CN106190482A - Metal pipe material drawing oil - Google Patents

Metal pipe material drawing oil Download PDF

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Publication number
CN106190482A
CN106190482A CN201610556854.7A CN201610556854A CN106190482A CN 106190482 A CN106190482 A CN 106190482A CN 201610556854 A CN201610556854 A CN 201610556854A CN 106190482 A CN106190482 A CN 106190482A
Authority
CN
China
Prior art keywords
oil
metal pipe
pipe material
drawing oil
material drawing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610556854.7A
Other languages
Chinese (zh)
Inventor
孙兰凤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Auloop Lubrication Technology Co Ltd
Original Assignee
Tianjin Auloop Lubrication Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Auloop Lubrication Technology Co Ltd filed Critical Tianjin Auloop Lubrication Technology Co Ltd
Priority to CN201610556854.7A priority Critical patent/CN106190482A/en
Publication of CN106190482A publication Critical patent/CN106190482A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal

Abstract

The present invention relates to a kind of metal pipe material drawing oil, being mainly composed of base oil, other additive and percentage composition thereof be in terms of the quality of drawing oil: sulfur-bearing phosphorus extreme pressure agent: the phosphorous extreme pressure agent of 0.5-3.0%: 0.5-2.5% sulfur-containing extreme-pressure additive: 4-11% lubricant: 2-7% antirust agent: 1-2% emulsifying agent: 2-6%.Phosphorous extreme pressure agent in the present invention, sulfur-containing extreme-pressure additive, sulfur-bearing phosphorus extreme pressure agent mixed proportion suitable, drawing process each serves as under the different temperatures of metal surface extreme boundary lubrication effect.Containing the compound emulsifying agent of function admirable in the present invention, make oil product have washability, oil film can be washed away by the material with water after processing.

Description

Metal pipe material drawing oil
Technical field
The invention belongs to drawing oil field, relate to metal pipe material, especially a kind of metal pipe material drawing oil.
Background technology
Metal drawing is the sectional area being reduced material by die hole, it is thus achieved that in high precision, high gloss bar, wire rod and pipe A kind of plastic working technique of material, is the important method preparing wire rod and tubing.Drawing is that a kind of technology requires the highest adding Work technique, bar, wire rod or the tubing after drawing requires that diameter or thickness will be highly uniform, and surface-brightening is without scratch, Careless slightly it is possible to cause seizing or drawing interruption, have a strong impact on the most whole batch of product quality and scrap.And draw at metal Pull out in the course of processing, the kind of lubricant, quality and using method to life-span of mould, draw piece quality (such as surface smoothness Deng) and the impact such as speed of drawing particularly significant.Therefore drawing lubrication oil is that technology requires the strictest product, but draws at present Pulling out and use oil also in a kind of without unified mass standard, production scale is small and scattered, and user requires multiformity and dependence on import etc. State, the development to metal drawing processing has a certain impact.
Summary of the invention
In place of it is an object of the invention to overcome the deficiencies in the prior art, it is provided that one can be washed, extreme boundary lubrication performance is good Metal pipe material drawing oil.
The present invention solves technical problem and be the technical scheme is that
A kind of metal pipe material drawing oil, is mainly composed of base oil, and other additive and percentage composition thereof are with drawing oil Quality meter:
And, described sulfur-bearing phosphorus extreme pressure agent is ZnDDP.
And, the described mixture that phosphorous extreme pressure agent is oil-soluble phosphate ester and phosphite ester.
And, described sulfur-containing extreme-pressure additive is made up of with sulfide aliphatic acid ester sulfide isobutene, and wherein sulfide isobutene accounts for The 2-6% of drawing oil gross mass, sulfide aliphatic acid ester accounts for the 2-5% of drawing oil gross mass.
And, described lubricant is tricarboxymethyl propane oleate.
And, described antirust agent is T705A.
And, described emulsifying agent is by fatty alcohol-polyoxyethylene ether and polyoxyethylene 20 sorbitan monolaurate group Becoming, wherein fatty alcohol-polyoxyethylene ether accounts for the 1-3% of drawing oil gross mass, and polyoxyethylene 20 sorbitan monolaurate accounts for The 1-3% of drawing oil gross mass.
The present invention is directed to the performance indications requirement of the metal pipe material drawing oil of market upper inlet, to lubricant component and interpolation Agent is screened, and for tribology, tribochemistry principle in drawing process, rust-proof mechanism etc. is studied, and grinds according to basis Study carefully the structure activity relationship drawn, carry out the composition and ratio design of metal pipe material drawing oil, utilize advanced Instrumental Analysis means to drawing Friction surface during pulling out carries out structural characterization, determine metal pipe material drawing oil component proportioning and production technology, preferably Go out the outstanding lubricant of combination property, extreme pressure agent, emulsifying agent, oiliness improver, rust inhibitor and optimal addn, excellent by technique Change, it is achieved large-scale production.
Advantages of the present invention and good effect be:
1, phosphorous extreme pressure agent in the present invention, sulfur-containing extreme-pressure additive, sulfur-bearing phosphorus extreme pressure agent mixed proportion suitable, at drawing process Extreme boundary lubrication effect is each served as under the different temperatures of middle metal surface.
2, containing the compound emulsifying agent of function admirable in the present invention, make oil product have washability, the material after processing is used Oil film can be washed away by water.
Detailed description of the invention
Below by specific embodiment, the invention will be further described, and following example are illustrative, is not limit Qualitatively, it is impossible to limit protection scope of the present invention with this.
Embodiment 1
A kind of metal pipe material drawing oil, is mainly composed of base oil, and other additive and percentage composition thereof are with drawing oil Quality meter:
ZnDDP 0.5%
ElCO phosphate ester and phosphite ester (oil-soluble) 2.5%
Sulfide isobutene 2%
Sulfide aliphatic acid ester 5%
Tricarboxymethyl propane oleate 2%
T705A antirust agent 2%
Fatty alcohol-polyoxyethylene ether 1%
Polyoxyethylene (4EO) sorbitan mono-laurate 3%
Base oil surplus
Embodiment 2
A kind of metal pipe material drawing oil, is mainly composed of base oil, and other additive and percentage composition thereof are with drawing oil Quality meter:
ZnDDP 3.0%
ElCO phosphate ester and phosphite ester (oil-soluble) 0.5%
Sulfide isobutene 6%
Sulfide aliphatic acid ester 2%
Tricarboxymethyl propane oleate 7%
T705A antirust agent 1%
Fatty alcohol-polyoxyethylene ether 3%
Polyoxyethylene (4EO) sorbitan mono-laurate 1%
Base oil: surplus
Embodiment 3
A kind of metal pipe material drawing oil, is mainly composed of base oil, and other additive and percentage composition thereof are with drawing oil Quality meter:
ZnDDP 1.5%
ElCO phosphate ester and phosphite ester (oil-soluble) 2%
Sulfide isobutene 3%
Sulfide aliphatic acid ester 3.5%
Tricarboxymethyl propane oleate 5%
T705A antirust agent 1.5%
Fatty alcohol-polyoxyethylene ether 2%
Polyoxyethylene (4EO) sorbitan mono-laurate 2%
Base oil: surplus
The testing result of the present invention see table:
Above-described is only the preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art For, on the premise of without departing from inventive concept, it is also possible to make some deformation and improvement, these broadly fall into the protection of the present invention Scope.

Claims (8)

1. a metal pipe material drawing oil, is mainly composed of base oil, and other additive and percentage composition thereof are with drawing oil Quality meter:
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described sulfur-bearing phosphorus extreme pressure agent is ZnDDP.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described phosphorous extreme pressure agent is oil-soluble phosphorus Acid esters and the mixture of phosphite ester.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described sulfur-containing extreme-pressure additive is by vulcanizing isobutyl Alkene forms with sulfide aliphatic acid ester, and wherein sulfide isobutene accounts for the 2-6% of drawing oil gross mass, and sulfide aliphatic acid ester accounts for drawing The 2-5% of oil gross mass.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described lubricant is trimethylolpropane Oleate.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described antirust agent is T705A.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described emulsifying agent is by fatty alcohol polyoxy second Alkene ether and polyoxyethylene 20 sorbitan monolaurate composition, wherein fatty alcohol-polyoxyethylene ether accounts for drawing oil gross mass 1-3%, polyoxyethylene 20 sorbitan monolaurate accounts for the 1-3% of drawing oil gross mass.
Metal pipe material drawing oil the most according to claim 1, it is characterised in that: described base oil is paraffinic base basis Oil.
CN201610556854.7A 2016-07-14 2016-07-14 Metal pipe material drawing oil Pending CN106190482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610556854.7A CN106190482A (en) 2016-07-14 2016-07-14 Metal pipe material drawing oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610556854.7A CN106190482A (en) 2016-07-14 2016-07-14 Metal pipe material drawing oil

Publications (1)

Publication Number Publication Date
CN106190482A true CN106190482A (en) 2016-12-07

Family

ID=57475661

Family Applications (1)

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CN201610556854.7A Pending CN106190482A (en) 2016-07-14 2016-07-14 Metal pipe material drawing oil

Country Status (1)

Country Link
CN (1) CN106190482A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106701286A (en) * 2017-01-05 2017-05-24 广东美商工业材料有限公司 Steel tube drawing oil and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031189A (en) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 Metal drawing oil
CN103725383A (en) * 2013-12-23 2014-04-16 天津市金岛润滑油有限公司 Stamping and stretching oil for sheet metal and preparation method thereof
CN104877733A (en) * 2015-04-23 2015-09-02 东莞市博奥润滑油有限公司 Stainless steel drawing oil
CN105542919A (en) * 2015-12-23 2016-05-04 天津川美环保科技发展有限公司 A preparing method of environmental friendly stamping oil

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031189A (en) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 Metal drawing oil
CN103725383A (en) * 2013-12-23 2014-04-16 天津市金岛润滑油有限公司 Stamping and stretching oil for sheet metal and preparation method thereof
CN104877733A (en) * 2015-04-23 2015-09-02 东莞市博奥润滑油有限公司 Stainless steel drawing oil
CN105542919A (en) * 2015-12-23 2016-05-04 天津川美环保科技发展有限公司 A preparing method of environmental friendly stamping oil

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
厉海祥: "《点线啮合齿轮传动》", 31 January 2011 *
蔡智等: "《油品调和技术》", 31 January 2006 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106701286A (en) * 2017-01-05 2017-05-24 广东美商工业材料有限公司 Steel tube drawing oil and preparation method thereof

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RJ01 Rejection of invention patent application after publication

Application publication date: 20161207

RJ01 Rejection of invention patent application after publication