CN106205788B - A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification - Google Patents
A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification Download PDFInfo
- Publication number
- CN106205788B CN106205788B CN201610761941.6A CN201610761941A CN106205788B CN 106205788 B CN106205788 B CN 106205788B CN 201610761941 A CN201610761941 A CN 201610761941A CN 106205788 B CN106205788 B CN 106205788B
- Authority
- CN
- China
- Prior art keywords
- nano
- silver thread
- pet
- base material
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
Landscapes
- Laminated Bodies (AREA)
- Conductive Materials (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Non-Insulated Conductors (AREA)
Abstract
The present invention relates to flexible transparent conductive film technical field, a kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification is specifically disclosed, including：PET base material selects the optical grade plated film PET handled by two-sided hardened layer, and PET base material is handled, cleaned using acetone and alcohol mixed solvent, drying for standby；0.1 10g coupling agents are added in the nano-silver thread ethanol solution that concentration is 0.01 10mg/ml, are warming up to 30 150 DEG C of 30 240min of stirring and obtain nano-silver thread mixed liquor；PET base material after the removal of impurities of surface is immersed in nano-silver thread mixed liquor, reaction temperature is controlled in 30 120 DEG C, the 180min of time 30, after reaction terminates, rinsed repeatedly through distilled water, then in 60 180 DEG C of 240min of oven cooking cycle 30, prepare transparent conductive film.The PET/ nano-silver thread transparent conductive films adhesive force of the present invention is strong, and resistance to deflection is improved, while mild condition, simple to operate, has very high application value for flexible electronic field.
Description
Technical field
The present invention relates to flexible transparent conductive film technical field, and in particular to a kind of PET/ nanometers of grafting modification
The preparation of silver wire nesa coating.
Background technology
Transparent conductive film is a kind of both conductive, has the film of high light transmittance again, is widely used in liquid crystal
Show, the electronic component field such as contact panel and solar cell.Following mobile terminal, wearable device, intelligent appliance etc. are produced
Product, have solid demand to touch panel, while as contact panel is in large size, low priceization, and traditional ito thin film can not
Applied to deformable surface, the factor such as the essential problem such as electric conductivity and light transmittance is not easily overcome, many manufacturers begin one's study ITO's one after another
Substitute, including the material such as nano-silver thread, metal grill, CNT and graphene.From market reaction, using new
Proportion shared by the film product of material technology production is being improved year by year.At present, graphene is still in development, from volume production also
There is far distance.CNT industrial volume production technology is not perfect enough, and its film product electric conductivity being made can't reach
The level of common ito thin film.The product of metal grill fabrication techniques has unsurmountable unauspicious interference problem, using being limited
System.To the line width of metal in reduction metal grill, then need more to change system into technique, cost can increase therewith, and have easily
The problems such as broken string.And nano-silver thread technology is then the most possible new material close to volume production.
Nano-silver thread technology is simple because of making technology, the contact panel of large area can be quickly produced using printing process, together
When there is less bending radius, and in bending, resistance change rate is smaller, applies in the equipment shown with flexible curved surface.It is existing
The backing material used in some flexible curved surface equipment is generally polyethylene terephthalate (PET) film, PET macromolecular chains
Compound with regular structure, crystallinity is higher, and without highly polar group in molecule, therefore its surface compatibility is poor.The side mainly used at present
Method has surface cladding process, surface oxidation method, plasma method, high-energy radiation, ultraviolet radiation etc., but this have impact on PET's
Bulk properties are unable to reach long-term modified effect.It can be seen that, prior art still suffers from larger defect.
The content of the invention
In view of this, it is necessary in view of the above-mentioned problems, offer is a kind of can both to have reached that surface was modified the mesh for improving adhesive force
, the preparation method of the PET/ nano-silver thread nesa coatings of the grafting modification of the bulk properties of base material will not be damaged again.
To achieve the above object, the present invention takes following technical scheme：
The preparation of the PET/ nano-silver thread nesa coatings of the grafting modification of the present invention, including：Remove on PET base material surface
Miscellaneous, nano-silver thread mixed liquor preparation and the preparation of nesa coating；
PET base material surface removal of impurities includes：PET base material selects the optical grade plated film PET handled by two-sided hardened layer,
And use acetone is handled PET base material, cleaned with alcohol mixed solvent, drying for standby；
Prepared by the nano-silver thread mixed liquor include：It is 0.01-10mg/ml's that 0.1-10g coupling agents are added into concentration
In nano-silver thread ethanol solution, obtained coupling agent-nano-silver thread ethanol solution is warming up to 30-150 DEG C of stirring 30-240min and obtained
To nano-silver thread mixed liquor；
The preparation of nesa coating includes：PET base material after the removal of impurities of surface is immersed in nano-silver thread mixed liquor, instead
Answer temperature control at 30-120 DEG C, time 30-180min after reaction terminates, is rinsed repeatedly through distilled water, then roasting at 60-180 DEG C
Case toasts 30-240min, prepares transparent conductive film.
As preferred, the coupling agent addition is 0.1-5g, and the concentration of nano-silver thread ethanol solution is 0.01-5mg/
ml。
As preferred, the coupling agent-nano-silver thread ethanol solution is warming up to 30-120 DEG C of stirring 30-150min.
As preferred, in the preparation of the nesa coating, reaction temperature is controlled in 30-100 DEG C, time 30-
150min；The oven cooking cycle temperature is 60-120 DEG C, and the time is 30-150min.
As preferred, the PET base material thickness is 50um, 100um, 125um, and carries diaphragm.
As preferred, the absolute ethyl alcohol is 1 with acetone volume ratio.
As preferred, the coupling agent is mercaptosilane coupling agents KH-580 or mercaptosilane coupling agents KH-590.
Further, the coupling agent is mercaptosilane coupling agents KH-590.
The transparent conductive film thickness that the present invention is prepared is 50-600nm, preferably 50-300nm.
Compared with existing nano-silver thread transparent conductive film technology, beneficial effects of the present invention are：
The present invention is scattered in ethanol using nano-silver thread substitution nano-Ag particles as thin film of conductive material, passes through silver wire
Between contact with each other and reach conductive purpose；
Made by the sulfydryl of silane coupler one end and the coordination of Nano Silver even on nano-silver thread surface chemical modification
Join agent, while the siloxy group of the coupling agent other end is combined with the hardened layer on pet sheet face, will be received in the form of chemical bonding
Rice silver wire is fixedly attached to pet sheet face, the adhesive force of the nano-silver thread transparent conductive film of preparation is largely increased.
The transparent conductive film adhesive force of the present invention is strong, and resistance to deflection is improved, while mild condition, simple to operate,
There is very high application value for flexible electronic field.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the embodiment of the present invention, to this hair
Bright technical scheme is made further clearly and completely to describe.It should be noted that described embodiment is only the present invention one
Section Example, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not doing
Go out the every other embodiment obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1
Step 1) removal of impurities of PET base material surface：50um optical-grade double-sides with diaphragm are hardened into the anhydrous second of PET base material
After alcohol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80 DEG C
The PET base material of clean surface is obtained after vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：0.5g silane couplers KH-590 is added to receiving for 0.08mg/ml
In rice silver wire ethanol solution, obtained coupling agent-nano-silver thread ethanol solution is prepared after 60 DEG C of magnetic agitation 90min
Nano-silver thread mixed liquor；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after 40 DEG C of temperature, reaction 150min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through toasting 60min at 100 DEG C of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Embodiment 2
Step 1) removal of impurities of PET base material surface：50um optical-grade double-sides with diaphragm are hardened into the anhydrous second of PET base material
After alcohol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80 DEG C
The PET base material of clean surface is obtained after vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：1g silane couplers KH-590 is added to 0.3mg/ml Nano Silver
In line ethanol solution, after 90 DEG C of magnetic agitation 60min, nano-silver thread mixed liquor is prepared；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after temperature 60 C, reaction 120min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through the lower 60min of 100 DEG C of bakings of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Embodiment 3
Step 1) removal of impurities of PET base material surface：By the 100um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：0.5g silane couplers KH-590 is added to receiving for 0.08mg/ml
In rice silver wire ethanol solution, after 60 DEG C of magnetic agitation 90min, nano-silver thread mixed liquor is prepared；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after 40 DEG C of temperature, reaction 150min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through toasting 60min at 100 DEG C of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Embodiment 4
Step 1) removal of impurities of PET base material surface：By the 100um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：1g silane couplers KH-590 is added to 0.3mg/ml Nano Silver
In line ethanol solution, after 90 DEG C of magnetic agitation 60min, nano-silver thread mixed liquor is prepared；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after temperature 60 C, reaction 120min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through the lower 60min of 100 DEG C of bakings of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Embodiment 5
Step 1) removal of impurities of PET base material surface：By the 125um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：0.5g silane couplers KH-590 is added to receiving for 0.08mg/ml
In rice silver wire ethanol solution, after 60 DEG C of magnetic agitation 90min, nano-silver thread mixed liquor is prepared；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after 40 DEG C of temperature, reaction 150min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through the lower 60min of 100 DEG C of bakings of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Embodiment 6
Step 1) removal of impurities of PET base material surface：By the 125um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread mixed liquor preparation：3g silane couplers KH-590 is added to 2mg/ml nano-silver thread
In ethanol solution, after 90 DEG C of magnetic agitation 60min, nano-silver thread mixed liquor is prepared；
Step 3) nesa coating preparation：By step 1) the obtained PET base material of clean surface is immersed in step 2) system
In standby nano-silver thread mixed liquor, after 90 DEG C of temperature, reaction 120min, rinse PET base material surface repeatedly through distilled water and do not connect
The polymer of branch, then through the lower 100min of 90 DEG C of bakings of oven temperature, obtain the PET/ nano-silver thread electrically conducting transparents that thickness is 50nm
Film.
Comparative example 1
Step 1) removal of impurities of PET base material surface：50um optical-grade double-sides with diaphragm are hardened into the anhydrous second of PET base material
After alcohol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80 DEG C
The PET base material of clean surface is obtained after vacuum drying；
Step 2) nano-silver thread transparent conductive film preparation：Directly by step 1) the obtained PET base material of clean surface
Be immersed in 0.3mg/ml nano-silver thread ethanol solution, 60 DEG C dipping 180min, with after distilled water flushing through oven temperature 100
DEG C baking 60min, obtain thickness be 40nm nano-silver thread transparent conductive film.
Comparative example 2
Step 1) removal of impurities of PET base material surface：By the 100um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread transparent conductive film preparation：Directly by step 1) the obtained PET base material of clean surface
Be immersed in 0.3mg/ml nano-silver thread ethanol solution, 60 DEG C dipping 180min, with after distilled water flushing through oven temperature 100
DEG C baking 60min, obtain thickness be 40nm nano-silver thread transparent conductive film.
Comparative example 3
Step 1) removal of impurities of PET base material surface：By the 125um optical-grade double-sides hardening PET base material with diaphragm with anhydrous
After ethanol/acetone volume ratio is 1 mixed solvent cleaning, then with the mixed solvent of distilled water flushing PET base material remained on surface, 80
The PET base material of clean surface is obtained after DEG C vacuum drying；
Step 2) nano-silver thread transparent conductive film preparation：Directly by step 1) the obtained PET base material of clean surface
Be immersed in 0.3mg/ml nano-silver thread ethanol solution, 60 DEG C dipping 180min, with after distilled water flushing through oven temperature 100
DEG C baking 60min, obtain thickness be 40nm nano-silver thread transparent conductive film.
It is the properties for determining each PET nano-silver thread transparent conductive film of the embodiment through grafting modification in table 1
Index：
The performance of nano-silver thread transparent conductive film in the various embodiments described above of table 1
As can be known from the above table, it is of the invention strong through grafting modification PET nano-silver thread transparent conductive films adhesive force, it is resistance to scratch
Song is improved, while mild condition, simple to operate, has very high application value for flexible electronic field.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (6)
1. a kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification, it is characterised in that including：PET base material
Surface removal of impurities, the preparation of nano-silver thread mixed liquor and the preparation of nesa coating；
PET base material surface removal of impurities includes：PET base material selects the optical grade plated film PET handled by two-sided hardened layer, and adopts
PET base material is handled with acetone and absolute ethyl alcohol mixed solvent, cleaned, drying for standby；
Prepared by the nano-silver thread mixed liquor include：0.1-10g coupling agents are added to the nanometer that concentration is 0.01-10mg/ml
In silver wire ethanol solution, obtained coupling agent-nano-silver thread ethanol solution is warming up to 30-150 DEG C of stirring 30-240min and received
Rice silver wire mixed liquor；
The preparation of nesa coating includes：PET base material after the removal of impurities of surface is immersed in nano-silver thread mixed liquor, reaction temperature
Degree control is at 30-120 DEG C, and time 30-180min after reaction terminates, is rinsed repeatedly through distilled water, then is dried in 60-180 DEG C of baking box
Roasting 30-240min, prepares transparent conductive film；
The coupling agent is mercaptosilane coupling agents KH-580 or mercaptosilane coupling agents KH-590.
2. the preparation of the PET/ nano-silver thread nesa coatings of grafting modification according to claim 1, its feature exists
In the coupling agent addition is 0.1-5g, and the concentration of nano-silver thread ethanol solution is 0.01-5mg/ml.
3. the preparation of the PET/ nano-silver thread nesa coatings of grafting modification according to claim 1, its feature exists
In the coupling agent-nano-silver thread ethanol solution is warming up to 30-120 DEG C of stirring 30-150min.
4. the preparation of the PET/ nano-silver thread nesa coatings of grafting modification according to claim 1, its feature exists
In in the preparation of the nesa coating, reaction temperature is controlled in 30-100 DEG C, time 30-150min；The oven cooking cycle temperature
Spend for 60-120 DEG C, the time is 30-150min.
5. the system of the PET/ nano-silver thread nesa coatings of the grafting modification according to claim 1-4 any one
It is standby, it is characterised in that the PET base material thickness is 50um, 100um, 125um, and carries diaphragm.
6. the system of the PET/ nano-silver thread nesa coatings of the grafting modification according to claim 1-4 any one
It is standby, it is characterised in that the absolute ethyl alcohol is 1 with acetone volume ratio.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610761941.6A CN106205788B (en) | 2016-08-29 | 2016-08-29 | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification |
| PCT/CN2017/098060 WO2018040955A1 (en) | 2016-08-29 | 2017-08-18 | Preparation of chemical grafting-modified pet/nano silver wire transparent conductive film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610761941.6A CN106205788B (en) | 2016-08-29 | 2016-08-29 | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106205788A CN106205788A (en) | 2016-12-07 |
| CN106205788B true CN106205788B (en) | 2017-10-31 |
Family
ID=58088530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610761941.6A Active CN106205788B (en) | 2016-08-29 | 2016-08-29 | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN106205788B (en) |
| WO (1) | WO2018040955A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106205788B (en) * | 2016-08-29 | 2017-10-31 | 广东纳路纳米科技有限公司 | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification |
| CN106648226A (en) * | 2016-12-08 | 2017-05-10 | 上海交通大学 | Transparent pressure sensor and manufacturing method of piezoresistive material thereof |
| CN109949974B (en) * | 2019-03-15 | 2020-08-25 | 广东格瑞纳思薄膜科技有限公司 | Covalently bonded PET-based nano silver wire graphene composite transparent flexible conductive film and preparation method thereof |
| CN111796344A (en) * | 2019-04-08 | 2020-10-20 | 超晶维(昆山)光电科技有限公司 | Preparation method of silicon dioxide nano silver wire antireflection film |
| CN111180112B (en) * | 2020-01-16 | 2021-05-28 | 南通纺织丝绸产业技术研究院 | Metal nanowire flexible conductive film and preparation method thereof |
| CN111440346B (en) * | 2020-03-12 | 2023-08-01 | 深圳市华科创智技术有限公司 | Antibacterial layer of nano silver wire and antibacterial mask of nano silver wire |
| CN113393975B (en) * | 2021-06-09 | 2022-11-04 | 哈尔滨工业大学 | Preparation method of surface-modified silver nanowire flexible transparent conductive film |
| CN114753142B (en) * | 2022-05-24 | 2023-11-24 | 浙江王金非织造布有限公司 | Durable antibacterial spunlaced non-woven fabric for artificial leather and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011228243A (en) * | 2010-03-31 | 2011-11-10 | Fujifilm Corp | Conductive composition, transparent conductor using the same, touch panel, and solar cell |
| CN103996455A (en) * | 2014-04-30 | 2014-08-20 | 天津宝兴威科技有限公司 | Manufacturing method for nanometal transparent conductive film |
| CN104658700A (en) * | 2015-01-23 | 2015-05-27 | 华南师范大学 | Preparation method for transparent silver nanowire conducting electrode |
| CN104867540A (en) * | 2015-04-16 | 2015-08-26 | 浙江科创新材料科技有限公司 | Low-haze transparent conductive film and preparation method thereof |
| CN104999072A (en) * | 2015-06-29 | 2015-10-28 | 南京宜洛辞电子科技有限公司 | Redispersible silver nanowire mixture and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140072826A1 (en) * | 2012-09-13 | 2014-03-13 | Carestream Health, Inc. | Anticorrosion agents for transparent conductive film |
| KR101518875B1 (en) * | 2013-12-31 | 2015-05-12 | 주식회사 효성 | Multi-branched silver nanowire, preparing method of the same and transparent conductive film including the same |
| CN104637570A (en) * | 2015-01-29 | 2015-05-20 | 深圳市东丽华科技有限公司 | Flexible transparent conductive thin film and preparation method thereof |
| CN105185468B (en) * | 2015-08-28 | 2017-12-05 | 东莞市纳利光学材料有限公司 | A kind of preparation method of nesa coating metal grill |
| CN106205788B (en) * | 2016-08-29 | 2017-10-31 | 广东纳路纳米科技有限公司 | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification |
-
2016
- 2016-08-29 CN CN201610761941.6A patent/CN106205788B/en active Active
-
2017
- 2017-08-18 WO PCT/CN2017/098060 patent/WO2018040955A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011228243A (en) * | 2010-03-31 | 2011-11-10 | Fujifilm Corp | Conductive composition, transparent conductor using the same, touch panel, and solar cell |
| CN103996455A (en) * | 2014-04-30 | 2014-08-20 | 天津宝兴威科技有限公司 | Manufacturing method for nanometal transparent conductive film |
| CN104658700A (en) * | 2015-01-23 | 2015-05-27 | 华南师范大学 | Preparation method for transparent silver nanowire conducting electrode |
| CN104867540A (en) * | 2015-04-16 | 2015-08-26 | 浙江科创新材料科技有限公司 | Low-haze transparent conductive film and preparation method thereof |
| CN104999072A (en) * | 2015-06-29 | 2015-10-28 | 南京宜洛辞电子科技有限公司 | Redispersible silver nanowire mixture and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018040955A1 (en) | 2018-03-08 |
| CN106205788A (en) | 2016-12-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106205788B (en) | A kind of preparation of the PET/ nano-silver thread nesa coatings of grafting modification | |
| CN104992752B (en) | A kind of production method of nano-silver thread transparent conductive film | |
| CN106128564B (en) | The preparation method of PET/ nano-silver thread nesa coatings through illumination sintering processes | |
| CN106298071B (en) | The preparation method of PET base material based on hydrophilic modifying/nano-silver thread nesa coating | |
| JP6832850B2 (en) | Compositions containing silver nanowires and crystalline cellulose fibers for the production of conductive transparent layers | |
| CN105118546B (en) | A kind of nano silver wire transparent conductive film of new oxide protection | |
| CN104927090B (en) | Flexible transparent conductive composite membrane made from graphene and cellulose, and preparation method therefor | |
| KR101670538B1 (en) | Conductive film, method for manufacturing same, touch panel, and solar cell | |
| CN104882223A (en) | Oxidized graphene/silver nanowire composite transparent conducting thin film and preparation method thereof | |
| CN105895196B (en) | A kind of novel transparent conductive film and preparation method thereof | |
| WO2011162322A1 (en) | Conductive film, touch panel, and solar cell | |
| CN103903682A (en) | Transparent conductor and apparatus including the same | |
| CN109095782A (en) | A kind of preparation method of the silver nanowires transparent conductive film based on 3 D stereo micro-structure | |
| CN105542641A (en) | Carbon nanotube antistatic film with strong adhesion, high light transmittance and low surface resistance, and production technology thereof | |
| Imazu et al. | Fabrication of flexible transparent conductive films from long double-walled carbon nanotubes | |
| CN106576425A (en) | Composition comprising silver nanowires and styrene/(meth)acrylic copolymers for the preparation of electroconductive transparent layers | |
| CN108039221B (en) | Flexible transparent conductive film and preparation method thereof | |
| CN107768023A (en) | There is composite construction conducting film of high adhesion force and preparation method thereof based on graphene | |
| WO2012023553A1 (en) | Electrically conductive material, touch panel, and solar cell | |
| CN104867541B (en) | A kind of transparent conductive film and preparation method thereof | |
| JP5639463B2 (en) | Conductive composition, and transparent conductor, touch panel and solar cell using the same | |
| CN106229081B (en) | A kind of preparation of chemical graft and the PET/ graphene transparent conductive films of coating process | |
| CN108766666B (en) | Low-resistance and high-transmittance nano silver wire transparent conductive film and preparation method thereof | |
| CN104527165B (en) | Half-reflection and half-transmission glass and preparation method thereof | |
| KR20130003467A (en) | Transparent conductive film containing a carbon nanotube and method for preparing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Duan Xidong Inventor after: Li Xiaofeng Inventor after: Mao Zhihao Inventor before: Duan Xiangfeng Inventor before: Duan Xidong Inventor before: Li Xiaofeng Inventor before: Mao Zhihao |
|
| CB03 | Change of inventor or designer information |