CN106011890B - Aqueous copper material brightening rust removing agent and preparation method thereof - Google Patents
Aqueous copper material brightening rust removing agent and preparation method thereof Download PDFInfo
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- CN106011890B CN106011890B CN201610496399.6A CN201610496399A CN106011890B CN 106011890 B CN106011890 B CN 106011890B CN 201610496399 A CN201610496399 A CN 201610496399A CN 106011890 B CN106011890 B CN 106011890B
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- rust removing
- copper material
- aqueous copper
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
Abstract
The invention discloses a kind of aqueous copper material brightening rust removing agents and preparation method thereof, are made by the raw material of following parts by weight: 3-10 parts of ethylene glycol monomethyl ether acetate, 13-16 parts of zinc dialkyl dithiophosphate, 3-6 parts of prodan, 3-7 parts of boric acid, 4-7 parts of barium sulfate, 3-8 parts of methyl cyclosiloxane, 11-18 parts of konjac glucomannan, 4-8 parts of Methyl Hydrogen Polysiloxane Fluid, 5-10 parts of sodium alginate, 3-7 parts of vinyltriethoxysilane, 3-6 parts of sulfide isobutene, 20-36 parts of butanol.Rationally, Recipe used is simple, environment friendly and pollution-free for the aqueous copper material brightening rust removing agent formula that the present invention is prepared, derusting rust-proofing effect is good, and can in blast metal surface gloss, and in the antirust solution each component environmental protection, it is nontoxic, and preparation method is simple, it is at low cost.
Description
Technical field
The present invention relates to a kind of aqueous copper material brightening rust removing agents and preparation method thereof.
Background technique
In the production of non-ferrous metal, the yield of copper is only second to aluminium, occupies second.Since it is with excellent intensity, machine
The features such as tool processing performance, electric conductivity, weldability and corrosion resistance, for a long time in each neck such as industrial, military and civilian
Domain is widely used.Data shows: as soon as 10 tons of only marine industry at present, annual consumption copper and its alloy with
On, with the development of power industry and the Large scale construction of thermal power generation, copper alloy is in each field using more and more extensive.Usually
In the case of, the tendency that copper does not corrode is in electrochemistry sequence, and copper has positive potential more higher than hydrogen, therefore copper has higher heating power
Stability is learned, the unpolarizing of hydrogen will not occur, be listed in one of corrosion resistant metal.But humidity is higher, corrosivity is situated between
More serious corrosion then occurs for matter, copper.Copper alloy shows corrosion resistance more higher than fine copper, and e.g., (Cu-Zn is closed brass
Gold) impact resistance corrosivity is good；Corronil has the characteristic of acid-fast alkali-proof, the performance of sea water resistance and stress corrosion dehiscence resistant；
Tin bronze alloys is resistant to various corrosion；Silicon bronze alloy high mechanical strength, anticorrosion stress-resistant cracking performance are good.Copper product makes for a long time
Used time, its etching problem also must be considered that, otherwise will bring harm to our production and life.In addition, since copper has beauty
The color of sight, so it is widely used for electronic material, construction material, packaging material, imitation gold copper-base alloy, ornaments modelled after an antique, work modelled after an antique
Skill product, copper word, copper label, copper coin and large-scale sculpture etc., with the passage for using the time, copper product is chronically exposed to table in air
Face will will receive different degrees of corrosion and discoloration and influence its use, once the appearance of oxidation corrosion product will generate contact
Property or transporting or conductibility failure.But copper is exposed under air atmosphere, and surface is easy to generate reddish brown coppery or brown-green
Or glaucous oxidation corrosion discoloration, being commonly called as verdigris, (verdigris has complicated chemical composition, and it is rotten that some of ingredients do not have reduction
The effect of erosion is that can just observe in verdigris once in a while there are also some ingredients) belong to the substance of insulating property (properties), and heat is bad
Conductor.Copper metallic face requires the characteristic and feature that must assure that and keep its intrinsic in industrial applications, is such as being in electrical contact
Surface, transmission line surface and conductive surface etc., be do not allow verdigris occur, once oxidation corrosion product appearance will produce
Raw contact or transporting or conductibility failure.And with advances in technology, more and more prevent copper golden using antirust agent
Category gets rusty, and the effective antirust of antirust agent depends on protection to metal surface, to stop or delay moisture, oxygen and other miscellaneous
The invasion of matter.And current Deruster for metal process is more, low efficiency, the processing time is long, and process is easy to metal watch
Face generates corrosion, cause metal surface it is coarse it is low and deep, do not work, therefore the appearance of metal product.For this purpose, our formulas from product
Set about with technique, a kind of aqueous copper material brightening rust removing agent and preparation method thereof is provided.
Summary of the invention
The purpose of the present invention is to provide a kind of aqueous copper material brightening rust removing agents and preparation method thereof.
To achieve the goals above, the present invention provides a kind of aqueous copper material brightening rust removing agent, raw material includes by weight
Following component: it is made by the raw material of following parts by weight: 3-10 parts of ethylene glycol monomethyl ether acetate, zinc dialkyl dithiophosphate
13-16 parts, 3-6 parts of prodan, 3-7 parts of boric acid, 4-7 parts of barium sulfate, 3-8 parts of methyl cyclosiloxane, 11-18 parts of konjac glucomannan,
4-8 parts of Methyl Hydrogen Polysiloxane Fluid, 5-10 parts of sodium alginate, 3-7 parts of vinyltriethoxysilane, 3-6 parts of sulfide isobutene, butanol
20-36 parts.
It also contains 2-8 parts of polyacrylamide.
It also contains 4-8 parts of decanedioic acid.
It also contains 2-10 parts of tannic acid.
A kind of preparation method of aqueous copper material brightening rust removing agent, comprising the following steps: weighed according to above-mentioned weight fraction ratio
Then each component is mixed, stirring evenly is completely dissolved each component, obtains the aqueous copper material brightening rust removing agent.
The invention has the following advantages: the aqueous copper material brightening rust removing agent formula that the present invention is prepared is rationally, institute
Simple with Recipe, environment friendly and pollution-free, derusting rust-proofing effect is good, and can be in blast metal surface gloss, and the antirust solution
Middle each component environmental protection, it is nontoxic, and preparation method is simple, it is at low cost.
Specific embodiment
Embodiment 1
The aqueous copper material brightening rust removing agent of the present embodiment, is made: ethylene glycol monobutyl ether acetic acid by the component of following parts by weight
3 parts of ester, 13 parts of zinc dialkyl dithiophosphate, 3 parts of prodan, 3 parts of boric acid, 4 parts of barium sulfate, 3 parts of methyl cyclosiloxane,
11 parts of konjac glucomannan, 4 parts of Methyl Hydrogen Polysiloxane Fluid, 5 parts of sodium alginate, 3 parts of vinyltriethoxysilane, 3 parts of sulfide isobutene, fourth
20 parts of alcohol.
Each component is weighed according to above-mentioned weight fraction ratio, is then mixed, stirring evenly is completely dissolved each component, obtains
To the aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can carry out workpiece surface using the method directly impregnated, sprayed
Processing of rust removing.
Embodiment 2
The aqueous copper material brightening rust removing agent of the present embodiment, is made: ethylene glycol monobutyl ether acetic acid by the component of following parts by weight
10 parts of ester, 16 parts of zinc dialkyl dithiophosphate, 6 parts of prodan, 7 parts of boric acid, 7 parts of barium sulfate, 8 parts of methyl cyclosiloxane,
18 parts of konjac glucomannan, 8 parts of Methyl Hydrogen Polysiloxane Fluid, 10 parts of sodium alginate, 7 parts of vinyltriethoxysilane, 6 parts of sulfide isobutene,
36 parts of butanol, 8 parts of polyacrylamide.
Each component is weighed according to above-mentioned weight fraction ratio, is then mixed, stirring evenly is completely dissolved each component, obtains
To the aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can carry out workpiece surface using the method directly impregnated, sprayed
Processing of rust removing.
Embodiment 3
The aqueous copper material brightening rust removing agent of the present embodiment, is made: ethylene glycol monobutyl ether acetic acid by the component of following parts by weight
3 parts of ester, 13 parts of zinc dialkyl dithiophosphate, 3 parts of prodan, 3 parts of boric acid, 4 parts of barium sulfate, 3 parts of methyl cyclosiloxane,
11 parts of konjac glucomannan, 4 parts of Methyl Hydrogen Polysiloxane Fluid, 5 parts of sodium alginate, 3 parts of vinyltriethoxysilane, 3 parts of sulfide isobutene, fourth
20 parts of alcohol, 2 parts of polyacrylamide, 4 parts of decanedioic acid.
Each component is weighed according to above-mentioned weight fraction ratio, is then mixed, stirring evenly is completely dissolved each component, obtains
To the aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can carry out workpiece surface using the method directly impregnated, sprayed
Processing of rust removing.
Embodiment 4
The aqueous copper material brightening rust removing agent of the present embodiment, is made: ethylene glycol monobutyl ether acetic acid by the component of following parts by weight
10 parts of ester, 16 parts of zinc dialkyl dithiophosphate, 6 parts of prodan, 7 parts of boric acid, 7 parts of barium sulfate, 8 parts of methyl cyclosiloxane,
18 parts of konjac glucomannan, 8 parts of Methyl Hydrogen Polysiloxane Fluid, 10 parts of sodium alginate, 7 parts of vinyltriethoxysilane, 6 parts of sulfide isobutene,
36 parts of butanol, 8 parts of polyacrylamide, 8 parts of decanedioic acid, 10 parts of tannic acid.
Each component is weighed according to above-mentioned weight fraction ratio, is then mixed, stirring evenly is completely dissolved each component, obtains
To the aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can carry out workpiece surface using the method directly impregnated, sprayed
Processing of rust removing.
Embodiment 5
The resulting rust remover of above-described embodiment 1-4 is used for workpiece derusting, rust cleaning efficiency is high, and a few minutes can be completed generally
The descaling process of workpiece, and derust after metal works it is non-discolouring, without dust, without hydrogen embrittlement.
The above is only preferred embodiment of the invention, it is noted that those skilled in the art, not
Under the premise of being detached from the invention design, some similar deformation and improvement can be made, these also should be regarded as the present invention
Protection scope within.
Claims (5)
1. a kind of aqueous copper material brightening rust removing agent, it is characterised in that be made by the raw material of following parts by weight: ethylene glycol monobutyl ether vinegar
3-10 parts of acid esters, 13-16 parts of zinc dialkyl dithiophosphate, 3-6 parts of prodan, 3-7 parts of boric acid, 4-7 parts of barium sulfate, first
3-8 parts of cyclosiloxane, 11-18 parts of konjac glucomannan, 4-8 parts of Methyl Hydrogen Polysiloxane Fluid, 5-10 parts of sodium alginate, vinyl triethoxyl
3-7 parts of silane, 3-6 parts of sulfide isobutene, 20-36 parts of butanol.
2. the aqueous copper material brightening rust removing agent according to claim 1, it is characterised in that: it also contains polyacrylamide 2-
8 parts.
3. the aqueous copper material brightening rust removing agent according to claim 2, it is characterised in that: it also contains 4-8 parts of decanedioic acid.
4. the aqueous copper material brightening rust removing agent according to claim 3, it is characterised in that: it also contains tannic acid 2-10
Part.
5. the preparation method of aqueous copper material brightening rust removing agent described in any one of -4 according to claim 1, it is characterised in that
The following steps are included: weighing each component according to above-mentioned weight fraction ratio, then it is mixed, stirring evenly keeps each component completely molten
Solution, obtains the aqueous copper material brightening rust removing agent.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496399.6A CN106011890B (en) | 2016-06-30 | 2016-06-30 | Aqueous copper material brightening rust removing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496399.6A CN106011890B (en) | 2016-06-30 | 2016-06-30 | Aqueous copper material brightening rust removing agent and preparation method thereof |
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| CN106011890A CN106011890A (en) | 2016-10-12 |
| CN106011890B true CN106011890B (en) | 2019-01-15 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104213141A (en) * | 2014-08-31 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | Improved metal cleaner |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104562065A (en) * | 2015-01-22 | 2015-04-29 | 南通恒隆化工有限公司 | Metal rust inhibitor |
-
2016
- 2016-06-30 CN CN201610496399.6A patent/CN106011890B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104213141A (en) * | 2014-08-31 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | Improved metal cleaner |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104562065A (en) * | 2015-01-22 | 2015-04-29 | 南通恒隆化工有限公司 | Metal rust inhibitor |
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| CN106011890A (en) | 2016-10-12 |
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Effective date of registration: 20180929 Address after: 325000 12 groups of Dou men residential areas in Binjiang street, Lucheng District, Wenzhou, Zhejiang. Applicant after: Zhou Shaoxia Address before: 214000 room 623, science and Technology Park 7, Changjiang Road, Wuxi New District, Jiangsu. Applicant before: Wuxi Epic Technology Co., Ltd. |
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Effective date of registration: 20181016 Address after: 221000 Sun Zhuang village, Liu Xin Town, Copper Mt. District, Xuzhou, Jiangsu Applicant after: Xuzhou Xin Gu steel mould Co., Ltd. Address before: 325000 12 groups of Dou men residential areas in Binjiang street, Lucheng District, Wenzhou, Zhejiang. Applicant before: Zhou Shaoxia |
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Effective date of registration: 20210618 Address after: 528000 No.54 workshop, No.1 Lian'an Road, Fu'an Industrial Zone, Leliu neighborhood committee, Leliu street, Shunde District, Foshan City, Guangdong Province Patentee after: Guangdong Shunde qinlang Environmental Protection Technology Co.,Ltd. Address before: 221000 Sun Zhuang village, Liu Xin Town, Copper Mt. District, Xuzhou, Jiangsu Patentee before: XUZHOU XINGU STEEL MOULD Co.,Ltd. |