CN106010132B - The anti-sticking titanium coating of aqueous high-temperature-resistant and its application - Google Patents
The anti-sticking titanium coating of aqueous high-temperature-resistant and its application Download PDFInfo
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- CN106010132B CN106010132B CN201610600295.5A CN201610600295A CN106010132B CN 106010132 B CN106010132 B CN 106010132B CN 201610600295 A CN201610600295 A CN 201610600295A CN 106010132 B CN106010132 B CN 106010132B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The present invention relates to a kind of coating for preventing from bonding between metal, and in particular to a kind of anti-sticking titanium coating of aqueous high-temperature-resistant and its application in titanium ingot preparation process.The anti-sticking titanium coating of aqueous high-temperature-resistant of the present invention, contains following parts by weight ingredient: 50~150 parts of Watery film-fomer, 0~50 part of Zn powder, and 30~80 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3250~350 parts of powder.Coating of the present invention can guarantee that titanium tube in 900 DEG C of rollings or perforation procedure, does not occur bonding with steel equipment roll or capstan winch and reacts, and improve the lumber recovery and production efficiency of titanium processing；Simple process, easy to operate, coating is environment friendly and pollution-free, and preparation method is simple.
Description
Technical field
The present invention relates to a kind of coating for preventing from bonding between metal, and in particular to a kind of anti-sticking titanium coating of aqueous high-temperature-resistant and
Its application in titanium ingot preparation process.
Background technique
Domestic manufacturer is applied without report using high temperature resistant titanium-steel anti-stick using during titanium ingot round billet production titanium tube at present
Layer；900 DEG C of titanium ingot round billet keeps the temperature 4h or more in heating furnace, could release heating furnace, carries out the rolling work of titanium tube.Due to titanium
And its with steel rolling equipment, roller-way and rolling capstan winch " viscous titanium " phenomenon is occurring for alloy after 900 DEG C of heat preservation 4h of high temperature, this
Titanium tube surface is set " misrun " phenomenon of different depth occur, due to being rotation perforation, rolling when rolling titanium tube, titanium base is in height
Drilling/rolling is carried out in fast rotation process, due to titanium-based titanium alloy high-temperature characteristic effect, is easy to be deposited with iron existing
As notably producing TiFe phase.If titanium tube Surface Creation TiFe, which meets, seriously affects titanium surface mechanical properties and tissue, make
Titanium tube brought in following process and use process various defects, loss, it is not corrosion-resistant the defects of problem；In addition, due to " equipment
Viscous titanium " causes to want first grinding apparatus that could roll subsequent titanium base again in the subsequent operation of rolling.It is unable to continuous rolling titanium tube
Or titanium product, waste a large amount of time and energy consumption；Meanwhile dimension of inner and outer diameters precision and surface quality to guarantee titanium tube, state
Interior producer is all to be carried out machining, lose in this way it is larger, due to titanium ingot be by titanium sponge react make, by titanium tube,
Outer portion machines away, and seriously affects the cost and lumber recovery of titanium, therefore carries out the protection work of high temperature resistant titanium-steel anti-stick coating
It is highly desirable.
And the prior art is all to be sprayed on titanium ingot surface before titanium ingot is made annealing treatment, to each titanium ingot surface
Spray treatment is carried out, along with coating needs certain time dry after spraying, technique, which is prepared, just becomes complicated, when preparation
Between it is especially long, be unable to serialization and efficiently produce.And in the operation of rolling of titanium tube, due to the deformation of titanium ingot, sprayed in titanium ingot surface
The coating is applied to prevent titanium-steel bonding ineffective.If directly by the coating be sprayed at rolling capstan winch surface, due to capstan winch with
The material of titanium ingot is different, and film forming and adhesion effect are poor, can not prevent titanium-steel bonding well.
Therefore, to solve the above-mentioned problems, need a kind of simple process, energy conservation and environmental protection, can with serialization, efficiently prepare titanium
Defect loss and production cost is effectively reduced, moreover it is possible to prevent the high temperature resistant anti-stick coating of equipment damage in pipe.
Summary of the invention
Technical problem to be solved by the invention is to provide one kind in the titanium tube operation of rolling, it is possible to reduce titanium tube surface lacks
It falls into, reduces production cost, improve titanium tube surface quality, coating can be bonded with the anti-titanium of the aqueous high-temperature-resistant of continuous production-steel.
The anti-sticking titanium coating of aqueous high-temperature-resistant of the present invention, contains following parts by weight ingredient: 50~150 parts of Watery film-fomer, Zn
0~50 part of powder, 30~80 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3250~350 parts of powder.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, contains following parts by weight
Ingredient: 50~150 parts of Watery film-fomer, 10~50 parts of Zn powder, 50 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3Powder 250~
350 parts；Preferably comprise following parts by weight ingredient: 100 parts of Watery film-fomer, 50 parts of Zn powder, 50 parts of Fe powder, Al2O3450 parts of powder,
Fe2O3350 parts of powder.
Further, the anti-sticking titanium coating of above-mentioned aqueous high-temperature-resistant, also contain following parts by weight ingredient: 1~2 part of curing agent,
0.5~1 part of dispersing agent, 1~5 part of water；Preferably 1 part of curing agent, 0.5 part of dispersing agent, 5 parts of water.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, by following parts by weight at
It is grouped as: 50~150 parts of Watery film-fomer, 10~50 parts of Zn powder, 50 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3Powder 250
~350 parts, 1~2 part of curing agent, 0.5~1 part of dispersing agent, 1~5 part of water；Preferably comprise following parts by weight ingredient: waterborne film-forming
100 parts of agent, 50 parts of Zn powder, 50 parts of Fe powder, Al2O3450 parts of powder, Fe2O3350 parts of powder, 1 part of curing agent, 0.5 part of dispersing agent, water 5
Part.
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein the Watery film-fomer is epoxy resin, aqueous polyurethane paint, water
At least one of property acrylic latex coating, Water-borne alkyd coating.
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein the curing agent is SiO2, waterglass, Al2(HPO4)3In extremely
Few one kind, preferably SiO2；The dispersing agent be at least one of polyvinyl alcohol, hydrolyzed maleic anhydride, barium stearate, preferably
For polyvinyl alcohol.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein described aqueous resistance to
The pH value of high-temperature adhesion resistant titanium coating is 7.5~9.5；Solid content is 85~90%, preferably 87%.
The present invention also provides a kind of application of the anti-sticking titanium coating of aqueous high-temperature-resistant in titanium tube rolling.
Application of the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant in titanium tube rolling, it is at room temperature, aqueous high-temperature-resistant is anti-sticking
Titanium coating is coated in steel equipment surface, roller surface or capstan winch surface, forms the film layer of 0.2~0.4mm thickness；Preferably
0.3mm。
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant titanium tube rolling in application, using pneumatic spraying, airless spraying or
The mode of manual brushing is coated.
Compared with the prior art, the present invention also has the following beneficial effects:
(1) coating of the present invention can guarantee titanium tube 900 DEG C rolling or perforation procedure in, not with steel equipment roll or capstan winch
Bonding reaction occurs, improves the lumber recovery and production efficiency of titanium processing；
(2) present invention can be set using simple production process, easy to operate equipped with pneumatic spraying, airless spraying and brushing
It is used on standby production line；
(3) this product is aqueous, environmental protective high temperature resistant anti-stick coating, does not contain the nocuousness limited in RoHS mass in coating
Element, meanwhile, this product is volatilized without noxious material in air, does not influence environmentally friendly effect of construction environment etc.；
(4) extemporaneous preparation when the anti-sticking titanium coating of aqueous high-temperature-resistant of the present invention can be used prepares period, simple possible；
After production can also being prepared, at room temperature, coating stabilization shelf-stability be can reach 6 months or more.
Specific embodiment
The anti-sticking titanium coating of aqueous high-temperature-resistant of the present invention, contains following parts by weight ingredient: 50~150 parts of Watery film-fomer, Zn
0~50 part of powder, 30~80 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3250~350 parts of powder.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, contains following parts by weight
Ingredient: 50~150 parts of Watery film-fomer, 10~50 parts of Zn powder, 50 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3Powder 250~
350 parts；Preferably comprise following parts by weight ingredient: 100 parts of Watery film-fomer, 50 parts of Zn powder, 50 parts of Fe powder, Al2O3450 parts of powder,
Fe2O3350 parts of powder.
Further, the anti-sticking titanium coating of above-mentioned aqueous high-temperature-resistant, also contain following parts by weight ingredient: 1~2 part of curing agent,
0.5~1 part of dispersing agent, 1~5 part of water；Preferably 1 part of curing agent, 0.5 part of dispersing agent, 5 parts of water.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, by following parts by weight at
It is grouped as: 50~150 parts of Watery film-fomer, 10~50 parts of Zn powder, 50 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3Powder 250
~350 parts, 1~2 part of curing agent, 0.5~1 part of dispersing agent, 1~5 part of water；Preferably comprise following parts by weight ingredient: waterborne film-forming
100 parts of agent, 50 parts of Zn powder, 50 parts of Fe powder, Al2O3450 parts of powder, Fe2O3350 parts of powder, 1 part of curing agent, 0.5 part of dispersing agent, water 5
Part.
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein the Watery film-fomer is epoxy resin, aqueous polyurethane paint, water
At least one of property acrylic latex coating, Water-borne alkyd coating.
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein the curing agent is SiO2, waterglass, Al2(HPO4)3In extremely
Few one kind, preferably SiO2；The dispersing agent be at least one of polyvinyl alcohol, hydrolyzed maleic anhydride, barium stearate, preferably
For polyvinyl alcohol.
Further, technical solution more preferably, the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant, wherein described aqueous resistance to
The pH value of high-temperature adhesion resistant titanium coating is 7.5~9.5；Solid content is 85~90%, preferably 87%, can guarantee rolling equipment in this way
Surface forms uniform high-temperature adhesion resistant knot protective film layer.
The present invention also provides a kind of application of the anti-sticking titanium coating of aqueous high-temperature-resistant in titanium tube rolling.
Application of the above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant in titanium tube rolling, it is at room temperature, aqueous high-temperature-resistant is anti-sticking
Titanium coating is coated in steel equipment surface, roller surface or capstan winch surface, forms the film layer of 0.2~0.4mm thickness；Preferably
0.3mm.When film layer adhesion amount is less than 0.20mm, in rolling or perforation procedure, the rotation of titanium ingot pastes and causes coating adhesion amount
Thickness gradually decreases, so to guarantee having enough coating layer thicknesses, prevents from all being sticked out by titanium tube, cannot get sufficient high temperature resistant
Oxidation protection.If film layer adhesion amount is more than 0.40mm, cost is increased.
The above-mentioned anti-sticking titanium coating of aqueous high-temperature-resistant titanium tube rolling in application, using pneumatic spraying, airless spraying or
The mode of manual brushing carries out after being coated in steel equipment surface, roller surface or capstan winch surface, and the film layer of formation is in room temperature
Under, rapid curing in 5~10min；Since solid part is high, phenomena such as being not in film layer trickling, sagging, coating adhesion is very
Good, either under wet film or when dry film, coating adhesion can meet the needs of titanium ingot roller-way bobbing machine friction, will not go out
Existing coating scaling or picking phenomenon；Coating method, drying means etc. are not particularly limited, coating method can be according to scene
Actual conditions need to carry out corresponding form of construction work.
The preparation method of the anti-sticking titanium coating of aqueous high-temperature-resistant of the present invention, can be using commonly used in the art each without particular/special requirement
Kind method can matching while using as long as each component is uniformly mixed.But the present inventor has found under study for action, preferably
The anti-sticking titanium coating of aqueous high-temperature-resistant is prepared with the following method, and each component can be made to mix more evenly.Method particularly includes: first will
Aqueous film forming agent is mixed with water to be diluted, then under stiring, be slowly added to zinc powder, iron powder, ferric oxide powder and
Then aluminium oxide powder adds curing agent, stir evenly, and adds dispersing agent, stirring is in uniform and stable phase.
In solidification process, it is only necessary to the moisture for being attached to coating surface is removed, because leading without adding any promotor again
Wanting curing mode is spontaneous curing, and in order to save curing time, the methods of heated-air drying or induction heating, coating also can be used
After solidification, coating is not in picking and crack phenomenon.
Coating high temperature resistant principle prepared by the present invention are as follows: when temperature reaches 900 DEG C, organic coating starts slowly burned
Fall, but Fe starts slowly to melt softening, it at this time can be the Al in coating2O3Powder is fixed on roll or capstan winch surface, plays heat-insulated
Effect；Alloying reaction occurs for Al and Ti in coating, forms TiAl3Alloy-layer, this layer of substance is very fine and close, can completely cut off machine
Bonding reaction occurs for the substances such as body titanium and extraneous (steel) ferro element, has the function that titanium-steel bonding occurs for prevention and treatment.
The temperature that the anti-titanium of high temperature resistant-steel bonding coating uses is not particularly limited, but molten due to inorganic agent of the invention
Agent is water, guarantees the temperature condition that water does not freeze and vaporizes, uses at normal temperature.
A kind of anti-titanium of high temperature resistant of the present invention-steel bonds coating, is painted on rolling capstan winch surface online, can consolidate rapidly
Change, form self-drying type coating, which can guarantee titanium tube under 900 DEG C of high temperature, and surface does not occur bonding with steel surface and generates
TiFe phase can be effectively reduced production cost and improve productivity effect, more main raising Product Precision size and surface quality；This
The corresponding coating process technology provided with good economic efficiency, social benefit and wide popularization and application foreground are provided.
A specific embodiment of the invention is further described below with reference to embodiment, is not therefore limited the present invention
System is among the embodiment described range.
Embodiment 1
The anti-sticking titanium coating of aqueous high-temperature-resistant is prepared according to each raw material in table 1 and its weight proportion:
The raw material and its proportion of the anti-sticking titanium coating of 1 aqueous high-temperature-resistant of table
Wherein, K1~K5 is experimental group, and D1~D2 is control group, and a blank control group D3 is separately arranged and (does not apply coating
Direct Rolling), and wherein Watery film-fomer is epoxy resin (solid content 50%)；Curing agent is SiO2, dispersing agent is poly- second
Enol.The anti-sticking titanium coating pH value of aqueous high-temperature-resistant prepared by the present invention is 7.5~9.5；Solid content is 85~90%.
Preparation method are as follows: at normal temperatures and pressures, by Watery film-fomer, Zn powder, Fe powder, Al2O3Powder, Fe2O3Powder is added
It into container, is stirred continuously in adition process, is stirring evenly and then adding into curing agent, dispersing agent and water, stirs evenly, be in solution
Uniform and stable phase is to get the anti-sticking titanium coating of aqueous high-temperature-resistant.
The anti-sticking titanium coating of aqueous high-temperature-resistant prepared by above-mentioned each group uses pneumatic spraying, airless spraying or manual brushing
Mode carry out be coated in steel equipment surface, roller surface or capstan winch surface after, at room temperature spontaneously dry, solidify 10~
15min obtains the film layer with a thickness of 0.2~0.4mm.Titanium tube rolling is carried out at 900 DEG C.The titanium tube surface matter obtained after rolling
Amount is good, and titanium tube and roll, capstan winch etc. are not adhered, and specific comparative situation is as follows:
The anti-sticking titanium coating of 2 aqueous high-temperature-resistant of table and control group test performance
From Table 2, it can be seen that using the coating coating equipment of embodiment K1~K5, the titanium tube surface matter that is obtained after rolling
Amount is good, and titanium tube and roll, capstan winch etc. hardly bond.It is not coated by the roll or strand of any coating (i.e. blank control group D3)
Disk, the titanium tube obtained after rolling, titanium tube surface defect is serious, and equipment also has a degree of viscous titanium, ability after needing to polish
It continues to use.Using the coating coating equipment of D1, D2, the titanium tube surface defect rate after rolling is still higher, cannot prevent well
Only titanium steel bonds.
10,000 tons of production capacities are produced in design per year, are calculated with 1.5 tons of each titanium ingot (semifinished product), to be produced 6300 or so titaniums every year
There is titanium steel bonding 5mm~20mm depth calculation with each titanium ingot in billet, and each titanium ingot will machine away 100~200 kilograms, with
80000 yuan/ton of titanium ingot calculating, each titanium ingot lose between 8000~16000 yuan because gluing titanium cutting tip, meanwhile, also to spend
Take a large amount of human and material resources to be cut, it is additional to increase production cost and production time, and use this technology, will for titanium tube and
A large amount of production cost is saved in the production of other titanium alloy products, in terms of in each titanium ingot operation of rolling using 2~5kg of coating
It calculates, every coating price is calculated by 200,000/ton, and the new returns of this technology are seen below shown in formula:
The output of the annual titanium ingot of W-: being calculated with 10,000 tons, about produces 6300 titanium ingots every year；
The each titanium ingot of A- is because gluing titanium-steel layer problem cutting amount: pressing 50Kg calculating/titanium ingot；
The cost of P1- titanium ingot: 80 yuan/Kg；
W1- sprays the consumption of high temperature resistant anti-stick coating, 3Kg/ ingot；
P2- high temperature resistant anti-stick coating price per ton: it is calculated by 200 yuan/Kg；
The new returns that Y- uses this technology to generate every year:
Then:
Y=(P1 × A-W1 × P2) × W
=(4000-600) × 6300
=2142 (ten thousand yuan)
As it can be seen that coating provided by the invention is with good economic efficiency, social benefit and wide popularization and application foreground.
Claims (11)
1. the anti-sticking titanium coating of aqueous high-temperature-resistant: it is made of following parts by weight ingredient: 50~150 parts of Watery film-fomer, Zn powder 10~
50 parts, 50 parts of Fe powder, Al2O3400~450 parts of powder, Fe2O3250~350 parts of powder, 1~2 part of curing agent, 0.5~1 part of dispersing agent,
1~5 part of water；Wherein, the anti-sticking titanium coating of the aqueous high-temperature-resistant is coated in steel equipment surface, roller surface or capstan winch surface.
2. the anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 1, it is characterised in that: be made of following parts by weight ingredient:
100 parts of Watery film-fomer, 50 parts of Zn powder, 50 parts of Fe powder, Al2O3450 parts of powder, Fe2O3350 parts of powder, 1 part of curing agent, dispersing agent
0.5 part, 5 parts of water.
3. the anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 1, it is characterised in that: the Watery film-fomer is asphalt mixtures modified by epoxy resin
At least one of rouge, aqueous polyurethane paint, Aqueous acrylic latex's paint, Water-borne alkyd coating.
4. the anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 1, it is characterised in that: the curing agent is SiO2, water glass
Glass, Al2(HPO4)3At least one of；The dispersing agent is polyvinyl alcohol, hydrolyzed maleic anhydride, at least one in barium stearate
Kind.
5. the anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 4, it is characterised in that: the curing agent is SiO2；Described point
Powder is polyvinyl alcohol.
6. any one anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 1~3, it is characterised in that: the aqueous resistance to height
The pH value of the anti-sticking titanium coating of temperature is 7.5~9.5；Solid content is 85~90%.
7. the anti-sticking titanium coating of aqueous high-temperature-resistant according to claim 6, it is characterised in that: the anti-sticking titanium of aqueous high-temperature-resistant applies
The solid content of material is 87%.
8. application of any one of the claim 1~7 anti-sticking titanium coating of aqueous high-temperature-resistant in titanium tube rolling.
9. applying according to claim 8, it is characterised in that: at room temperature, the anti-sticking titanium coating of aqueous high-temperature-resistant is coated in
Steel equipment surface, roller surface or capstan winch surface form the film layer of 0.2~0.4mm thickness.
10. applying according to claim 9, it is characterised in that: form the film layer of 0.3mm thickness.
11. applying according to claim 10, it is characterised in that: using pneumatic spraying, airless spraying or manual brushing
Mode is coated.
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| CN103992686B (en) * | 2014-05-30 | 2015-11-18 | 攀钢集团攀枝花钢铁研究院有限公司 | The production method of high temperature resistant oxygen uptake coating and application and titanium ingot |
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