CN106189422A - A kind of calligraphy artwork flame-proof antibiotic inorganic agent - Google Patents

A kind of calligraphy artwork flame-proof antibiotic inorganic agent Download PDF

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CN106189422A
CN106189422A CN201610612836.6A CN201610612836A CN106189422A CN 106189422 A CN106189422 A CN 106189422A CN 201610612836 A CN201610612836 A CN 201610612836A CN 106189422 A CN106189422 A CN 106189422A
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parts
powder
vinyl acetate
flame
inorganic agent
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王志英
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of calligraphy artwork flame-proof antibiotic inorganic agent, composed of the following components: PVC resin powder, styrenated alkyd, vinyl acetate, tricaprylin, phosphate ester, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea polyphenols, silicon powder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder, APP, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1, 6 hexanediyl esters, 2, 2 dihydromethyl propionic acids, 2 mercaptobenzimidazoles, N, penylene BMI between N', N methyl 2 ketopyrrolidine, carbendazim.Product of the present invention has the most superior fire-retardant, acid and alkali-resistance, anti-mildew anti-microbial property, improves properties of product.

Description

A kind of calligraphy artwork flame-proof antibiotic inorganic agent
Technical field
The present invention relates to a kind of calligraphy artwork flame-proof antibiotic inorganic agent, belong to calligraphy artwork technical field.
Background technology
The art work, refers generally to the works of plastic arts.Art work kind is more, and painting and calligraphy are one of them.Calligraphy artwork Storage the most necessary, it is necessary to use suitable inorganic agent, in order to be preferably easy to the storage of calligraphy artwork, convenient after Use.
Summary of the invention
It is an object of the invention to provide a kind of calligraphy artwork flame-proof antibiotic inorganic agent, in order to painting and calligraphy skill is better achieved The use function of art product flame-proof antibiotic inorganic agent, makes product have fire-retardant, acid and alkali-resistance, anti-mildew anti-microbial property, improves product and make Use performance.
To achieve these goals, technical scheme is as follows.
A kind of calligraphy artwork flame-proof antibiotic inorganic agent, is made up of the component of following mass fraction: PVC resin powder 26~30 Part, styrenated alkyd 24~28 parts, vinyl acetate 24~28 parts, tricaprylin 22~26 parts, phosphate ester 24 ~28 parts, Oleum Ricini 24~28 parts, ethyl propionate 22~26 parts, acrylate and vinyl acetate emulsion 24~28 parts, Bravo 24~28 parts, hexadecane Base trimethylammonium bromide 22~26 parts, benzalkonium chloride 22~26 parts, tea polyphenols 22~26 parts, silicon powder 24~28 parts, cupric oxalate 22~26 parts, sodium phosphate 20~24 parts, MDA 24~28 parts, zinc fluoride 22~26 parts, zinc sulfate 20~24 parts, Glass fiber powder 22~26 parts, aluminium nitride powder 20~24 parts, APP 20~24 parts, ammonium dihydrogen phosphate 22~26 parts, phosphorus Acid three esters 22~26 parts, HBCD 22~26 parts, 1,6-hexanediyl ester 22~26 parts, 2,2-dihydroxymethyl Propanoic acid 22~26 parts, 2-mercaptobenzimidazole 22~26 parts, N, N '-penylene BMI 22~26 parts, N-methyl-2- Ketopyrrolidine 22~26 parts, carbendazim 20~24 parts.
Further, above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent, it is made up of the component of following mass fraction: PVC tree 26 parts of cosmetics, styrenated alkyd 24 parts, vinyl acetate 24 parts, tricaprylin 22 parts, phosphate ester 24 parts, Semen Ricini Oil 24 parts, ethyl propionate 22 parts, acrylate and vinyl acetate emulsion 24 parts, Bravo 24 parts, cetyl trimethylammonium bromide 22 parts, benzalkonium chloride 22 parts, tea polyphenols 22 parts, silicon powder 24 parts, cupric oxalate 22 parts, sodium phosphate 20 parts, MDA 24 parts, zinc fluoride 22 Part, 20 parts of zinc sulfate, glass fiber powder 22 parts, aluminium nitride powder 20 parts, APP 20 parts, ammonium dihydrogen phosphate 22 parts, phosphoric acid Three esters 22 parts, HBCD 22 parts, 1,6-hexanediyl ester 22 parts, 2,2-dihydromethyl propionic acid 22 parts, 2-mercapto Base benzimidazole 22 parts, N, N '-penylene BMI 22 parts, METHYLPYRROLIDONE 22 parts, carbendazim 20 parts.
Further, above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent, it is made up of the component of following mass fraction: PVC tree 28 parts of cosmetics, styrenated alkyd 26 parts, vinyl acetate 26 parts, tricaprylin 24 parts, phosphate ester 26 parts, Semen Ricini Oil 26 parts, ethyl propionate 24 parts, acrylate and vinyl acetate emulsion 26 parts, Bravo 26 parts, cetyl trimethylammonium bromide 24 parts, benzalkonium chloride 24 parts, tea polyphenols 24 parts, silicon powder 26 parts, cupric oxalate 24 parts, sodium phosphate 22 parts, MDA 26 parts, zinc fluoride 24 Part, 22 parts of zinc sulfate, glass fiber powder 24 parts, aluminium nitride powder 22 parts, APP 22 parts, ammonium dihydrogen phosphate 24 parts, phosphoric acid Three esters 24 parts, HBCD 24 parts, 1,6-hexanediyl ester 24 parts, 2,2-dihydromethyl propionic acid 24 parts, 2-mercapto Base benzimidazole 24 parts, N, N '-penylene BMI 24 parts, METHYLPYRROLIDONE 24 parts, carbendazim 22 parts.
Further, above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent, it is made up of the component of following mass fraction: PVC tree 30 parts of cosmetics, styrenated alkyd 28 parts, vinyl acetate 28 parts, tricaprylin 26 parts, phosphate ester 28 parts, Semen Ricini Oil 28 parts, ethyl propionate 26 parts, acrylate and vinyl acetate emulsion 28 parts, Bravo 28 parts, cetyl trimethylammonium bromide 26 parts, benzalkonium chloride 26 parts, tea polyphenols 26 parts, silicon powder 28 parts, cupric oxalate 26 parts, sodium phosphate 24 parts, MDA 28 parts, zinc fluoride 26 Part, 24 parts of zinc sulfate, glass fiber powder 26 parts, aluminium nitride powder 24 parts, APP 24 parts, ammonium dihydrogen phosphate 26 parts, phosphoric acid Three esters 26 parts, HBCD 26 parts, 1,6-hexanediyl ester 26 parts, 2,2-dihydromethyl propionic acid 26 parts, 2-mercapto Base benzimidazole 26 parts, N, N '-penylene BMI 26 parts, METHYLPYRROLIDONE 26 parts, carbendazim 24 parts.
Further, above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent preparation method step is as follows:
(1) by the PVC resin powder of described mass fraction, styrenated alkyd, vinyl acetate, three octanoic acid glycerol Ester, phosphate ester, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea are many Phenol, silicon powder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder give With mixing, ultrasonic high speed dispersion, ultrasonic frequency is 20~40KHz, and rate of dispersion 5000~about 5400r/min, during dispersion Between be 30~60min;
(2) add the APP of described mass fraction, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1,6-oneself Omega-diol diacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20~35KHz, and rate of dispersion 4800~5200r/min is left The right side, jitter time is 30~50min;
(3) the 2 of described mass fraction is added, 2-dihydromethyl propionic acid, 2-mercaptobenzimidazole, N, a N '-penylene span Coming acid imide, METHYLPYRROLIDONE, carbendazim, ultrasonic high speed dispersion, ultrasonic frequency is 20~30KHz, rate of dispersion 4600~about 4800r/min, jitter time is 20~40min;This product is prepared after mix homogeneously.
This beneficial effect of the invention is: the calligraphy artwork flame-proof antibiotic inorganic agent in the present invention, by following components group Become: PVC resin powder, styrenated alkyd, vinyl acetate, tricaprylin, phosphate ester, Oleum Ricini, ethyl propionate, Acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea polyphenols, silicon powder, cupric oxalate, sodium phosphate, two Diaminodiphenylmethane, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder, APP, ammonium dihydrogen phosphate, tricresyl phosphate Ester, HBCD, 1,6-hexanediyl ester, 2,2-dihydromethyl propionic acid, 2-mercaptobenzimidazole, N, N '- Penylene BMI, METHYLPYRROLIDONE, carbendazim.Product of the present invention has the most superior fire-retardant, acidproof Alkali, anti-mildew anti-microbial property, improve properties of product.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described, in order to be better understood from the present invention.
Embodiment 1
Calligraphy artwork flame-proof antibiotic inorganic agent in the present embodiment, is made up of the component of following mass fraction: polyvinyl chloride resin 26 parts of powder, styrenated alkyd 24 parts, vinyl acetate 24 parts, tricaprylin 22 parts, phosphate ester 24 parts, Oleum Ricini 24 parts, ethyl propionate 22 parts, acrylate and vinyl acetate emulsion 24 parts, Bravo 24 parts, cetyl trimethylammonium bromide 22 parts, benzalkonium chloride 22 Part, tea polyphenols 22 parts, silicon powder 24 parts, cupric oxalate 22 parts, sodium phosphate 20 parts, MDA 24 parts, zinc fluoride 22 parts, 20 parts of zinc sulfate, glass fiber powder 22 parts, aluminium nitride powder 20 parts, APP 20 parts, ammonium dihydrogen phosphate 22 parts, phosphotriester 22 parts, HBCD 22 parts, 1,6-hexanediyl ester 22 parts, 2,2-dihydromethyl propionic acid 22 parts, 2-sulfydryl benzene And imidazoles 22 parts, N, N '-penylene BMI 22 parts, METHYLPYRROLIDONE 22 parts, carbendazim 20 parts.
Above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent preparation method step is as follows:
(1) by the PVC resin powder of described mass fraction, styrenated alkyd, vinyl acetate, three octanoic acid glycerol Ester, phosphate ester, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea are many Phenol, silicon powder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder give With mixing, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5400r/min, and jitter time is 60min;
(2) add the APP of described mass fraction, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1,6-oneself Omega-diol diacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion about 5200r/min, jitter time For 50min;
(3) the 2 of described mass fraction is added, 2-dihydromethyl propionic acid, 2-mercaptobenzimidazole, N, a N '-penylene span Coming acid imide, METHYLPYRROLIDONE, carbendazim, ultrasonic high speed dispersion, ultrasonic frequency is 20kHz, rate of dispersion About 4800r/min, jitter time is 40min;This product is prepared after mix homogeneously.
Embodiment 2
Calligraphy artwork flame-proof antibiotic inorganic agent in the present embodiment, is made up of the component of following mass fraction: polyvinyl chloride resin 28 parts of powder, styrenated alkyd 26 parts, vinyl acetate 26 parts, tricaprylin 24 parts, phosphate ester 26 parts, Oleum Ricini 26 parts, ethyl propionate 24 parts, acrylate and vinyl acetate emulsion 26 parts, Bravo 26 parts, cetyl trimethylammonium bromide 24 parts, benzalkonium chloride 24 Part, tea polyphenols 24 parts, silicon powder 26 parts, cupric oxalate 24 parts, sodium phosphate 22 parts, MDA 26 parts, zinc fluoride 24 parts, 22 parts of zinc sulfate, glass fiber powder 24 parts, aluminium nitride powder 22 parts, APP 22 parts, ammonium dihydrogen phosphate 24 parts, phosphotriester 24 parts, HBCD 24 parts, 1,6-hexanediyl ester 24 parts, 2,2-dihydromethyl propionic acid 24 parts, 2-sulfydryl benzene And imidazoles 24 parts, N, N '-penylene BMI 24 parts, METHYLPYRROLIDONE 24 parts, carbendazim 22 parts.
Above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent preparation method step is as follows:
(1) by the PVC resin powder of described mass fraction, styrenated alkyd, vinyl acetate, three octanoic acid glycerol Ester, phosphate ester, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea are many Phenol, silicon powder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder give With mixing, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion about 5200r/min, and jitter time is 45min;
(2) add the APP of described mass fraction, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1,6-oneself Omega-diol diacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 27kHz, rate of dispersion about 5000r/min, jitter time For 40min;
(3) the 2 of described mass fraction is added, 2-dihydromethyl propionic acid, 2-mercaptobenzimidazole, N, a N '-penylene span Coming acid imide, METHYLPYRROLIDONE, carbendazim, ultrasonic high speed dispersion, ultrasonic frequency is 25kHz, rate of dispersion About 4700r/min, jitter time is 30min;This product is prepared after mix homogeneously.
Embodiment 3
Calligraphy artwork flame-proof antibiotic inorganic agent in the present embodiment, is made up of the component of following mass fraction: polyvinyl chloride resin 30 parts of powder, styrenated alkyd 28 parts, vinyl acetate 28 parts, tricaprylin 26 parts, phosphate ester 28 parts, Oleum Ricini 28 parts, ethyl propionate 26 parts, acrylate and vinyl acetate emulsion 28 parts, Bravo 28 parts, cetyl trimethylammonium bromide 26 parts, benzalkonium chloride 26 Part, tea polyphenols 26 parts, silicon powder 28 parts, cupric oxalate 26 parts, sodium phosphate 24 parts, MDA 28 parts, zinc fluoride 26 parts, 24 parts of zinc sulfate, glass fiber powder 26 parts, aluminium nitride powder 24 parts, APP 24 parts, ammonium dihydrogen phosphate 26 parts, phosphotriester 26 parts, HBCD 26 parts, 1,6-hexanediyl ester 26 parts, 2,2-dihydromethyl propionic acid 26 parts, 2-sulfydryl benzene And imidazoles 26 parts, N, N '-penylene BMI 26 parts, METHYLPYRROLIDONE 26 parts, carbendazim 24 parts.
Above-mentioned calligraphy artwork flame-proof antibiotic inorganic agent preparation method step is as follows:
(1) by the PVC resin powder of described mass fraction, styrenated alkyd, vinyl acetate, three octanoic acid glycerol Ester, phosphate ester, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea are many Phenol, silicon powder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder give With mixing, ultrasonic high speed dispersion, ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, and jitter time is 30min;
(2) add the APP of described mass fraction, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1,6-oneself Omega-diol diacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 35kHz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) the 2 of described mass fraction is added, 2-dihydromethyl propionic acid, 2-mercaptobenzimidazole, N, a N '-penylene span Coming acid imide, METHYLPYRROLIDONE, carbendazim, ultrasonic high speed dispersion, ultrasonic frequency is 30kHz, rate of dispersion About 4600r/min, jitter time is 20min;This product is prepared after mix homogeneously.
Performance measurement is carried out for the product in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available prod, measured Data are as shown in table 1.Fire protection flame retarding level estimate uses UL94 standard.
Table 1 the performance test results
Visible, product of the present invention has the most corrosion-resistant, fire protection flame retarding, anti-mildew, anti-microbial property.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (5)

1. a calligraphy artwork flame-proof antibiotic inorganic agent, it is characterised in that: it is made up of the component of following mass fraction: PVC tree Cosmetics 26~30 parts, styrenated alkyd 24~28 parts, vinyl acetate 24~28 parts, tricaprylin 22~26 Part, phosphate ester 24~28 parts, Oleum Ricini 24~28 parts, ethyl propionate 22~26 parts, acrylate and vinyl acetate emulsion 24~28 parts, Bravo 24~ 28 parts, cetyl trimethylammonium bromide 22~26 parts, benzalkonium chloride 22~26 parts, tea polyphenols 22~26 parts, silicon powder 24~ 28 parts, cupric oxalate 22~26 parts, sodium phosphate 20~24 parts, MDA 24~28 parts, zinc fluoride 22~26 parts, sulphuric acid Zinc 20~24 parts, glass fiber powder 22~26 parts, aluminium nitride powder 20~24 parts, APP 20~24 parts, ammonium dihydrogen phosphate 22~26 parts, phosphotriester 22~26 parts, HBCD 22~26 parts, 1,6 hexanediol diacrylate 22~26 parts, 2,2-dihydromethyl propionic acid 22~26 parts, 2-mercaptobenzimidazole 22~26 parts, N, penylene BMI 22~26 between N'- Part, METHYLPYRROLIDONE 22~26 parts, carbendazim 20~24 parts.
Calligraphy artwork flame-proof antibiotic inorganic agent the most according to claim 1, it is characterised in that: described calligraphy artwork hinders Combustion antibiosis additive is made up of the component of following mass fraction: PVC resin powder 26 parts, styrenated alkyd 24 parts, vinegar Acid ethylene 24 parts, tricaprylin 22 parts, phosphate ester 24 parts, Oleum Ricini 24 parts, ethyl propionate 22 parts, acrylate and vinyl acetate emulsion 24 parts, Bravo 24 parts, cetyl trimethylammonium bromide 22 parts, benzalkonium chloride 22 parts, tea polyphenols 22 parts, silicon powder 24 parts, cupric oxalate 22 parts, sodium phosphate 20 parts, MDA 24 parts, zinc fluoride 22 parts, 20 parts of zinc sulfate, glass fiber powder 22 parts, nitridation Aluminium powder 20 parts, APP 20 parts, ammonium dihydrogen phosphate 22 parts, phosphotriester 22 parts, HBCD 22 parts, 1,6-oneself two Alcohol diacrylate 22 parts, 2,2-dihydromethyl propionic acid 22 parts, 2-mercaptobenzimidazole 22 parts, N, between N'-, penylene span carrys out acyl Imines 22 parts, METHYLPYRROLIDONE 22 parts, carbendazim 20 parts.
3. according to the calligraphy artwork flame-proof antibiotic inorganic agent described in claim 1 to 2, it is characterised in that: described calligraphy and painting art Product flame-proof antibiotic inorganic agent is made up of the component of following mass fraction: PVC resin powder 28 parts, styrenated alkyd 26 Part, vinyl acetate 26 parts, tricaprylin 24 parts, phosphate ester 26 parts, Oleum Ricini 26 parts, ethyl propionate 24 parts, acrylate and vinyl acetate emulsion 26 parts, Bravo 26 parts, cetyl trimethylammonium bromide 24 parts, benzalkonium chloride 24 parts, tea polyphenols 24 parts, silicon powder 26 parts, Cupric oxalate 24 parts, sodium phosphate 22 parts, MDA 26 parts, zinc fluoride 24 parts, 22 parts of zinc sulfate, glass fiber powder 24 Part, aluminium nitride powder 22 parts, APP 22 parts, ammonium dihydrogen phosphate 24 parts, phosphotriester 24 parts, HBCD 24 parts, 1,6 hexanediol diacrylate 24 parts, 2,2-dihydromethyl propionic acid 24 parts, 2-mercaptobenzimidazole 24 parts, N, penylene between N'- BMI 24 parts, METHYLPYRROLIDONE 24 parts, carbendazim 22 parts.
4. according to the calligraphy artwork flame-proof antibiotic inorganic agent described in claims 1 to 3, it is characterised in that: described calligraphy and painting art Product flame-proof antibiotic inorganic agent is made up of the component of following mass fraction: PVC resin powder 30 parts, styrenated alkyd 28 Part, vinyl acetate 28 parts, tricaprylin 26 parts, phosphate ester 28 parts, Oleum Ricini 28 parts, ethyl propionate 26 parts, acrylate and vinyl acetate emulsion 28 parts, Bravo 28 parts, cetyl trimethylammonium bromide 26 parts, benzalkonium chloride 26 parts, tea polyphenols 26 parts, silicon powder 28 parts, Cupric oxalate 26 parts, sodium phosphate 24 parts, MDA 28 parts, zinc fluoride 26 parts, 24 parts of zinc sulfate, glass fiber powder 26 Part, aluminium nitride powder 24 parts, APP 24 parts, ammonium dihydrogen phosphate 26 parts, phosphotriester 26 parts, HBCD 26 parts, 1,6 hexanediol diacrylate 26 parts, 2,2-dihydromethyl propionic acid 26 parts, 2-mercaptobenzimidazole 26 parts, N, penylene between N'- BMI 26 parts, METHYLPYRROLIDONE 26 parts, carbendazim 24 parts.
Calligraphy artwork flame-proof antibiotic inorganic agent the most according to claim 1, it is characterised in that: described calligraphy artwork hinders Combustion antibiosis additive preparation method step is as follows:
(1) by the PVC resin powder of described mass fraction, styrenated alkyd, vinyl acetate, tricaprylin, phosphorus Acid esters, Oleum Ricini, ethyl propionate, acrylate and vinyl acetate emulsion, Bravo, cetyl trimethylammonium bromide, benzalkonium chloride, tea polyphenols, silicon Micropowder, cupric oxalate, sodium phosphate, MDA, zinc fluoride, zinc sulfate, glass fiber powder, aluminium nitride powder are mixed Closing, ultrasonic high speed dispersion, ultrasonic frequency is 20~40KHz, and rate of dispersion about 5000~5400r/min, jitter time is 30 ~about 60min;
(2) APP of described mass fraction, ammonium dihydrogen phosphate, phosphotriester, HBCD, 1,6-HD are added Diacrylate, ultrasonic high speed dispersion, ultrasonic frequency is 20~35KHz, and rate of dispersion is about 4800~5200r/min, point The scattered time is 30~about 50min;
(3) adding the 2,2-dihydromethyl propionic acid of described mass fraction, 2-mercaptobenzimidazole, N, between N'-, penylene span carrys out acyl Imines, METHYLPYRROLIDONE, carbendazim, ultrasonic high speed dispersion, ultrasonic frequency is 20~30KHz, and rate of dispersion is about 4600~4800r/min, jitter time is 20~about 40min;This product is prepared after mix homogeneously.
CN201610612836.6A 2016-07-29 2016-07-29 A kind of calligraphy artwork flame-proof antibiotic inorganic agent Pending CN106189422A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502145A (en) * 2017-09-29 2017-12-22 江苏瑞腾涂装科技有限公司 A kind of coating
CN110714327A (en) * 2019-10-18 2020-01-21 安徽职业技术学院 Flame-retardant, moisture-proof and antibacterial treating agent for painting and calligraphy artworks and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502145A (en) * 2017-09-29 2017-12-22 江苏瑞腾涂装科技有限公司 A kind of coating
CN110714327A (en) * 2019-10-18 2020-01-21 安徽职业技术学院 Flame-retardant, moisture-proof and antibacterial treating agent for painting and calligraphy artworks and preparation method thereof

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Application publication date: 20161207

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