CN106011890A - Water-based copper brightening rust removing agent and preparing method thereof - Google Patents
Water-based copper brightening rust removing agent and preparing method thereof Download PDFInfo
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- CN106011890A CN106011890A CN201610496399.6A CN201610496399A CN106011890A CN 106011890 A CN106011890 A CN 106011890A CN 201610496399 A CN201610496399 A CN 201610496399A CN 106011890 A CN106011890 A CN 106011890A
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- rust removing
- removing agent
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- aqueous copper
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a water-based copper brightening rust removing agent and a preparing method thereof. The rust removing agent is prepared from, by weight, 3-10 parts of ethylene glycol monobutyl ether acetate, 13-16 parts of zinc dialkyl dithiophosphate, 3-6 parts of sodium fluorosilicate, 3-7 parts of boric acid, 4-7 parts of barium sulfate, 3-8 parts of dimethylcydosiloxane, 11-18 parts of konjac gum, 4-8 parts of methyl hydrogen silicone oil, 5-10 parts of sodium alga acid, 3-7 parts of triethoxyvinylsilane, 3-6 parts of sulfurized isobutylene and 20-36 parts of butanol. The obtained water-based copper brightening rust removing agent is reasonable in formula, the used formula process is simple, the rust removing agent is environment-friendly, free of pollution, good in rust removing and preventing effect and capable of brightening surface gloss of metal, all the components in rustproof liquid are environment-friendly and non-toxic, the preparation method is simple, and cost is low.
Description
Technical field
The present invention relates to a kind of aqueous copper material brightening rust removing agent and preparation method thereof.
Background technology
In the production of non-ferrous metal, the yield of copper is only second to aluminum, occupies second.Owing to it has a feature such as intensity, machining property, electric conductivity, weldability and corrosion resistance of excellence, all it is widely used in the every field such as industrial, military and civilian for a long time.Data shows: at present the most only marine industry one, annual just consumes copper and alloy more than 10 tons thereof, and along with development and the Large scale construction of thermal power generation of power industry, copper alloy is more and more extensive in the application of each field.Under normal circumstances, the tendency that copper does not corrode is in electrochemistry order, and copper has more higher positive potential than hydrogen, therefore copper has higher thermodynamic stability, the unpolarizing of hydrogen will not occur, be listed in one of corrosion resistant metal.But, Korrosionsmedium higher in humidity, then there is the most serious corrosion in copper.Copper alloy shows more higher corrosion resistance than fine copper, and e.g., pyrite (Cu-Zn alloy) impact resistance corrosivity is good；Corronil has acid-fast alkali-proof, the performance of sea water resistance and the characteristic of stress corrosion dehiscence resistant；Tin bronze alloys is resistant to various corrosion；Silicon bronze alloy mechanical strength is high, anticorrosion stress-resistant cracking performance is good.During copper product life-time service, its etching problem also must be considered that, brings harm otherwise will to our production and life.Additionally, owing to copper has color and luster attractive in appearance, so it is widely used for electronic material, construction material, packaging material, imitation gold copper-base alloy, ornaments modelled after an antique, archaizeding handicraft, copper word, copper label, copper coin and large-scale sculpture etc., passage along with the time of use, copper product is chronically exposed to surface in air will be affected it use by corrosion in various degree and variable color, and once oxide etch product occurs producing contact or transporting or conductivity fault.But copper is exposed under air atmosphere, its surface is easy to produce reddish brown coppery or brown-green or glaucous oxide etch variable color, (Aerugo has complicated chemical composition to be commonly called as Aerugo, some of them composition does not have the effect reducing corrosion, also having some compositions is the most just can to observe in Aerugo) belong to the material of insulating property (properties), also it is the non-conductor of heat.Copper metallic face requires to must assure that and keep its intrinsic characteristic and feature in industrial applications, as in electrical contact surface, transmission line surface and conductive surface etc., being not allow Aerugo occur, once oxide etch product occurs producing contact or transporting or conductivity fault.And along with the progress of technology, increasing employing antirust agent prevents copper metal rusting, antirust agent is the most antirust depends on the protection to metal surface, thus stops or postponing moisture, oxygen and the invasion of other impurity.And current Deruster for metal operation is many, efficiency is low, process the time long, and the course of processing easily to metal surface produce corrosion, cause metal surface coarse low and deep, do not work, the therefore outward appearance of metallic article.To this end, we set about from formula and the technique of product, it is provided that a kind of aqueous copper material brightening rust removing agent and preparation method thereof.
Summary of the invention
It is an object of the invention to provide a kind of aqueous copper material brightening rust removing agent and preparation method thereof.
To achieve these goals, the invention provides a kind of aqueous copper material brightening rust removing agent, raw material includes following component by weight: prepared by the raw material of following weight portion: ethylene glycol monomethyl ether acetate 3-10 part, zinc dialkyl dithiophosphate 13-16 part, prodan 3-6 part, boric acid 3-7 part, barium sulfate 4-7 part, methyl cyclosiloxane 3-8 part, Konjac glucomannan 11-18 part, Methyl Hydrogen Polysiloxane Fluid 4-8 part, sodium alginate 5-10 part, VTES 3-7 part, sulfide isobutene 3-6 part, butanol 20-36 part.
It is possibly together with polyacrylamide 2-8 part.
It is possibly together with decanedioic acid 4-8 part.
It is possibly together with tannic acid 2-10 part.
The preparation method of a kind of aqueous copper material brightening rust removing agent, comprises the following steps: weighs each component, then mix and blend according to above-mentioned weight fraction ratio, stirs and make each component be completely dissolved, and obtains described aqueous copper material brightening rust removing agent.
The method have the advantages that the aqueous copper material brightening rust removing agent formula that the present invention prepares is reasonable, Recipe used is simple, environment friendly and pollution-free, derusting rust-proofing is effective, and can be at blast metal surface gloss, and each component environmental protection in this antirust solution, nontoxic, and preparation method is simple, low cost.
Detailed description of the invention
Embodiment
1
The aqueous copper material brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: ethylene glycol monomethyl ether acetate 3 parts, zinc dialkyl dithiophosphate 13 parts, prodan 3 parts, boric acid 3 parts, 4 parts of barium sulfate, methyl cyclosiloxane 3 parts, Konjac glucomannan 11 parts, Methyl Hydrogen Polysiloxane Fluid 4 parts, sodium alginate 5 parts, VTES 3 parts, sulfide isobutene 3 parts, 20 parts of butanol.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment
2
The aqueous copper material brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: ethylene glycol monomethyl ether acetate 10 parts, zinc dialkyl dithiophosphate 16 parts, prodan 6 parts, boric acid 7 parts, 7 parts of barium sulfate, methyl cyclosiloxane 8 parts, Konjac glucomannan 18 parts, Methyl Hydrogen Polysiloxane Fluid 8 parts, sodium alginate 10 parts, VTES 7 parts, sulfide isobutene 6 parts, 36 parts of butanol, polyacrylamide 8 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment
3
The aqueous copper material brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: ethylene glycol monomethyl ether acetate 3 parts, zinc dialkyl dithiophosphate 13 parts, prodan 3 parts, boric acid 3 parts, 4 parts of barium sulfate, methyl cyclosiloxane 3 parts, Konjac glucomannan 11 parts, Methyl Hydrogen Polysiloxane Fluid 4 parts, sodium alginate 5 parts, VTES 3 parts, sulfide isobutene 3 parts, 20 parts of butanol, polyacrylamide 2 parts, decanedioic acid 4 parts.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment
4
The aqueous copper material brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: ethylene glycol monomethyl ether acetate 10 parts, zinc dialkyl dithiophosphate 16 parts, prodan 6 parts, boric acid 7 parts, 7 parts of barium sulfate, methyl cyclosiloxane 8 parts, Konjac glucomannan 18 parts, Methyl Hydrogen Polysiloxane Fluid 8 parts, sodium alginate 10 parts, VTES 7 parts, sulfide isobutene 6 parts, 36 parts of butanol, polyacrylamide 8 parts, decanedioic acid 8 parts, 10 parts of tannic acid.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous copper material brightening rust removing agent.
The aqueous copper material brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment
5
The rust remover of above-described embodiment 1-4 gained is used for workpiece rust cleaning, and rust cleaning efficiency is high, and a few minutes can complete the metal works invariant color after the descaling process of general workpiece, and rust cleaning, without dust, without hydrogen embrittlement.
The above is only the optimal way of the present invention, it is noted that to those skilled in the art, without departing from the concept of the premise of the invention, it is also possible to make some similar deformation and improvement, within these also should be regarded as protection scope of the present invention.
Claims (5)
1. an aqueous copper material brightening rust removing agent, it is characterised in that prepared by the raw material of following weight portion: ethylene glycol monomethyl ether acetate 3-10 part, zinc dialkyl dithiophosphate
13-16 part, prodan 3-6 part, boric acid 3-7 part, barium sulfate 4-7 part, methyl cyclosiloxane 3-8 part, Konjac glucomannan 11-18 part, Methyl Hydrogen Polysiloxane Fluid 4-8 part, sodium alginate 5-10 part, VTES 3-7 part, sulfide isobutene 3-6 part, butanol 20-36 part.
2. according to the aqueous copper material brightening rust removing agent described in claim 1, it is characterised in that: it is possibly together with polyacrylamide 2-8 part.
3. according to the aqueous copper material brightening rust removing agent described in claim 2, it is characterised in that: it is possibly together with decanedioic acid 4-8 part.
4. according to the aqueous copper material brightening rust removing agent described in claim 3, it is characterised in that: it is possibly together with tannic acid 2-10 part.
5. according to the preparation method of the aqueous copper material brightening rust removing agent according to any one of claim 1-4, it is characterized in that comprising the following steps: weigh each component according to above-mentioned weight fraction ratio, then mix and blend, stirs and makes each component be completely dissolved, and obtains described aqueous copper material brightening rust removing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496399.6A CN106011890B (en) | 2016-06-30 | 2016-06-30 | Aqueous copper material brightening rust removing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610496399.6A CN106011890B (en) | 2016-06-30 | 2016-06-30 | Aqueous copper material brightening rust removing agent and preparation method thereof |
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| CN106011890A true CN106011890A (en) | 2016-10-12 |
| CN106011890B CN106011890B (en) | 2019-01-15 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104213141A (en) * | 2014-08-31 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | Improved metal cleaner |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104562065A (en) * | 2015-01-22 | 2015-04-29 | 南通恒隆化工有限公司 | Metal rust inhibitor |
-
2016
- 2016-06-30 CN CN201610496399.6A patent/CN106011890B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104213141A (en) * | 2014-08-31 | 2014-12-17 | 青岛承天伟业机械制造有限公司 | Improved metal cleaner |
| CN104513987A (en) * | 2014-11-28 | 2015-04-15 | 宿州市祁南工贸有限责任公司 | Multifunctional composite gas phase anti rust agent and preparation method thereof |
| CN104562065A (en) * | 2015-01-22 | 2015-04-29 | 南通恒隆化工有限公司 | Metal rust inhibitor |
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| CN106011890B (en) | 2019-01-15 |
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Effective date of registration: 20180929 Address after: 325000 12 groups of Dou men residential areas in Binjiang street, Lucheng District, Wenzhou, Zhejiang. Applicant after: Zhou Shaoxia Address before: 214000 room 623, science and Technology Park 7, Changjiang Road, Wuxi New District, Jiangsu. Applicant before: Wuxi Epic Technology Co., Ltd. |
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Effective date of registration: 20181016 Address after: 221000 Sun Zhuang village, Liu Xin Town, Copper Mt. District, Xuzhou, Jiangsu Applicant after: Xuzhou Xin Gu steel mould Co., Ltd. Address before: 325000 12 groups of Dou men residential areas in Binjiang street, Lucheng District, Wenzhou, Zhejiang. Applicant before: Zhou Shaoxia |
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Effective date of registration: 20210618 Address after: 528000 No.54 workshop, No.1 Lian'an Road, Fu'an Industrial Zone, Leliu neighborhood committee, Leliu street, Shunde District, Foshan City, Guangdong Province Patentee after: Guangdong Shunde qinlang Environmental Protection Technology Co.,Ltd. Address before: 221000 Sun Zhuang village, Liu Xin Town, Copper Mt. District, Xuzhou, Jiangsu Patentee before: XUZHOU XINGU STEEL MOULD Co.,Ltd. |
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