CN106189456A - Aqueous high-temperature-resistant isolation titanium steel coating and application thereof - Google Patents

Aqueous high-temperature-resistant isolation titanium steel coating and application thereof Download PDF

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CN106189456A
CN106189456A CN201610598848.8A CN201610598848A CN106189456A CN 106189456 A CN106189456 A CN 106189456A CN 201610598848 A CN201610598848 A CN 201610598848A CN 106189456 A CN106189456 A CN 106189456A
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parts
titanium
powder
temperature
coating
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CN106189456B (en
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许哲峰
郑昊青
徐权
肖聪
李军
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Pangang Group Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of coating preventing and boning between metal, be specifically related to a kind of aqueous high-temperature-resistant isolation titanium steel coating and the application in titanium ingot preparation process thereof.Aqueous high-temperature-resistant of the present invention isolation titanium steel coating, containing following parts by weight ingredient: Watery film-fomer 50~150 parts, Zn powder 0~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts.Coating of the present invention can guarantee that titanium pipe, in 900 DEG C of rollings or perforation procedure, does not occurs bonding reaction with steel equipment roll or capstan winch, improves lumber recovery and the production efficiency of the processing of titanium material;Simply, easily operate, coating is environment friendly and pollution-free, and preparation method is simple for technique.

Description

Aqueous high-temperature-resistant isolation titanium-steel coating and application thereof
Technical field
The present invention relates to a kind of coating preventing and boning between metal, be specifically related to a kind of aqueous high-temperature-resistant isolation titanium-steel and be coated with Material and the application in titanium ingot preparation process thereof.
Background technology
Domestic manufacturer uses titanium ingot circle base not report that use high temperature resistant titanium-steel anti-stick is coated with during producing titanium pipe at present Layer;Titanium ingot circle base 900 DEG C is incubated more than 4h in heating furnace, could release heating furnace, carry out the rolling work of titanium pipe.Due to titanium And alloy is after high temperature 900 DEG C insulation 4h, there is " viscous titanium " phenomenon with iron and steel rolling equipment, roller-way and rolling capstan winch, this Making titanium tube-surface " misrun " phenomenon of different depth occur, owing to being to rotate perforation, rolling when rolling titanium pipe, titanium base is at height Carrying out drilling/rolling in speed rotation process, due to titanio titanium alloy high-temperature characteristic effect, it is easy to be deposited with existing with ferrum As, notably can generate TiFe phase.If titanium tube-surface generation TiFe meets has a strong impact on titanium material surface mechanical properties and tissue, make Titanium pipe brings various defect, loss, the defect problem such as the most corrosion-resistant in following process and during using;Further, since " equipment Viscous titanium " cause wanting first grinding apparatus could again roll follow-up titanium base in the follow-up operation of rolling.Can not continuous rolling titanium pipe Or titanium material product, waste substantial amounts of time and energy consumption;Meanwhile, for ensureing dimension of inner and outer diameters precision and surface quality, the state of titanium pipe Interior producer is all to be carried out machining, and so loss is relatively big, owing to titanium ingot is by titanium sponge reaction system, by titanium pipe, Outer portion machines away, and has a strong impact on cost and the lumber recovery of titanium material, therefore carries out the protection work of high temperature resistant titanium-steel anti-stick coating It is highly desirable to.
And prior art is all before titanium ingot makes annealing treatment, it is sprayed on titanium ingot surface, to each titanium ingot surface Spray treatment to be carried out, after adding spraying, coating needs certain time to be dried, and technique is prepared and just becomes complicated, during preparation Between the longest, it is impossible to serialization efficiently produces.And in the operation of rolling of titanium pipe, due to the deformation of titanium ingot, spray at titanium ingot surface It is coated with this coating to prevent the poor effect of titanium-steel bonding.If directly by this spray painting in rolling capstan winch surface, due to capstan winch with The material of titanium ingot is different, and film forming and adhesion effect are poor, it is impossible to well prevent titanium-steel bonding.
Therefore, in order to solve the problems referred to above, need a kind of technique simple, energy-conserving and environment-protective, can be with serialization, efficiently prepare titanium Pipe, effectively reduces defect loss and production cost, moreover it is possible to prevent the high temperature resistant anti-stick coating of device damage.
Summary of the invention
The technical problem to be solved is to provide a kind of in the titanium pipe operation of rolling, it is possible to reduce titanium tube-surface lacks Fall into, reduce production cost, improve titanium tube-surface quality, can be with the anti-titanium of the aqueous high-temperature-resistant of continuous prodution-steel bonding coating.
Aqueous high-temperature-resistant of the present invention isolation titanium-steel coating, containing following parts by weight ingredient: Watery film-fomer 50~150 parts, Zn powder 0~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, containing following heavy Amount part composition: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts;Excellent Choosing is containing following parts by weight ingredient: Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3450 parts of powder, 350 parts of Fe powder.
Further, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, possibly together with following parts by weight ingredient: firming agent 1~2 Part, dispersant 0.5~1 part, water 1~5 parts;It is preferably 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, by following weight Part becomes to be grouped into: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts, Firming agent 1~2 parts, dispersant 0.5~1 part, water 1~5 parts;Preferably Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3Powder 450 Part, 350 parts of Fe powder, 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said Watery film-fomer is epoxy resin, aqueous polyurethane At least one in paint, Aqueous acrylic latex's paint, Water-borne alkyd coating.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said firming agent is SiO2, waterglass, Al2(HPO4)3In At least one, preferably SiO2;Described dispersant is at least one in polyvinyl alcohol, hydrolyzed maleic anhydride, barium stearate, excellent Elect polyvinyl alcohol as.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said water The pH value of the high temperature resistant isolation titanium-steel coating of property is 7.5~9.5;Solid content is 85~90%, preferably 87%.
The present invention also provides for the application in titanium pipe rolls of a kind of aqueous high-temperature-resistant isolation titanium-steel coating.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating titanium pipe roll in application, at room temperature, by aqueous high-temperature-resistant every It is coated in steel equipment surface, roller surface or capstan winch surface from titanium-steel coating, forms 0.2~0.4mm thick film layer;Preferably For 0.3mm.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating titanium pipe roll in application, use pneumatic spraying, airless spraying or The mode of person's manual brushing is coated.
Compared to prior art, the present invention also has the advantages that
(1) coating of the present invention can guarantee that titanium pipe rolls or in perforation procedure at 900 DEG C, not with steel equipment roll or capstan winch There is bonding reaction, improve lumber recovery and the production efficiency of the processing of titanium material;
(2) present invention uses production technology simply, easily operate, and can set equipped with pneumatic spraying, airless spraying and brushing Use on standby production line;
(3) this product is aqueous, environmental protective high temperature resistant anti-stick coating, does not contains limit in RoHS mass harmful in coating Element, meanwhile, this product does not has noxious substance to volatilize in atmosphere, does not affect environmental protection effect of construction environment etc.;
(4) extemporaneous preparation when aqueous high-temperature-resistant of the present invention isolation titanium-steel coating can use, prepares the time period, simply may be used OK;After can also preparing production, under room temperature, coating stabilization shelf-stability can reach more than 6 months.
Detailed description of the invention
Aqueous high-temperature-resistant of the present invention isolation titanium-steel coating, containing following parts by weight ingredient: Watery film-fomer 50~150 parts, Zn powder 0~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, containing following heavy Amount part composition: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts;Excellent Choosing is containing following parts by weight ingredient: Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3450 parts of powder, 350 parts of Fe powder.
Further, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, possibly together with following parts by weight ingredient: firming agent 1~2 Part, dispersant 0.5~1 part, water 1~5 parts;It is preferably 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, by following weight Part becomes to be grouped into: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts, Firming agent 1~2 parts, dispersant 0.5~1 part, water 1~5 parts;Preferably Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3Powder 450 Part, 350 parts of Fe powder, 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said Watery film-fomer is epoxy resin, aqueous polyurethane At least one in paint, Aqueous acrylic latex's paint, Water-borne alkyd coating.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said firming agent is SiO2, waterglass, Al2(HPO4)3In At least one, preferably SiO2;Described dispersant is at least one in polyvinyl alcohol, hydrolyzed maleic anhydride, barium stearate, excellent Elect polyvinyl alcohol as.
Further, as preferred technical scheme, above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating, wherein said water The pH value of the high temperature resistant isolation titanium-steel coating of property is 7.5~9.5;Solid content is 85~90%, preferably 87%, so can guarantee that Rolling equipment surface forms uniform high-temperature adhesion resistant knot protecting film layer.
The present invention also provides for the application in titanium pipe rolls of a kind of aqueous high-temperature-resistant isolation titanium-steel coating.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating titanium pipe roll in application, at room temperature, by aqueous high-temperature-resistant every It is coated in steel equipment surface, roller surface or capstan winch surface from titanium-steel coating, forms 0.2~0.4mm thick film layer;Preferably For 0.3mm.When film layer adhesion amount is less than 0.20mm, in rolling or perforation procedure, titanium ingot rotates, pastes and cause coating to adhere to Amount thickness is gradually lowered, so to ensure having enough coating layer thicknesses, prevents from all being sticked out by titanium pipe, can not get sufficient resistance to height Temperature oxidation protection.If film layer adhesion amount is more than 0.40mm, cost raises.
Above-mentioned aqueous high-temperature-resistant isolation titanium-steel coating titanium pipe roll in application, use pneumatic spraying, airless spraying or The mode of person's manual brushing is coated behind steel equipment surface, roller surface or capstan winch surface, and the film floor of formation is in room Under temperature, fast setting in 5~10min;Owing to solid part is high, do not have film laminar flow drop down, the phenomenon such as sagging, coating tack is non- Chang Hao, either under wet film or during dry film, coating tack can meet the needs of titanium ingot roller-way bobbing machine friction, will not Coating scaling or dry linting phenomenon occur;Being not particularly limited for coating method, drying means etc., coating method can be according to existing Field practical situation needs to carry out corresponding form of construction work.
The preparation method of aqueous high-temperature-resistant of the present invention isolation titanium-steel coating, without particular/special requirement, can use commonly used in the art Various methods, as long as by each component mix homogeneously, can matching while using.But the present inventor finds under study for action, Preferably employ following method and prepare aqueous high-temperature-resistant isolation titanium-steel coating, it is possible to make each component mix evenly.Concrete grammar For: first aqueous film former is mixed with water and be diluted, the most under agitation, be slowly added to zinc powder, Fe powder and three oxidations Two aluminium powders, then add firming agent, stir, and add dispersant, and stirring is in uniform and stable phase.
In solidification process, it is only necessary to remove the moisture being attached to coating surface, because of without adding any accelerator again, main Wanting curing mode is spontaneous curing, in order to save hardening time, it is possible to use the methods such as hot air drying or sensing heating, coating After solidification, coating does not haves dry linting and crack performance.
The high temperature resistant principle of coating prepared by the present invention is: when temperature reaches 900 DEG C, and organic coating starts the most burned Fall, but Fe starts slowly to melt deliquescing, now can be the Al in coating2O3Powder is fixed on roll or capstan winch surface, plays heat insulation Effect;There is alloying reaction in Al Yu Ti in coating, forms TiAl3Alloy-layer, this layer of material is the finest and close, can completely cut off machine There is bonding reaction in the materials such as body titanium and extraneous (iron and steel) ferrum element, reaches preventing and treating and the effect of titanium-steel bonding occurs.
The temperature that high temperature resistant anti-titanium-steel bonding coating uses is not particularly limited, but due to inorganic agent molten of the present invention Agent is water, it is ensured that the temperature conditions that water does not freezes and vaporizes, and uses at normal temperatures.
A kind of high temperature resistant anti-titanium of the present invention-steel bonding coating, is painted on rolling capstan winch surface online, can consolidate rapidly Change, formed self-drying type coating, this coating can guarantee that titanium pipe under 900 DEG C of high temperature, surface with steel surface occur bonding generate TiFe phase, can effectively reduce production cost and improve productivity effect, main raising Product Precision size and surface quality;This The corresponding coating process technology that invention provides has good economic benefit, social benefit and wide popularizing application prospect.
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described, the most therefore the present invention is limited System is among described scope of embodiments.
Embodiment 1
According to raw material each in table 1 and weight proportion thereof prepare aqueous high-temperature-resistant isolation titanium-steel coating:
The raw material of table 1 aqueous high-temperature-resistant isolation titanium-steel coating and proportioning thereof
Raw material Watery film-fomer/g Zn powder/g Al2O3Powder/g Fe powder/g Firming agent/g Dispersant/g Water/g
K1 100 50 450 350 1 0.5 5
K2 150 10 400 250 2 1 1
K3 50 30 450 250 1 0.5 5
K4 100 0 450 300 1 0.5 5
K5 100 50 400 250 1 0.5 5
D1 100 0 450 0 1 0.5 5
D2 100 50 0 300 1 0.5 5
Wherein, K1~K5 is experimental group, D1~D2 is matched group, separately arranges blank group D3 and (is not the most coated with coating Direct Rolling), and wherein Watery film-fomer is epoxy resin (solid content is 50%);Firming agent is SiO2, dispersant is poly-second Enol.Aqueous high-temperature-resistant isolation titanium-steel coating pH value prepared by the present invention is 7.5~9.5;Solid content is 85~90%.
Its preparation method is: at normal temperatures and pressures, by Watery film-fomer, Zn powder, Fe powder, Al2O3Powder, joins in container, Adition process is stirred continuously, is stirring evenly and then adding into firming agent, dispersant and water, stirs, treat that solution is uniform and stable Phase, obtains aqueous high-temperature-resistant isolation titanium-steel coating.
The aqueous high-temperature-resistant isolation titanium-steel coating prepared above-mentioned each group uses pneumatic spraying, airless spraying or craft The mode brushed is coated behind steel equipment surface, roller surface or capstan winch surface, at room temperature natural drying, solidification 10~15min, obtain the film layer that thickness is 0.2~0.4mm.Titanium pipe rolling is carried out at 900 DEG C.The titanium pipe table obtained after rolling Face quality is good, and titanium pipe is not adhered with roll, capstan winch etc., and concrete contrast situation is as follows:
Table 2 aqueous high-temperature-resistant isolation titanium-steel coating and matched group test performance
From Table 2, it can be seen that use embodiment K1~the coating coating equipment of K5, the titanium tube-surface matter obtained after rolling Amount is good, and titanium pipe bonds hardly with roll, capstan winch etc..It is not coated by roll or the strand of any coating (i.e. blank group D3) Dish, the titanium pipe obtained after rolling, titanium tube-surface defect is serious, and equipment also has a certain degree of viscous titanium, needs ability after polishing It is continuing with.Using the coating coating equipment of D1, D2, the titanium tube-surface ratio of defects after rolling remains unchanged higher, it is impossible to well prevent Only titanium steel bonding.
10,000 tons of production capacities are produced in design per year, with the 1.5 tons of calculating of each titanium ingot (semifinished product), to produce the titanium of about 6300 every year , there is titanium steel bonding 5mm~20mm depth calculation with each titanium ingot in billet, and each titanium ingot to machine away 100~200 kilograms, with The calculating of 80000 yuan/ton of titanium ingot, each titanium ingot is lost between 8000~16000 yuan because of viscous titanium cutting tip, also to spend meanwhile Take substantial amounts of human and material resources to cut, extra increase production cost and production time, and use this technology, will for titanium pipe and Substantial amounts of production cost is saved in the production of other titanium alloy products, to use in terms of coating 2~5kg in each titanium ingot operation of rolling Calculating, every coating price is calculated by 200,000/ton, and the new returns of this technology see below shown in formula:
The volume of production of W-annual titanium ingot: with 10,000 tons of calculating, produces 6300 titanium ingots the most every year;
A-each titanium ingot is because of the amount of viscous titanium-steel layer problem cutting: by 50Kg calculating/titanium ingot;
The cost of P1-titanium ingot: 80 yuan/Kg;
W1-sprays the consumption of high temperature resistant anti-stick coating, 3Kg/ ingot;
P2-high temperature resistant anti-stick coating price per ton: calculate by 200 yuan/Kg;
Y-uses the new returns that this technology produces every year:
Then:
Y=(P1 × A-W1 × P2) × W
=(4000-600) × 6300
=2142 (ten thousand yuan)
Visible, the coating that the present invention provides has good economic benefit, social benefit and wide popularizing application prospect.

Claims (10)

1. aqueous high-temperature-resistant isolation titanium-steel coating, it is characterised in that: containing following parts by weight ingredient: Watery film-fomer 50~150 Part, Zn powder 0~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts.
Aqueous high-temperature-resistant isolation titanium-steel coating the most according to claim 1, it is characterised in that: containing following parts by weight ingredient: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts;Preferably comprise following Parts by weight ingredient: Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3450 parts of powder, 350 parts of Fe powder.
Aqueous high-temperature-resistant the most according to claim 1 or claim 2 isolation titanium-steel coating, it is characterised in that: possibly together with following weight portion Composition: firming agent 1~2 parts, dispersant 0.5~1 part, water 1~5 parts;It is preferably 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
4. according to aqueous high-temperature-resistant isolation titanium-steel coating described in any one of claims 1 to 3, it is characterised in that: by following weight Part becomes to be grouped into: Watery film-fomer 50~150 parts, Zn powder 10~50 parts, Al2O3Powder 400~450 parts, Fe powder 250~350 parts, Firming agent 1~2 parts, dispersant 0.5~1 part, water 1~5 parts;Preferably Watery film-fomer 100 parts, 50 parts of Zn powder, Al2O3Powder 450 Part, 350 parts of Fe powder, 1 part of firming agent, dispersant 0.5 part, 5 parts of water.
5. according to aqueous high-temperature-resistant isolation titanium-steel coating described in any one of Claims 1 to 4, it is characterised in that: described aqueous becomes Membrane is at least one in epoxy resin, aqueous polyurethane paint, Aqueous acrylic latex's paint, Water-borne alkyd coating.
6. according to aqueous high-temperature-resistant isolation titanium-steel coating described in any one of Claims 1 to 4, it is characterised in that: described firming agent For SiO2, waterglass, Al2(HPO4)3In at least one, preferably SiO2;Described dispersant is polyvinyl alcohol, hydrolysis maleic acid At least one in acid anhydride, barium stearate, preferably polyvinyl alcohol.
7. according to aqueous high-temperature-resistant isolation titanium-steel coating described in any one of Claims 1 to 4, it is characterised in that: described aqueous is resistance to The pH value of high temperature isolation titanium-steel coating is 7.5~9.5;Solid content is 85~90%, preferably 87%.
8. aqueous high-temperature-resistant isolation titanium-steel coating application in titanium pipe rolls described in any one of claim 1~7.
Apply the most according to claim 8, it is characterised in that: at room temperature, aqueous high-temperature-resistant is isolated titanium-steel coating coating On steel equipment surface, roller surface or capstan winch surface, form 0.2~0.4mm thick film layer;It is preferably 0.3mm.
Apply the most according to claim 8, it is characterised in that: use pneumatic spraying, airless spraying or the side of manual brushing Formula is coated.
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