowed to stand 2-4h, then is cooled to 30 DEG C, 5-10 parts of hydrogen peroxide are then added, stirs 6-10min, stands 1.2-
1.6h；
（4）By above-mentioned steps（3）Obtained solution carries out ultrasonic wave dispersion 1.5-2h, obtains modified graphene solution；
（5）Dispersant, the weight ratio of the modified graphene solution and dispersant are added into the modified graphene solution
It is 1:5-10 disperses to obtain modified graphene suspension using blender, and blender rotating speed is 1500-2500r/min；
（6）By 40-60 parts of silk fibers through degumming, dissolving, dialysis, purification, filtering, pure silk fibroin solution is obtained, pure silk element is molten
Liquid, which is placed in container to spontaneously dry at room temperature, forms Regenerated Silk Fibroin Film, then Regenerated Silk Fibroin Film is dissolved in solvent, silk is made
Spinning solution；
（7）The chitosan of graphene suspension and 10-20 parts of low molecular weights will be added in silk spinning solution, stirs shape
At uniform and stable spinning solution, regenerated silk fiber is obtained through electrostatic spinning technique；
（8）By modified graphene suspension through depositing to regenerated silk fiber surface under high-pressure electrostatic atomizing, then lazy
Property gas protection under be heating and curing to obtain the silk fiber of graphene modification；
（9）Underwear ontology is made to obtain the final product according to existing step using the silk fiber.
2. the production method of graphene intelligent health-care underwear according to claim 1, which is characterized in that the dispersant is
3- aminopropyl triethoxysilanes.
3. the production method of graphene intelligent health-care underwear according to claim 1, which is characterized in that the step（5）
A concentration of 15-20mg/mL of middle modified graphene suspension.
4. the production method of graphene intelligent health-care underwear according to claim 1, which is characterized in that the step (6)
The mass fraction of fibroin is 18-22% in middle silk spinning solution.
5. the production method of graphene intelligent health-care underwear according to claim 1, which is characterized in that the inert gas
For nitrogen or argon gas.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109652894A (en) * | 2019-02-13 | 2019-04-19 | 南开大学 | The preparation method of smart fabric based on silk artificial-muscle |
| CN113215815A (en) * | 2021-01-20 | 2021-08-06 | 北京航空航天大学 | Preparation method of graphene functionalized silk fiber |
| CN113863000A (en) * | 2021-11-01 | 2021-12-31 | 浙江莹隆纤维科技有限公司 | Preparation method of three-dimensional fluorescent graphene fiber |
| CN114875508A (en) * | 2022-04-29 | 2022-08-09 | 上海旦芯悦灵脑智能科技有限公司 | In-situ preparation method of self-heating flexible wearable nanofiber material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105926075A (en) * | 2016-05-13 | 2016-09-07 | 东莞市联洲知识产权运营管理有限公司 | Graphene modified silk fiber preparing method |
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| CN107224010A (en) * | 2017-08-08 | 2017-10-03 | 佳莱科技有限公司 | A kind of graphene far infrared germanium fabric health care underwear |
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| CN109652894A (en) * | 2019-02-13 | 2019-04-19 | 南开大学 | The preparation method of smart fabric based on silk artificial-muscle |
| CN113215815A (en) * | 2021-01-20 | 2021-08-06 | 北京航空航天大学 | Preparation method of graphene functionalized silk fiber |
| CN113863000A (en) * | 2021-11-01 | 2021-12-31 | 浙江莹隆纤维科技有限公司 | Preparation method of three-dimensional fluorescent graphene fiber |
| CN114875508A (en) * | 2022-04-29 | 2022-08-09 | 上海旦芯悦灵脑智能科技有限公司 | In-situ preparation method of self-heating flexible wearable nanofiber material |
| CN114875508B (en) * | 2022-04-29 | 2024-02-02 | 上海旦芯悦灵脑智能科技有限公司 | In-situ preparation method of self-heating flexible wearable nanofiber material |
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