CN106189776A - A kind of plastic anti-flaming dope - Google Patents
A kind of plastic anti-flaming dope Download PDFInfo
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- CN106189776A CN106189776A CN201610589090.1A CN201610589090A CN106189776A CN 106189776 A CN106189776 A CN 106189776A CN 201610589090 A CN201610589090 A CN 201610589090A CN 106189776 A CN106189776 A CN 106189776A
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- parts
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- flaming dope
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The present invention relates to preparation and the applied technical field of novel high polymer material, particularly relate to a kind of plastic anti-flaming dope, be mainly made up of the following material in terms of mass fraction: waterborne polyurethane resin 20 30 parts, flame-retardant system compositions 35 parts, hydrophobic polymer compound 8 15 parts, barium hydroxide octahydrate 25 parts, petroleum ether 36 parts, high temperature resistant binder 12 parts, carbonic ester coupling agent 24 parts, cycloalkane and alkane mixture 13 parts, polyhydric alcohol 12 parts, emulsifying agent 12 parts, filler 35 parts, 20 30 parts of water；Described flame-retardant system compositions is the mixture of silicon compounds, graphene oxide and polyamide；Described silicon compounds includes carborundum and silicon sulfide；Described emulsifying agent is the mixture of Cyclohexanone peroxides and poly-lactic acid ester.The anti-flaming dope of the present invention is particularly well-suited to the incrustation of plastic, and stable chemical performance, fire resistance are good, and flame-retardant system compositions addition is little.
Description
Technical field
The present invention relates to preparation and the applied technical field of novel high polymer material, particularly relate to a kind of plastic fire-retardant
Coating.
Background technology
Along with the development of industry, plastics are increasingly widely applied.Polyethylene, ABS etc. use in a large number and are building
Build, indoor decoration, the industry such as household electrical appliances.But the carbon in plastics, two kinds of constituent contents of hydrogen are the highest, so as easy as rolling off a log burning, typically
All need to carry out flame treatment when using plastics.The current fire-retardant main fire retardant that adds in addition is main.Use outer interpolation fire retardant side
Formula carries out flame treatment to material, but the general content of halogen of fire retardant added is higher, during burning, releases Halogen flue gas, has
Toxicity, the health of meeting harmful to human.And the adhesive force of coating is required the strictest by plastic, it is therefore desirable to consider again
A kind of novel environment-friendly water paint is researched and developed on the basis of adhesive force and fire resistance.
Summary of the invention
In order to solve above-mentioned technical problem, it is provided that a kind of fire resistance is good, adhesive force strong, dispersibility and stable chemical performance
Coating, the present invention provides techniques below scheme:
A kind of plastic anti-flaming dope, is made up of the following material in terms of mass fraction: waterborne polyurethane resin 20-30
Part, flame-retardant system compositions 3-5 part, hydrophobic polymer compound 8-15 part, barium hydroxide octahydrate 2-5 part, petroleum ether 3-6
Part, high temperature resistant binder 1-2 part, carbonic ester coupling agent 2-4 part, cycloalkane and alkane mixture 1-3 part, polyhydric alcohol 1-2 part,
Emulsifying agent 1-2 part, filler 3-5 part, water 20-30 part；Described flame-retardant system compositions is by silicon compounds, graphene oxide and gathers
Amide mixes.
The present invention have developed a kind of novel flame-retardant system compositions, by silicon compounds, graphene oxide and polyamide
Mixing, described silicon compounds is extensive as conventional flame retardant additive application, but it cooperates with graphene oxide
After can more significantly suppress combustion chain reaction, it is more stable that the mixture of above-mentioned three kinds of materials can produce structure when being heated
Crosslinking shape solid matter or carburization zone, on the one hand the formation of carburization zone can stop polymer to be pyrolyzed further, on the other hand can hinder
Only its internal thermal decomposition produces thing and enters gas phase participation combustion process.On the other hand, described flame-retardant system compositions adds painting
Material serves not only as fire retardant work, the reaction between each composition of coating can also be promoted as catalyst, be conducive to simultaneously
Improve the dispersibility of coating.
Further, described silicon compounds, graphene oxide are 10:1:5 with the mixed proportion of polyamide.By above-mentioned ratio
The flame-retardant system compositions stability that example mixes is the strongest, fire resistance is optimal.
Further, described silicon compounds is the mixture of carborundum and silicon sulfide, described carborundum and silicon sulfide
Ratio is 2-3:1, and the covering effect at high temperature of the silicon compounds of aforementioned proportion is the most preferable.
Further, described emulsifying agent is the mixture of Cyclohexanone peroxides and poly-lactic acid ester, described Ketohexamethylene peroxide
Compound is 1-2:4 with the ratio of poly-lactic acid ester, and its dispersibility of the emulsifying agent of aforementioned proportion is relative with film property preferable.
Further, described hydrophobic polymer compound is the one in politef or polymethyl or two
The mixture planted, is conducive to improving the surface soiling ability of coating.
Further, described polyhydric alcohol is the mixture of isopropanol and ethylene glycol, described isopropanol and the ratio of ethylene glycol
For 4:1, the polyhydric alcohol of aforementioned proportion has preferably effect to the glossiness and brightness that improve coating.
The beneficial effects of the present invention is:
(1), providing a kind of new flame-retardant system compositions, addition is few, the advantage with cigarette efficient, low；
(2), work in-process do not produce toxic gas, its dispersibility, physical property, mechanical performance, heat stability and fire-retardant
Performance is improved and improves.
Detailed description of the invention
Embodiment 1,
A kind of plastic anti-flaming dope, is made up of the following material in terms of mass fraction: waterborne polyurethane resin 25 parts,
Flame-retardant system compositions 4 parts, hydrophobic polymer compound 11.5 parts, barium hydroxide octahydrate 3.5 parts, petroleum ether 4.5 parts, resistance to
High-temperature agglomerant 1.5 parts, carbonic ester coupling agent 3 parts, cycloalkane and alkane mixture 2 parts, polyhydric alcohol 1.5 parts, emulsifying agent 1.5
Part, filler 4 parts, 25 parts of water；Described flame-retardant system compositions is mixed with polyamide by silicon compounds, graphene oxide.
Described silicon compounds, graphene oxide are 10:1:5 with the mixed proportion of polyamide.Described silicon compounds is
Carborundum and the mixture of silicon sulfide, described carborundum is 2:1 with the ratio of silicon sulfide.Described emulsifying agent is Ketohexamethylene peroxidating
Thing and the mixture of poly-lactic acid ester, described Cyclohexanone peroxides is 1:3 with the ratio of poly-lactic acid ester.Described hydrophobic polymer
Compound is politef.Described polyhydric alcohol is the mixture of isopropanol and ethylene glycol, described isopropanol and the ratio of ethylene glycol
Example is 4:1.
Embodiment 2,
A kind of plastic anti-flaming dope, is made up of the following material in terms of mass fraction: waterborne polyurethane resin 20 parts,
Flame-retardant system compositions 3 parts, hydrophobic polymer compound 8 parts, barium hydroxide octahydrate 2 parts, petroleum ether 3 parts, high temperature resistant viscous
Knot agent 1 part, carbonic ester coupling agent 2 parts, cycloalkane and alkane mixture 1 part, polyhydric alcohol 1 part, emulsifying agent 1 part, filler 3 parts,
20 parts of water；Described flame-retardant system compositions is mixed with polyamide by silicon compounds, graphene oxide.
Described silicon compounds, graphene oxide are 10:1:5 with the mixed proportion of polyamide.Described silicon compounds is
Carborundum and the mixture of silicon sulfide, described carborundum is 2:1 with the ratio of silicon sulfide.Described emulsifying agent is Ketohexamethylene peroxidating
Thing and the mixture of poly-lactic acid ester, described Cyclohexanone peroxides is 1:2 with the ratio of poly-lactic acid ester.Described hydrophobic polymer
Compound is politef.Described polyhydric alcohol is the mixture of isopropanol and ethylene glycol, described isopropanol and the ratio of ethylene glycol
Example is 4:1.
Embodiment 3,
A kind of plastic anti-flaming dope, is made up of the following material in terms of mass fraction: waterborne polyurethane resin 30 parts,
Flame-retardant system compositions 5 parts, hydrophobic polymer compound 15 parts, barium hydroxide octahydrate 5 parts, petroleum ether 6 parts, high temperature resistant viscous
Knot agent 2 parts, carbonic ester coupling agent 4 parts, cycloalkane and alkane mixture 3 parts, polyhydric alcohol 2 parts, emulsifying agent 2 parts, filler 5 parts,
30 parts of water；Described flame-retardant system compositions is mixed with polyamide by silicon compounds, graphene oxide.
Described silicon compounds, graphene oxide are 10:1:5 with the mixed proportion of polyamide.Described silicon compounds is
Carborundum and the mixture of silicon sulfide, described carborundum is 2:1 with the ratio of silicon sulfide.Described emulsifying agent is Ketohexamethylene peroxidating
Thing and the mixture of poly-lactic acid ester, described Cyclohexanone peroxides is 1:2 with the ratio of poly-lactic acid ester.Described hydrophobic polymer
Compound is politef.Described polyhydric alcohol is the mixture of isopropanol and ethylene glycol, described isopropanol and the ratio of ethylene glycol
Example is 4:1.
The fire-retardant index of above-mentioned three kinds of embodiments and the actual measurement of other technical specifications are as follows:
In analysis, table understands, and three kinds of embodiments of the present invention all can reach V0 fire rating, and mechanical performance and chemistry are surely
Qualitative the most excellent, wherein the comprehensive technical indexes of embodiment 1 is optimum.
With above-mentioned foundation desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff is complete
Various change and amendment can be carried out in the range of without departing from this invention technological thought.This invention technical
Scope is not limited to the content in description, it is necessary to determine its technical scope according to right.
Claims (6)
1. a plastic anti-flaming dope, it is characterised in that: it is made up of the following material in terms of mass fraction: aqueous polyurethane
Resin 20-30 part, flame-retardant system compositions 3-5 part, hydrophobic polymer compound 8-15 part, barium hydroxide octahydrate 2-5 part,
Petroleum ether 3-6 part, high temperature resistant binder 1-2 part, carbonic ester coupling agent 2-4 part, cycloalkane and alkane mixture 1-3 part, many
Unit alcohol 1-2 part, emulsifying agent 1-2 part, filler 3-5 part, water 20-30 part；Described flame-retardant system compositions is by silicon compounds, oxidation
Graphene mixes with polyamide.
2. a kind of plastic anti-flaming dope as claimed in claim 1, it is characterised in that: described silicon compounds, oxidation stone
Ink alkene is 10:1:5 with the mixed proportion of polyamide.
3. a kind of plastic anti-flaming dope as claimed in claim 1, it is characterised in that: described silicon compounds is carborundum
With the mixture of silicon sulfide, described carborundum is 2-3:1 with the ratio of silicon sulfide.
4. a kind of plastic anti-flaming dope as claimed in claim 1, it is characterised in that: described emulsifying agent is Ketohexamethylene peroxide
Compound and the mixture of poly-lactic acid ester, described Cyclohexanone peroxides is 1-2:4 with the ratio of poly-lactic acid ester.
5. a kind of plastic anti-flaming dope as claimed in claim 1, it is characterised in that: described hydrophobic polymer compound
For one or both the mixture in politef or polymethyl.
6. a kind of plastic anti-flaming dope as claimed in claim 1, it is characterised in that: described polyhydric alcohol is isopropanol and second
The mixture of glycol, described isopropanol is 4:1 with the ratio of ethylene glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610589090.1A CN106189776A (en) | 2016-07-25 | 2016-07-25 | A kind of plastic anti-flaming dope |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610589090.1A CN106189776A (en) | 2016-07-25 | 2016-07-25 | A kind of plastic anti-flaming dope |
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| Publication Number | Publication Date |
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| CN106189776A true CN106189776A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610589090.1A Pending CN106189776A (en) | 2016-07-25 | 2016-07-25 | A kind of plastic anti-flaming dope |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314960A (en) * | 2018-02-08 | 2018-07-24 | 深圳市能驭生态化工科技有限公司 | A kind of aqueous ecologic coating of fire protection flame retarding and preparation method thereof |
| CN108360294A (en) * | 2018-02-08 | 2018-08-03 | 深圳市能驭生态化工科技有限公司 | A kind of fire protection flame retarding water paint and preparation method thereof for paper product |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108314960A (en) * | 2018-02-08 | 2018-07-24 | 深圳市能驭生态化工科技有限公司 | A kind of aqueous ecologic coating of fire protection flame retarding and preparation method thereof |
| CN108360294A (en) * | 2018-02-08 | 2018-08-03 | 深圳市能驭生态化工科技有限公司 | A kind of fire protection flame retarding water paint and preparation method thereof for paper product |
| CN108314960B (en) * | 2018-02-08 | 2020-06-26 | 深圳市能驭生态化工科技有限公司 | Fireproof flame-retardant water-based ecological coating and preparation method thereof |
| CN108360294B (en) * | 2018-02-08 | 2021-02-12 | 深圳市能驭生态化工科技有限公司 | Fireproof flame-retardant water-based paint for paper products and preparation method thereof |
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