CN106191883A - Copper material surface degreasing rust remover and preparation method thereof - Google Patents
Copper material surface degreasing rust remover and preparation method thereof Download PDFInfo
- Publication number
- CN106191883A CN106191883A CN201610496382.0A CN201610496382A CN106191883A CN 106191883 A CN106191883 A CN 106191883A CN 201610496382 A CN201610496382 A CN 201610496382A CN 106191883 A CN106191883 A CN 106191883A
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- CN
- China
- Prior art keywords
- parts
- copper material
- material surface
- rust remover
- surface degreasing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
Abstract
The invention discloses a kind of copper material surface degreasing rust remover and preparation method thereof, the raw material of following weight portion prepare: polyvinyl alcohol 8 11 parts, polyacrylamide 10 13 parts, decanedioic acid 11 14 parts, alkylphenol polyoxyethylene 26 parts, Konjac glucomannan 8 11 parts, phenylpropyl alcohol triazole 37 parts, methyl-phosphoric acid dimethyl ester 36 parts, VTES 36 parts, boric acid 37 parts, sodium alginate 11 14 parts, 36 parts of tannic acid, N methylol 3 (dimethoxy phosphono) propionic acid amide. 25 parts.The copper material surface degreasing rust remover formula that the present invention prepares is reasonable, eliminates rust effective, and efficiency of derusting is high, can quickly remove metal surface greasy dirt, rusty stain, occurs without each component environmental protection in corrosion phenomenon, and this antirust solution to copper material, nontoxic, and preparation method is simple, low cost.
Description
Technical field
The present invention relates to a kind of copper material surface degreasing rust remover and preparation method thereof.
Background technology
In the production of non-ferrous metal, the yield of copper is only second to aluminum, occupies second.Owing to it has the intensity of excellence, machine
The features such as tool processing characteristics, electric conductivity, weldability and corrosion resistance, for a long time at each neck such as industrial, military and civilian
Territory is all widely used.Data shows: at present the most only marine industry one, annual just consume copper and alloy 10 tons thereof with
On, along with development and the Large scale construction of thermal power generation of power industry, copper alloy is more and more extensive in the application of each field.Generally
In the case of, the tendency that copper does not corrode is in electrochemistry order, and copper has more higher positive potential than hydrogen, therefore copper has higher heating power
Learn stability, the unpolarizing of hydrogen will not occur, be listed in one of corrosion resistant metal.But, corrosivity higher in humidity is situated between
Matter, then there is the most serious corrosion in copper.Copper alloy shows more higher corrosion resistance than fine copper, and e.g., (Cu-Zn closes pyrite
Gold) impact resistance corrosivity is good；Corronil has acid-fast alkali-proof, the performance of sea water resistance and the characteristic of stress corrosion dehiscence resistant；
Tin bronze alloys is resistant to various corrosion；Silicon bronze alloy mechanical strength is high, anticorrosion stress-resistant cracking performance is good.Copper product makes for a long time
Used time, its etching problem also must be considered that, brings harm otherwise will to our production and life.Further, since copper has U.S.
The color and luster seen, so it is widely used for electronic material, construction material, packaging material, imitation gold copper-base alloy, ornaments modelled after an antique, work modelled after an antique
Skill product, copper word, copper label, copper coin and large-scale sculpture etc., along with the passage of the time of use, copper product is chronically exposed to table in air
Face will be affected it use by corrosion in various degree and variable color, and once oxide etch product occurs producing contact
Property or transporting or conductivity fault.But copper is exposed under air atmosphere, its surface is easy to produce reddish brown coppery or brown-green
Or glaucous oxide etch variable color, (Aerugo has the chemical composition of complexity, and some of them composition does not have reduction corruption to be commonly called as Aerugo
The effect of erosion, also having some compositions is the most just can to observe in Aerugo) belong to the material of insulating property (properties), also it is the bad of heat
Conductor.Copper metallic face requires to must assure that and keep its intrinsic characteristic and feature in industrial applications, as in electrical contact
Surface, transmission line surface and conductive surface etc., be not allow Aerugo occur, and once producing occurs in oxide etch product
Give birth to contact or transporting or conductivity fault.And along with the progress of technology, increasing employing antirust agent prevents copper gold
Genus gets rusty, and antirust agent is the most antirust depends on the protection to metal surface, thus stops or postponing moisture, oxygen and other is miscellaneous
The invasion of matter.In order to adapt to the market competition needs of fast development, improve the quality of rust remover, reduce energy consumption cost, technique mistake
Journey simplification, functionalization etc. become current development trend, therefore develop the oil-removing rust-removing agent with multifunction.But it is existing
(energy consumption is high, pollute weight, and the oil slick on working solution surface is to quilt mostly to be to use strong basicity hot solution at oil-removing rust-removing agent on the market
Handling member causes secondary oil to pollute), or with strong acid, or with organic solvent inflammable, explosive, virulent, produce gas, liquid, solid three
Useless toxic deep-etching heavily contaminated.To this end, we set about from formula and the technique of product, it is provided that a kind of copper material surface degreasing removes
Rust agent and preparation method thereof.
Summary of the invention
It is an object of the invention to provide a kind of copper material surface degreasing rust remover and preparation method thereof.
To achieve these goals, the invention provides a kind of copper material surface degreasing rust remover, raw material includes by weight
Following component: prepared by the raw material of following weight portion: polyvinyl alcohol 8-11 part, polyacrylamide 10-13 part, decanedioic acid 11-14
Part, alkylphenol polyoxyethylene 2-6 part, Konjac glucomannan 8-11 part, phenylpropyl alcohol triazole 3-7 part, methyl-phosphoric acid dimethyl ester 3-6 part, second
Thiazolinyl triethoxysilane 3-6 part, boric acid 3-7 part, sodium alginate 11-14 part, tannic acid 3-6 part, N-methylol-3-(diformazan
Epoxide phosphono) propionic acid amide. 2-5 part.
It is possibly together with sodium xylene sulfonate 2-6 part.
It is possibly together with sodium alginate 2-5 part.
It is possibly together with zinc acetate 4-7 part.
The preparation method of a kind of copper material surface degreasing rust remover, comprises the following steps: weigh according to above-mentioned weight fraction ratio
Each component, then mix and blend, stir and make each component be completely dissolved, and obtains described copper material surface degreasing rust remover.
The method have the advantages that the copper material surface degreasing rust remover formula that the present invention prepares is reasonable, remove
Becoming rusty effective, efficiency of derusting is high, can quickly remove metal surface greasy dirt, rusty stain, copper material occur without corrosion phenomenon, and this is antirust
In liquid, each component environmental protection, nontoxic, and preparation method is simple, low cost.
Detailed description of the invention
Embodiment 1
The copper material surface degreasing rust remover of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 8 parts, polyacrylamide
Amine 10 parts, decanedioic acid 11 parts, alkylphenol polyoxyethylene 2 parts, Konjac glucomannan 8 parts, phenylpropyl alcohol triazole 3 parts, methyl-phosphoric acid dimethyl ester 3
Part, VTES 3 parts, boric acid 3 parts, sodium alginate 11 parts, 3 parts of tannic acid, N-methylol-3-(dimethoxy
Phosphono) propionic acid amide. 2 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved,
To described copper material surface degreasing rust remover.
The copper material surface degreasing rust remover of the present embodiment can use directly immersion, the method for spraying to carry out surface of the work
Processing of rust removing.
Embodiment 2
The copper material surface degreasing rust remover of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 11 parts, polyacrylamide
Amine 13 parts, decanedioic acid 14 parts, alkylphenol polyoxyethylene 6 parts, Konjac glucomannan 11 parts, phenylpropyl alcohol triazole 7 parts, methyl-phosphoric acid dimethyl ester
6 parts, VTES 6 parts, boric acid 7 parts, sodium alginate 14 parts, 6 parts of tannic acid, N-methylol-3-(dimethoxy
Phosphono) propionic acid amide. 5 parts, sodium xylene sulfonate 6 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved,
To described copper material surface degreasing rust remover.
The copper material surface degreasing rust remover of the present embodiment can use directly immersion, the method for spraying to carry out surface of the work
Processing of rust removing.
Embodiment 3
The copper material surface degreasing rust remover of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 8 parts, polyacrylamide
Amine 10 parts, decanedioic acid 11 parts, alkylphenol polyoxyethylene 2 parts, Konjac glucomannan 8 parts, phenylpropyl alcohol triazole 3 parts, methyl-phosphoric acid dimethyl ester 3
Part, VTES 3 parts, boric acid 3 parts, sodium alginate 11 parts, 3 parts of tannic acid, N-methylol-3-(dimethoxy
Phosphono) propionic acid amide. 2 parts, sodium xylene sulfonate 2 parts, sodium alginate 2 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved,
To described copper material surface degreasing rust remover.
The copper material surface degreasing rust remover of the present embodiment can use directly immersion, the method for spraying to carry out surface of the work
Processing of rust removing.
Embodiment 4
The copper material surface degreasing rust remover of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 11 parts, polyacrylamide
Amine 13 parts, decanedioic acid 14 parts, alkylphenol polyoxyethylene 6 parts, Konjac glucomannan 11 parts, phenylpropyl alcohol triazole 7 parts, methyl-phosphoric acid dimethyl ester
6 parts, VTES 6 parts, boric acid 7 parts, sodium alginate 14 parts, 6 parts of tannic acid, N-methylol-3-(dimethoxy
Phosphono) propionic acid amide. 5 parts, sodium xylene sulfonate 6 parts, sodium alginate 5 parts, zinc acetate 7 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved,
To described copper material surface degreasing rust remover.
The copper material surface degreasing rust remover of the present embodiment can use directly immersion, the method for spraying to carry out surface of the work
Processing of rust removing.
Embodiment 5
The rust remover of above-described embodiment 1-4 gained is used for workpiece rust cleaning, and rust cleaning efficiency is high, and a few minutes can complete general workpiece
Descaling process, and rust cleaning after metal works invariant color, without dust, without hydrogen embrittlement.
The above is only the optimal way of the present invention, it is noted that to those skilled in the art, not
On the premise of departing from the invention design, it is also possible to making some similar deformation and improvement, these also should be regarded as the present invention
Protection domain within.
Claims (5)
1. a copper material surface degreasing rust remover, it is characterised in that prepared by the raw material of following weight portion: polyvinyl alcohol 8-11 part,
Polyacrylamide 10-13 part, decanedioic acid 11-14 part, alkylphenol polyoxyethylene 2-6 part, Konjac glucomannan 8-11 part, phenylpropyl alcohol triazole
3-7 part, methyl-phosphoric acid dimethyl ester 3-6 part, VTES 3-6 part, boric acid 3-7 part, sodium alginate 11-14 part,
Tannic acid 3-6 part, N-methylol-3-(dimethoxy phosphono) propionic acid amide. 2-5 part.
2. according to the copper material surface degreasing rust remover described in claim 1, it is characterised in that: it is possibly together with sodium xylene sulfonate
2-6 part.
3. according to the copper material surface degreasing rust remover described in claim 2, it is characterised in that: it is possibly together with sodium alginate 2-5
Part.
4. according to the copper material surface degreasing rust remover described in claim 3, it is characterised in that: it is possibly together with zinc acetate 4-7 part.
5. according to the preparation method of the copper material surface degreasing rust remover according to any one of claim 1-4, it is characterised in that
Comprise the following steps: weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component the most molten
Solve, obtain described copper material surface degreasing rust remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496382.0A CN106191883A (en) | 2016-06-30 | 2016-06-30 | Copper material surface degreasing rust remover and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496382.0A CN106191883A (en) | 2016-06-30 | 2016-06-30 | Copper material surface degreasing rust remover and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106191883A true CN106191883A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610496382.0A Pending CN106191883A (en) | 2016-06-30 | 2016-06-30 | Copper material surface degreasing rust remover and preparation method thereof |
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| CN (1) | CN106191883A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070100009A1 (en) * | 2005-11-01 | 2007-05-03 | Creazzo Joseph A | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| CN101475878A (en) * | 2009-01-19 | 2009-07-08 | 大连三达奥克化学股份有限公司 | Cleaning agent and cleaning method for air conditioner |
| CN102797004A (en) * | 2012-08-23 | 2012-11-28 | 李征 | Environmentally-friendly non-ferrous metal surface treating agent and preparation method thereof |
-
2016
- 2016-06-30 CN CN201610496382.0A patent/CN106191883A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070100009A1 (en) * | 2005-11-01 | 2007-05-03 | Creazzo Joseph A | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| CN101475878A (en) * | 2009-01-19 | 2009-07-08 | 大连三达奥克化学股份有限公司 | Cleaning agent and cleaning method for air conditioner |
| CN102797004A (en) * | 2012-08-23 | 2012-11-28 | 李征 | Environmentally-friendly non-ferrous metal surface treating agent and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20161207 |