CN103740229B - A kind of wear-resistant paint - Google Patents
A kind of wear-resistant paint Download PDFInfo
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- CN103740229B CN103740229B CN201310719414.5A CN201310719414A CN103740229B CN 103740229 B CN103740229 B CN 103740229B CN 201310719414 A CN201310719414 A CN 201310719414A CN 103740229 B CN103740229 B CN 103740229B
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Abstract
The invention discloses a kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 20-35 part, silicone modified polyester resin 15-22 part, silicon dioxide gel 8-11 part, Xylo-Mucine 2-5 part, toluene 13-17 part, ethylbenzene 8-15 part, Graphite Powder 99 6-9 part, p-Xylol 10-15 part, vinyl acetic monomer 7-12 part, 2-(2-ethyl-butoxy) ethanol 5-8 part, Virahol 3-7 part, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.3-0.6.In the present invention, described wear-resistant paint, wear resisting property is excellent, and cost is lower, long service life.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of wear-resistant paint.
Background technology
Coating is as a kind of material, belong to fine chemical product, this material can be coated in article surface by different construction technologies, form adhere well, there is some strength and continuous print solid film, wear-resistant paint is the new function coating that a class has specific function, there is better wearability good, such as wear-resistant coating is plated on glass and eyeglass, cut be there will be no by glass and eyeglass, wear-resisting functions coating is the core in new coating field, plays important promotion and supporting role to the development of modern coatings industry and technology.In the industry of global modern coatings with the research field of technology, wear-resisting functions coating accounts for 25-35%, has become the emphasis of countries in the world new coating area research development, is also countries in the world modern coatings industry and the focus of Strategic Competition in technical development.Although develop multiple wear-resistant paint at present, but still can not meet demand, how to prepare a kind of wear resisting property excellent, cost is low, and the coating of long service life becomes the current technical issues that need to address.
Summary of the invention
The present invention proposes a kind of wear-resistant paint, wear resisting property is excellent, and cost is lower, long service life.
A kind of wear-resistant paint that the present invention proposes, its raw material comprises by weight: zinc borate modified phenolic resins 20-35 part, silicone modified polyester resin 15-22 part, silicon dioxide gel 8-11 part, Xylo-Mucine 2-5 part, toluene 13-17 part, ethylbenzene 8-15 part, Graphite Powder 99 6-9 part, p-Xylol 10-15 part, vinyl acetic monomer 7-12 part, 2-(2-ethyl-butoxy) ethanol 5-8 part, Virahol 3-7 part, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.3-0.6.
In a specific embodiment, the weight part of zinc borate modified phenolic resins can be 20, 22, 24, 25, 26, 28, 30, 31, 33, 34, 35, the weight part of silicone modified polyester resin can be 15, 15.6, 17, 17.7, 18, 19.4, 20, 20.4, 21, 21.5, 22, the weight part of silicon dioxide gel can be 8, 8.2, 8.5, 8.6, 9, 9.5, 10, 10.3, 10.5, 10.8, 11, the weight part of Xylo-Mucine can be 2, 2.3, 2.6, 3, 3.2, 3.7, 4, 4.5, 4.8, 5, the weight part of toluene can be 13, 13.4, 13.8, 14, 14.5, 15, 15.1, 15.7, 16, 16.4, 16.8, 17, the weight part of ethylbenzene can be 8, 9, 9.4, 10, 11, 12, 12.7, 13, 14, 14.5, 15, the weight part of Graphite Powder 99 can be 6, 6.2, 6.6, 7, 7.2, 7.5, 8, 8.4, 8.9, 9, the weight part of p-Xylol can be 10, 10.4, 11.7, 12, 12.8, 13, 13.4, 14, 14.2, 15, the weight part of vinyl acetic monomer can be 7, 7.4, 7.8, 8, 8.3, 8.6, 9, 9.5, 9.9, 10, 11, the weight part of 12,2-(2-ethyl-butoxy) ethanol can be 5, 5.3, 5.7, 6, 6.4, 6.7, 7, 7.2, 7.4, 7.9, 8, the weight part of Virahol can be 3, 3.3, 4, 4.2, 5, 5.8, 6, 6.5, 7.
Preferably, the content of toluene, ethylbenzene and p-Xylol three is no less than 30%.
Preferably, the weight ratio of 2-(2-ethyl-butoxy) ethanol and Virahol is (2.1-4.66): 2.
Preferably, the weight ratio of zinc borate modified phenolic resins and silicone modified polyester resin is (3-4): 2.
Preferably, its raw material comprises by weight: zinc borate modified phenolic resins 27-32 part, silicone modified polyester resin 17-20 part, silicon dioxide gel 8-10 part, toluene 14-16 part, ethylbenzene 10-13 part, Graphite Powder 99 7-8 part, p-Xylol 11-13 part, vinyl acetic monomer 10-11 part, 2-(2-ethyl-butoxy) ethanol 7-8 part, Virahol 5-6 part, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.3-0.6.
Preferably, its raw material comprises by weight: zinc borate modified phenolic resins 30 parts, silicone modified polyester resin 19 parts, silicon dioxide gel 8 parts, toluene 15 parts, 13 parts, ethylbenzene, Graphite Powder 99 7 parts, p-Xylol 13 parts, vinyl acetic monomer 10 parts, 2-(2-ethyl-butoxy) ethanol 8 parts, Virahol 6 parts, wherein the pH value of Xylo-Mucine is 8.4, and substitution value is 0.3.
In the present invention, zinc borate modified phenolic resins and silicone modified polyester resin are as the base material of high-abrasive material, both control ratio is in certain scope, significantly improve the wear resisting property of wear-resistant paint, toluene, ethylbenzene and p-Xylol are the organic solvent of coating, conservative control three content in the feed, dilution and the steady volatilization of coating are effective, more level and smooth film can be formed, the wear resisting property of Graphite Powder 99 is good, with silicon dioxide gel acting in conjunction, can under the prerequisite of adhesion property significantly improving wear-resistant paint and substrate, greatly strengthen the wear resisting property of coating, add the tackiness agent of Xylo-Mucine as wear-resistant paint, add the adhesive property that can strengthen coating on a small quantity, and bond properties is excellent, the spreading property of coating is good, jointly use with Graphite Powder 99 and silicon dioxide gel, significantly can improve the wear resisting property of coating, in the present invention, the wear resisting property of described high-strength wearable coating is excellent, good with the adhesion property of substrate, cost is lower.
Embodiment
Embodiment 1
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 28 parts, silicone modified polyester resin 17.7 parts, silicon dioxide gel 10.5 parts, toluene 14.5 parts, 14.5 parts, ethylbenzene, Graphite Powder 99 6.6 parts, p-Xylol 14.2 parts, vinyl acetic monomer 8.3 parts, 2-(2-ethyl-butoxy) ethanol 7.2 parts, Virahol 4.2 parts, wherein the pH value of Xylo-Mucine is 6.7, and substitution value is 0.6.
Embodiment 2
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 25 parts, silicone modified polyester resin 19.4 parts, silicon dioxide gel 9.5 parts, toluene 15.7 parts, 12.7 parts, ethylbenzene, Graphite Powder 99 7.2 parts, p-Xylol 13.4 parts, vinyl acetic monomer 9.5 parts, 2-(2-ethyl-butoxy) ethanol 6.7 parts, Virahol 5.8 parts, wherein the pH value of Xylo-Mucine is 6.8, and substitution value is 0.53.
Embodiment 3
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 24 parts, silicone modified polyester resin 20.4 parts, silicon dioxide gel 88.6 parts, toluene 16.4 parts, 10 parts, ethylbenzene, Graphite Powder 99 7.5 parts, p-Xylol 12.8 parts, vinyl acetic monomer 10 parts, 2-(2-ethyl-butoxy) ethanol 6 parts, Virahol 6.5 parts, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.5.
Embodiment 4
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 35 parts, silicone modified polyester resin 15 parts, silicon dioxide gel 11 parts, toluene 13.4 parts, 15 parts, ethylbenzene, Graphite Powder 99 6 parts, p-Xylol 15 parts, vinyl acetic monomer 7.4 parts, 2-(2-ethyl-butoxy) ethanol 7.9 parts, Virahol 3.3 parts, wherein the pH value of Xylo-Mucine is 7, and substitution value is 0.42.
Embodiment 5
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 22 parts, silicone modified polyester resin 21.5 parts, silicon dioxide gel 8.2 parts, toluene 17 parts, 9 parts, ethylbenzene, Graphite Powder 99 8.9 parts, p-Xylol 10.4 parts, vinyl acetic monomer 12 parts, 2-(2-ethyl-butoxy) ethanol 5.3 parts, Virahol 7 parts, wherein the pH value of Xylo-Mucine is 7.6, and substitution value is 0.35.
Embodiment 6
A kind of wear-resistant paint, its raw material comprises by weight: zinc borate modified phenolic resins 30 parts, silicone modified polyester resin 19 parts, silicon dioxide gel 8 parts, toluene 15 parts, 13 parts, ethylbenzene, Graphite Powder 99 7 parts, p-Xylol 13 parts, vinyl acetic monomer 10 parts, 2-(2-ethyl-butoxy) ethanol 8 parts, Virahol 6 parts, wherein the pH value of Xylo-Mucine is 8.4, and substitution value is 0.3.
In embodiment 1-6, zinc borate modified phenolic resins and silicone modified polyester resin are as the base material of high-abrasive material, both control ratio is in certain scope, significantly improve the wear resisting property of wear-resistant paint, toluene, ethylbenzene and p-Xylol are the organic solvent of coating, conservative control three content in the feed, dilution and the steady volatilization of coating are effective, more level and smooth film can be formed, the wear resisting property of Graphite Powder 99 is good, with silicon dioxide gel acting in conjunction, can under the prerequisite of adhesion property significantly improving wear-resistant paint and substrate, greatly strengthen the wear resisting property of coating, add the tackiness agent of Xylo-Mucine as wear-resistant paint, add the adhesive property that can strengthen coating on a small quantity, and bond properties is excellent, the spreading property of coating is good, jointly use with Graphite Powder 99 and silicon dioxide gel, significantly can improve the wear resisting property of coating, in the present invention, the wear resisting property of described high-strength wearable coating is excellent, good with the adhesion property of substrate, cost is lower.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (6)
1. a wear-resistant paint, it is characterized in that, its raw material comprises by weight: zinc borate modified phenolic resins 20-35 part, silicone modified polyester resin 15-22 part, silicon dioxide gel 8-11 part, Xylo-Mucine 2-5 part, toluene 13-17 part, ethylbenzene 8-15 part, Graphite Powder 99 6-9 part, p-Xylol 10-15 part, vinyl acetic monomer 7-12 part, 2-(2-ethyl-butoxy) ethanol 5-8 part, Virahol 3-7 part, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.3-0.6.
2. wear-resistant paint according to claim 1, is characterized in that, the content of toluene, ethylbenzene and p-Xylol three is no less than 30%.
3. wear-resistant paint according to claim 1, is characterized in that, the weight ratio of 2-(2-ethyl-butoxy) ethanol and Virahol is (2.1-4.66): 2.
4. wear-resistant paint according to claim 1, is characterized in that, the weight ratio of zinc borate modified phenolic resins and silicone modified polyester resin is (3-4): 2.
5. wear-resistant paint according to claim 1, it is characterized in that, its raw material comprises by weight: zinc borate modified phenolic resins 27-32 part, silicone modified polyester resin 17-20 part, Xylo-Mucine 3-4 part, silicon dioxide gel 8-10 part, toluene 14-16 part, ethylbenzene 10-13 part, Graphite Powder 99 7-8 part, p-Xylol 11-13 part, vinyl acetic monomer 10-11 part, 2-(2-ethyl-butoxy) ethanol 7-8 part, Virahol 5-6 part, wherein the pH value of Xylo-Mucine is 6.7-8.4, and substitution value is 0.3-0.6.
6. wear-resistant paint according to claim 5, is characterized in that, its raw material comprises by weight: zinc borate modified phenolic resins 30 parts, silicone modified polyester resin 19 parts, Xylo-Mucine 3 parts, silicon dioxide gel 8 parts, toluene 15 parts, 13 parts, ethylbenzene, Graphite Powder 99 7 parts, p-Xylol 13 parts, vinyl acetic monomer 10 parts, 2-(2-ethyl-butoxy) ethanol 8 parts, Virahol 6 parts, wherein the pH value of Xylo-Mucine is 8.4, and substitution value is 0.3.
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| CN201310719414.5A CN103740229B (en) | 2013-12-23 | 2013-12-23 | A kind of wear-resistant paint |
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| CN201310719414.5A CN103740229B (en) | 2013-12-23 | 2013-12-23 | A kind of wear-resistant paint |
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| CN103740229B true CN103740229B (en) | 2015-10-07 |
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Cited By (1)
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| CN106590317A (en) * | 2016-12-13 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Wear-resistant coating for universal joint |
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| JP5010806B2 (en) * | 2005-02-01 | 2012-08-29 | 日本ペイント株式会社 | Powder coating composition and method for coating aluminum wheel |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106590317A (en) * | 2016-12-13 | 2017-04-26 | 苏州纽东精密制造科技有限公司 | Wear-resistant coating for universal joint |
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Inventor after: Zhu Hengheng Inventor after: Hu Lan Inventor after: Zhang Guosheng Inventor before: Zhu Hengheng Inventor before: Hu Lan Inventor before: Zhang Guosheng |
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Denomination of invention: A kind of wear resistant coating Effective date of registration: 20210401 Granted publication date: 20151007 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI JINDUN PAINT Co.,Ltd. Registration number: Y2021980002363 |
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Date of cancellation: 20220325 Granted publication date: 20151007 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI JINDUN PAINT Co.,Ltd. Registration number: Y2021980002363 |