CN106191944A - A kind of preparation method of metal film artware - Google Patents
A kind of preparation method of metal film artware Download PDFInfo
- Publication number
- CN106191944A CN106191944A CN201610829986.2A CN201610829986A CN106191944A CN 106191944 A CN106191944 A CN 106191944A CN 201610829986 A CN201610829986 A CN 201610829986A CN 106191944 A CN106191944 A CN 106191944A
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- Prior art keywords
- artware
- metal film
- preparation
- plating
- metal
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
Abstract
The present invention relates to the preparation method of a kind of metal film artware.The invention belongs to artware technical field.The preparation method of a kind of metal film artware, comprises the following steps that: 1. surface processes: being modified by handicraft surface, shaping also carries out cleaning process；The quickest activation: artware liquid immersion is processed, clean by pure water rinsing after process；3. metallization: the artware after activation is metallized by conductive paint or chemical plating method, makes handicraft surface cover metal conducting layer；4. copper facing: metallized artware carries out copper facing by electro-plating method, makes handicraft surface cover metallic copper；5. nickel plating: the artware after copper facing carries out metal nickel plating by electro-plating method, 6, plating precious metal；Finally make handicraft surface cover layer of precious metal, make metal film artware.It is unique that the present invention has technique, simple and practical, makes the advantages such as fine, applied widely；Artware form preserves complete, comes in every shape, attractive in appearance beautiful, magnificent wealth and rank, and ornamental value is high.
Description
Technical field
The invention belongs to artware technical field, particularly relate to the preparation method of a kind of metal film artware.
Background technology
At present, raw material or semi-finished product are typically processed by artware by craft or machine.Conventional smithcraft
Product generally use metal handicraft wire to carry out the modern technology woven, and it can be woven into various colourful life
Articles for use, it is also possible to be woven into the various adornment with art collection value or artistic decoration effect.Existing technique and for
Plant or animal body cannot be carried out practical operation to be implemented, and, there is complex manufacturing process, manual system in the artware prepared
Making, become more meticulous difference, and unsightly, particularly its form is true, does not has natural intelligence for product, can long-term preservability poor, artistic ornamental
It is worth the technical problems such as low.
Summary of the invention
The present invention solves technical problem present in known technology and the preparation method of a kind of metal film artware is provided.
It is an object of the invention to provide one and there is technique uniqueness, simple and practical, make fine, applied widely；Technique
Product form preserves complete, comes in every shape, attractive in appearance beautiful, magnificent wealth and rank, the system of the metal film artware of ornamental value high
Preparation Method.
Natural and Artifact can be processed by the present invention, make handicraft.
Scorpio alive in large nature is lifted a case and makes the flow process of ancient method plating gold: 1, whole process handwork is compared
Many, the most careful, ultimate attainment is careful.2, starting to select the Scorpio alive of little 5-7 centimetre, first research it each lower is made
Type, the most aggressive, or defence type, so remember that action can be as subsequent reference.3, first its euthanasia, afterwards
With vacuum pump, connect pipe and insert in Scorpio health, internal meat is sucked out as far as possible.Then since using dipped into formalin
Reach antiseptic effect.4, carrying out dewatered drying shaping, link is the most crucial here can be with in liquid curing class material obturator.
5, close, with resin material Scorpio closed 6, plating, first have to metallize on surface, quick activation is removed photoresist-silver
End copper facing.More than at least 12 hours electroplating times.7, after plating, Scorpio surface is essentially copper sheet cladding.8, plating is started
Nickel, more gold-plated.Such as gold, silver color, rose golden etc..
Through the specimen of so plating, configuration of surface preserves complete, trickle including some, hair on such as Scorpio foot and
Joint lines.Biological sample or the plating of plant Gu method, good is each come in every shape, superb craftsmanship, non-any first progressive die
The natural feeling gone out that the modern crafts such as tool can be processed.Make follow-up each details that reaches of result the most clearly to remain unchanged, gold
The weak integrity that coating covers, can reach permanent Storing quality and ornamental value.
The preparation method of metal film artware of the present invention is adopted the technical scheme that:
The preparation method of a kind of metal film artware, is characterized in: the preparation method of metal film artware includes following work
Skill step,
1) surface processes
Carry out handicraft surface repairing, arranging, and carry out cleaning process；
2) quick activation
Artware liquid immersion is processed, rinses well with water after process；Dispergation: the quick activating solution of artware solves after processing
Glue；
3) metallization
Artware after quick activation is metallized by conductive paint or chemical plating method, makes handicraft surface cover metal
Conductive layer；
4) copper facing
Metallized artware carries out copper facing by electro-plating method, makes handicraft surface cover metallic copper；
5) nickel plating
Artware after copper facing carries out metal nickel plating by electro-plating method；
6) noble metal plating
Artware after nickel plating carries out noble metal plating by electro-plating method, makes handicraft surface cover layer of precious metal, makes
Metal film artware.
The preparation method of metal film artware of the present invention can also adopt the following technical scheme that
The preparation method of described metal film artware, is characterized in: before electroplate precious metal, first uses electro-plating method to carry out
Nickel Plating Treatment, makes handicraft surface cover metal nickel dam, re-plating gold or silver metal layer on metal nickel dam.
The preparation method of described metal film artware, is characterized in: the quick activating solution weight hundred that quick activation process uses
Proportion by subtraction consists of stannous chloride 80-95, lauryl sulphate acid 1-3, and remaining is water, and quick soak time is 5-40min.
The preparation method of described metal film artware, is characterized in: described artware is plant or animal body；Plant
Or before animal body surface processes, carry out vacuum, dehydration shaping, sealing treatment.
The preparation method of described metal film artware, is characterized in: plant or animal body application of vacuum, is to use vacuum
Pump, by vacuum tube or vacuum syringe needle by plant or animal body fluid or meat sucking-off, then, carries out anticorrosion by plant or animal body
Process.
The preparation method of described metal film artware, is characterized in: after plant or animal body application of vacuum, carry out whole
Shape, keeps plant or the original figure of animal, then carries out sealing treatment.
The preparation method of described metal film artware, is characterized in: after plant or animal body shaping, uses resin material
Plant or animal body are carried out sealing treatment.
The preparation method of described metal film artware, is characterized in: nano-sized membrane is resin.
The preparation method of described metal film artware, is characterized in: when electro-plating method carries out copper facing, electrolyte quality hundred
Proportion by subtraction consists of copper sulfate 8-15, open cylinder agent 8-15, brightener 8-15, and remaining is water, and voltage is 0.6-1.8V, and electroplating time is
4-12h。
The preparation method of described metal film artware, is characterized in: when electro-plating method carries out nickel plating, electrolyte quality hundred
Proportion by subtraction consists of nickel sulfate 8-15, Nickel dichloride. 10-20, boric acid 1-10, and remaining is water, and voltage is 2.6-4.4V, and electroplating time is
30-120min；When electro-plating method carries out gold-plated, electrolyte quality percentage ratio consists of gold salt 50-70, and remaining is water, voltage
1.2-3.3V, electroplating time is 1-3min.
The present invention has the advantage that with good effect:
The technical scheme that the preparation method of metal film artware is brand-new owing to have employed the present invention, compared with prior art,
It is unique that the present invention has technique, and simple operation is simple and practical, makes the advantages such as fine, applied widely；Artware form preserves
Completely, come in every shape, superb craftsmanship, weak integrity, attractive in appearance beautiful, magnificent wealth and rank, can reach permanent Storing quality and
Ornamental value.
Detailed description of the invention
For the summary of the invention of the present invention, feature and effect can be further appreciated that, hereby enumerate following example, and describe in detail
As follows:
Embodiment 1
The preparation method of a kind of Folium Alangii metal film artware, comprises the following steps that,
1. surface processes
Carry out Folium Alangii surface repairing, arranging, and carry out cleaning process；
2. activation
Folium Alangii activating solution wiping is dipped process, and after process, water is rinsed well；
3. metallization
Folium Alangii artware after activation is metallized by chemical plating method, makes handicraft surface cover metallic conduction
Layer；
4. copper facing
Metallized Folium Alangii artware carries out copper facing by electro-plating method, makes handicraft surface cover metallic copper；
5. nickel plating
Folium Alangii artware after copper facing carries out nickel plating by electro-plating method, makes handicraft surface cover metallic nickel；
6. electrogilding
Folium Alangii artware after nickel plating carries out gold-plated by electro-plating method, makes handicraft surface cover gold, makes magnificent drift
Bright Folium Alangii metal film artware.
Embodiment 2
The preparation method of a kind of Scorpio metal film artware, is with the Scorpio alive in large nature, makes the work of plating gold
Skill process:
1. the scorpion that lives processes
Selecting the Scorpio alive of 5-7 centimetre, under first studying, its each moulding, the most aggressive, or defence
Type, so remember that action can be as subsequent reference.
1) application of vacuum: first its euthanasia, afterwards with vacuum pump, connect pipe and insert in Scorpio health, as far as possible body
Interior meat sucks out.Then since dipped into formalin, antiseptic effect has been reached.
2) Shape correction: carrying out shaping, link is the most crucial here can be with in metal particle class material obturator.
3) sealing treatment: Scorpio is closed with nano-sized membrane.Nano-sized membrane is resin material.
4) quick activation
By the Scorpio of nano-sized membrane sealing treatment, process with quick activating solution immersion, rinse well with water after process；Activation
The mass percent of liquid consists of stannous chloride 90 grams, sodium lauryl sulphate 2 grams, 8 grams of water.
3. metallization
Scorpio after activation is metallized by conductive paint method, makes handicraft surface cover metal conducting layer；Conduction
The mass percent of paint consists of: diluent percent 60, and conductive paint percent 40, electroless plating time is 30min.
5) copper facing
Metallized Scorpio carries out copper facing by electro-plating method, makes handicraft surface cover metallic copper；Electroplate during electro-coppering
The mass percent of liquid consists of copper sulfate 10%, open cylinder agent 10%, brightener 10%, water 70%, and electrode voltage is 1.3, electricity
The copper facing time is 12 hours, and copper electroplating layer thickness is 30 to 60 microns.
6) nickel plating
Scorpio after copper facing carries out nickel plating by electro-plating method, makes Scorpio body surface cover metallic nickel；Electroplate liquid during electronickelling
Mass percent consist of nickel sulfate 10%, Nickel dichloride. 15%, boric acid 3%, remaining is water.Electrode voltage is 2.6-4.4V,
Electroplating time is 30-120min, and electroless nickel layer thickness is 10 to 40 microns.
7) gold-plated
Scorpio after nickel plating carries out gold-plated by electro-plating method, makes handicraft surface cover gold, makes magnificent beautiful scorpion
Sub-artware.During electrogilding, the mass percent of electroplate liquid consists of gold salt 60%, water 40%.Electrode voltage is 1.2-3.3V,
Electroplating time is 1 to 10min.Electrogilding layer thickness is 20 microns.
The present embodiment is through the specimen of so plating, and configuration of surface preserves complete, trickle including some, such as Scorpio
Hair on foot and joint lines.Biological sample or veggetable electricity depositing process, good is each come in every shape, superb craftsmanship, non-
The natural feeling gone out that the modern crafts such as any advanced mould can be processed.Making result, follow-up to reach each details the most clear
Still, the weak integrity that gold coating covers, permanent Storing quality and ornamental value can be reached.
Embodiment 3
The preparation method of a kind of Eriocheir sinensis metal film artware, is with the live crab in large nature, makes gold-plated technique
Process:
Manufacturing process includes: live crab processes (application of vacuum, Shape correction, sealing treatment), activate, metallize, copper facing,
Nickel Plating Treatment process, with embodiment 2.
After nickel plating, carry out gold plating process: during electrogilding, the mass percent of electroplate liquid consists of gold salt 60%, water 40%,
Electrode voltage is 1.2-3.3V, and electroplating time is 1-10min, and electrogilding layer thickness is 20 to 30 microns.Eriocheir sinensis after nickel plating is led to
Cross electro-plating method and carry out gold-plated, make Eriocheir sinensis surface cover gold film, be made for magnificent beautiful Gold production Scorpio artware.
It is unique that the present embodiment has described technique, and simple operation is simple and practical, makes fine, equivalance applied widely
Pole effect；Artware form preserves complete, comes in every shape, superb craftsmanship, and weak integrity is attractive in appearance beautiful, magnificent wealth and rank, permissible
Reach permanent Storing quality and ornamental value.
Although above the preferred embodiments of the present invention being described, but the invention is not limited in above-mentioned concrete
Embodiment, above-mentioned detailed description of the invention is only schematically, is not restrictive, and those skilled in the art is at this
Under the enlightenment of invention, in the case of without departing from present inventive concept and scope of the claimed protection, it is also possible to make a lot of shape
Formula.Within these belong to protection scope of the present invention.
Claims (10)
1. a preparation method for metal film artware, is characterized in that: the preparation method of metal film artware includes following technique
Step,
1) surface processes
Carry out handicraft surface modifying, shaping carry out hydrophilicity-imparting treatment；
2) quick activation
Artware is processed with quick activating solution immersion, clean by pure water rinsing after process；
3) metallization
Artware after activation is metallized by conductive paint or chemical plating method, makes handicraft surface cover metallic conduction
Layer；
4) copper facing
Metallized artware carries out copper facing by electro-plating method, makes handicraft surface cover metallic copper；
5) electroplate precious metal
Artware after nickel plating carries out noble metal plating by electro-plating method, makes handicraft surface cover layer of precious metal, makes metal
Membrane process product.
The preparation method of metal film artware the most according to claim 1, is characterized in that: before electroplate precious metal, first uses
Electro-plating method carries out Nickel Plating Treatment, makes handicraft surface cover metal nickel dam, re-plating gold, platinum, rose on metal nickel dam
Rare gold or silver.
The preparation method of metal film artware the most according to claim 1 and 2, is characterized in that: quick activation process uses
Quick activating solution percentage by weight consists of stannous chloride 80-95, lauryl sulphate acid 1-3, and remaining is water, and quick soak time is 5-
40min。
The preparation method of metal film artware the most according to claim 1 and 2, is characterized in that: described artware is for planting
Thing or animal body；Before plant or animal body surface process, carry out vacuum, shaping, sealing treatment.
The preparation method of metal film artware the most according to claim 4, is characterized in that: at plant or animal body vacuum
Reason, is to use vacuum pump, by vacuum tube or vacuum syringe needle by plant or animal body fluid or meat sucking-off, then, by plant or
Animal body carries out preservative treatment.
The preparation method of metal film artware the most according to claim 4, is characterized in that: plant or animal body application of vacuum
After, carry out being dehydrated shaping drying and shaping, keep plant or the original figure of animal, then carry out sealing treatment.
The preparation method of metal film artware the most according to claim 6, is characterized in that: after plant or animal body shaping,
Use resin material that plant or animal body are carried out sealing treatment.
The preparation method of metal film artware the most according to claim 7, is characterized in that: nano-sized membrane is resin.
The preparation method of metal film artware the most according to claim 1, is characterized in that: when electro-plating method carries out copper facing,
Electrolyte quality percentage ratio consists of copper sulfate 8-15, open cylinder agent 8-15, brightener 8-15, and remaining is water, and voltage is 0.6-
1.8V, electroplating time is 4-12h.
The preparation method of metal film artware the most according to claim 2, is characterized in that: when electro-plating method carries out nickel plating,
Electrolyte quality percentage ratio consists of nickel sulfate 8-15, Nickel dichloride. 10-20, boric acid 1-10, and remaining is water, and voltage is 2.6-
4.4V, electroplating time is 30-120min；When electro-plating method carries out gold-plated, electrolyte quality percentage ratio consists of gold salt 50-70,
Remaining is water, voltage 1.2-3.3V, and electroplating time is 1-3min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610829986.2A CN106191944A (en) | 2016-09-17 | 2016-09-17 | A kind of preparation method of metal film artware |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610829986.2A CN106191944A (en) | 2016-09-17 | 2016-09-17 | A kind of preparation method of metal film artware |
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| CN106191944A true CN106191944A (en) | 2016-12-07 |
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| CN201610829986.2A Pending CN106191944A (en) | 2016-09-17 | 2016-09-17 | A kind of preparation method of metal film artware |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108221017A (en) * | 2018-03-02 | 2018-06-29 | 张磊 | A kind of non-metallic process product and electroplating manufacturing process |
| GB2596354A (en) * | 2020-06-26 | 2021-12-29 | Malondji Makango | Decorative artificial nail and method of manufacture |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86101391A (en) * | 1986-03-06 | 1987-09-16 | 中国人民解放军装甲兵工程学院 | Method with metalization of non-metal product surface by brush plating |
| CN1339620A (en) * | 2000-08-24 | 2002-03-13 | 韩巍 | Gold electroplatic method for flowers |
| CN103882488A (en) * | 2014-03-15 | 2014-06-25 | 沈阳师范大学 | Natural plant electroplating and finishing technique |
-
2016
- 2016-09-17 CN CN201610829986.2A patent/CN106191944A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86101391A (en) * | 1986-03-06 | 1987-09-16 | 中国人民解放军装甲兵工程学院 | Method with metalization of non-metal product surface by brush plating |
| CN1339620A (en) * | 2000-08-24 | 2002-03-13 | 韩巍 | Gold electroplatic method for flowers |
| CN103882488A (en) * | 2014-03-15 | 2014-06-25 | 沈阳师范大学 | Natural plant electroplating and finishing technique |
Non-Patent Citations (1)
| Title |
|---|
| 伍学高: "《塑料电镀技术》", 30 April 1983, 四川科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108221017A (en) * | 2018-03-02 | 2018-06-29 | 张磊 | A kind of non-metallic process product and electroplating manufacturing process |
| GB2596354A (en) * | 2020-06-26 | 2021-12-29 | Malondji Makango | Decorative artificial nail and method of manufacture |
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