CN1061955C - Electronic radiation coating solidified light magnesium cement plate and working technology thereof - Google Patents
Electronic radiation coating solidified light magnesium cement plate and working technology thereof Download PDFInfo
- Publication number
- CN1061955C CN1061955C CN96122263A CN96122263A CN1061955C CN 1061955 C CN1061955 C CN 1061955C CN 96122263 A CN96122263 A CN 96122263A CN 96122263 A CN96122263 A CN 96122263A CN 1061955 C CN1061955 C CN 1061955C
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- CN
- China
- Prior art keywords
- cement plate
- coating
- magnesium cement
- light magnesium
- electronic radiation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4826—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to an electronic radiation coating solidified light magnesium cement plate and a processing technology thereof. The product uses a magnesium cement plate as a base material, coating is spread on the magnesium cement plate, and then, the magnesium cement plate is solidified through electron radiation. The coating is composed of modified unsaturated polyester resin, epocryl, trimethylolpropane triacrylate, styrene, 1, 6, hexanediol biacrylate, an additive agent and pigment. The present invention has the processing technology that the surface of the cement plate is coated by glue solution, and coating is coated on the glue solution; then, irradiation is carried out on the basis of acceleration. The magnesium cement plate prepared by the present invention has the advantages of thermal insulation, high mechanical strength, high surface smoothness, water resistance, dirt resistance and corrosion resistance, and the technology has the advantages of energy conservation and no pollution.
Description
The present invention relates to a kind of electronic radiation coating solidified light magnesium cement plate and complete processing thereof.
Nuclear technique is one of contemporary new and high technology.Radiation processing technology is the widest, the most active emerging manufacture field of range of application in the nuclear technique, it in this century the seventies formed some scale industries.The branch of industry of at present existing many sophisticated steady growths.Owing to adopt the material of construction of radiotechnology processing to have higher intensity and surface of good chemical physical property, thereby adopt the technology of coating curing radiation processing building materials also to use more; As all there is the producer of New Building Materials such as radiation processing plank, force fit plate, silicon cement plate, plasterboard, iron plate in states such as (beautiful, add), West Europe (method, meaning, moral), Russia, order and Indonesia in the North America.Muscovite Slmferopol and Kiev plant produced a kind of EB coating curing plank, the prescription of its coating is made up of trimethylolpropane allyl ether and modified unsaturated polyester 50%, triethylene glycol dimethacrylate 40%, triethylene glycol phthalic acid ester 10%; This coating is coated in that to carry out irradiation time institute nitrogen consuming amount on the plank less, but residual volume height, the irradiation dose of oxygen are big, curing speed is slow.The wood coatings prescription that U.S. Sartomer company is recommended is by acrylic-amino ester 12%.The third oxidation neopentylglycol diacrylate 20.15%.Ethoxyquin Viscoat 295 22%.Ethoxy ethoxy ethyl propylene acid esters 7%, titanium oxide 35%, additive 3.85% are formed; When the coating of this formulated was coated on the timber irradiation, its curing speed was fast, but raw material is rare and valency is high.Units such as domestic Shanghai Science and Technology Univ., Sichuan University also did the radiation curing research of building materials such as plank, silicon cement plate, plasterboard.As the metal sheet coating curing material of Shanghai University of Science and Technology development, its coating formula is made up of acroleic acid resin 35%, acroleic acid polyurethane 15%, butyl acrylate 32%, vinylformic acid 4%, vinylformic acid 2-diethyl acetamidomalonate 5%, cyclohexyl acrylate 9%; The paint brush of this formulated is when metal sheet surface, and its flexibility is good, and it is fast to add the man-hour curing speed; But its low in glossiness, nitrogen consuming amount is big.At present with low energy (200keV) electrocurtain accelerator, at high O
2The research of irradiation processing lightweight chloro-magnesium cement plate does not appear in the newspapers as yet under the environment.At present, along with increasing day by day and all kinds of decorations day by day luxurious of Highrise buildings, novel fire prevention, water-fastly wash, the demand of corrosion resistant building and ornament materials also increases day by day; Thereby the kind of all kinds of matrix materials is more on the market, as in China 93215903.6, disclosing a kind of " magnesite fire-resistant decoration plate ", this sheet material is to be base material with the magnesite plate, brushing one deck adhesive linkage thereon, one deck paper rete is pasted on the upper strata of adhesive linkage, the paper rete can be selected color pattern arbitrarily, top attaching one top layer of paper rete
The objective of the invention is for a kind of lightweight, insulation, physical strength height, surface smoothness height be provided, water-fastly wash, resistant, corrosion-resistant, energy-conservation, free of contamination electronic radiation coating solidified light magnesium cement plate.
Another object of the present invention is for the complete processing of the electronic radiation coating solidified light magnesium cement plate that a kind of complete processing is simple, cost is low, the equipment working cost is low is provided.
Purpose of the present invention can realize by following measure:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 10-55%, Epocryl 10-30%, Viscoat 295 5-21%, vinylbenzene 3-20%, 1,6 hexanediol diacrylate 5-20%, additive 0.5-3%, pigment 5-25%.
Its complete processing contains following step: (1) removes the floating ash in light magnesium cement plate surface; (2) become (4-6) with vegetable jelly with 75% ethanol: the glue that 1 weight ratio is made sprays the surface; (3) coat the coating of making by the coating material prescription on its surface again, its coat-thickness is 40-70g/m
2(4) logical nitrogen and oxygen in the accelerator irradiation box, the control oxygen content is (2-5) * 10
3Ppm; (5) will be coated with the light magnesium cement plate of coating and carry out irradiation on accelerator, its irradiation dose is 5-7Mrad.
Purpose of the present invention also can realize by following measure:
Additive in the coating material prescription of electronic radiation coating solidified light magnesium cement plate is defoamer, flow agent, Ricinate, and its pigment is at least a kind of in carbon black, toluidine red, titanium white, the medium chrome yellow medium yellow; The molecular structural formula of the modified unsaturated polyester resin in the prescription (nearly company of Lanzhou section produces) is:
In the formula: R is fatty chain hydrocarbon, carbon number-2-4, and 0-8-9, molecular-weight average are 2000-3000, and acid number is 20-30, and the molecular structural formula of the Epocryl in the side (nearly company of Lanzhou section produces) is:
, R is in the formula:
Acid number is 9-11.
The present invention has following advantage compared to existing technology:
1, the present invention is matrix with the light magnesium cement plate, apply coating thereon, again through electron irradiation, its top coat is solidified, thereby improve magnesia cement plate Surface Physical chemical property, the smooth finish on magnesia cement plate surface is improved reach the glaze effect, its gloss can improve 94%, and water-fastly wash, fire prevention, resistant, heat-resisting, corrosion-resistant.
2, in the coating compounding of the present invention with modified unsaturated polyester resin and Epocryl as main film forming matter, thereby make coating have super quality and competitive price, and fire prevention, water-fastly wash, acid-resistant property,, 10%HCL not show-through through washing more than 2000 times soak 48 hours non-foaming, do not come off.
3, add Viscoat 295 in the coating compounding of the present invention as reactive monomer, can improve speed of response, increase film forming matter hardness, and can reduce irradiation dose.
4, add vinylbenzene in the coating compounding of the present invention as reactive monomer,, improve into film hardness so that reduce cost; And add 1,6 hexanediol diacrylate and make reactive monomer, to increase the sticking power of film, the smooth finish of coatingsurface is improved, and adhere to evenly.
5, light magnesium cement plate of the present invention hardening with radiation after coated increases the intensity of sheet material greatly.Thereby can be used as furred ceiling, indoor and outdoor wall decorates, provides a kind of type material for the decoration of house, public place, Highrise buildings.
6, use N during simple, the irradiation of complete processing of the present invention
2Amount is few, the environmental oxygen concentration height, thus can cut down finished cost.Can reduce equipment running cost thereby the energy of its required irradiation apparatus is low in addition, dosage is low.
The present invention also will be described in further detail in conjunction with the embodiments:
Embodiment one:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, thereon applying coating, make through electron beam curing; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 55%.Epocryl 10%, Viscoat 295 21%, vinylbenzene 3%, 1,6 hexanediol diacrylate 5%, additive 1%, pigment carbon black 5%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is 2.Its structural formula is HO-CH
2-CH
2-OH, molecular-weight average are 2000, acid number is 20; The acid number of described Epocryl is 10; Described additive is a defoamer.Flow agent and Ricinate can directly be bought finished product from the market; Its usage quantity separately should be looked end properties index Field adjustment, but the total amount of additive is constant.
A kind of complete processing of electronic radiation coating solidified light magnesium cement plate contains following step: (1) removes the floating ash in light magnesium cement plate surface; (2) glue that becomes 5: 1 weight ratio to make with vegetable jelly with 75% ethanol sprays the surface; (3) coat the coating of making by the coating material prescription on its surface again, its coat-thickness is 45g/m
2(4) logical nitrogen and oxygen in the accelerator irradiation box, the control oxygen content is 4.5 * 10
3Ppm; (5) will be coated with the light magnesium cement plate of coating and carry out irradiation on accelerator, its irradiation dose is 6Mrad.
Embodiment two:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 45%, Epocryl 15%, Viscoat 295 20%, vinylbenzene 7%, 1,6 hexanediol diacrylate 5%, additive 1%, toluidine red 7%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is 3, and its structural formula is HO-CH
3CH
2CH
2-OH, molecular-weight average are 2500, acid number is 25.
Its complete processing and example together, its coat-thickness is 60g/m
2, oxygen content is 4 * 10
3Ppm, required irradiation dose are 5Mrad.
Embodiment three:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 35%, Epocryl 20%, Viscoat 295 15%, vinylbenzene 8%, 1,6 hexanediol diacrylate 6%, additive 1.5%, titanium white 14.5%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is 4, and its structural formula is HO-CH
2(CH
2)
2CH
2-OH, molecular-weight average are 3000, acid number is 30.
Its complete processing and example together, its coat-thickness is 70g/m
2, oxygen content is 4 * 10
3Ppm, required irradiation dose are 7Mrad.
Embodiment four:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 25%, Epocryl 25%, Viscoat 295 10%, vinylbenzene 20%, 1,6 hexanediol diacrylate 10%, additive 0.5%, titanium white 9.5%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is 4, and its structural formula is HO-CH
2(CH
2)
2CH
2-OH, molecular-weight average are 2800, acid number is 27.
Its complete processing and example together, its coat-thickness is 55g/m
2, oxygen content is 3 * 10
3Ppm, required irradiation dose are 6.5Mrad.
Embodiment five:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 15%, Epocryl 30%, Viscoat 295 5%, vinylbenzene 10%, 1,6 hexanediol diacrylate 15%, additive 0.5%, titanium white 24.5%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is 3, and its structural formula is:
Molecular-weight average is 2600, acid number is 24.
Its complete processing and example together, its coat-thickness is 55g/m
2, oxygen content is 2.5 * 10
3Ppm, required irradiation dose are 5.5Mrad.
Embodiment six:
A kind of electronic radiation coating solidified light magnesium cement plate is to be base-material with the light magnesium cement plate, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is: modified unsaturated polyester resin 10%, Epocryl 30%, Viscoat 295 10%, vinylbenzene 13%, 1,6 hexanediol diacrylate 20%, additive 3%, medium chrome yellow medium yellow 14%.The carbon number of R in the molecular structural formula of described modified unsaturated polyester resin is that 2 its structural formulas are HO-CH
2-CH
2-OH, molecular-weight average are 2200, acid number is 22.
Its complete processing and example together, its coat-thickness is 45g/m
2, oxygen content is 2 * 10
3Ppm, required irradiation dose are 6Mrad.
Claims (3)
1, a kind of electronic radiation coating solidified light magnesium cement plate is characterized in that with the light magnesium cement plate being base-material, and applying coating is made through electron beam curing thereon; The raw material weight percentage composition of its coating is:
Modified unsaturated polyester resin 10-55%, the molecular structural formula of described modified unsaturated polyester resin is:
In the formula: R is fatty chain hydrocarbon, carbon number=2-4, and n=8-9, molecular-weight average are 2000-3000, acid number is 20-30;
Epocryl 10-30%, the molecular structural formula of described Epocryl is:
, R is in the formula:
Acid number is 9-11;
Viscoat 295 5-21%
Vinylbenzene 3-20%
1,6 hexanediol diacrylate 5-20%
Additive 0.5-3%, described additive are defoamer, flow agent, Ricinate;
Pigment 5-25%.
2, electronic radiation coating solidified light magnesium cement plate as claimed in claim 1 is characterized in that pigment in its coating material prescription is at least a kind of in carbon black, toluidine red, titanium white, the medium chrome yellow medium yellow.
3, the production method of the described electronic radiation coating solidified light magnesium cement plate of a kind of claim 1, its feature foot contains following step: (1) removes the floating ash in light magnesium cement plate surface; (2) become (4-6) with vegetable jelly with 75% ethanol: the glue that 1 weight ratio is made sprays the surface; (3) coat the coating of making by the coating material prescription on its surface again, its coat-thickness is 40-709/m
2: (4) are helium injection gas in the accelerator irradiation box, and the control oxygen content is (2-5) * 10 ' ppm; (5) will be coated with the light magnesium cement plate of coating and carry out irradiation on accelerator, its irradiation dose is 5-7Mrad.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96122263A CN1061955C (en) | 1996-11-20 | 1996-11-20 | Electronic radiation coating solidified light magnesium cement plate and working technology thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96122263A CN1061955C (en) | 1996-11-20 | 1996-11-20 | Electronic radiation coating solidified light magnesium cement plate and working technology thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1182724A CN1182724A (en) | 1998-05-27 |
| CN1061955C true CN1061955C (en) | 2001-02-14 |
Family
ID=5127212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96122263A Expired - Fee Related CN1061955C (en) | 1996-11-20 | 1996-11-20 | Electronic radiation coating solidified light magnesium cement plate and working technology thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1061955C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1989161B (en) * | 2004-07-29 | 2010-05-05 | 大日本油墨化学工业株式会社 | Actinic radiation-curable resin composition for shaping, shaping sheet, and shaped product |
| US8202578B2 (en) | 2005-11-15 | 2012-06-19 | Valspar Sourcing, Inc. | Crush resistant latex topcoat composition for fiber cement substrates |
| US9783622B2 (en) | 2006-01-31 | 2017-10-10 | Axalta Coating Systems Ip Co., Llc | Coating system for cement composite articles |
| US7834086B2 (en) | 2006-06-02 | 2010-11-16 | Valspar Sourcing, Inc. | High performance aqueous coating compositions |
| US8932718B2 (en) | 2006-07-07 | 2015-01-13 | Valspar Sourcing, Inc. | Coating systems for cement composite articles |
| BRPI0721910A2 (en) * | 2007-08-01 | 2014-02-25 | Valspar Sourcing Inc | COATED ARTICLE, AND METHOD FOR PREPARING COATED ARTICLE. |
| WO2010060109A1 (en) | 2008-11-24 | 2010-05-27 | Valspar Sourcing, Inc. | Coating system for cement composite articles |
| CN101935494B (en) * | 2010-08-18 | 2013-11-13 | 梁鹏飞 | Ultraviolet-cured resin composition and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263749A1 (en) * | 1986-10-02 | 1988-04-13 | Societe Nationale Des Poudres Et Explosifs | Process for the preparation of radiocrosslinked coatings |
| EP0429279A1 (en) * | 1989-11-17 | 1991-05-29 | Mitsubishi Rayon Co., Ltd. | Photocross-linkable resin compositions and their use in the manufacture of dry film resists |
-
1996
- 1996-11-20 CN CN96122263A patent/CN1061955C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263749A1 (en) * | 1986-10-02 | 1988-04-13 | Societe Nationale Des Poudres Et Explosifs | Process for the preparation of radiocrosslinked coatings |
| EP0429279A1 (en) * | 1989-11-17 | 1991-05-29 | Mitsubishi Rayon Co., Ltd. | Photocross-linkable resin compositions and their use in the manufacture of dry film resists |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1182724A (en) | 1998-05-27 |
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