CN105233404B - A kind of electrode manufacturing method applied to wearable device - Google Patents

A kind of electrode manufacturing method applied to wearable device Download PDF

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Publication number
CN105233404B
CN105233404B CN201510816244.1A CN201510816244A CN105233404B CN 105233404 B CN105233404 B CN 105233404B CN 201510816244 A CN201510816244 A CN 201510816244A CN 105233404 B CN105233404 B CN 105233404B
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cloth
electrode
silver
wearable device
electrode manufacturing
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CN105233404A (en
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董青
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Zhejiang Revformula HEALTH Tech Co.,Ltd.
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Zhejiang Li Fang Health Technology Co Ltd
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Priority to PCT/CN2016/000125 priority patent/WO2017088276A1/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/24Detecting, measuring or recording bioelectric or biomagnetic signals of the body or parts thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/24Detecting, measuring or recording bioelectric or biomagnetic signals of the body or parts thereof
    • A61B5/25Bioelectric electrodes therefor
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/24Detecting, measuring or recording bioelectric or biomagnetic signals of the body or parts thereof
    • A61B5/25Bioelectric electrodes therefor
    • A61B5/279Bioelectric electrodes therefor specially adapted for particular uses
    • A61B5/28Bioelectric electrodes therefor specially adapted for particular uses for electrocardiography [ECG]
    • A61B5/283Invasive
    • A61B5/288Invasive for foetal cardiography, e.g. scalp electrodes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/24Detecting, measuring or recording bioelectric or biomagnetic signals of the body or parts thereof
    • A61B5/25Bioelectric electrodes therefor
    • A61B5/279Bioelectric electrodes therefor specially adapted for particular uses
    • A61B5/291Bioelectric electrodes therefor specially adapted for particular uses for electroencephalography [EEG]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/24Detecting, measuring or recording bioelectric or biomagnetic signals of the body or parts thereof
    • A61B5/25Bioelectric electrodes therefor
    • A61B5/279Bioelectric electrodes therefor specially adapted for particular uses
    • A61B5/296Bioelectric electrodes therefor specially adapted for particular uses for electromyography [EMG]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61NELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N1/00Electrotherapy; Circuits therefor
    • A61N1/02Details
    • A61N1/04Electrodes

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Biophysics (AREA)
  • Pathology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Surgery (AREA)
  • Cardiology (AREA)
  • Radiology & Medical Imaging (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pediatric Medicine (AREA)
  • Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)

Abstract

The invention discloses a kind of electrode manufacturing method applied to wearable device, including step:1) silver-plated cloth is made:Using nylon fiber as base material, silver-plated cloth is obtained;It is characterized in that:Further include following steps:2) adhesive film or sticky high molecular material:Adhesive film or sticky high molecular material on the silver-plated cloth;3) composite elastic layer:Composite elastic layer on the membrane, so as to obtain it is compound after electrode cloth;4) it is cut and formed:Electrode cloth size as needed is cut, thus obtains the electrode applied to wearable device.It, can be so that fiber conductive coil be cured, comparatively fast stores sweat, the loss for reducing Fabric Physical contact point silver, so as to reduce resistivity, improve wash durability by the adhesive film on silver-plated cloth;Pass through composite elastic layer and basic cloth, moreover it is possible to so that fitting is more comfortable, integrally plays the role of protection to electrode cloth and can reduce and skin friction and the noise that generates.

Description

A kind of electrode manufacturing method applied to wearable device
Technical field
The present invention relates to a kind of manufacturing process of electrode, especially a kind of electrode manufacturing method applied to wearable device.
Background technology
Metabolism and activities in life process all generate electricity, environmental stimuli, heartbeat, contraction of muscle, eye Eyeball opening and closing, human thinking etc., all with bioelectric generation and variation.Physiologic Studies show biological electricity be not organ or The byproduct or accompaniment of organ functional activity, but cell realizes the key or determinant of some important physiological functions, it is special It is not that the electromyography signal that neuron provides stimulates muscle to respond, muscle systems is made to generate to the active force of skeletal system with complete Into various mechanical actions.
The bioelectrical signals sent by human body itself, (myoelectricity is believed for heartbeat (electrocardiosignal) described above, contraction of muscle Number) etc., it is collected, filtered by electrode, amplifying the subsequent analysis of progress.
Electricity can also be applied to human body by the external world via electrode, and high electric field pulse is applied such as defibrillator, low tension arteries and veins Punching application such as electronics muscular irritation (EMS) technology, can stimulate muscle that muscle is made to make systole response and reach the effect to exercise one's muscles Fruit.
Electric current wherein in EMS technologies, frequency contains intermediate frequency and low frequency simultaneously, and electrode is surrounded muscle in couples Group's arrangement, can " entirety is mobilized " participates in fortune simultaneously under electric signal no matter to surface layer and muscle and deep or fast muscle, slow muscle It is dynamic, and certain frequency wave bag can be passed through so that muscle, which is rapidly shunk, to be loosened, and is obtained by people nervous system itself all much The exercise efficiency being not achieved.With EMS technological progresses, not only it is applied to professional motion field, and rapidly to the common day for human beings The market development often taken exercise, according to the usage experience of common people, a kind of electrode object wearing device that can cover whole body of market in urgent need, electricity Pole and electric wire are all bonded body, and the small-sized carrying of current feedback circuit is controlled by wireless blue tooth, and electrode can be pasted fully Body contour is closed, homogeneous current distribution, which does not generate local point discharge, stimulates human body, together between current feedback circuit and electrode Electric wire has good elasticity and comfort, meets the needs of human body free movement.
With the development of material science and technology, existing electrode assembly common from electroded Wearable is such as fine by carbon Dimension is woven into comparatively dense net structure, to form the electrode of contact human body, but due to the brittle material property of carbon fiber, So that electrode life is not short, washable;Or such as conductive material is coated in high molecular material substrate, and then electrode is formed, it is the most frequently used It is a kind of wearable heart as disclosed in the Chinese patent of Application No. 200910064618.3 on the fabric using chemical silvering Electric electrode assembly and its manufacturing method, comprise the step of:Clothing is cut according to the pattern of clothing;Using composite fibre as base material, Nano-silver layer is plated on composite fibre, manufactured electrode is arranged on the corresponding position of clothing, silver is affine to skin, and kills Bacterium effect, but this electrode, washing times are still fairly limited, and wash durability is poor, and importantly, are transported in human body Body curved surface variation when dynamic cannot be guaranteed fitting of the entire electrode surface to body when stretching, so that body current circuit Impedance constantly changes, and can cause electric current shouting pain or burn, market in urgent need wants novel electrode to realize these requirements.
Equally, the electrode needs for connecting electric generating means and fitting corporal parts are flexible, exterior insulation, low Electric wire impedance and that skin is affine.
The content of the invention
The technical problems to be solved by the invention are for the above-mentioned prior art, to provide a kind of raising Wash durability, reduce resistivity and the electrode manufacturing method applied to wearable device that body good fit can be kept.
Technical solution is used by the present invention solves above-mentioned technical problem:A kind of electrode applied to wearable device manufactures Method, including step:
1) silver-plated cloth is made:Using nylon fiber as base material, silver-plated cloth is obtained;It is characterized in that:Further include following steps:
2) adhesive film or sticky high molecular material:Adhesive film or sticky high molecular material on the silver-plated cloth, Gu The coil bottom of the fixed silver-plated cloth;
3) composite elastic layer:The composite elastic layer on the film or sticky high molecular material, so as to obtain it is compound after Electrode cloth;
4) it is cut and formed:Electrode cloth size and shape as needed are cut, obtain electrode finished product.
Preferably, in step 3), compound one layer of elastic fabric is used as protection again on the elastic layer of the electrode cloth Basic cloth, basic cloth can reduce outer shell fabric package pressure down spring layer and outer shell fabric frictional noise.
The elastic fabric is compound by spot printing or flaming mode.
Preferably, in step 1), it is made into close knitted fabric with ultra-fine nylon fiber ammonification synthetic fibre and does chemical silvering, it is special Point is that coil arrangement is completely embedded between conductiving point, and sheet resistance is small, and electrode interior will not form local electricity under any circumstance Potential energy difference.
Preferably, the production method of silver-plated cloth is, in step 1), at the nylon fiber surface elder generation chemical silvering Reason, then ammoniates synthetic fibre woven stretch fabrics, so as to obtain the silver-plated cloth again.
Preferably, the production method of silver-plated cloth is in step 1), to be done on the nylon fiber surface at chemical silvering Reason, then ammoniates synthetic fibre woven stretch fabrics, is obtained after chemical silvering is done to fabric again on the basis of the stockinette again The silver-plated cloth.
The physical contact of above two mode reinforcement fabric coil silver coating continues to improve washability on the basis of above.
In above method step, bonding or compound mode are preferably, and in step 2), the film passes through spot printing Mode bonds.In step 3), the elastic layer is compound by flaming mode.Also other bondings in the prior art can be selected, answer The mode of conjunction.
Preferably, the elastic layer is sponge, and the thickness of the sponge is 2.0~8mm, can be according to the reality of application scenario Border needs to choose suitable thickness.
Compared with prior art, the advantage of the invention is that:Silver-plated place is then done by manufacturing close high-tension fabric Reason, so as to obtain the base material of low resistivity;Adhesive film or sticky high molecular material, can comparatively fast receive on above-mentioned silver-plated cloth The sweat of skin of receiving volatilization so that internal body tissue connects with external electrode energy Low ESR, while is carried out to fiberoptic coil It fixes to reduce the loss of fabric coil physical contact point position silver in washing process, improves wash durability;By compound Elastic layer can to keep during human motion and the fitting of human body surface so that electric current stepless action is in Large Area Skin Skin avoids electric current shouting pain or burns;Basic cloth integrally plays the role of electrode cloth protection and can reduce to produce with skin friction Raw noise.
Description of the drawings
Fig. 1 is the structure diagram of the electrode of the method manufacture of the present invention.
Specific embodiment
The present invention is described in further detail below in conjunction with attached drawing embodiment.
Referring to Fig. 1, a kind of electrode applied to wearable device, including the silver-plated cloth 1, film 2, elastic layer 3 set gradually It is compound and form electrode with basic cloth 4, basic cloth 4 for connect it is fixed (usually by way of suture) on the inside of clothing, plating Silver-colored cloth 1 is bonded human muscle.
The manufacturing method of above-mentioned electrode is:
1) silver-plated cloth 1 is made:In commercial Application, conductive material is there are many kinds of class, predominantly various metals, wherein your gold Belong to as golden and silver-colored, electric conductivity is especially excellent, therefore, in the present invention, selects nylon fiber ammonification synthetic fibre woven stretch fabrics (warp It compiles, weft knitting or woven fabric).
Preferably, synthetic fibre weaving is ammoniated into close high resiliency knitted fabric for ultra-fine nylon fiber, ultra-fine nylon fiber is Refer to the chemical fibre of micron (about 1~2 micron) grade, its main feature is that coil arrangement is completely embedded between conductiving point, sheet resistance is small, It is poor will not to form local potential's energy for electrode interior under any circumstance;
Chemical silvering (coating elargol) processing is done on the basis of this stockinette and obtains silver-plated cloth, alternatively, plating Silver-colored cloth 1 can also be used described in background technology, first in nylon fiber electroplate, be then woven into stockinette again, also It can again be carried out on the basis of this stockinette silver-plated;
2) adhesive film 2 or sticky high molecular material:On silver-plated cloth 1 first thin film 2 or viscous is bonded with spot printing mode Property high molecular material, in invention, preferably film.Film 2 can improve the storage to sweat, and sweat surface is allowed to ooze rapidly It opens so that impedance reduces faster after skin perspiration, faster makes internal bodily tissue and the low-impedance connection of external electrode, cooperation electricity Generator, usage experience are more preferable;The coil bottom of silver-plated cloth 1 can also be cured simultaneously, substantially reduced in washing process The loss of middle physical contact point position silver, it is ensured that it remains to keep good physical contact between the coil after repeatedly washing, Improve washability;
3) composite elastic layer 3:On film 2 with flaming mode composite elastic layer 3 obtain it is compound after electrode cloth;Elastic layer Even if 3 may be such that and electrode be still ensured that during human motion and human skin is good is bonded.
Preferably sponge, the thickness of sponge is optionally 2.0~8.0mm as needed;Alternatively, can also select Air layer, honeycomb fabric etc.;
4) composite base cloth 4:To play the Global Macros to electrode, and make an uproar after reducing wearing with what skin friction generated Sound, electrode cloth finally can again by the use of spot printing or flaming mode on elastic layer 3 compound one layer of elastic fabric as the base of protection Layer cloth 4;
5) it is cut and formed:It is set after the size cutting as needed of electrode cloth that step 3) or step 4) are obtained as dressing Standby electrode uses, and obtained electrode is low with resistivity, water-fastness, conductive uniform, and fitting is close comfortable, comparatively fast stores sweat The characteristics of connecting internal bodily tissue afterwards Low ESR.
Optionally, can also be bonded between film 2 and basic cloth 4 according to different needs or compound mesh cloth.
Water-wash resistance test is carried out to the electrode of above method manufacture:
(1) experimental condition
1st, wash conditions
1. reference standard GB/T 8629-2001《The home washings and drying program used during Textile Test》(with ISO 6330:2000《Textile textile testing home washings and drying program one by one》It is equivalent);
2. use horizontal cylinder, front door charging type washing machine (A types washing machine);
3. drying program uses F- oven dryings, drying temperature is 60 DEG C of 5 DEG C of scholars, and drying time is as being 25min;
4. accompany washing:Nothing;
5. washing procedure:5A;Water temperature:Room temperature;Wash time 15min, rinsing 18min, drying 2min;
6. detergent:Without phosphorus ECE standard detergents (being free of fluorescent whitening agent), dosage are 66 ± 1g of washing every time.
2nd, sample prepares
Electrode cloth is cut, cutting specification (is used for for 18cm × 18cm according to peel strength test size of sample and electrode cloth Cut size during clothes determines), specimen electrode is obtained, for the sample in water-washing process is avoided to be removed along edge, sample should be into Row lock seaming is handled, with edge sealing effect of the simulation electrode when being applied on clothes.
(2) test operation
1st, roller washing machine washing procedure is set and gets out sample according to wash conditions and washed;
2nd, each time after washing, noticing whether the cosmetic variation for observing each sample (starts peel test specimen occur, if occur A large amount of peel test specimens and washing to several times when there is the block number of peel test specimen and ratio), as evaluate electrode cloth stripping performance Qualitative foundation;It often washs 5 times, each 1 piece of number sample is taken to test its warp-wise (length) peel strength and electric conductivity respectively;It leads Sample after electric performance test carries out secondary cutting, carries out peel strength test;
3rd, after each sampling and testing (integral multiples that washing is 5 times), in order to ensure that wash conditions do not change, it is necessary to supplement equal Quantity, the sample of specification are washed, that is, one piece of sample will be supplemented by taking out one piece of sample;
4th, according to test result, the data of electrode cloth stripping performance and electric conductivity with washing times situation of change are summarized.
(3) test results and analysis
For 15cm × 5cm, (specimen width 5cm, both ends clamping wire spacing are the effective specification of electrode conductivuty test sample 15cm), all samples to be tested through certain washing times are placed in climatic chamber, the humiture for setting climatic chamber is Standard atmosphere condition (T=20 DEG C, RH%=65%), when balance 12 is small more than, then tested.
By ohmer the two poles of the earth short circuit, line resistance is deducted by setting operation method.Due to when testing sample to be tested resistance, Substantially all occur resistance value at any time continuous decrement the phenomenon that (rate of decay is slower and slower), therefore arrange the polarization time be 30S, I.e. with gripper sample to be tested after 30 seconds, resistance value is read, although resistance value is still decaying at this time.
The testing time of per sample (p.s.) is 3 times, and it is longitudinal direction (warp-wise) that sample, which cuts direction, and test result is shown in Table 1.
Table 1:Electrode samples electric conductivity is tested
It was found from from upper table 1, after washing 45 times, sheet resistance is still increased with the speed slowed down, on the whole electric conductivity It can keep very good, the function after long-term repeated washing can be met and kept.

Claims (10)

1. a kind of electrode manufacturing method applied to wearable device, including step:
1) silver-plated cloth (1) is made:Using nylon fiber as base material, silver-plated cloth (1) is obtained;
It is characterized in that:Further include following steps:
2) adhesive film (2) or sticky high molecular material:Adhesive film (2) or sticky macromolecule material on the silver-plated cloth (1) Material, the coil bottom of the fixed silver-plated cloth (1);
3) composite elastic layer (3):The composite elastic layer (3) on the film (2), so as to obtain it is compound after electrode cloth;
4) it is cut and formed:Electrode cloth size and shape as needed are cut, obtain electrode finished product.
2. it is applied to the electrode manufacturing method of wearable device as described in claim 1, it is characterised in that:In step 3), Basic cloth (4) of the compound one layer of elastic fabric as protection again on the elastic layer (3) of the electrode cloth.
3. it is applied to the electrode manufacturing method of wearable device as claimed in claim 2, it is characterised in that:The elastic fabric leads to It crosses spot printing or flaming mode is compound.
4. it is applied to the electrode manufacturing method of wearable device as described in claim 1, it is characterised in that:In step 1), use The nylon fiber ammoniates synthetic fibre woven stretch fabrics, done on the basis of the stockinette chemical silvering processing obtain it is described Silver-plated cloth (1).
5. it is applied to the electrode manufacturing method of wearable device as described in claim 1, it is characterised in that:In step 1), use Ultra-fine nylon fiber long filament ammonification synthetic fibre is made into close knitted fabric and does chemical silvering.
6. it is applied to the electrode manufacturing method of wearable device as claimed in claim 5, it is characterised in that:In step 1), The nylon fiber surface elder generation chemical silvering processing, then ammoniates synthetic fibre woven stretch fabrics, so as to obtain the silver-plated cloth again (1)。
7. it is applied to the electrode manufacturing method of wearable device as claimed in claim 5, it is characterised in that:In step 1), Chemical silvering processing is done on the nylon fiber surface, then ammoniates synthetic fibre woven stretch fabrics again, on the basis of the stockinette On chemical silvering is done to stockinette again after obtain the silver-plated cloth (1).
8. such as the electrode manufacturing method according to any one of claims 1 to 7 applied to wearable device, it is characterised in that: In step 2), the film (2) is bonded by spot printing mode.
9. such as the electrode manufacturing method according to any one of claims 1 to 7 applied to wearable device, it is characterised in that: In step 3), the elastic layer (3) is compound by flaming mode.
10. it is applied to the electrode manufacturing method of wearable device as claimed in claim 9, it is characterised in that:The elastic layer (3) For sponge, the thickness of the sponge is 2.0~8.0mm.
CN201510816244.1A 2015-11-23 2015-11-23 A kind of electrode manufacturing method applied to wearable device Active CN105233404B (en)

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PCT/CN2016/000125 WO2017088276A1 (en) 2015-11-23 2016-03-10 Electrode manufacturing method applicable for wearable apparatus

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CN105233404B (en) * 2015-11-23 2018-05-22 浙江力方健康科技有限公司 A kind of electrode manufacturing method applied to wearable device
CN106551693A (en) * 2017-01-18 2017-04-05 包磊 Textile electrode and electrocardiogram test instrument
CN110440958A (en) * 2019-08-06 2019-11-12 江南大学 A kind of capacitance pressure transducer, based on warp-knitted spacer fabric
WO2021128215A1 (en) * 2019-12-26 2021-07-01 鹏鼎控股(深圳)股份有限公司 Stretchable smart fabric
US11839759B2 (en) 2020-09-21 2023-12-12 Neuro20 Technologies Corp. Systems and methods for managed training and rehabilitation via electrical stimulation
CN113171099B (en) * 2021-03-29 2023-08-25 歌尔股份有限公司 Printing opacity electrode structure and intelligent wearing equipment

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