CN106189807A - High abrasion frosted ultraviolet-curing paint - Google Patents
High abrasion frosted ultraviolet-curing paint Download PDFInfo
- Publication number
- CN106189807A CN106189807A CN201610649061.XA CN201610649061A CN106189807A CN 106189807 A CN106189807 A CN 106189807A CN 201610649061 A CN201610649061 A CN 201610649061A CN 106189807 A CN106189807 A CN 106189807A
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- Prior art keywords
- parts
- frosted
- ultraviolet
- high abrasion
- curing paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high abrasion frosted ultraviolet-curing paint, it is made up of the raw material of following weight parts, six 20 30 parts of degree of functionality polyurethane acroleic acid fat, 20 30 parts of four degree of functionality polyurethane acroleic acid fat, six functional acrylate monomers 8 15 parts, auxiliary agent 24 parts, frosting powder 15 parts, solvent 20 30 parts, light trigger 2.0 3.0 parts.The anti scuffing performance of frosted ultraviolet-curing paint prepared by the present invention improves a lot, and sand streak effect is evenly distributed, and air is attractive in appearance.With sense of touch and the texture of sand streak effect while ensureing conventional ultra-violet photocureable coating performance.
Description
Technical field
The present invention relates to paint field, especially, relate to a kind of high abrasion frosted ultraviolet-curing paint.
Background technology
Frosted ultraviolet-curing paint, is a kind of new coating, and its product is attractive in appearance, graceful, generous, thus promotes and be exceedingly fast.
A few years, just at tobacco bale, Jiu Bao, cosmetics and mobile phone, the electronics field such as computer occupies sizable ratio.But
It is owing to the domestic even world of frosted ultraviolet-curing paint is all formed without unified detection criterion, so that market now
On the universal anti scuffing of product poor, easily damage；Sand streak effect is uneven, and granule texture is poor.
Along with the raising of ultraviolet-curing paint level, the scratch resistance anti-wear performance also day to frosted ultraviolet-curing paint
Benefit improve, the scratch resistance of former frosted ultraviolet-curing paint and anti-wear performance can not meet current product painting with
Printing needs.Thus, in order to meet the demand in market, extend product service life, it would be highly desirable to work out a kind of super abrasive height anti-zoned
Hinder the frosted ultraviolet-curing paint of excellent performance.
Summary of the invention
Present invention aim at providing a kind of high abrasion frosted uv curing coating, to solve existing frosted ultra-violet curing
Coating is the most wear-resisting, the technical problem of adhesion strength difference.
For achieving the above object, according to an aspect of the invention, it is provided a kind of high abrasion frosted uv curing coating,
It is made up of the raw material of following weight parts, six degree of functionality polyurethane acroleic acid fat 20-30 parts, four degree of functionality polyurethane acrylic resins
20-30 part, six functional acrylate monomers's 8-15 parts, auxiliary agent 2-4 part, frosting powder 1-5 part, solvent 20-30 part, light trigger
2.0-3.0 part.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent one or many in ethyl acetate, butyl acetate, methyl iso-butyl ketone (MIBK), isopropanol and butanone
Kind.
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
Described frosting powder includes: one or more in sand streak powder, wax powder, PMMA micropowder, fine silica powder or microballon.
The method have technical effect that:
The wearability of high abrasion frosted ultraviolet-curing paint, adhesion strength prepared by the present invention improve a lot；Mill
Sand uniform in effect, air are attractive in appearance: frosted sense of touch is good, granular sensation is strong.
The mechanism of action of the present invention: function functional group number contained by six degree of functionality polyurethane acroleic acid fat is many, and strand is relative
Shorter, finish paint has shorter molecular chain length and can strengthen finish paint hardness and wear resistance, resistance to marring.When topcoating cures,
The high official of short chain can be easily caused paint film and slight crack occur by aliphatic polyurethane acrylate, and four degree of functionality polyurethane acroleic acid fat by
Less in its functional group, strand is longer, takes into account hardness and toughness, and the high official that can buffer high rigidity in the curing process can poly-ammonia
The one-tenth membrane stress that ester acrylic resin produces, prevents from bursting apart during solidification, can assist the adhesion strength improving finish paint.Six senses third
The addition of alkene acid ester monomer can improve the finish paint speed when curing reaction, the most also has auxiliary and improves the effect of wearability.
Light trigger can absorb ultraviolet light, when topcoating cures, can be six degree of functionality polyurethane acroleic acid fat, four degree of functionality polyurethane third
Olefin(e) acid fat, the cross-linking reaction of six functional acrylate monomers provide free group to promote the speed of paint film cross-linking reaction.Dilution
The addition of agent can regulate the viscosity of finish paint, prevents finish paint from crossing viscous or the dilutest, beneficially the production of finish paint and construction.Auxiliary agent improves mill
The coating performance of sand uv curing coating and surface effect, it is ensured that product appearance planarization.Frosting powder is provided that different-grain diameter is thick
Thin frosted finish effect.Component and content according to the present invention are combined, and finish paint not only can guarantee that certain hardness but also unlikely due to firmly
Spend height and lose flexibility, and the properties such as the resistance to marring of institute's film forming, wearability all can reach optimum；If it is each in finish paint
The too high levels or too low of component, all will affect the hardness of finish paint, adhesion strength and anti-wear performance.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages.
Below with reference to embodiment, the present invention is further detailed explanation.
Detailed description of the invention
Below in conjunction with description, embodiments of the invention are described in detail, but the present invention can be limited by claim
Multitude of different ways that is fixed and that cover is implemented.
Embodiment 1
A kind of high abrasion frosted ultraviolet-curing paint, is made up of the raw material of following weight parts, six degree of functionality polyurethane third
30 parts of olefin(e) acid fat, four degree of functionality urethane acrylate 25 parts, six degree of functionality acrylate monomer 10 parts, auxiliary agent 2 parts, sand streak powder
4 parts, solvent 26 parts, light trigger 3 parts.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent is selected from ethyl acetate and butyl acetate, methyl iso-butyl ketone (MIBK).
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
Embodiment 2
A kind of high abrasion frosted uv curing coating, is made up of the raw material of following weight parts, six degree of functionality polyurethane propylene
Acid 20 parts of fat, four degree of functionality urethane acrylate 30 parts, six degree of functionality acrylate monomer 15 parts, auxiliary agent 2 parts, 6 parts of wax powder,
Solvent 24 parts, light trigger 3 parts.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent is selected from butyl acetate, methyl iso-butyl ketone (MIBK), butanone.
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
Embodiment 3
A kind of high abrasion frosted uv curing coating, is made up of the raw material of following weight parts, six degree of functionality polyurethane propylene
Acid 20 parts of fat, four degree of functionality urethane acrylate 35 parts, six degree of functionality acrylate monomer 10 parts, auxiliary agent 2 parts, sand streak powder 2
Part, solvent 28.5 parts, light trigger 2.5 parts.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent is selected from ethyl acetate and methyl iso-butyl ketone (MIBK).
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
Embodiment 4
A kind of high abrasion frosted ultraviolet-curing paint, is made up of the raw material of following weight parts, six degree of functionality polyurethane third
30 parts of olefin(e) acid fat, four degree of functionality urethane acrylate 25 parts, six degree of functionality acrylate monomer 10 parts, auxiliary agent 2 parts, PMMA are micro-
4 parts of powder, solvent 26 parts, light trigger 3 parts.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent is selected from ethyl acetate and butyl acetate, methyl iso-butyl ketone (MIBK).
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
Embodiment 5
A kind of high abrasion frosted uv curing coating, is made up of the raw material of following weight parts, six degree of functionality polyurethane propylene
Acid 20 parts of fat, four degree of functionality urethane acrylate 30 parts, six degree of functionality acrylate monomer 15 parts, auxiliary agent 2 parts, organosilicon are micro-
6 parts of powder, solvent 24 parts, light trigger 3 parts.
Described light trigger is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
Described solvent is selected from butyl acetate, methyl iso-butyl ketone (MIBK), butanone.
Described auxiliary agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described froth breaking
Agent is polydimethylsiloxane.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, that is made any repaiies
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (6)
1. a high abrasion frosted ultraviolet-curing paint, it is characterised in that be made up of the raw material of following weight parts, six degrees of functionality
Polyurethane acroleic acid fat 20-30 part, four degree of functionality polyurethane acrylate 20-30 parts, six functional acrylate monomers's 8-15 parts,
Auxiliary agent 2-4 part, frosting powder 1-5 part, solvent 20-30 part, light trigger 2.0-3.0 part.
High abrasion frosted ultraviolet-curing paint the most according to claim 1, it is characterised in that former by following weight parts
Material composition, six degree of functionality polyurethane acrylic resin 20-30 parts, four degree of functionality polyurethane acrylic resin 20-30 parts, six senses
Acrylate monomer 8-15 part, auxiliary agent 2-4 part, frosting powder 1-5 part, solvent 20-30 part, light trigger 2.0-3.0 part.
3. according to the high abrasion frosted ultraviolet-curing paint described in any one of claim 1 to 2, it is characterised in that described light
Initiator is Alpha-hydroxy phenylcyclohexyl ketone and 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide.
4. according to the high abrasion frosted ultraviolet-curing paint described in any one of claim 1 to 2, it is characterised in that described molten
One or more in ethyl acetate, butyl acetate, methyl iso-butyl ketone (MIBK), isopropanol and butanone of agent.
5. according to the high abrasion frosted ultraviolet-curing paint described in any one of claims 1 to 3, it is characterised in that described in help
Agent includes that levelling agent and defoamer, described levelling agent are poly-methyl alkyl siloxane solution；Described defoamer is poly dimethyl silicon
Oxygen alkane.
6. according to the high abrasion frosted ultraviolet-curing paint described in any one of claims 1 to 3, it is characterised in that described mill
Sand powder includes: one or more in sand streak powder, wax powder, PMMA micropowder, fine silica powder or microballon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649061.XA CN106189807A (en) | 2016-08-09 | 2016-08-09 | High abrasion frosted ultraviolet-curing paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610649061.XA CN106189807A (en) | 2016-08-09 | 2016-08-09 | High abrasion frosted ultraviolet-curing paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189807A true CN106189807A (en) | 2016-12-07 |
Family
ID=57514835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610649061.XA Pending CN106189807A (en) | 2016-08-09 | 2016-08-09 | High abrasion frosted ultraviolet-curing paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN106189807A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107116016A (en) * | 2017-06-30 | 2017-09-01 | 广东龙昕科技有限公司 | The stereo carving manufacturing technique for painting dressing and its emanation spraying paint of a kind of housing |
| CN107189540A (en) * | 2017-07-11 | 2017-09-22 | 深圳市深赛尔股份有限公司 | A kind of UV offset printings frosted ink and preparation method thereof |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN108084858A (en) * | 2017-12-06 | 2018-05-29 | 曹结宾 | For the frosted coating of glass surface |
| CN109181447A (en) * | 2018-08-15 | 2019-01-11 | 东莞市佩琦涂料有限公司 | A kind of optical curing of UV coating and preparation method thereof |
| CN109439151A (en) * | 2018-10-30 | 2019-03-08 | 连云港泽阳装饰材料有限公司 | A kind of white enamel polyester paint of particle |
| CN109555289A (en) * | 2019-01-18 | 2019-04-02 | 广州厚邦木业制造有限公司 | One kind is imitative to inlay flower wood floors and preparation method thereof |
| CN113773755A (en) * | 2021-09-25 | 2021-12-10 | 王家国 | Photocatalyst coating and preparation process and application thereof |
| CN114875710A (en) * | 2022-03-24 | 2022-08-09 | 上海睿途新材料科技有限公司 | Frosted coating and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778848A (en) * | 2004-11-23 | 2006-05-31 | 比亚迪股份有限公司 | Ultraviolet light curing coating and production thereof |
| CN1796478A (en) * | 2004-12-20 | 2006-07-05 | 比亚迪股份有限公司 | Coating material solidified by ultraviolet light and prepartion method |
| CN1800274A (en) * | 2004-12-31 | 2006-07-12 | 深圳松辉化工有限公司 | Ultraviolet cured printing ink composition and its uses |
-
2016
- 2016-08-09 CN CN201610649061.XA patent/CN106189807A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1778848A (en) * | 2004-11-23 | 2006-05-31 | 比亚迪股份有限公司 | Ultraviolet light curing coating and production thereof |
| CN1796478A (en) * | 2004-12-20 | 2006-07-05 | 比亚迪股份有限公司 | Coating material solidified by ultraviolet light and prepartion method |
| CN1800274A (en) * | 2004-12-31 | 2006-07-12 | 深圳松辉化工有限公司 | Ultraviolet cured printing ink composition and its uses |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107116016A (en) * | 2017-06-30 | 2017-09-01 | 广东龙昕科技有限公司 | The stereo carving manufacturing technique for painting dressing and its emanation spraying paint of a kind of housing |
| CN107189540A (en) * | 2017-07-11 | 2017-09-22 | 深圳市深赛尔股份有限公司 | A kind of UV offset printings frosted ink and preparation method thereof |
| CN107189540B (en) * | 2017-07-11 | 2020-11-06 | 深圳市深赛尔股份有限公司 | UV offset frosted ink and preparation method thereof |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN108084858A (en) * | 2017-12-06 | 2018-05-29 | 曹结宾 | For the frosted coating of glass surface |
| CN109181447A (en) * | 2018-08-15 | 2019-01-11 | 东莞市佩琦涂料有限公司 | A kind of optical curing of UV coating and preparation method thereof |
| CN109439151A (en) * | 2018-10-30 | 2019-03-08 | 连云港泽阳装饰材料有限公司 | A kind of white enamel polyester paint of particle |
| CN109555289A (en) * | 2019-01-18 | 2019-04-02 | 广州厚邦木业制造有限公司 | One kind is imitative to inlay flower wood floors and preparation method thereof |
| CN113773755A (en) * | 2021-09-25 | 2021-12-10 | 王家国 | Photocatalyst coating and preparation process and application thereof |
| CN114875710A (en) * | 2022-03-24 | 2022-08-09 | 上海睿途新材料科技有限公司 | Frosted coating and preparation method and application thereof |
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Application publication date: 20161207 |
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