CN105647383A - Intumescent flame-retardant spray-coating fast-setting rubber asphalt water-resistant paint and preparation method thereof - Google Patents
Intumescent flame-retardant spray-coating fast-setting rubber asphalt water-resistant paint and preparation method thereof Download PDFInfo
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- CN105647383A CN105647383A CN201610008665.6A CN201610008665A CN105647383A CN 105647383 A CN105647383 A CN 105647383A CN 201610008665 A CN201610008665 A CN 201610008665A CN 105647383 A CN105647383 A CN 105647383A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to an intumescent flame-retardant spray-coating fast-setting rubber asphalt water-resistant paint and a preparation method thereof. The water-resistant paint is composed of a latex component with the solid content of 40-60% and a coagulant component. The latex component is prepared from the following raw materials in percentage by mass: 15-50% of emulsified asphalt, 5-30% of deionized water, 0.1-3% of dispersing agent, 0.1-3% of wetting agent, 0.1-1% of defoaming agent, 0.1-5% of thickener, 0.1-2% of pH regulator, 2-10% of char forming agent, 1-10% of foaming agent, 8-50% of flame-retardant synergist, 20-50% of high-polymer latex and 1-5% of tackifier. The coagulant component is prepared from the following raw materials in percentage by mass: 30-80% of chloride, 1-20% of polymerized sulfuric acid metal salt and 20-50% of carbonifying catalyst. The product has the characteristics of favorable tensile property, favorable low-temperature flexibility, favorable heat resistance and the like, and has the advantages of favorable flame retardancy, low cost and environment friendliness.
Description
Technical field
The present invention relates to waterproof material of a kind of flame retardant type and preparation method thereof, be specifically related to oneExpansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof.
Background technology
Spraying rapid hardening rubber asphalt waterproof coating is called as liquid rubber, last century 90 abroadAge is originated from Lei Na company of the U.S., due to its excellent waterproof reliability, construction convenience withAnd environment-friendly type, obtain Rapid Popularization at world wide. In recent years, the U.S., Canada, Russia sieveThis, Israel, Belgium, Korea S, Thailand and Middle East have this product production andApplication. But because spraying rapid hardening rubber asphalt waterproof coating medium pitch contains oil content, easy firing.When pitch burning, first melting, drippage, trickling, then bead burning, the then bead of burningDrippage, trickling, cause fire spreading to expand; Meanwhile, pitch also can decompose in combustion processGo out the inflammable gas such as hydrogen, methane class, the burning of these inflammable gases has strengthened again the intensity of a fire. Therefore,Greatly hinder the extensive use of spraying rapid hardening rubber asphalt waterproof coating.
At present, the fire retardant adding in flame retardant type spraying rapid hardening rubber asphalt waterproof coating is to be added toIn emulsion components, and emulsion is ionic, adds that some are with the macromolecule of electric charge easyCause product unstable, thereby make water resistance poor; Meanwhile conventional fire retardant comprisesOrganochlorine, antimony oxide and bromide etc., toxicity is environmental protection very much not. For example, prior artCN201210500200.4 discloses a kind of flame retardant type spraying rapid hardening rubber asphalt waterproof coating,This invention does not disclose the composition of high molecular weight flame retardant, and due to liquid rubber asphalt adhesive emulsionIonic, add some macromolecules with electric charge easily affect product water resistance andStability, carbon black, two kinds of fillers of porcelain powder and fine powder material of in formula, adding make production cost simultaneouslyAlso high.
Therefore, develop a kind of efficient, stable, low toxicity, environmental protection, cheap flame retardant type sprayBe coated with the task of top priority that rapid hardening rubber asphalt waterproof coating has been water-repellent paint research.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of and stablize, ensure efficiently productIn use reduce the catch fire expansion type flame-retarding spraying rapid hardening rubber of the loss that causes of buildingGlue asphalt waterproofing paint.
The technical scheme that the present invention solves its technical problem employing is that a kind of expansion type flame-retarding spraysRapid hardening rubber asphalt waterproof coating is 40%-60% latex component and coagulating agent component by solid contentTwo components composition, wherein, described latex component comprises that the raw material of following mass fraction makes,Emulsified asphalt 15%-50%, deionized water 5%-30%, dispersant 0.1-3%, wetting agent 0.1-3%,Defoamer 0.1-1%, thickener 0.1-5%, pH adjusting agent 0.1-2%, carbon forming agent 2-10%,Blowing agent 1%-10%, fire retarding synergist 8-50%, polymer latex 20%-50%, tackifier 1-5%;Described coagulating agent component comprises that the raw material of following mass fraction makes, villaumite 30-80%, polymerizationSulfuric acid slaine 1%-20%, carbonifying catalyst 20%-50%.
Further, described carbon forming agent is polyol.
Further, described carbon forming agent is sweet mellow wine, D-sorbite, pentaerythrite, two seasons penta 4Alcohol, tripentaerythritol, methylol melamine, starch and glucose one or more kinds ofMixture.
Further, described blowing agent is the one in melamine, urea, dicyandiamide and melamineOr two or more mixture.
Further, described fire retarding synergist is aluminium hydroxide, magnesium hydroxide, Firebrake ZB, oxidationOne or more kinds of mixtures in zinc, imvite, titanium dioxide and calcium carbonate.
Further, described thickener is the cellulose ethers of nonionic or anionic, natural heightOne or both compositions in molecule and derivative class thereof, synthetic high score subclass; Described macromolecule glueBreast is polychloroprene latex, styrene-butadiene latex, EVA emulsion, cis-butadiene cement breast, NBR latex and second the third glueThe mixture of one or more of Ruzhong; Described tackifier are acrylic latex and/or waterEpoxy resin; In addition, dispersant, wetting agent, defoamer pH adjusting agent are common the moonIonic.
Further, described carbonifying catalyst is phosphate, sulfate, borate and poly-phosphorusOne or more kinds of mixtures in acid ammonium.
Further, described villaumite be in calcium chloride, magnesium chloride and iron chloride one or both withOn mixture.
Further, described polyaluminum sulfate slaine is polyaluminium sulfate potassium or PAFS.
The technical scheme that the present invention further solves its technical problem employing is that a kind of intumescent hindersThe preparation method of combustion spraying rapid hardening rubber asphalt waterproof coating, comprises the following steps:
(1) preparation of latex component: first in reactor, add deionized water, then by dispersant,Wetting agent, defoamer, thickener, pH adjusting agent add in proportion successively, often add oneAll disperse 5-10 minute with the low speed of 100-200 rev/min; Then add into successively in proportionCharcoal agent, blowing agent, fire retarding synergist, with the high speed dispersion of 500-800 rev/min evenly afterFor subsequent use as white slurry, finally will starch in vain and join in emulsified asphalt, with 200-500 rev/minMiddling speed disperse 20-30min, add tackifier, continue to disperse 20-30min, then add successivelyEnter polymer latex, disperse 30-60min;
(2) preparation of coagulating agent component: adopt homogenizer by villaumite, polyaluminum sulfate slaine,Carbonifying catalyst three proportionally mix;
(3) preparation of expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating: by latex component withCoagulating agent component is pressed 45-55:1 proportioning.
The composite flame-retardant agent of the expansion type flame retardant that the present invention adopts taking nitrogen, phosphorus as chief component,Comprise that carbonifying catalyst, carbon forming agent, blowing agent and fire retarding synergist form, not halogen-containing,Also do not adopt antimony oxide as synergist, this based flame retardant foaming and intumescing in the time being heated, therefore be calledExpansion type flame retardant, is the environment friendly flame retardant of a class high-efficiency low-toxicity, wherein, carbon forming agent, send outInfusion and fire retarding synergist are distributed in latex component, and carbonifying catalyst is distributed in solidifyingIn knot agent component, fire resistance is superior, not only can play catalyst action but also can play coagulating agent and doWith, not only fire retardation can be played but also filler effect can be played. 150 DEG C of left and right, be dehydrated into charcoalCatalyst produces energy esterification polyol and can be used as the acid of dehydrating agent, at slightly high temperature, and acidCarry out esterification with carbon forming agent, the amido in system adds as the catalyst of esterificationSpeed reaction, system melting before esterification and in esterification process, produces not in course of reactionCombustion property gas makes that the system in molten condition is expanded foamed, meanwhile, and polyalcohol and esterDehydration carbonization, forms inorganic matter and carbon residue, and system further foams; Reaction has approachedTime, system gel and curing, finally forms and contains solid, liquid and gaseous state product at material surfaceThe porous foam coke layer of thing, this multiphase system has been brought into play the fire-retardant work of dominance in the present inventionWith, flame-retardant nature is mainly reflected in and makes heat be difficult to penetrate condensed phase, stops oxygen to enter combustion zoneTerritory, the gaseous state or the liquid product that stop degraded to generate overflow material surface, to the water proofing property of productEnergy and stability do not affect, and can reduce production costs.
Compared with prior art, the present invention has following useful technique effect:
(1) the not halogen-containing and antimony oxide of expansion type flame retardant adopting is a kind of resistance of environment-friendly typeCombustion agent, and inorganic component in fire retardant is with low cost, is added to and in system, is used for replacing filler,Lower with respect to flame retardant type product cost on the market.
(2) in formula for a product, added tackifier (for example acrylic emulsion and/or epoxy resin),The adhesiveness of itself and basic unit is high, has significantly promoted the water resistance of product.
(3) formula for a product adopts multiple emulsion synergy, product have good tensile property,Low temperature flexibility, heat resistance etc.
(4) in product, do not contain organic solvent,, containing environmentally harmful component, do not avoided environmentThe pollution causing, has good environmental protection feature.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
1, the preparation of latex component: first add deionized water 10% in reactor, open at a high speed and divideLoose machine switch, is adjusted to the low speed of 100-200 rev/min, then by dispersant 0.5%, wettingAgent 0.8%, defoamer 0.5%, thickener hydroxyethyl ether cellulose 0.4%, the RW-8W of DOW ChemicalType 0.8%, pH adjusting agent 0.5% add successively, often add a kind of Monodispersed 5-10 minute;Then the high speed that is adjusted to 500-800 rev/min adds carbon forming agent sweet mellow wine 5%, foaming successivelyAgent dicyandiamide 8%, fire retarding synergist zinc oxide 5.5% and powdered whiting 19%, be uniformly dispersedFor subsequent use as white slurry afterwards, finally will starch in vain and join commercially available or homemade common anion emulsificationIn pitch 24%, open the middling speed of 200-500 rev/min and disperse 30min, add tackifier propyleneAcid 3% and aqueous epoxy resins 2%, continue to disperse 30min, then add successively polymer latexPolychloroprene latex 20%, disperses 30-60min.
2, the preparation of coagulating agent component: adopt homogenizer by calcium chloride 65%, polyaluminium sulfatePotassium 8%, carbonifying catalyst magnesium phosphate 12% mix with line borate 15% three, to obtain final productCoagulating agent component.
3, the preparation of expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating: by latex component and solidifyingKnot agent component is pressed 50:1 proportioning. When use, coagulating agent component need to be diluted with water 10 times, adoptsWith two component spray guns, the coagulating agent component of latex component and dilution ratio in the time of spraying is 5:1.
By the expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating product water proofing property preparingCan detect according to professional standard " JC/T2317-2015 sprays rubber asphalt waterproof coating " resistanceCombustion performance is according to floor file in " GB8624-2006 construction material and goods classification system for fire performance "Material tests, test data is in table 1.
Embodiment 2
1, the preparation of latex component: first add deionized water 15% in reactor, open at a high speed and divideLoose machine switch, is adjusted to the low speed of 100-200 rev/min, then by dispersant 0.7%, wettingRW-12W type 1.3%, the pH of agent 0.5%, defoamer 0.5%, thickener DOW Chemical regulateAgent 0.5% adds successively, often adds a kind of Monodispersed 5-10 minute; Then be adjusted to 500-800Rev/min high speed add successively carbon forming agent methylol melamine 6.5%, blowing agent melamine4%, fire retarding synergist magnesium hydroxide 4% and powdered whiting 19%, starches as white after being uniformly dispersedFor subsequent use, finally will starch in vain and join in commercially available or homemade common anion emulsified asphalt 20%,Open the middling speed of 200-500 rev/min and disperse 30min, add tackifier acrylic acid 2% and water-basedEpoxy resin 3%, continues to disperse 30min, then adds successively polymer latex styrene-butadiene latex 8%With polychloroprene latex 15%, disperse 30-60min.
2, the preparation of coagulating agent component: adopt homogenizer by magnesium chloride 70%, polyaluminium sulfateIron 5%, carbonifying catalyst magnesium sulfate 15% mix with APP 10% three,Obtain coagulating agent component.
3, the preparation of expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating: by latex component and solidifyingKnot agent component is pressed 50:1 proportioning. When use, coagulating agent component need to be diluted with water 10 times, adoptsWith two component spray guns, the coagulating agent component of latex component and dilution ratio in the time of spraying is 5:1.
By the product waterproof property preparing, according to professional standard, " JC/T2317-2015 sprays rubberGlue asphalt waterproofing paint " detect, fire resistance according to " GB8624-2006 construction material andGoods classification system for fire performance " middle floor file material tests, test data is in table 1.
Embodiment 3
1, the preparation of latex component: first add deionized water 7% in reactor, open high speed dispersionMachine switch, is adjusted to the low speed of 100-200 rev/min, then by dispersant 0.2%, wetting agent0.4%, defoamer 0.4%, thickener hydroxyethyl ether cellulose 0.2%, the RW-8W of DOW ChemicalType 0.6%, pH adjusting agent 0.4% add successively, often add a kind of Monodispersed 5-10 minute;Then the high speed that is adjusted to 500-800 rev/min adds carbon forming agent pentaerythrite 3% and two successivelyPentaerythrite 3%, blowing agent melamine 3% and urea 4.5%, fire retarding synergist imvite 4.3%With powdered whiting 18%, for subsequent use as white slurry after being uniformly dispersed, finally will starch in vain and join citySell or homemade common anion emulsified asphalt 29% in, open 200-500 rev/min inSpeed is disperseed 30min, adds tackifier aqueous epoxy resins 6%, continues to disperse 30min, then complies withInferior macromolecule glue NBR latex 2% and the polychloroprene latex 18% of adding, disperses 30-60min.
2, the preparation of coagulating agent component: adopt homogenizer by iron chloride 30%, calcium chloride 40%,PAFS 6%, carbonifying catalyst Boratex 14% mix with magnesium sulfate 10% threeEvenly, obtain coagulating agent component.
3, the preparation of expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating: by latex component and solidifyingKnot agent component is pressed 50:1 proportioning. When use, coagulating agent component need to be diluted with water 10 times, adoptsWith two component spray guns, the coagulating agent component of latex component and dilution ratio in the time of spraying is 5:1.
By the product waterproof property preparing, according to professional standard, " JC/T2317-2015 sprays rubberGlue asphalt waterproofing paint " detect, fire resistance according to " GB8624-2006 construction material andGoods classification system for fire performance " middle floor file material tests, test data is in table 1.
Table 1-flame retardant type spraying rapid hardening rubber asphalt waterproof coating test result
Claims (10)
1. an expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating, is characterized in that, by solidContent is two component compositions of 40%-60% latex component and coagulating agent component, wherein, and described glueBreast component comprises that the raw material of following mass fraction makes, emulsified asphalt 15%-50%, deionized water5%-30%, dispersant 0.1-3%, wetting agent 0.1-3%, defoamer 0.1-1%, thickener0.1-5%, pH adjusting agent 0.1-2%, carbon forming agent 2-10%, blowing agent 1%-10%, fire-retardant associationEffect agent 8-50%, polymer latex 20%-50%, tackifier 1-5%; Described coagulating agent component bagDraw together the raw material of following mass fraction and make, villaumite 30-80%, polyaluminum sulfate slaine 1%-20%,Carbonifying catalyst 20%-50%.
2. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described carbon forming agent is polyol.
3. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 2,It is characterized in that, described carbon forming agent is sweet mellow wine, D-sorbite, pentaerythrite, two seasons penta 4Alcohol, tripentaerythritol, methylol melamine, starch and glucose one or more kinds ofMixture.
4. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described blowing agent is the one in melamine, urea, dicyandiamide and melamineOr two or more mixture.
5. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described fire retarding synergist is aluminium hydroxide, magnesium hydroxide, Firebrake ZB, oxidationOne or more kinds of mixtures in zinc, imvite, titanium dioxide and calcium carbonate.
6. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described thickener is the cellulose ethers of nonionic or anionic, natural heightOne or both compositions in molecule and derivative class thereof, synthetic high score subclass; Described macromolecule glueBreast is polychloroprene latex, styrene-butadiene latex, EVA emulsion, cis-butadiene cement breast, NBR latex and second the third glueThe mixture of one or more of Ruzhong; Described tackifier are acrylic latex and/or waterEpoxy resin.
7. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described carbonifying catalyst is phosphate, sulfate, borate and poly-phosphorusOne or more kinds of mixtures in acid ammonium.
8. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described villaumite be in calcium chloride, magnesium chloride and iron chloride one or both withOn mixture.
9. expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating according to claim 1,It is characterized in that, described polyaluminum sulfate slaine is polyaluminium sulfate potassium or PAFS.
10. the expansion type flame-retarding spraying rapid hardening rubber asphalt as described in one of claim 1-9 is anti-The preparation method of water paint, comprises the following steps:
(1) preparation of latex component: first in reactor, add deionized water, then by dispersant,Wetting agent, defoamer, thickener, pH adjusting agent add in proportion successively, often add oneAll disperse 5-10 minute with the low speed of 100-200 rev/min; Then add into successively in proportionCharcoal agent, blowing agent, fire retarding synergist, with the high speed dispersion of 500-800 rev/min evenly afterFor subsequent use as white slurry, finally will starch in vain and join in emulsified asphalt, with 200-500 rev/minMiddling speed disperse 20-30min, add tackifier, continue to disperse 20-30min, then add successivelyEnter polymer latex, disperse 30-60min;
(2) preparation of coagulating agent component: adopt homogenizer by villaumite, polyaluminum sulfate slaine,Carbonifying catalyst three proportionally mix;
(3) preparation of expansion type flame-retarding spraying rapid hardening rubber asphalt waterproof coating: by latex component withCoagulating agent component is pressed 45-55:1 proportioning.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107446502A (en) * | 2017-08-11 | 2017-12-08 | 太原市路邦科技有限公司 | Self-repairing water-based epoxy/asphalt composite waterproof coating and preparation method thereof |
| CN108949029A (en) * | 2018-08-05 | 2018-12-07 | 佛山市矢达新材料科技有限公司 | A kind of aqueous high bonding anticorrosive paint and preparation method thereof suitable for automobile chassis |
| CN109161341A (en) * | 2018-09-10 | 2019-01-08 | 雨中情防水技术集团有限责任公司 | A kind of anti-viscous type spraying rubber asphalt waterproof coating of fire-retardant, the pre- spray of not chloride ion-containing |
| CN110256965A (en) * | 2019-07-08 | 2019-09-20 | 宏恒达防水材料有限公司 | A kind of spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof |
| CN111763477A (en) * | 2020-07-10 | 2020-10-13 | 北方民族大学 | Colored anti-aging spraying quick-setting rubber asphalt waterproof coating |
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| CN102329564A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing zinc borate |
| CN102675889A (en) * | 2012-05-22 | 2012-09-19 | 山西明科斯科技有限公司 | Polymer modified emulsified asphalt composition and preparation method thereof |
| CN102965016A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | High-temperature resistant spray fast-setting rubber asphalt waterproof coating |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102329564A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing zinc borate |
| CN102675889A (en) * | 2012-05-22 | 2012-09-19 | 山西明科斯科技有限公司 | Polymer modified emulsified asphalt composition and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107446502A (en) * | 2017-08-11 | 2017-12-08 | 太原市路邦科技有限公司 | Self-repairing water-based epoxy/asphalt composite waterproof coating and preparation method thereof |
| CN108949029A (en) * | 2018-08-05 | 2018-12-07 | 佛山市矢达新材料科技有限公司 | A kind of aqueous high bonding anticorrosive paint and preparation method thereof suitable for automobile chassis |
| CN109161341A (en) * | 2018-09-10 | 2019-01-08 | 雨中情防水技术集团有限责任公司 | A kind of anti-viscous type spraying rubber asphalt waterproof coating of fire-retardant, the pre- spray of not chloride ion-containing |
| CN110256965A (en) * | 2019-07-08 | 2019-09-20 | 宏恒达防水材料有限公司 | A kind of spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof |
| CN110256965B (en) * | 2019-07-08 | 2021-06-25 | 宏恒达防水材料有限公司 | Spraying quick-setting rubber asphalt waterproof coating and preparation method thereof |
| CN111763477A (en) * | 2020-07-10 | 2020-10-13 | 北方民族大学 | Colored anti-aging spraying quick-setting rubber asphalt waterproof coating |
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| Publication number | Publication date |
|---|---|
| CN105647383B (en) | 2019-04-16 |
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